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1. 发明授权

US07439316B2 Process for preparation of stable polycarbodiimide dispersions in water, which are free of organic solvents and may be used as crosslinking agent 有权
标题翻译：在水中制备稳定的聚碳二亚胺分散体的方法，其不含有机溶剂并可用作交联剂
公开(公告)号：US07439316B2
公开(公告)日：2008-10-21
申请号：US11320189
申请日：2005-12-28
申请人： Laurentius Cornelius Josephus Hesselmans , Andries Johannes Derksen , Jacob Christiaan Munneke
发明人： Laurentius Cornelius Josephus Hesselmans , Andries Johannes Derksen , Jacob Christiaan Munneke
IPC分类号： C08G18/70 , C08G18/08
CPC分类号： C08G18/025 , C08G18/283
摘要： A process for the preparation of stable aqueous polycarbodiimide dispersions, to be used as crosslinking agent, which are free of organic solvents is described. Sid process is characterized in: reacting a polyisocyanate in the presence of a carbodiimide catalyst to form a polycarbodiimide, terminating and/or chain extending the polycarbodiimide chain by the addition of formation dispersion of the resulting compound in water, wherein pH is adjusted to a value between 9 and 14 by the addition of a base and/or a buffer to the water used for the dispersion and/or to the obtained aqueous dispersion. According to the present process said terminating or chain extending with the compound containing a hydrophylic group and one or more amine functions may also occur during or after the dispersion of the polycarboiimide in water. The preferred pH of the polycarbodiimide dispersions is between 11 and 13. Furthermore the invention related to a coating mixture comprising the polycarbodiimide dispersions obtained by the invention as crosslinking agent and an aqueous resin containing carboxylic acid functions. Finally the invention comprises cured material obtained by applying said coating mixture to a substrate, and evaporating the water.
摘要翻译：描述了用作制备用作交联剂的稳定的聚碳化二亚胺分散体水溶液的方法，其不含有机溶剂。 Sid方法的特征在于：在碳二亚胺催化剂的存在下使多异氰酸酯反应形成聚碳二亚胺，通过将所得化合物的形成分散体加入水中终止和/或链延伸聚碳二亚胺链，其中将pH调节至一个值通过向用于分散体的水和/或所获得的水分散体中加入碱和/或缓冲剂在9和14之间。根据本发明方法，在含有亲水基团和一种或多种胺官能团的化合物中延伸的终止或链可以在聚碳酰亚胺在水中分散期间或之后发生。聚碳二亚胺分散体的优选pH为11-13。此外，本发明涉及包含本发明获得的作为交联剂的聚碳二亚胺分散体和含有羧酸官能团的含水树脂的涂料混合物。最后，本发明包括通过将所述涂料混合物施加到基材上并蒸发水而获得的固化材料。

2. 发明申请

US20100076153A1 PROCESS FOR THE PREPARATION OF DISPERSIONS OF CROSS-LINKING AGENTS IN WATER 有权
标题翻译：制备水中交联剂分散体的方法
公开(公告)号：US20100076153A1
公开(公告)日：2010-03-25
申请号：US12278275
申请日：2007-01-10
申请人： Laurentius Cornelis Josephus Hesselmans , Marthe Hesselmans , Andries Johannes Derksen
发明人： Laurentius Cornelis Josephus Hesselmans , Marthe Hesselmans , Andries Johannes Derksen
IPC分类号： C08G18/32 , C08F283/04
CPC分类号： C08G18/025 , C08G18/2825 , C08G18/283 , C08G18/2885 , C08G18/289 , C08G18/706 , C08G18/71 , C08G18/758 , C09D175/04 , Y10T442/2189
摘要： A process for the preparation of stable aqueous polycarbodiimide dispersions to be used as cross-linking agents, in which initially an isocyanate functional polycarbodiimide is prepared from a polyisocyanate and a mono- or polyisocyanate which contains a hydrophobic group. Thereafter the polycarbodiimide chain is capped and/or extended by reaction of the isocyanate functions or a part thereof with a hydrophilic amine- or hydroxy functional compound and of the remaining isocyanate functions with an amine- or hydroxy functional compound which contains hydrophobic groups, after which the obtained product is dispersed in water and the pH is adjusted to 9-14. The hydrophobic groups are hydrocarbons with 4-25 carbon atoms, fluorinated hydrocarbons, silicone functional hydrocarbons or polysilicones. Further, the invention relates to a coating mixture in which the polycarbodiimide dispersion is used as cross-linking agent and to the cured material obtained with the coating mixture.
摘要翻译：用于制备用作交联剂的稳定的聚碳化二亚胺分散体的方法，其中最初由多异氰酸酯和含有疏水基团的单或多异氰酸酯制备异氰酸酯官能聚碳化二亚胺。此后，通过异氰酸酯官能团或其一部分与亲水性胺或羟基官能化合物的反应和剩余的异氰酸酯官能团与含有疏水基团的胺或羟基官能化合物反应，聚碳二亚胺链被封端和/或延伸，之后将得到的产物分散在水中，将pH调节至9-14。疏水基团是具有4-25个碳原子的烃，氟化烃，硅酮官能烃或多晶硅。此外，本发明涉及其中使用聚碳二亚胺分散体作为交联剂的涂料混合物和用涂料混合物获得的固化物质。

