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1. 发明申请

US20120283341A1 System and Method for Converting Biomass to Ethanol via Syngas 有权
标题翻译：通过合成气将生物质转化为乙醇的系统和方法
公开(公告)号：US20120283341A1
公开(公告)日：2012-11-08
申请号：US13309084
申请日：2011-12-01
申请人： Larry Jack Melnichuk , Karen Venita Kelly , Robert S. Davis
发明人： Larry Jack Melnichuk , Karen Venita Kelly , Robert S. Davis
IPC分类号： C07C29/149
CPC分类号： C07C29/15 , B01J8/44 , C07C29/149 , C07C29/1518 , C07C51/12 , C07C51/44 , C07C67/36 , C10J3/482 , C10J3/721 , C10J2300/0909 , C10J2300/0916 , C10J2300/0956 , C10J2300/1246 , C10J2300/1606 , C10J2300/1621 , C10J2300/1665 , C10J2300/1853 , C10J2300/1876 , C10K1/026 , C10K1/08 , C10K1/12 , C10K3/00 , Y02E50/18 , Y02E50/346 , Y02P20/129 , Y02P20/13 , Y02P20/145 , Y02P20/52 , C07C31/08 , C07C31/04 , C07C53/08 , C07C69/14
摘要： A method and apparatus for synthesizing ethanol using synthetic routes via synthesis gas are disclosed. A method and apparatus for gasifying biomass, such as biomass, in a steam gasifier that employs a fluidized bed and heating using hot flue gases from the combustion of synthesis gas is described. Methods and apparatus for converting synthesis gas into ethanol are also disclosed, using stepwise catalytic reactions to convert the carbon monoxide and hydrogen into ethanol using catalysts including iridium acetate.
摘要翻译：公开了一种使用合成路线合成乙醇的方法和装置。描述了一种用于在使用流化床的蒸汽气化器中并且使用来自合成气的燃烧的热烟道气进行加热的生物质如生物质气化的方法和装置。还公开了将合成气转化为乙醇的方法和装置，使用逐步催化反应，使用包括乙酸铱在内的催化剂将一氧化碳和氢转化成乙醇。

2. 发明授权

US08088832B2 System and method for converting biomass to ethanol via syngas 有权
标题翻译：通过合成气将生物质转化为乙醇的系统和方法
公开(公告)号：US08088832B2
公开(公告)日：2012-01-03
申请号：US11784508
申请日：2007-04-05
申请人： Larry Jack Melnichuk , Karen Venita Kelly , Robert S. Davis
发明人： Larry Jack Melnichuk , Karen Venita Kelly , Robert S. Davis
IPC分类号： C07C27/00 , C07C27/04 , C07C51/12 , C07C67/36
CPC分类号： C07C29/15 , B01J8/44 , C07C29/149 , C07C29/1518 , C07C51/12 , C07C51/44 , C07C67/36 , C10J3/482 , C10J3/721 , C10J2300/0909 , C10J2300/0916 , C10J2300/0956 , C10J2300/1246 , C10J2300/1606 , C10J2300/1621 , C10J2300/1665 , C10J2300/1853 , C10J2300/1876 , C10K1/026 , C10K1/08 , C10K1/12 , C10K3/00 , Y02E50/18 , Y02E50/346 , Y02P20/129 , Y02P20/13 , Y02P20/145 , Y02P20/52 , C07C31/08 , C07C31/04 , C07C53/08 , C07C69/14
摘要： A method and apparatus for synthesizing ethanol using synthetic routes via synthesis gas are disclosed. A method and apparatus for gasifying biomass, such as biomass, in a steam gasifier that employs a fluidized bed and heating using hot flue gases from the combustion of synthesis gas is described. Methods and apparatus for converting synthesis gas into ethanol are also disclosed, using stepwise catalytic reactions to convert the carbon monoxide and hydrogen into ethanol using catalysts including iridium acetate.
摘要翻译：公开了一种使用合成路线合成乙醇的方法和装置。描述了一种用于在使用流化床的蒸汽气化器中并且使用来自合成气的燃烧的热烟道气进行加热的生物质如生物质气化的方法和装置。还公开了将合成气转化为乙醇的方法和装置，使用逐步催化反应，使用包括乙酸铱在内的催化剂将一氧化碳和氢转化成乙醇。

