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1. 发明授权

US06376114B1 Reformate fuel treatment system for a fuel cell power plant 有权
标题翻译：改革燃料电池发电厂的燃料处理系统
公开(公告)号：US06376114B1
公开(公告)日：2002-04-23
申请号：US09583824
申请日：2000-05-30
申请人： Leonard J. Bonville, Jr. , Ned E. Cipollini , Jay Garow , Roger R. Lesieur , Donald F. Szydlowski , Zebulon D. Vance , Douglas J. Wheeler
发明人： Leonard J. Bonville, Jr. , Ned E. Cipollini , Jay Garow , Roger R. Lesieur , Donald F. Szydlowski , Zebulon D. Vance , Douglas J. Wheeler
IPC分类号： H01M806
CPC分类号： H01M8/0625 , H01M8/04089 , H01M8/04156 , H01M8/0662
摘要： The invention is a reformate fuel treatment system for a fuel cell power plant that includes at least one fuel cell for generating electricity from process oxidant and reducing fluid reactant streams; fuel processing components including a steam supply and a reformer for producing a hydrogen enriched reformate fuel for the fuel cell from a hydrocarbon fuel; and, an ammonia removal apparatus that treats the reformate fuel to make it appropriate for supplying hydrogen to an anode electrode of the fuel cell. The ammonia removal apparatus may be a disposable ammonia scrubber, an ammonia scrubbing cool water bed and an ammonia stripping warm water bed, a pair of first and second regenerable scrubbers, or a single regenerable ammonia scrubber.
摘要翻译：本发明是用于燃料电池发电厂的重整燃料处理系统，其包括至少一个用于从工艺氧化剂发电和减少流体反应物流的燃料电池; 燃料处理部件，包括蒸汽源和重整器，用于从烃燃料生产用于燃料电池的富氢重整油燃料; 以及处理重整燃料使其适合于向燃料电池的阳极供给氢的氨去除装置。氨去除装置可以是一次性氨洗涤器，氨洗涤冷水床和氨汽提温水床，一对第一和第二可再生洗涤器或单个可再生氨洗涤器。

2. 发明授权

US6120926A Inhibition of carbon deposition on fuel gas steam reformer walls 有权
标题翻译：抑制燃料气体蒸汽重整器壁上的碳沉积
公开(公告)号：US6120926A
公开(公告)日：2000-09-19
申请号：US190856
申请日：1998-11-10
申请人： Donald F. Szydlowski , Roger R. Lesieur , Ned E. Cipollini
发明人： Donald F. Szydlowski , Roger R. Lesieur , Ned E. Cipollini
IPC分类号： B01J8/02 , B01J19/00 , C01B3/38 , H01M8/06 , H01M4/86
CPC分类号： H01M8/0631 , B01J19/0026 , B01J8/02 , C01B3/38 , C01B3/382 , C01B3/386 , C01B2203/0233 , C01B2203/0261 , C01B2203/066 , C01B2203/16 , Y02P20/52
摘要： A fuel gas reformer assembly for use in a fuel cell power plant includes fuel gas passages, some of which contain a particulate alumina packing in which a vaporized steam-hydrocarbon fuel stream mixture is heated. The walls of the fuel gas passages are provided with an alumina coating which protects the walls of the passages from corrosion. The alumina coating of the walls, and alumina packing are both overlain by an alkaline earth metal oxide layer, such as a calcium oxide layer, that acts to limit carbon build-up on the surfaces of the coated passage walls. Limiting of carbon build-up in the reformer passages prevents premature clogging of the passages. The carbon build-up-limiting layer is formed on components of the reformer passages by applying a water-based slurry of alkaline earth metal compounds to the reformer passage surfaces, and then drying the slurry so as to solidify it. The formation of the desired crystalline phase of the coating occurs in situ on the coated passage surfaces during initial operation of the reformer. The coated packing material is operative to convert any free carbon remaining in the gas stream to carbon dioxide, or carbon monoxide, thereby further limiting carbon deposition in the assembly.
摘要翻译：用于燃料电池发电厂的燃料气体重整器组件包括燃料气体通道，其中一些气体通道包含其中蒸发的蒸汽 - 烃燃料流混合物被加热的颗粒氧化铝填料。燃料气体通道的壁设置有氧化铝涂层，其保护通道的壁免受腐蚀。壁的氧化铝涂层和氧化铝填料都被诸如氧化钙层的碱土金属氧化物层覆盖，其用于限制在涂覆的通道壁的表面上积聚碳。在重整器通道中限制碳积累可以防止通道过早堵塞。通过将碱土金属化合物的水性浆料施加到重整器通道表面上，在重整器通道的部件上形成碳积聚限制层，然后干燥该浆料以使其固化。在重整器的初始操作期间，涂层的所需结晶相的形成在涂覆的通道表面上原位发生。涂覆的包装材料可操作以将残留在气流中的任何游离碳转化为二氧化碳或一氧化碳，从而进一步限制组件中的碳沉积。

