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1. 发明申请

US20140312273A1 SUPERABSORBING POLYMERS WITH RAPID ABSORPTION PROPERTIES AND METHOD FOR PRODUCING THE SAME 有权
标题翻译：具有快速吸收性能的超吸收聚合物及其制造方法
公开(公告)号：US20140312273A1
公开(公告)日：2014-10-23
申请号：US14352091
申请日：2012-11-12
申请人： Laurent Wattebled , Jorg Harren , Matthias Naumann , Franck Furno , Matthias Lobert , Rainer Teni
发明人： Laurent Wattebled , Jorg Harren , Matthias Naumann , Franck Furno , Matthias Lobert , Rainer Teni
IPC分类号： A61L15/22 , B01J20/30 , B01J20/26
CPC分类号： A61L15/225 , A61L15/24 , A61L15/60 , B01J20/267 , B01J20/3064 , C08F216/1416 , C08F220/06 , C08F222/1006 , C08J3/245 , C08J2333/02 , C08L33/02
摘要： This invention relates to a method for producing a water-absorbing polymer, including the following steps: (i) mixing (α1) 0.1 to 99.999 wt % polymerizable, ethylenically unsaturated, acid-group-containing monomers; (α2) 0 to 70 wt % polymerized ethylenically unsaturated, monomers copolymerizable with (α1); (α3) 0.00 1 to 10 wt %, cross-linking agent(s); (α4) 0 to 30 wt % water-soluble polymers; and (α5) 0 to 20 wt % additive(s), wherein the total quantity by weight of (α1) to (α5) amounts to 100 wt %, (ii) radical polymerization while cross-linking, in order to form a hydrogel polymer, (iii) drying the hydrogel polymer, (iv) grinding and sifting the water-absorbing polymer, (v) surface post-cross-linking the hydrogel polymer, and (vi) drying and processing the polymer, wherein, before the admixture of the initiator and the start of radical polymerization, 0.01 to 5 wt % of a surfactant, relative to acrylic acid, 0.01 to 5 wt % foaming agent, are added.
摘要翻译：本发明涉及一种吸水性聚合物的制造方法，包括以下步骤：（i）将（α1）0.1〜99.999重量％的可聚合的烯属不饱和的含酸基单体混合; （α2）0-70重量％聚合的烯属不饱和单体，可与（α1）共聚的单体; （α3）0.001-10重量％，交联剂; （α4）0〜30重量％水溶性聚合物; 和（α5）0〜20重量％的添加剂，其中（α1）〜（α5）的总量为100重量％，（ii）交联时的自由基聚合，以形成水凝胶聚合物，（iii）干燥水凝胶聚合物，（iv）研磨和筛选吸水聚合物，（v）表面后交联水凝胶聚合物，和（vi）干燥和加工聚合物，其中在混合物的引发剂和自由基聚合的开始，添加相对于丙烯酸的0.01〜5重量％的表面活性剂，0.01〜5重量％的发泡剂。

2. 发明申请

US20120001122A1 USE OF HOLLOW BODIES FOR PRODUCING WATER-ABSORBING POLYMER STRUCTURES 审中-公开
标题翻译：用于生产吸水聚合物结构的中空体的使用
公开(公告)号：US20120001122A1
公开(公告)日：2012-01-05
申请号：US13201780
申请日：2010-03-09
申请人： Laurent Wattebled , Rainer Teni , Jorg Harren
发明人： Laurent Wattebled , Rainer Teni , Jorg Harren
IPC分类号： C09K3/00 , C09K17/22
CPC分类号： C08F2/44 , A61F13/00 , A61L15/22 , A61L15/60 , B32B27/00 , C08F20/10 , C08J3/128 , C08J3/245 , C08J9/32 , C08J2301/14 , C08J2333/02 , C08K7/22 , C08K9/10 , C08L101/14
摘要： The present invention relates to water-absorbing polymer structures at least partly comprising hollow bodies with a shell of an inorganic or organic material. The invention further relates to a process for producing water-absorbing polymer structures, to the water-absorbing polymer structures obtainable by this process, to a composite, to a process for producing a composite, to the composite obtainable by this process, to chemical products, for instance foams, moldings or fibers, to the use of water-absorbing polymer structures or of a composite in chemical products, for instance foams, moldings or fibers, and to the use of hollow bodies with a shell of an inorganic or organic material.
摘要翻译：本发明涉及至少部分地包含具有无机或有机材料壳的中空体的吸水聚合物结构。本发明还涉及一种生产吸水性聚合物结构的方法，通过该方法可获得的吸水性聚合物结构，复合材料，复合材料的制造方法与通过该方法获得的复合材料相对于化学产品例如泡沫，模制品或纤维，使用吸水聚合物结构或化学产品中的复合材料，例如泡沫，模制品或纤维，以及使用具有无机或有机材料壳的中空体。