3. 发明授权

US08710107B2 System and method for converting biomass to ethanol via syngas 有权
标题翻译：通过合成气将生物质转化为乙醇的系统和方法
公开(公告)号：US08710107B2
公开(公告)日：2014-04-29
申请号：US13309084
申请日：2011-12-01
申请人： Larry Jack Melnichuk , Karen Venita Kelly , Robert S. Davis
发明人： Larry Jack Melnichuk , Karen Venita Kelly , Robert S. Davis
IPC分类号： C07C27/00 , C07C27/04 , C07C51/12 , C07C69/62
CPC分类号： C07C29/15 , B01J8/44 , C07C29/149 , C07C29/1518 , C07C51/12 , C07C51/44 , C07C67/36 , C10J3/482 , C10J3/721 , C10J2300/0909 , C10J2300/0916 , C10J2300/0956 , C10J2300/1246 , C10J2300/1606 , C10J2300/1621 , C10J2300/1665 , C10J2300/1853 , C10J2300/1876 , C10K1/026 , C10K1/08 , C10K1/12 , C10K3/00 , Y02E50/18 , Y02E50/346 , Y02P20/129 , Y02P20/13 , Y02P20/145 , Y02P20/52 , C07C31/08 , C07C31/04 , C07C53/08 , C07C69/14
摘要： A method and apparatus for synthesizing ethanol using synthetic routes via synthesis gas are disclosed. A method and apparatus for gasifying biomass, such as biomass, in a steam gasifier that employs a fluidized bed and heating using hot flue gases from the combustion of synthesis gas is described. Methods and apparatus for converting synthesis gas into ethanol are also disclosed, using stepwise catalytic reactions to convert the carbon monoxide and hydrogen into ethanol using catalysts including iridium acetate.
摘要翻译：公开了一种使用合成路线合成乙醇的方法和装置。描述了一种用于在使用流化床的蒸汽气化器中并且使用来自合成气的燃烧的热烟道气进行加热的生物质如生物质气化的方法和装置。还公开了将合成气转化为乙醇的方法和装置，使用逐步催化反应，使用包括乙酸铱在内的催化剂将一氧化碳和氢转化成乙醇。

4. 发明申请

US20140256993A1 System and Method for Converting Biomass to Ethanol via Syngas 审中-公开
标题翻译：通过合成气将生物质转化为乙醇的系统和方法
公开(公告)号：US20140256993A1
公开(公告)日：2014-09-11
申请号：US14203024
申请日：2014-03-10
申请人： Larry Jack Melnichuk , Karen Venita Kelly , Robert S. Davis
发明人： Larry Jack Melnichuk , Karen Venita Kelly , Robert S. Davis
IPC分类号： C07C29/15
CPC分类号： C07C29/15 , B01J8/44 , C07C29/149 , C07C29/1518 , C07C51/12 , C07C51/44 , C07C67/36 , C10J3/482 , C10J3/721 , C10J2300/0909 , C10J2300/0916 , C10J2300/0956 , C10J2300/1246 , C10J2300/1606 , C10J2300/1621 , C10J2300/1665 , C10J2300/1853 , C10J2300/1876 , C10K1/026 , C10K1/08 , C10K1/12 , C10K3/00 , Y02E50/18 , Y02E50/346 , Y02P20/129 , Y02P20/13 , Y02P20/145 , Y02P20/52 , C07C31/08 , C07C31/04 , C07C53/08 , C07C69/14
摘要： A method and apparatus for synthesizing ethanol using synthetic routes via synthesis gas are disclosed. A method and apparatus for gasifying biomass, such as biomass, in a steam gasifier that employs a fluidized bed and heating using hot flue gases from the combustion of synthesis gas is described. Methods and apparatus for converting synthesis gas into ethanol are also disclosed, using stepwise catalytic reactions to convert the carbon monoxide and hydrogen into ethanol using catalysts including iridium acetate.
摘要翻译：公开了一种使用合成路线合成乙醇的方法和装置。描述了一种用于在使用流化床的蒸汽气化器中并且使用来自合成气的燃烧的热烟道气进行加热的生物质如生物质气化的方法和装置。还公开了将合成气转化为乙醇的方法和装置，使用逐步催化反应，使用包括乙酸铱在内的催化剂将一氧化碳和氢转化成乙醇。