3. 发明授权

US08906448B2 Method of treating a material to achieve sufficient hydrophilicity for making hydrophilic articles 有权
标题翻译：处理材料以达到足够的亲水性以制备亲水制品的方法
公开(公告)号：US08906448B2
公开(公告)日：2014-12-09
申请号：US13176309
申请日：2011-07-05
申请人： Gennady Resnick , Glenn M. Allen , Zebulon D. Vance, Jr. , Ned E. Cipollini
发明人： Gennady Resnick , Glenn M. Allen , Zebulon D. Vance, Jr. , Ned E. Cipollini
IPC分类号： C04B41/00 , C04B35/628 , C04B41/87 , H01M8/02 , C04B41/45 , C04B41/50 , C04B111/00
CPC分类号： C04B41/4584 , C04B35/62805 , C04B35/62807 , C04B35/62813 , C04B35/62818 , C04B35/62821 , C04B35/62823 , C04B35/62886 , C04B41/009 , C04B41/5041 , C04B41/87 , C04B2111/00853 , C04B2235/425 , C04B2235/528 , C04B2235/5436 , H01M8/023 , H01M8/0232 , H01M8/0234 , H01M8/0245 , Y02E60/50 , C04B41/4537 , C04B41/5027 , C04B41/4515 , C04B35/522 , C04B38/00 , C04B35/00
摘要： An exemplary method of treating a material such as carbon or graphite to render at least some surfaces of the material hydrophilic includes coating at least a portion of the at least some surfaces with an oxygenated element and controlling a rate of a breakdown of the oxygenated element to leave a corresponding elemental oxide on the surfaces. In one example, the material is treated before being incorporated into an article comprising the material. Another example method includes treating an article comprising the material. Disclosed examples include precipitation or decomposition as the breakdown of the oxygenated element.
摘要翻译：处理诸如碳或石墨的材料以使材料的至少一些表面亲水的示例性方法包括用氧化元素涂覆所述至少一些表面的至少一部分并控制氧化元素的分解速率在表面留下相应的元素氧化物。在一个实例中，在将所述材料并入包含所述材料的制品中之前将所述材料进行处理。另一个示例性方法包括处理包含该材料的制品。公开的实例包括沉淀或分解为氧化元素的分解。

4. 发明申请

US20120003382A1 METHOD OF TREATING A MATERIAL TO ACHIEVE SUFFICIENT HYROPHILICITY FOR MAKING HYROPHILIC ARTICLES 有权
标题翻译：处理材料以实现有效的高性能制造高分子物品的方法
公开(公告)号：US20120003382A1
公开(公告)日：2012-01-05
申请号：US13176309
申请日：2011-07-05
申请人： Gennady Resnick , Glenn M. Allen , Zebulon D. Vance, JR. , Ned E. Cipollini
发明人： Gennady Resnick , Glenn M. Allen , Zebulon D. Vance, JR. , Ned E. Cipollini
IPC分类号： H01M8/00 , B05D3/10 , B05D3/02 , B05D5/00 , B05D3/00
CPC分类号： C04B41/4584 , C04B35/62805 , C04B35/62807 , C04B35/62813 , C04B35/62818 , C04B35/62821 , C04B35/62823 , C04B35/62886 , C04B41/009 , C04B41/5041 , C04B41/87 , C04B2111/00853 , C04B2235/425 , C04B2235/528 , C04B2235/5436 , H01M8/023 , H01M8/0232 , H01M8/0234 , H01M8/0245 , Y02E60/50 , C04B41/4537 , C04B41/5027 , C04B41/4515 , C04B35/522 , C04B38/00 , C04B35/00
摘要： An exemplary method of treating a material such as carbon or graphite to render at least some surfaces of the material hydrophilic includes coating at least a portion of the at least some surfaces with an oxygenated element and controlling a rate of a breakdown of the oxygenated element to leave a corresponding elemental oxide on the surfaces. In one example, the material is treated before being incorporated into an article comprising the material. Another example method includes treating an article comprising the material. Disclosed examples include precipitation or decomposition as the breakdown of the oxygenated element.
摘要翻译：处理诸如碳或石墨的材料以使材料的至少一些表面亲水的示例性方法包括用氧化元素涂覆所述至少一些表面的至少一部分并控制氧化元素的分解速率在表面留下相应的元素氧化物。在一个实例中，在将所述材料并入包含所述材料的制品中之前将所述材料进行处理。另一个示例性方法包括处理包含该材料的制品。公开的实例包括沉淀或分解为氧化元素的分解。

