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1. 发明授权

US06869647B2 Print media products for generating high quality, water-fast images and methods for making the same 有权
标题翻译：打印媒体产品，用于生成高质量，防水的图像和制作相同的方法
公开(公告)号：US06869647B2
公开(公告)日：2005-03-22
申请号：US09944177
申请日：2001-08-30
申请人： Loretta Ann Grezzo Page , Richard J. McManus
发明人： Loretta Ann Grezzo Page , Richard J. McManus
IPC分类号： B41M5/00 , B41M5/52 , B41M5/40
CPC分类号： B41M5/52 , B41M5/5218 , B41M5/5227 , B41M5/5236 , B41M5/5245 , B41M5/5254 , Y10T428/24802
摘要： Ink-receiving print media products having multiple capabilities including (A) minimal drying time; (B) improved smear-fastness; (C) a high level of water-fastness; (D) the ability to generate high-definition images; and (E) excellent ink compatibility. The media products have at least one ink-receiving layer on a substrate (e.g. paper pre-coated with one or more binders and/or pigments). The ink-receiving layer includes a pigment (boehmite, pseudo-boehmite, or mixtures thereof) optimally combined with a special binder blend [polyvinyl alcohol, a poly(vinyl acetate-ethylene) copolymer, and a poly(vinyl pyrrolidone-vinyl acetate) copolymer]. Also included is a special dye fixative (namely, a cationic emulsion polymer) which provides enhanced water-fastness. This fixative is of a particular type (a quaternary amine) that also allows high pigment levels to be employed (at least about 65% by weight) which further promotes the foregoing benefits.
摘要翻译：具有多种能力的接收墨水的打印介质产品包括（A）最短的干燥时间; （B）改善涂片坚牢度; （C）耐水性高; （D）产生高分辨率图像的能力; 和（E）优异的油墨相容性。介质产品在基材上具有至少一个油墨接受层（例如预先涂覆有一种或多种粘合剂和/或颜料的纸张）。油墨接收层包括与特殊的粘合剂共混物（聚乙烯醇，聚（乙酸乙烯酯 - 乙烯）共聚物和聚（乙烯基吡咯烷酮 - 乙酸乙烯酯））最佳组合的颜料（勃姆石，假勃姆石或其混合物）共聚物]。还包括提供增强的耐水性的特殊染料固定剂（即阳离子乳液聚合物）。该固定剂是特殊类型（季胺），其还允许使用高颜料水平（至少约65重量％），这进一步促进了上述益处。

2. 发明授权

US06176908B1 Aqueous ink jet inks for postal metering 有权
标题翻译：用于邮政计量的水性喷墨油墨
公开(公告)号：US06176908B1
公开(公告)日：2001-01-23
申请号：US09399260
申请日：1999-09-20
申请人： Richard D. Bauer , John Morrow Gardner , Loretta Ann Grezzo Page , David Alvin Tyvoll
发明人： Richard D. Bauer , John Morrow Gardner , Loretta Ann Grezzo Page , David Alvin Tyvoll
IPC分类号： C09D1100
CPC分类号： C09D11/32 , C09D11/50
摘要： Aqueous, fluorescent red ink jet inks which meet US Postal Service requirements for metered mail are disclosed and comprise an aqueous vehicle, a red or magenta pigment, a polymeric dispersant, a fluorescent dye and, optionally a hydrotrope additive.
摘要翻译：公开了满足美国邮政服务对计量邮件要求的水性荧光红色喷墨油墨，其包含水性载体，红色或品红色颜料，聚合物分散剂，荧光染料和任选的水溶助长剂添加剂。

