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1. 发明授权

US5744258A High power, high energy, hybrid electrode and electrical energy storage device made therefrom 失效
标题翻译：大功率，高能量，混合电极和电能储存装置
公开(公告)号：US5744258A
公开(公告)日：1998-04-28
申请号：US774048
申请日：1996-12-23
申请人： Lijun Bai , Changming Li , Anaba A. Anani , George Thomas , Han Wu , Ke Keryn Lian , Frank R. Denton, III , Jason N. Howard
发明人： Lijun Bai , Changming Li , Anaba A. Anani , George Thomas , Han Wu , Ke Keryn Lian , Frank R. Denton, III , Jason N. Howard
IPC分类号： H01M4/04 , H01M4/13 , H01M4/131 , H01M4/133 , H01M4/137 , H01M4/36 , H01M4/60 , H01M6/40 , H01M10/052 , H01M10/0525 , H01M10/0585 , H01M10/36
CPC分类号： H01M4/13 , H01M10/052 , H01M4/04 , H01M4/0402 , H01M4/0404 , H01M4/36 , H01M4/364 , H01M4/366 , H01M4/602 , H01M10/0525 , H01M10/0585 , H01M4/131 , H01M4/133 , H01M4/137 , H01M6/40
摘要： A hybrid electrode for a high power, high energy, electrical storage device contains both a high-energy electrode material (42) and a high-rate electrode material (44). The two materials are deposited on a current collector (40), and the electrode is used to make an energy storage device that exhibits both the high-rate capability of a capacitor and the high energy capability of a battery. The two materials can be co-deposited on the current collector in a variety of ways, either in superimposed layers, adjacent layers, intermixed with each other or one material coating the other to form a mixture that is then deposited on the current collector.
摘要翻译：用于高功率，高能量的蓄电装置的混合电极包含高能电极材料（42）和高速电极材料（44）。这两种材料沉积在集电器（40）上，并且该电极用于制造表现出电容器的高速率能力和电池的高能量能力的能量存储装置。这两种材料可以以各种方式共同沉积在集电器上，无论是叠加层，相邻层，彼此混合或涂覆另一种材料，形成混合物，然后沉积在集电器上。

2. 发明授权

US5729427A Macrocyclic complex modified electrodes and capacitors made therefrom 失效
标题翻译：大环复合改性电极和由其制成的电容器
公开(公告)号：US5729427A
公开(公告)日：1998-03-17
申请号：US780557
申请日：1997-01-08
申请人： Changming Li , Ke Keryn Lian , Anaba A. Anani
发明人： Changming Li , Ke Keryn Lian , Anaba A. Anani
IPC分类号： H01G9/04 , H01G9/042 , H01G9/00
CPC分类号： H01G9/042
摘要： Electrodes for electrochemical capacitor are modified with a metal macrocyclic complex made up of phthalocyanine or porphyrin ligands bound to a transition metal to achieve improved conductivity, reversibility, and charge storage capacity. The electrode is formed from a metal base and coated with an oxide, nitride or carbide of a transition metal or with a conductive polymer. This coating is modified with the metal macrocyclic complex. Suitable metal macrocyclic complexes are iron phthalocyanine (FePc), iron meso-tetra(N-methyl-4-phenyl)porphyrin (FeTPP) or cobalt protoporphyrin (CoPP).
摘要翻译：用电化学电容器的电极用与过渡金属结合的酞菁或卟啉配体组成的金属大环络合物进行改性以实现改进的导电性，可逆性和电荷存储容量。电极由金属基底形成并涂覆有过渡金属或导电聚合物的氧化物，氮化物或碳化物。该涂层用金属大环络合物改性。合适的金属大环配合物是铁酞菁（FePc），内消旋 - 四（N-甲基-4-苯基）卟啉（FeTPP）或钴原卟啉（CoPP）。