5. 发明授权

US06773684B2 Compact fuel gas reformer assemblage 失效
标题翻译：紧凑型燃气改质机组合
公开(公告)号：US06773684B2
公开(公告)日：2004-08-10
申请号：US09814911
申请日：2001-03-23
申请人： Roger R. Lesieur , Ned E. Cipollini , Thomas F. Fuller
发明人： Roger R. Lesieur , Ned E. Cipollini , Thomas F. Fuller
IPC分类号： F28D0000
CPC分类号： F28D7/12 , B01J19/249 , B01J2219/00157 , B01J2219/00186 , B01J2219/2453 , B01J2219/2462 , B01J2219/2479 , C01B3/384 , C01B2203/0205 , C01B2203/0811 , C01B2203/82
摘要： A fuel gas reformer assemblage for use in a fuel cell power plant is formed from a composite plate assembly which includes spaced-apart divider plates with columns of individual gas passages. The reformer assemblage is constructed from a series of repeating sub-assemblies, each of which includes a core of separate regenerator/heat exchanger gas passages. The core in each sub-assembly is sandwiched between a pair of reformer gas passage skins, which complete the assembly. Adjacent reformer gas/regenerator/reformer gas passage sub-assemblies in the composite plate assembly are separated from each other by burner gas passages. The regenerator/heat exchanger gas passages and the reformer gas passages in each sub-assembly are connected by gas flow reversing manifolds which form a part of each sub-assembly. The fuel gases flow in one end of the assemblage, through the reformer gas passages, and then reverse their direction of flow in the return manifolds so as to exit the reformer assemblage through the regenerator gas flow passages. The burner gases flow in one end of the reformer assemblage and out the other end. The walls of the burner and reformer gas flow passages are selectively catalyzed after the assemblage has been constructed.
摘要翻译：用于燃料电池发电厂的燃料气体重整器组合体由复合板组件形成，该复合板组件包括具有独立气体通道列的间隔开的分隔板。重整器组合由一系列重复子组件构成，每个重复组件包括单独的再生器/热交换器气体通道的核心。每个子组件中的芯子夹在一对完成组装的重整器气体通道表皮之间。复合板组件中相邻的重整器气体/再生器/重整器气体通道子组件通过燃烧器气体通道相互分离。每个子组件中的再生器/热交换器气体通道和重整器气体通道通过形成每个子组件的一部分的气流反向歧管连接。燃料气体通过重整器气体通道在组合件的一端中流动，然后在回流歧管中反转它们的流动方向，从而通过再生器气体流动通道离开重整器组件。燃烧器气体在重整器组合的一端流动，另一端流出。燃烧器和重整器气体流动通道的壁在构造组装之后被选择性地催化。