3. 发明授权

US07651216B2 Fusible inkjet recording materials containing hollow beads, system using the recording materials, and methods of using the recording materials 有权
标题翻译：含有空心珠的熔融喷墨记录材料，使用记录材料的系统以及使用该记录材料的方法
公开(公告)号：US07651216B2
公开(公告)日：2010-01-26
申请号：US10963097
申请日：2004-10-12
申请人： Tienteh Chen , Radha Sen , Steven L. Webb , Anne M. Kelly-Rowley , Loretta Ann Grezzo Page , Gary O. Page, legal representative
发明人： Tienteh Chen , Radha Sen , Steven L. Webb , Anne M. Kelly-Rowley , Loretta Ann Grezzo Page
IPC分类号： B41J2/01
CPC分类号： B41M5/52 , B41M7/00
摘要： Briefly described, embodiments of this disclosure include fusible print media, methods of making fusible print media, and systems for preparing a fused ink-jet image. One exemplary embodiment of the fusible print medium, among others, includes a substrate and an ink-receiving layer disposed on the substrate. The ink-receiving layer includes a plurality of hollow polymer beads having substantially the same diameter.
摘要翻译：简要描述，本公开的实施例包括可熔打印介质，制造可熔打印介质的方法以及用于制备熔融喷墨图像的系统。可熔打印介质的一个示例性实施例包括基板和设置在基板上的墨接收层。油墨接收层包括具有基本上相同直径的多个中空聚合物珠粒。

4. 发明授权

US5750594A Ink set and process for alleviating bleed in printed elements 失效
标题翻译：用于减轻印刷元件渗色的墨水设置和处理
公开(公告)号：US5750594A
公开(公告)日：1998-05-12
申请号：US820917
申请日：1997-03-19
申请人： Loretta Ann Grezzo Page , Kathryn Amy Pearlstine
发明人： Loretta Ann Grezzo Page , Kathryn Amy Pearlstine
IPC分类号： C09D11/02 , B41M5/00 , C09D11/00 , C09D11/10
CPC分类号： C09D11/40 , Y10S260/38
摘要： Bleed between two adjacent inks on a printing medium may be reduced by selecting inks having the same ionic character, at least one ink containing an aqueous carrier medium and a pigment dispersion wherein the dispersant is a quaternized amine containing polymeric dispersant, and wherein the second ink contains an aqueous carrier medium, a colorant and optionally a polymer, wherein the colorant or the polymer has a sulfonate or phosphonate group. A process for alleviating bleed in printed elements comprising applying the first and second inks to a substrate in contact with each another is also described.
摘要翻译：通过选择具有相同离子性质的油墨，至少一种含有载体介质的油墨和颜料分散体，其中分散剂是含季铵化的含胺聚合物分散剂，可以减少打印介质上两相邻油墨之间的渗色，并且其中第二油墨含有水性载体介质，着色剂和任选的聚合物，其中着色剂或聚合物具有磺酸盐或膦酸酯基团。还描述了一种用于减轻印刷元件渗色的方法，包括将第一和第二墨水彼此接触的基底施加。

5. 发明授权

US5708095A Graft copolymers containing sulfonate and phosphonate groups having particular utility as pigmented ink dispersants 失效
标题翻译：含有磺酸盐和膦酸盐基团的接枝共聚物作为着色的油墨分散剂具有特别的用途
公开(公告)号：US5708095A
公开(公告)日：1998-01-13
申请号：US706420
申请日：1996-08-30
申请人： Loretta Ann Grezzo Page , Milan Bohuslav Bednarek
发明人： Loretta Ann Grezzo Page , Milan Bohuslav Bednarek
IPC分类号： B41J2/01 , B01F17/52 , B41M5/00 , C08F265/00 , C08F273/00 , C08F275/00 , C09D11/00 , C09D11/10 , C08F267/02 , C08F267/06 , C08F267/08
CPC分类号： C08F273/00 , C08F275/00
摘要： A graft polymer having (a) a hydrophilic backbone prepared from unneutralized acid containing monomers wherein the acid has a pKa of at least 3, and wherein the backbone is completely soluble in water and insoluble in non-polar organic solvents; and (b) at least one discrete hydrophobic side chain, wherein 20 to 100% of the side chains are prepared from non-polar aliphatic or aromatic monomers having a chain length of at least 4 carbon atoms; wherein the side chains are attached to the backbone at a single terminal point and wherein the at least one discrete hydrophobic side chain has a weight average molecular weight of 1000 to 30,000. These graft polymers are useful as dispersants in aqueous solutions, particularly in ink jet inks.
摘要翻译：一种接枝聚合物，其具有（a）由未中和的含酸单体制备的亲水性主链，其中所述酸的pKa至少为3，并且其中所述骨架完全可溶于水并且不溶于非极性有机溶剂; 和（b）至少一个离散的疏水侧链，其中20至100％的侧链由链长至少为4个碳原子的非极性脂族或芳族单体制备; 其中所述侧链在单个末端连接到所述骨架上，并且其中所述至少一个离散的疏水侧链的重均分子量为1000至30,000。这些接枝聚合物可用作水溶液中的分散剂，特别是在喷墨油墨中。