3. 发明授权

US5961810A Method for fabricating a conductive polymer energy storage device 失效
标题翻译：导电聚合物储能装置的制造方法
公开(公告)号：US5961810A
公开(公告)日：1999-10-05
申请号：US964618
申请日：1997-11-05
申请人： Changming Li , Ke Keryn Lian , Han Wu
发明人： Changming Li , Ke Keryn Lian , Han Wu
IPC分类号： C09D5/44 , H01B1/12 , H01G9/02 , H01G9/025 , H01M4/04 , H01M4/66 , H01M4/74 , C23C22/78 , C25D5/34
CPC分类号： H01G9/025 , C09D5/4476 , H01B1/127 , H01B1/128 , H01M4/0438 , H01M4/0466 , H01M4/662 , H01M4/661 , H01M4/74
摘要： A method for making high power electrochemical charge storage devices, provides for depositing an electrically conducting polymer (16), (18), onto a non-noble metal substrate (10), which has been prepared by treatment with a surfactant. Using this method, high power, high energy electrochemical charge storage devices may be fabricated with highly reproducible low cost.
摘要翻译：一种用于制造高功率电化学电荷存储装置的方法，提供将导电聚合物（16）（18）沉积到已经通过用表面活性剂处理制备的非贵金属基底（10）上。使用该方法，可以以高度可重现的低成本制造高功率，高能量的电化学电荷存储装置。

4. 发明授权

US5728181A Electrodes for electrochemical cells and method of making same 失效
标题翻译：电化学电池用电极及其制作方法
公开(公告)号：US5728181A
公开(公告)日：1998-03-17
申请号：US743610
申请日：1996-11-04
申请人： Richard H. Jung , Ke Keryn Lian , Changming Li , Han Wu
发明人： Richard H. Jung , Ke Keryn Lian , Changming Li , Han Wu
IPC分类号： H01G9/04 , H01G9/042 , H01M4/00 , H01M4/02 , H01M4/66 , H01M10/38
CPC分类号： H01G9/042 , H01M4/00 , H01M4/02 , H01M4/66 , H01M4/667 , H01M4/661 , H01M4/668 , H01M4/669 , Y10T29/49108 , Y10T29/49115
摘要： An electrochemical cell is provided with a first and second electrode assemblies (10) (11), and an electrolyte (15) disposed therebetween. The electrodes may either be of the same or different materials and may be fabricated from ruthenium, iridium, cobalt, tungsten, vanadium, iron, molybdenum, nickel, silver, zinc, and combinations thereof. The electrode assemblies are fabricated by depositing a layer (16) of a conductive ink adhesive on a surface of a current collecting substrate (12). Thereafter, a layer of powdered active material (18) is impregnated onto the surface of the conductive ink layer.
摘要翻译：电化学电池设置有第一和第二电极组件（10）（11）以及设置在它们之间的电解质（15）。电极可以是相同或不同的材料，并且可以由钌，铱，钴，钨，钒，铁，钼，镍，银，锌及其组合制成。通过在集电衬底（12）的表面上沉积导电油墨粘合剂层（16）来制造电极组件。此后，将一层粉状活性物质（18）浸渍在导电油墨层的表面上。

5. 发明授权

US5830601A Rechargeable electrochemical cell with modified electrolyte 失效
标题翻译：具有改性电解质的可充电电化学电池
公开(公告)号：US5830601A
公开(公告)日：1998-11-03
申请号：US613697
申请日：1996-03-11
申请人： Ke Keryn Lian , Han Wu , Changming Li
发明人： Ke Keryn Lian , Han Wu , Changming Li
IPC分类号： H01M4/24 , H01M10/26 , H01M10/40
CPC分类号： H01M4/244 , H01M10/26
摘要： An electrochemical battery cell (10) including a zinc electrode (20), and may be fabricated with an electrolyte (50) system including an electrolyte active species and a modifier. The electrolyte active species is typically a metal hydroxide such as KOH or NaOH, while the modifier may be a porphine such as a metal porphine, and/or a polymeric material. The polymeric material may be, for example, a polyvinyl resin such as polyvinyl alcohol or polyvinyl acetate. The resulting electrolyte typically includes between 3 and 10 weight percent of the polyvinyl resin, 5 and 50 weight percent of the metal hydroxide, and between 1 PPM and 1 wt % of the modifier. Employing such an electrolyte in a cell including a zinc electrode results in an energy storage device having improved power density and substantially longer cycle life.
摘要翻译：一种包括锌电极（20）的电化学电池（10），并且可以用包括电解质活性物质和改性剂的电解质（50）系统制造。电解质活性物质通常是金属氢氧化物如KOH或NaOH，而改性剂可以是卟吩如金属卟吩和/或聚合物材料。聚合物材料可以是例如聚乙烯醇树脂如聚乙烯醇或聚乙酸乙烯酯。所得电解质通常包含3至10重量％的聚乙烯基树脂，5重量％和50重量％的金属氢氧化物，以及1PPM与1重量％的改性剂之间。在包括锌电极的电池中使用这种电解质导致能量存储装置具有改善的功率密度和显着更长的循环寿命。