5. 发明授权

US06747067B2 Process for converting cellulosic material into liquids 失效
标题翻译：将纤维素材料转化为液体的方法
公开(公告)号：US06747067B2
公开(公告)日：2004-06-08
申请号：US09799342
申请日：2001-03-06
申请人： Larry Jack Melnichuk , Karen Venita Kelly
发明人： Larry Jack Melnichuk , Karen Venita Kelly
IPC分类号： C07C2700
CPC分类号： C10J3/00 , C07C1/0485 , C07C29/1518 , C07C51/12 , C10J3/721 , C10J2300/092 , C10J2300/0976 , C10J2300/1223 , C10J2300/1656 , C10J2300/1665 , C10J2300/1807 , C10K1/026 , C10K1/20 , C10K3/04 , Y02E50/18 , C07C31/04 , C07C53/08
摘要： A process for the production of oxygenated C2 hydrocarbons from cellulose is disclosed. The input cellulose waste is gasified using steam in the absence of air and the primary gaseous products of carbon monoxide and hydrogen are subjected to heat, pressure, and catalysts to form methyl alcohol. Carbon monoxide is added to the methyl alcohol and further subjected to heat, pressure and catalysts to form acetic acid. The acetic acid is purified using a distillation tower, and removed for sale. Output production is increased by adding further carbon monoxide and hydrogen from burners used to heat the gasifiers. Further carbon monoxide and hydrogen are also produced by steam gasification of the carbon residue to promote a water/gas shift. These gases are fed into the gas stream produced by the gasification of cellulose, and provide more feedstock for the reactions. The three input gas streams arising from: 1) the steam gasification of cellulose; 2) the water/gas shift in the carbon reactor; and 3) the sub-stoichiometic oxygen burning of input burner gas to heat both retorts, maximize the output chemical production while reducing the consumption of energy needed for processing the cellulose and the carbon.
摘要翻译：公开了一种从纤维素生产含氧C2烃的方法。输入的纤维素废物在没有空气的情况下使用蒸汽气化，并且一氧化碳和氢气的主要气态产物经受热，压力和催化剂以形成甲醇。将一氧化碳加入到甲醇中，并进一步进行加热，加压和催化剂以形成乙酸。使用蒸馏塔纯化乙酸，并将其除去。通过从用于加热气化器的燃烧器中进一步加入一氧化碳和氢气来增加输出产量。通过碳残余物的蒸汽气化也产生进一步的一氧化碳和氢气，以促进水/气转移。将这些气体进料到由纤维素气化产生的气流中，为反应提供更多的原料。三种输入气流产生于：1）纤维素的蒸汽气化; 2）碳反应堆中的水/气转移; 和3）输入燃烧器气体的亚化学计量氧气燃烧以加热两个蒸馏器，最大化输出化学生产，同时减少加工纤维素和碳所需的能量消耗。

6. 发明授权

US5902915A Process for producing liquid hydrocarbons 失效
标题翻译：生产液态烃的方法
公开(公告)号：US5902915A
公开(公告)日：1999-05-11
申请号：US822613
申请日：1997-03-20
申请人： Larry Jack Melnichuk , Karen Venita Kelly
发明人： Larry Jack Melnichuk , Karen Venita Kelly
IPC分类号： B01J12/00 , B01J19/12 , C10G1/02 , C10G1/10 , C10G15/12 , C10G1/00 , C07C1/00 , C10B53/00
CPC分类号： B01J19/126 , B01J12/007 , C10G1/02 , C10G1/10 , C10G15/12 , B01J2219/0894
摘要： A process for producing liquid hydrocarbons from hydrocarbon materials is disclosed. The hydrocarbon materials are heated to a temperature above 400.degree. C. thereby producing a gas stream. A gaseous plasma is generated. The gas stream is passed through the gaseous plasma thereby producing a heated gas stream. The heated gas stream is saturated with a hydroxide ion to produce a saturated gas stream. The saturated gas stream is cooled to standard temperature and pressure and is condensed to produce liquid hydrocarbons and waste gases.
摘要翻译：公开了一种从烃类材料制备液体烃的方法。将烃材料加热至高于400℃的温度，从而产生气流。产生气体等离子体。气流通过气态等离子体，从而产生加热的气流。加热的气流用氢氧化物离子饱和以产生饱和气流。将饱和气流冷却至标准温度和压力并冷凝以产生液体烃和废气。

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