6. 发明授权

US6087416A Aqueous pigmented ink jet inks for printing on vinyls 失效
标题翻译：用于在乙烯基上印刷的水性着色喷墨油墨
公开(公告)号：US6087416A
公开(公告)日：2000-07-11
申请号：US120922
申请日：1998-07-22
申请人： Kathryn Amy Pearlstine , Loretta Ann Grezzo Page , Robert Paul Held
发明人： Kathryn Amy Pearlstine , Loretta Ann Grezzo Page , Robert Paul Held
IPC分类号： C09D151/00 , B41M1/30 , B41M7/00 , C09D11/00 , C09D153/00 , C09D183/10 , C09D11/02 , C09D11/10 , C09D133/08 , C09D133/10
CPC分类号： C09D11/322 , B41M7/0027
摘要： An ink jet ink composition and process for printing on vinyl substrates in which the ink comprises an aqueous vehicle containing at least water and a water-miscible glycol or glycol ether, wherein water constitutes no more than 80% by weight based on the total weight of the vehicle; an insoluble colorant (preferably a pigment); a polymeric dispersant; a silicon or fluorinated surfactant; and, optionally but preferably, a graft copolymer binder having a hydrophobic backbone and non-ionic, hydrophilic side chains, which binder is soluble in the aqueous vehicle but insoluble in water.
摘要翻译：一种喷墨油墨组合物和用于在乙烯基底上印刷的方法，其中油墨包含至少含有水和水混溶性二醇或二醇醚的水性载体，其中水基于总重量不超过80重量％机动车; 不溶性着色剂（优选颜料）; 聚合物分散剂; 硅或氟化表面活性剂; 和任选但优选的具有疏水骨架和非离子亲水侧链的接枝共聚物粘合剂，该粘合剂可溶于水性载体但不溶于水。

7. 发明授权

US6040358A Ink jet inks containing linear polymer additives 失效
标题翻译：含有线性聚合物添加剂的喷墨油墨
公开(公告)号：US6040358A
公开(公告)日：2000-03-21
申请号：US774991
申请日：1996-12-27
申请人： Loretta Ann Grezzo Page , Harry Joseph Spinelli , Waifong Liew Anton
发明人： Loretta Ann Grezzo Page , Harry Joseph Spinelli , Waifong Liew Anton
IPC分类号： B41M5/00 , C09D11/00 , C09D11/10
CPC分类号： C09D11/30 , C09D11/322 , Y10S260/38
摘要： Inks for ink jet printers contain an aqueous carrier medium; a colorant that is insoluble in the aqueous carrier, a polymer dispersant; and a linear polymer additive selected from the group consisting of an water soluble, elastomeric ABA block polymer comprising an elastomeric B block and non-elastomeric A blocks; anionic polymers selected from neutralized acrylic and methacrylic acid polymers; cationic polymers selected from neutralized or quaternized amine polymers; water-dispersible .beta.-diketone containing polymers and ethylene oxide containing polymers.
摘要翻译：用于喷墨打印机的墨水含有载体介质; 不溶于水性载体的着色剂，聚合物分散剂; 以及选自包含弹性体B嵌段和非弹性体A嵌段的水溶性弹性体ABA嵌段聚合物的线性聚合物添加剂; 选自中和的丙烯酸和甲基丙烯酸聚合物的阴离子聚合物; 选自中和或季铵化胺聚合物的阳离子聚合物; 含水分散体的含有β-二酮的聚合物和含环氧乙烷的聚合物。