3. 发明授权

US09737874B2 Water-absorbing polymer having a high absorption rate 有权
公开(公告)号：US09737874B2
公开(公告)日：2017-08-22
申请号：US14110579
申请日：2012-04-03
申请人： Laurent Wattebled , Christoph Loick , Jorg Harren , Stefan Leininger
发明人： Laurent Wattebled , Christoph Loick , Jorg Harren , Stefan Leininger
IPC分类号： B01J20/28 , B01J20/30 , C08F220/06 , A61L15/42 , A61L15/60 , C08F2/16 , B01J20/18 , B01J20/20 , B01J20/26 , C08J3/12 , C08J3/24 , B01J20/04 , C08F2/44
CPC分类号： B01J20/28045 , A61L15/425 , A61L15/60 , B01J20/043 , B01J20/18 , B01J20/20 , B01J20/264 , B01J20/267 , B01J20/28004 , B01J20/28023 , B01J20/28028 , B01J20/28033 , B01J20/3014 , B01J20/3021 , B01J20/3028 , B01J2220/68 , C08F2/16 , C08F2/44 , C08F220/06 , C08J3/12 , C08J3/24 , C08J2333/00 , C08F2222/1013
摘要： A process for producing a water-absorbing polymer composition, comprising the process steps of (i) mixing (α1) 0.1 to 99.999% by weight of ethylenically unsaturated monomers containing acid groups or salts thereof (α2) 0 to 70% by weight of polymerized, ethylenically unsaturated monomers copolymerizable with (α1), (α3) 0.001 to 10% by weight of one or more crosslinkers, (α4) 0 to 30% by weight of water-soluble polymers, and (α5) 0 to 20% by weight of one or more assistants, where the sum of their weights (α1) to (α5) is 100% by weight, (ii) free-radical polymerization with crosslinking to form a water-insoluble aqueous untreated hydrogel polymer, and surface postcrosslinking the ground hydrogel polymer wherein blowing agents having a particle size of 100 μm to 900 μm are added to the aqueous monomer solution prior to the addition of the initiator and the start of the free-radical polymerization.

4. 发明申请

US20140045683A1 PROCESS FOR PRODUCING IMPROVED ABSORBENT POLYMERS BY MEANS OF CRYOGENIC GRINDING 有权
标题翻译：通过低温磨削生产改进的吸收聚合物的方法
公开(公告)号：US20140045683A1
公开(公告)日：2014-02-13
申请号：US13876736
申请日：2011-10-05
申请人： Christoph Loick , Dominik Gartz , Laurent Wattebled , Jorg Harren
发明人： Christoph Loick , Dominik Gartz , Laurent Wattebled , Jorg Harren
IPC分类号： B01J20/26
CPC分类号： B01J20/267 , A61L15/22 , A61L15/60 , C08F6/008 , C08J3/12 , C08J3/245 , C08J2300/14 , C08J2333/00 , C08L33/00
摘要： A process for producing a water-absorbing polymer comprises: (i) mixing (α1) 0.1-99.99% by weight of ethylenically unsaturated monomers containing acid groups or salts thereof, or ethylenically unsaturated monomers including a protonated or quaternized nitrogen, or mixtures thereof, (α2) 0-70% by weight of ethylenically unsaturated monomers copolymerizable with (α1), (α3) 0.001-10% by weight of one or more crosslinkers, (α4) 0-30% by weight of water-soluble polymers, and (α5) 0-20% by weight of one or more assistants, where the sum of the weights (α1) to (α5) is 100%; (ii) free-radical polymerization with crosslinking to form an untreated hydrogel polymer; (iii) coarse comminution of the untreated hydrogel polymer to give pieces having a diameter from 0.1 mm to 5.0 cm; (iv) cooling and grinding the untreated hydrogel polymer; (v) drying the untreated hydrogel polymer after grinding at a temperature from 85° C. to 260° C.; (vi) postcrosslinking the hydrogel polymer and (vii) drying the water-absorbing polymer.
摘要翻译：制备吸水性聚合物的方法包括：（i）将0.1-99.99重量％含有酸基或其盐的烯属不饱和单体或包括质子化或季铵化的氮的烯键式不饱和单体或其混合物（α1）（α2）0-70重量％的可与（α1），（α3）0.001-10重量％的一种或多种交联剂共聚的烯属不饱和单体，（α4）0-30重量％的水溶性聚合物，和（α5）0-20重量％的一种或多种助剂，其中重量（α1）至（α5）的总和为100％; （ii）通过交联进行自由基聚合以形成未处理的水凝胶聚合物; （iii）未经处理的水凝胶聚合物的粗粉碎，得到直径为0.1mm至5.0cm的片; （iv）冷却和研磨未处理的水凝胶聚合物; （v）在85℃至260℃的温度下研磨后将未处理的水凝胶聚合物干燥; （vi）将水凝胶聚合物后交联，和（vii）干燥吸水聚合物。