6. 发明授权

US09118081B2 Membrane electrode assemblies with hydrogen peroxide decomposition catalyst 有权
标题翻译：膜电极组件用过氧化氢分解催化剂
公开(公告)号：US09118081B2
公开(公告)日：2015-08-25
申请号：US12513701
申请日：2004-12-28
申请人： Ned E. Cipollini , David A. Condit , Jared B. Hertzberg , Thomas D. Jarvi , James A. Leistra , Michael L. Perry , Sathya Motupally
发明人： Ned E. Cipollini , David A. Condit , Jared B. Hertzberg , Thomas D. Jarvi , James A. Leistra , Michael L. Perry , Sathya Motupally
IPC分类号： H01M4/86 , H01M4/92 , H01M4/96 , H01M8/10 , H01M8/24
CPC分类号： H01M4/8657 , H01M4/86 , H01M4/8605 , H01M4/9041 , H01M4/9075 , H01M4/9083 , H01M4/92 , H01M4/926 , H01M4/96 , H01M8/1004 , H01M8/1023 , H01M8/1025 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1048 , H01M8/1058 , H01M8/1072 , H01M8/241 , H01M2008/1095 , H01M2300/0082 , Y02E60/521 , Y02P70/56
摘要： A membrane electrode assembly includes an anode including a hydrogen oxidation catalyst; a cathode; a membrane disposed between the anode and the cathode; and a peroxide decomposition catalyst positioned in at least one position selected from the group consisting of a layer between the anode and the membrane and a layer between the cathode and the membrane wherein the peroxide decomposition catalyst has selectivity when exposed to hydrogen peroxide toward reactions which form benign products from the hydrogen peroxide. The peroxide decomposition catalyst can also be positioned within the membrane. Also disclosed is a power-generating fuel cell system including such a membrane electrode assembly, and a process for operating such a fuel cell system. The assembly components contain ionomer material which can be perfluorinated or non-perfluorinated, high temperature, hydrocarbon, and the like.
摘要翻译：膜电极组件包括：包含氢氧化催化剂的阳极; 阴极设置在阳极和阴极之间的膜; 以及位于选自阳极和膜之间的层和阴极和膜之间的层中的至少一个位置的过氧化物分解催化剂，其中当暴露于过氧化氢时，过氧化物分解催化剂具有选择性，反应形成来自过氧化氢的良性产物。过氧化物分解催化剂也可以位于膜内。还公开了包括这种膜电极组件的发电燃料电池系统和用于操作这种燃料电池系统的方法。组装部件包含可以是全氟化或非全氟化，高温，烃等的离聚物材料。

7. 发明申请

US20110020727A1 Protective and Precipitation Layers for PEM Fuel Cell 有权
标题翻译： PEM燃料电池的保护和降水层
公开(公告)号：US20110020727A1
公开(公告)日：2011-01-27
申请号：US12863159
申请日：2008-01-03
申请人： Sergei F. Burlatsky , Ned E. Cipollini , David A. Condit , Thomas H. Madden , Sathya Motupally , Lesia V. Protsailo , Timothy W. Patterson , Lei Chen , Mallika Gummalla
发明人： Sergei F. Burlatsky , Ned E. Cipollini , David A. Condit , Thomas H. Madden , Sathya Motupally , Lesia V. Protsailo , Timothy W. Patterson , Lei Chen , Mallika Gummalla
IPC分类号： H01M8/10
CPC分类号： H01M8/04291 , H01M4/92 , H01M4/921 , H01M4/926 , H01M8/1004 , H01M8/1018 , H01M2008/1095 , H01M2250/10 , H01M2250/20 , H01M2300/0082 , Y02B90/14 , Y02E60/521 , Y02T90/32
摘要： A membrane electrode assembly is provided which includes an anode; a cathode; a membrane between the anode and the cathode; and a protective layer between the membrane and at least one electrode of the anode and the cathode, the protective layer having a layer of ionomer material containing a catalyst, the layer having a porosity of between 0 and 10%, an ionomer content of between 50 and 80% vol., a catalyst content of between 10 and 50% vol., and an electrical connectivity between catalyst particles of between 35 and 75%. A configuration using a precipitation layer to prevent migration of catalyst ions is also provided.
摘要翻译：提供一种膜电极组件，其包括阳极; 阴极阳极和阴极之间的膜; 以及在所述膜和所述阳极和所述阴极的至少一个电极之间的保护层，所述保护层具有包含催化剂的离聚物材料层，所述层的孔隙率为0至10％，离聚物含量为50 和80体积％，催化剂含量为10至50体积％，催化剂颗粒之间的电连接率为35至75％。还提供了使用沉淀层以防止催化剂离子迁移的构造。