6. 发明授权

US5824436A Electrically conductive polymeric coating for an electrochemical charge storage device 失效
标题翻译：用于电化学电荷存储装置的导电聚合物涂层
公开(公告)号：US5824436A
公开(公告)日：1998-10-20
申请号：US808269
申请日：1997-02-28
申请人： Ke Keryn Lian , Han Wu , Changming Li
发明人： Ke Keryn Lian , Han Wu , Changming Li
IPC分类号： H01B1/20 , H01M4/66 , H01G9/00
CPC分类号： H01M4/667 , H01B1/20 , H01M4/66 , H01M4/668
摘要： An electrochemical cell is provided with first (10) and second (11) electrodes and a solid polymer electrolyte (15) disposed therebetween. The electrodes include a current collecting layer, a layer of electrode active material, and a layer of an electrically conductive, polymeric protection material disposed therebetween. The protective layer protects, for example, the current collecting layer from the deleterious effects of the acid or alkaline electrolyte active species found in most electrochemical cells. The protective layer is formed of an intermetallic compound dispersed through a layer of appropriately chosen polymeric material.
摘要翻译：电化学电池设置有第一电极（10）和第二电极（11），以及设置在其间的固体聚合物电解质（15）。电极包括集流层，电极活性材料层和设置在它们之间的导电的聚合物保护材料层。保护层例如保护电流收集层免受大多数电化学电池中发现的酸或碱性电解质活性物质的有害影响。保护层由分散在适当选择的聚合材料层中的金属间化合物形成。

7. 发明授权

US5723231A Polymer electrolyte and an electrochemical cell containing the electrolyte 失效
标题翻译：聚合物电解质和含有电解质的电化学电池
公开(公告)号：US5723231A
公开(公告)日：1998-03-03
申请号：US762477
申请日：1996-12-09
申请人： Han Wu , Changming Li , Ke Keryn Lian
发明人： Han Wu , Changming Li , Ke Keryn Lian
IPC分类号： H01M6/18 , H01M6/04
CPC分类号： H01M6/181
摘要： An electrolyte for an electrochemical cell is provided. The electrolyte is an admixture of H.sub.3 PO.sub.4 and a high temperature polymer such as poly(benzimidazole) in ratios between 2:1 and 50:1, Fumed silica is added to the electrolyte at levels between 0.2% and 8% by weight. An electrochemical cell is fabricated using the electrolyte, and exhibits improved adhesion between the electrolyte and the electrode.
摘要翻译：提供了一种用于电化学电池的电解质。电解质是H 3 PO 4和高温聚合物如聚（苯并咪唑）之比为2:1至50:1的混合物，热解法二氧化硅以0.2重量％至8重量％的含量加入到电解质中。使用电解质制造电化学电池，并且在电解质和电极之间表现出改进的粘附性。

8. 发明授权

US5693434A Electrochemical cell having a polymer electrolyte 失效
标题翻译：具有聚合物电解质的电化学电池
公开(公告)号：US5693434A
公开(公告)日：1997-12-02
申请号：US693780
申请日：1996-07-22
申请人： Changming Li , Ke Keryn Lian , Richard H. Jung
发明人： Changming Li , Ke Keryn Lian , Richard H. Jung
IPC分类号： H01G9/02 , H01G9/025 , H01M6/18 , H01M6/22 , H01M8/02 , H01M8/10 , H01M10/02 , H01M10/10 , H01M10/40
CPC分类号： H01G9/025 , H01G11/54 , H01M10/02 , H01M10/10 , H01M6/181 , H01M6/22 , H01M8/0289 , H01M8/1025 , H01M8/103 , H01M8/1048 , H01M8/1069 , Y02E60/13 , Y02P70/54 , Y02P70/56 , Y10T29/49115
摘要： An electrochemical cell is provided with first (10) and second (11) electrodes and a solid polymer electrolyte (15) disposed therebetween. The solid polymer electrolyte is preferably fabricated by providing a linear powdered polymeric precursor material which is thereafter heated to temperatures sufficient to drive off moisture and in the presence of an electrolyte active species. The electrolyte active species is preferably an acidic electrolyte active species which has the effect of protonating the powdered polymeric precursor material. Electrochemical cells fabricated using these devices demonstrate performance characteristics far better than those available in the prior art.
摘要翻译：电化学电池设置有第一电极（10）和第二电极（11），以及设置在其间的固体聚合物电解质（15）。固体聚合物电解质优选通过提供线性粉末状聚合物前体材料制造，然后将其加热至足以驱除水分并在电解质活性物质存在下的温度。电解质活性物质优选是酸性电解质活性物质，其具有质子化粉末状聚合物前体材料的作用。使用这些装置制造的电化学电池显示出比现有技术中可获得的性能特征更好的性能特征。