5. 发明申请

US20140054497A1 WATER-ABSORBING POLYMER HAVING A HIGH ABSORPTION RATE 有权
标题翻译：具有高吸收率的吸水聚合物
公开(公告)号：US20140054497A1
公开(公告)日：2014-02-27
申请号：US14110579
申请日：2012-04-03
申请人： Laurent Wattebled , Christoph Loick , Jorg Harren , Stefan Leininger
发明人： Laurent Wattebled , Christoph Loick , Jorg Harren , Stefan Leininger
IPC分类号： B01J20/28 , B01J20/30
CPC分类号： B01J20/28045 , A61L15/425 , A61L15/60 , B01J20/043 , B01J20/18 , B01J20/20 , B01J20/264 , B01J20/267 , B01J20/28004 , B01J20/28023 , B01J20/28028 , B01J20/28033 , B01J20/3014 , B01J20/3021 , B01J20/3028 , B01J2220/68 , C08F2/16 , C08F2/44 , C08F220/06 , C08J3/12 , C08J3/24 , C08J2333/00 , C08F2222/1013
摘要： A process for producing a water-absorbing polymer composition, comprising the process steps of (i) mixing (α1) 0.1 to 99.999% by weight of ethylenically unsaturated monomers containing acid groups or salts thereof (α2) 0 to 70% by weight of polymerized, ethylenically unsaturated monomers copolymerizable with (α1), (α3) 0.001 to 10% by weight of one or more crosslinkers, (α4) 0 to 30% by weight of water-soluble polymers, and (α5) 0 to 20% by weight of one or more assistants, where the sum of their weights (α1) to (α5) is 100% by weight, (ii) free-radical polymerization with crosslinking to form a water-insoluble aqueous untreated hydrogel polymer, and surface postcrosslinking the ground hydrogel polymer wherein blowing agents having a particle size of 100 μm to 900 μm are added to the aqueous monomer solution prior to the addition of the initiator and the start of the free-radical polymerization.
摘要翻译：一种制备吸水性聚合物组合物的方法，包括以下工艺步骤：（i）将0.1至99.999重量％的含有酸基的烯键式不饱和单体或其盐（α2）混合（α1）0至70重量％的聚合可与（α1），（α3）0.001〜10重量％的一种或多种交联剂共聚的烯属不饱和单体，（α4）0〜30重量％的水溶性聚合物，和（α5）0〜20重量％的一种或多种助剂，其中其重量（α1）至（α5）的总和为100重量％，（ii）通过交联进行自由基聚合以形成水不溶性水性未处理水凝胶聚合物，以及将地面交联水凝胶聚合物，其中在加入引发剂和开始自由基聚合之前，将具有100μm至900μm的粒度的发泡剂加入到单体水溶液中。

6. 发明申请

US20100209379A1 SUPERABSORBENT COMPOSITION WITH TANNINS FOR ODOR CONTROL 有权
标题翻译：用于气味控制的鞣剂的超吸收组合物
公开(公告)号：US20100209379A1
公开(公告)日：2010-08-19
申请号：US12679631
申请日：2008-09-24
申请人： Franck Furno , Laurent Wattebled , Anne Ix-Mund , Harald Schmidt , Markus Henn , Jorg Harren
发明人： Franck Furno , Laurent Wattebled , Anne Ix-Mund , Harald Schmidt , Markus Henn , Jorg Harren
IPC分类号： A61L9/01 , C09K3/00
CPC分类号： C08F220/06 , A61L15/46 , A61L15/60 , A61L2300/216 , A61L2300/30 , A61L2300/622 , C08F220/40 , C08J3/128 , C08J3/245 , C08J2300/14 , C08J2333/02
摘要： The present invention relates to a water-absorbing composition comprising water-absorbing polymer structures, on the surface of which is at least one tannin fraction which has a number-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, which has a weight-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, or which is a hydrolysable gallotannin.The present invention also relates to a process for the preparation of a water-absorbing composition, the water-absorbing composition obtainable by this process, a composite, a process for the production of a composite, the composite obtainable by this process, chemical products, such as, for example, hygiene articles, the use of a water-absorbing composition or of a composite and the use of a tannin fraction.
摘要翻译：本发明涉及一种吸水组合物，其包含吸水聚合物结构，其表面至少是根据本文所述的测试方法确定的至少一种具有数均分子量的单宁部分，至少 1,000g / mol，其具有根据本文所述的测试方法测定的重均分子量为至少1,000g / mol，或其是可水解的鞣兰宁。本发明还涉及一种制备吸水组合物的方法，可通过该方法获得的吸水组合物，复合材料，复合材料的制备方法，通过该方法获得的复合材料，化学产品，例如卫生制品，吸水组合物或复合材料的使用以及单宁部分的使用。