8. 发明授权

US07718302B2 Electrochemical deoxygenation of fuel by electrolysis 有权
标题翻译：通过电解电化学脱氧燃料
公开(公告)号：US07718302B2
公开(公告)日：2010-05-18
申请号：US11581300
申请日：2006-10-16
申请人： Ned E. Cipollini
发明人： Ned E. Cipollini
IPC分类号： H01M2/14
CPC分类号： C25B9/10 , B01D19/0005 , B01D19/0073 , B01D19/0084 , C10G32/02 , C10G45/02 , C10G49/007
摘要： A fuel stabilization device reduces the amount of dissolved oxygen within a fuel stream utilizing the combination of an electrochemical device to produce hydrogen gas and water and a catalyst that promotes the formation of water utilizing dissolved oxygen within the fuel and hydrogen gas generated by the electrochemical device.
摘要翻译：燃料稳定装置利用电化学装置组合产生氢气和水来减少燃料流中的溶解氧的量，以及催化剂利用燃料内的溶解氧和电化学装置产生的氢气促进水的形成。

9. 发明申请

US20080083608A1 Electrochemical oxygen pump for fuel stabilization unit 有权
标题翻译：用于燃料稳定装置的电化学氧气泵
公开(公告)号：US20080083608A1
公开(公告)日：2008-04-10
申请号：US11543535
申请日：2006-10-05
申请人： Ned E. Cipollini
发明人： Ned E. Cipollini
IPC分类号： C01B13/00 , B01D53/22 , B01D59/12
CPC分类号： B01D19/0031 , B01D19/0084
摘要： A fuel stabilization unit includes an electrochemical device for promoting the formation of water utilizing oxygen from a fuel stream for generating an oxygen partial pressure differential across an oxygen permeable membrane.
摘要翻译：燃料稳定单元包括用于利用来自燃料流的氧促进水的形成的电化学装置，用于在透氧膜上产生氧分压差。

10. 发明申请

US20120028172A1 MANUFACTURE OF A FUEL CELL WITH LIQUID ELECTROLYTE MIGRATION PREVENTION 审中-公开
标题翻译：具有液体电解质迁移预防的燃料电池的制造
公开(公告)号：US20120028172A1
公开(公告)日：2012-02-02
申请号：US13145626
申请日：2009-06-18
申请人： Sridhar V. Kanuri , Richard D. Breault , Kishore Kumar Tenneti , Ned E. Cipollini , Frank E. Kenney
发明人： Sridhar V. Kanuri , Richard D. Breault , Kishore Kumar Tenneti , Ned E. Cipollini , Frank E. Kenney
IPC分类号： H01M8/00
CPC分类号： H01M8/086 , H01M8/0228 , H01M8/0284 , H01M8/0286 , Y02P70/56
摘要： A stack (10) of fuel cells (11) is manufactured with barriers (32) to prevent migration of a liquid electrolyte (such as phosphoric acid) out of the cells (11). The barrier (32) is secured within a step (34) formed within a land region (28) of a separator plate assembly (18) and extends from an edge (30) of the separator plate assembly (18) all or a portion of a distance between the edge (30) and a flow channel (24) defined within the separator plate assembly (18). The barrier (32) also extends away from the edge (30) a distance of between 0.051 and about 2.0 millimeters (about 2 and about 80 mils. The barrier (32) includes a hydrophobic, polymeric film (36), a pressure sensitive adhesive (38) as an assembly aid, and a fluoroelastomer bonding agent (40).
摘要翻译：燃料电池（11）的堆叠（10）制造有阻挡层（32），以防止液体电解质（例如磷酸）从电池（11）中迁移。隔板（32）固定在形成在隔离板组件（18）的平台区域（28）内的台阶（34）内，并从分隔板组件（18）的边缘（30）延伸，全部或一部分所述边缘（30）和限定在所述分隔板组件（18）内的流动通道（24）之间的距离。屏障（32）还从边缘（30）远离了0.051至约2.0毫米（约2和约80密耳）之间的距离。阻挡层（32）包括疏水性聚合物膜（36），压敏粘合剂（38）作为组合助剂，和含氟弹性体粘合剂（40）。

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