3. 发明授权

US08969471B2 Process for the preparation of dispersions of cross-linking agents in water 有权
标题翻译：制备交联剂在水中的分散体的方法
公开(公告)号：US08969471B2
公开(公告)日：2015-03-03
申请号：US12278275
申请日：2007-01-10
申请人： Laurentius Cornelis Josephus Hesselmans , Marthe Hesselmans , Andries Johannes Derksen
发明人： Laurentius Cornelis Josephus Hesselmans , Marthe Hesselmans , Andries Johannes Derksen
IPC分类号： C08L83/00 , C08L83/04 , C08G18/08 , C08L75/00 , C08G18/28 , C08K3/20 , C07C251/00 , C07C249/00 , C07C257/00 , C07C263/00 , C07C265/00 , C07C267/00 , C07C291/00 , B32B5/02 , B32B27/04 , B32B27/12 , C08G18/02 , C08G18/70 , C08G18/71 , C08G18/75 , C09D175/04
CPC分类号： C08G18/025 , C08G18/2825 , C08G18/283 , C08G18/2885 , C08G18/289 , C08G18/706 , C08G18/71 , C08G18/758 , C09D175/04 , Y10T442/2189
摘要： A process for the preparation of stable aqueous polycarbodiimide dispersions to be used as cross-linking agents, in which initially an isocyanate functional polycarbodiimide is prepared from a polyisocyanate and a mono- or polyisocyanate which contains a hydrophobic group. Thereafter the polycarbodiimide chain is capped and/or extended by reaction of the isocyanate functions or a part thereof with a hydrophilic amine- or hydroxy functional compound and of the remaining isocyanate functions with an amine- or hydroxy functional compound which contains hydrophobic groups, after which the obtained product is dispersed in water and the pH is adjusted to 9-14. The hydrophobic groups are hydrocarbons with 4-25 carbon atoms, fluorinated hydrocarbons, silicone functional hydrocarbons or polysilicones. Further, the invention relates to a coating mixture in which the polycarbodiimide dispersion is used as cross-linking agent and to the cured material obtained with the coating mixture.
摘要翻译：用于制备用作交联剂的稳定的聚碳化二亚胺分散体的方法，其中最初由多异氰酸酯和含有疏水基团的单或多异氰酸酯制备异氰酸酯官能聚碳化二亚胺。此后，通过异氰酸酯官能团或其一部分与亲水性胺或羟基官能化合物的反应和剩余的异氰酸酯官能团与含有疏水基团的胺或羟基官能化合物反应，聚碳二亚胺链被封端和/或延伸，之后将得到的产物分散在水中，将pH调节至9-14。疏水基团是具有4-25个碳原子的烃，氟化烃，硅酮官能烃或多晶硅。此外，本发明涉及其中使用聚碳二亚胺分散体作为交联剂的涂料混合物和用涂料混合物获得的固化物质。

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