7. 发明授权

US08859701B2 Process for producing improved absorbent polymers by means of cryogenic grinding 有权
标题翻译：通过低温研磨生产改进的吸收性聚合物的方法
公开(公告)号：US08859701B2
公开(公告)日：2014-10-14
申请号：US13876736
申请日：2011-10-05
申请人： Christoph Loick , Dominik Gartz , Laurent Wattebled , Jorg Harren
发明人： Christoph Loick , Dominik Gartz , Laurent Wattebled , Jorg Harren
IPC分类号： C08J9/36 , C08F20/06 , C08J3/12 , A61L15/60 , A61L15/22 , C08F6/00 , C08J3/24 , B01J20/26
CPC分类号： B01J20/267 , A61L15/22 , A61L15/60 , C08F6/008 , C08J3/12 , C08J3/245 , C08J2300/14 , C08J2333/00 , C08L33/00
摘要： A process for producing a water-absorbing polymer comprises: (i) mixing (α1) 0.1-99.99% by weight of ethylenically unsaturated monomers containing acid groups or salts thereof, or ethylenically unsaturated monomers including a protonated or quaternized nitrogen, or mixtures thereof, (α2) 0-70% by weight of ethylenically unsaturated monomers copolymerizable with (α1), (α3) 0.001-10% by weight of one or more crosslinkers, (α4) 0-30% by weight of water-soluble polymers, and (α5) 0-20% by weight of one or more assistants, where the sum of the weights (α1) to (α5) is 100%; (ii) free-radical polymerization with crosslinking to form an untreated hydrogel polymer; (iii) coarse comminution of the untreated hydrogel polymer to give pieces having a diameter from 0.1 mm to 5.0 cm; (iv) cooling and grinding the untreated hydrogel polymer; (v) drying the untreated hydrogel polymer after grinding at a temperature from 85° C. to 260° C.; (vi) postcrosslinking the hydrogel polymer and (vii) drying the water-absorbing polymer.
摘要翻译：制备吸水性聚合物的方法包括：（i）将（α1）0.1-99.99重量％的含有酸基团的烯属不饱和单体或包含质子化或季铵化的氮的烯属不饱和单体或其混合物，（α2）0-70重量％的可与（α1），（α3）0.001-10重量％的一种或多种交联剂共聚的烯属不饱和单体，（α4）0-30重量％的水溶性聚合物，和（α5）0-20重量％的一种或多种助剂，其中权重（α1）至（α5）之和为100％; （ii）通过交联进行自由基聚合以形成未处理的水凝胶聚合物; （iii）未经处理的水凝胶聚合物的粗粉碎，得到直径为0.1mm至5.0cm的片; （iv）冷却和研磨未处理的水凝胶聚合物; （v）在85℃至260℃的温度下研磨后将未处理的水凝胶聚合物干燥; （vi）将水凝胶聚合物后交联，和（vii）干燥吸水聚合物。

