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    • 8. 发明授权
    • Method of depositing a nitrogen-doped FSG layer
    • 沉积氮掺杂FSG层的方法
    • US06468927B1
    • 2002-10-22
    • US09574271
    • 2000-05-19
    • Lin ZhangWen MaZhuang Li
    • Lin ZhangWen MaZhuang Li
    • H01L2131
    • H01L21/02131C23C16/401C23C16/507H01L21/02211H01L21/02274H01L21/02304H01L21/3143H01L21/31629Y10S438/958
    • Gap-fill and damascene methods are disclosed for depositing an insulating thin film of nitrofluorinated silicate glass on a substrate in a process chamber. A high-density plasma, generated from a gaseous mixture of silicon-, fluorine-, oxygen-, and nitrogen-containing gases, deposits a layer of nitrofluorinated silicate glass onto the substrate. For gap-fill applications, the substrate is biased with a bias power density between 4.8 and 11.2 W/cm2 and the ratio of flow rate for the oxygen-containing gas to the combined flow rate for all silicon-containing gases in the process chamber is between 1.0 and 1.8, preferably between 1.2 and 1.4. For damascene applications, the bias power density is less than 3.2 W/cm2, preferably 1.6 W/cm2, and the flow rate ratio is between 1.2 and 3.0. Using optimized parameters, the thin film has a lower dielectric constant and better adhesion properties than fluorosilicate glass.
    • 公开了间隙填充和镶嵌方法,用于在处理室中的基底上沉积硝基氟化硅酸盐玻璃的绝缘薄膜。 由硅,氟,氧和含氮气体的气体混合物产生的高密度等离子体将一层硝基氟化硅酸盐玻璃沉积在基底上。 对于间隙填充应用,衬底偏置功率密度在4.8和11.2W / cm2之间,并且含氧气体的流速与处理室中所有含硅气体的组合流速之比为 在1.0和1.8之间,优选在1.2和1.4之间。 对于镶嵌应用,偏压功率密度小于3.2W / cm2,优选1.6W / cm 2,流速比在1.2和3.0之间。 使用优化的参数,薄膜具有比氟硅酸盐玻璃更低的介电常数和更好的粘合性能。
    • 10. 发明授权
    • Fiberglass compositions
    • 玻璃纤维组合物
    • US08334228B2
    • 2012-12-18
    • US12637737
    • 2009-12-14
    • Yuqiang ZhangGuorong CaoBing ZhangLin ZhangWenzhong XingGuijiang Gu
    • Yuqiang ZhangGuorong CaoBing ZhangLin ZhangWenzhong XingGuijiang Gu
    • C03C13/02C03C13/06
    • C03C13/00
    • This invention involves a fiberglass composition containing the following components: SiO2, Al2O3, CaO, MgO, B2O3, F2, TiO2, K2O, Na2O, Fe2O3 and SO3. The weight percentage of each of the components are as follows: SiO2 58˜65%, CaO 20˜26%, Al2O3 9˜17%, MgO 0.5˜1%, B2O3 0˜5%, F2 0˜1%, TiO2 0.1˜1%, K2O+Na2O 0˜0.8%, Fe2O3 0.1˜0.5%, SO3 0˜0.6%. The ternary system, SiO2—Al2O3—CaO, is basis of the fiberglass composition in this invention, which also has low quantities of MgO and B2O3. In addition, the total amount of alkaline earth oxide and the proportional relationship between MgO and CaO are rationally designed, which helps to improve the mechanical strength, heat resistance, and chemical stability of the glass. It also has excellent manufacturing performance. Moreover, the raw materials of the fiberglass composition in this invention are low in cost, and the invention meets environmental protection requirements.
    • 本发明涉及含有以下组分的玻璃纤维组合物:SiO2,Al2O3,CaO,MgO,B2O3,F2,TiO2,K2O,Na2O,Fe2O3和SO3。 每种组分的重量百分比如下:SiO 2 58〜65%,CaO 20〜26%,Al 2 O 3 9〜17%,MgO 0.5〜1%,B 2 O 3〜5%,F2 0〜1%,TiO 2 0.1 〜1%,K2O + Na2O 0〜0.8%,Fe2O3 0.1〜0.5%,SO3 0〜0.6%。 三元体系SiO2-Al2O3-CaO是本发明玻璃纤维组合物的基础,它也具有低量的MgO和B2O3。 此外,合理设计碱土金属的总量和MgO与CaO的比例关系,有利于提高玻璃的机械强度,耐热性和化学稳定性。 它也具有优良的制造性能。 此外,本发明的玻璃纤维组合物的原料成本低,本发明符合环保要求。