9. 发明授权

US5688613A Electrochemical cell having a polymer electrolyte 失效
标题翻译：具有聚合物电解质的电化学电池
公开(公告)号：US5688613A
公开(公告)日：1997-11-18
申请号：US629174
申请日：1996-04-08
申请人： Changming Li , Ke Keryn Lian , Florence O. Eschbach
发明人： Changming Li , Ke Keryn Lian , Florence O. Eschbach
IPC分类号： H01G9/02 , H01G9/025 , H01M10/052 , H01M10/0565 , H01M6/18
CPC分类号： H01G9/025 , H01M10/052 , H01M10/0565 , Y02P70/54
摘要： An electrochemical cell is provided with a first and second electrodes, and a solid polymer electrolyte disposed therebetween. The electrodes may either be of the same or different materials and may be fabricated from ruthenium, iridium, cobalt, tungsten, vanadium, iron, molybdenum, nickel, silver, zinc, and combinations thereof. The solid polymer electrolyte is in intimate contact with both the anode and the cathode, and is made from a polymeric support structure having dispersed therein an electrolyte active species. The polymer support structure is preferably a polybenzimidazole.
摘要翻译：电化学电池设置有第一和第二电极以及设置在它们之间的固体聚合物电解质。电极可以是相同或不同的材料，并且可以由钌，铱，钴，钨，钒，铁，钼，镍，银，锌及其组合制成。固体聚合物电解质与阳极和阴极紧密接触，并且由其中分散有电解质活性物质的聚合物支撑结构制成。聚合物载体结构优选为聚苯并咪唑。

10. 发明授权

US5807412A Electrochemical cell having a polymer electrolyte 失效
标题翻译：具有聚合物电解质的电化学电池
公开(公告)号：US5807412A
公开(公告)日：1998-09-15
申请号：US865619
申请日：1997-05-30
申请人： Changming Li , Ke Keryn Lian , Richard H. Jung
发明人： Changming Li , Ke Keryn Lian , Richard H. Jung
IPC分类号： H01G9/02 , H01G9/025 , H01M6/18 , H01M6/22 , H01M8/02 , H01M8/10 , H01M10/02 , H01M10/10 , H01M10/40
CPC分类号： H01G9/025 , H01G11/54 , H01M10/02 , H01M10/10 , H01M6/181 , H01M6/22 , H01M8/0289 , H01M8/1025 , H01M8/103 , H01M8/1048 , H01M8/1069 , Y02E60/13 , Y02P70/54 , Y02P70/56 , Y10T29/49115
摘要： An electrochemical cell is provided with first (10) and second (11) electrodes and a solid polymer electrolyte (15) disposed therebetween. The solid polymer electrolyte is preferably fabricated by providing a linear powdered polymeric precursor material which is thereafter heated to temperatures sufficient to drive off moisture and in the presence of an electrolyte active species. The electrolyte active species is preferably an acidic electrolyte active species which has the effect of protonating the powdered polymeric precursor material. Electrochemical cells fabricated using these devices demonstrate performance characteristics far better than those available in the prior art.
摘要翻译：电化学电池设置有第一电极（10）和第二电极（11），以及设置在其间的固体聚合物电解质（15）。固体聚合物电解质优选通过提供线性粉末状聚合物前体材料制造，然后将其加热至足以驱除水分并在电解质活性物质存在下的温度。电解质活性物质优选是酸性电解质活性物质，其具有质子化粉末状聚合物前体材料的作用。使用这些装置制造的电化学电池显示出比现有技术中可获得的性能特征更好的性能特征。

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