8. 发明授权

US08658146B2 Superabsorbent composition with tannins for odor control 有权
标题翻译：超吸收剂组合物，含有单宁，用于气味控制
公开(公告)号：US08658146B2
公开(公告)日：2014-02-25
申请号：US12679631
申请日：2008-09-24
申请人： Franck Furno , Laurent Wattebled , Anne Ix-Mund , Harald Schmidt , Markus Henn , Jorg Harren
发明人： Franck Furno , Laurent Wattebled , Anne Ix-Mund , Harald Schmidt , Markus Henn , Jorg Harren
IPC分类号： A61L101/34 , A61K31/78
CPC分类号： C08F220/06 , A61L15/46 , A61L15/60 , A61L2300/216 , A61L2300/30 , A61L2300/622 , C08F220/40 , C08J3/128 , C08J3/245 , C08J2300/14 , C08J2333/02
摘要： The present invention relates to a water-absorbing composition comprising water-absorbing polymer structures, on the surface of which is at least one tannin fraction which has a number-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, which has a weight-average molecular weight, determined in accordance with the test method described herein, of at least 1,000 g/mol, or which is a hydrolysable gallotannin.The present invention also relates to a process for the preparation of a water-absorbing composition, the water-absorbing composition obtainable by this process, a composite, a process for the production of a composite, the composite obtainable by this process, chemical products, such as, for example, hygiene articles, the use of a water-absorbing composition or of a composite and the use of a tannin fraction.
摘要翻译：本发明涉及一种吸水组合物，其包含吸水聚合物结构，其表面至少是根据本文所述的测试方法确定的至少一种具有数均分子量的单宁部分，至少 1,000g / mol，其具有根据本文所述的测试方法测定的重均分子量为至少1,000g / mol，或其是可水解的鞣兰宁。本发明还涉及一种制备吸水组合物的方法，可通过该方法获得的吸水组合物，复合材料，复合材料的制备方法，通过该方法获得的复合材料，化学产品，例如卫生制品，吸水组合物或复合材料的使用以及单宁部分的使用。

9. 发明授权

US08772378B2 Thermoplastic starch compositions 失效
标题翻译：热塑性淀粉组合物
公开(公告)号：US08772378B2
公开(公告)日：2014-07-08
申请号：US13301926
申请日：2011-11-22
申请人： Norman Scott Broyles , Pier-Lorenzo Caruso , Emily Charlotte Boswell , Robert Earl Magness , Ludwig Busam , Jörg Harren , Laurent Wattebled
发明人： Norman Scott Broyles , Pier-Lorenzo Caruso , Emily Charlotte Boswell , Robert Earl Magness , Ludwig Busam , Jörg Harren , Laurent Wattebled
IPC分类号： C08L3/00 , D21H19/58
CPC分类号： C08L23/06 , C08K3/014 , C08K3/30 , C08K5/0016 , C08K5/005 , C08K5/092 , C08K5/098 , C08K5/36 , C08K5/41 , C08L23/12 , C08L67/02 , C08L3/02 , C08K3/0041 , C08L3/00
摘要： The present invention relates to improvements in prevention of discoloration of thermoplastic starch materials and their blends with other thermoplastic materials.
摘要翻译：本发明涉及防止热塑性淀粉材料及其与其它热塑性材料的混合物变色的改进。

10. 发明授权

US08686216B2 Superabsorbent composition with metal salicylate for odor control 失效
标题翻译：超吸收组合物与金属水杨酸盐进行气味控制
公开(公告)号：US08686216B2
公开(公告)日：2014-04-01
申请号：US12867943
申请日：2009-02-27
申请人： Laurent Wattebled , Franck Furno
发明人： Laurent Wattebled , Franck Furno
IPC分类号： A61F13/15 , A61K31/60 , A61K47/30 , A61K33/32
CPC分类号： A61K31/60 , A61L15/18 , A61L15/46 , A61L15/60 , A61L2300/102 , A61L2300/21 , A61L2300/404 , C08K5/098 , C08L33/02
摘要： The present invention relates to a water-absorbing particulate composition comprising water-absorbing polymer particulate structure comprising partly neutralized, crosslinked polyacrylate, a surface crosslinking agent and a compound of the structure I in which R1, R2, R3 and R4 can be identical or different and in each case represent a hydrogen atom, a halogen atom, a C1- to C4-hydrocarbon group or a hydroxyl group, R5 represents a hydrogen atom, a C1- to C4-hydrocarbon group or an acetyl group, n represents an integer chosen from the group consisting of 1, 2 or 3 and Mn+ represents an n-valent metal cation or an H+ cation. In addition, the present invention also relates to a process for the preparation of a water-absorbing composition, the water-absorbing composition obtainable by this process, a composite, a process for the production of a composite, the composite obtainable by this process, and products, such as hygiene articles.
摘要翻译：本发明涉及一种吸水性颗粒组合物，其包含吸水聚合物颗粒结构，其包含部分中和的交联聚丙烯酸酯，表面交联剂和结构I的化合物，其中R 1，R 2，R 3和R 4可以相同或不同并且在每种情况下都表示氢原子，卤素原子，C 1〜C 4烃基或羟基，R 5表示氢原子，C 1〜C 4烃基或乙酰基，n表示选择的整数由1,2或3组成的组，Mn +表示n价金属阳离子或H +阳离子。此外，本发明还涉及一种制备吸水组合物的方法，可通过该方法获得的吸水组合物，复合材料，复合材料的制备方法，可通过该方法获得的复合材料，和卫生用品等产品。

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