8. 发明授权

US07008992B1 Water insoluble non-ionic graft copolymers 失效
标题翻译：水不溶性非离子接枝共聚物
公开(公告)号：US07008992B1
公开(公告)日：2006-03-07
申请号：US09120608
申请日：1998-07-22
申请人： Loretta Ann Grezzo Page , Kathryn Amy Pearlstine , Waifong L. Anton
发明人： Loretta Ann Grezzo Page , Kathryn Amy Pearlstine , Waifong L. Anton
IPC分类号： C08L51/00 , C09D11/10
CPC分类号： C08F291/00 , C08F265/04 , C08F290/06 , C09D151/003
摘要： A non-ionic graft copolymer has a hydrophobic backbone and non-ionic, hydrophilic side chains having a molecular weight of at least 500, preferably 100–2000 is substantially insoluble in water, but soluble in an aqueous vehicle, and is particularly suited for use in aqueous coating compositions in which water comprises no more than 80% by weight of the vehicle for the composition.
摘要翻译：非离子接枝共聚物具有疏水主链，分子量至少为500，优选100-2000的非离子亲水侧链基本上不溶于水，但可溶于水性载体，并且特别适用于使用在水性涂料组合物中，其中水包含不超过组合物载体的80重量％。

9. 发明授权

US06841207B2 Porous media coatings having surface-modified alumina particulates 有权
标题翻译：具有表面改性氧化铝颗粒的多孔介质涂层
公开(公告)号：US06841207B2
公开(公告)日：2005-01-11
申请号：US10261378
申请日：2002-09-30
申请人： Eric L Burch , Loretta Ann Grezzo Page
发明人： Eric L Burch , Loretta Ann Grezzo Page
IPC分类号： B41J2/01 , B41M5/00 , B41M5/50 , B41M5/52 , C09D7/12 , C09D201/00 , B41M5/40
CPC分类号： B41M5/5218 , B41M5/508 , B41M5/5227 , B41M5/529
摘要： The present invention is drawn to systems and coated substrates for ink-jet ink printing. The coated media substrate can comprise a substrate, having coated thereon, a porous coating, wherein the porous coating comprises an alumina particulate having an active ligand covalently attached thereto or adsorbed thereon. Preferably, the alumina particulate is an aluminum oxide having surface hydroxyls.
摘要翻译：本发明涉及用于喷墨印刷的系统和涂覆的基底。涂覆的介质基底可以包括其上涂覆有多孔涂层的基底，其中多孔涂层包含具有共价连接到其上或吸附在其上的活性配体的氧化铝颗粒。优选地，氧化铝颗粒是具有表面羟基的氧化铝。

10. 发明授权

US6037390A Smear resistant pigmented ink jet inks containing .beta.-diketone or ureido dispersants 失效
标题翻译：含有β-二酮或脲基分散剂的抗污染着色喷墨油墨
公开(公告)号：US6037390A
公开(公告)日：2000-03-14
申请号：US2066
申请日：1997-12-31
申请人： Loretta Ann Grezzo Page , Sheau-Hwa Ma , John A. Simms
发明人： Loretta Ann Grezzo Page , Sheau-Hwa Ma , John A. Simms
IPC分类号： B41J2/01 , B41M5/00 , C09D11/00 , C09D11/10 , C08K5/21 , C08K5/3415 , C08L39/04 , C08L61/00
CPC分类号： C09D11/326
摘要： An ink jet ink composition is provided which contains an aqueous vehicle; a colorant; and a polymeric dispersant comprising 2 to 50% by weight of monomers selected from .beta.-diketone containing monomers and ureido monomers, as well as a combination of such ink with a media having basic groups such as primary or secondary amines and divalent cations.
摘要翻译：提供含有载体的喷墨油墨组合物; 着色剂和包含2-50重量％的选自含有β-二酮单体和脲基单体的单体的聚合物分散剂，以及这种油墨与具有碱性基团如伯胺或仲胺和二价阳离子的介质的组合。

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