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1. 发明授权

US6004519A Aluminum promoted hydrogenation of alkylation sludge for aluminum chloride recovery 失效
标题翻译：铝促进了氯化铝回收的烷基化污泥的氢化
公开(公告)号：US6004519A
公开(公告)日：1999-12-21
申请号：US775522
申请日：1997-01-02
申请人： Elliott P. Doane , Jim Yuen-Fong Low , Larry G. Sherman , William A. Yuill
发明人： Elliott P. Doane , Jim Yuen-Fong Low , Larry G. Sherman , William A. Yuill
IPC分类号： C01F7/56 , C07C2/60 , C10G47/08
CPC分类号： C10G47/08 , C01F7/56 , C07C2/60 , C07C2527/126 , Y02P20/544
摘要： The recovery of aluminum chloride from deactivated alkylation catalyst complexes by hydrogenation using hydrogen gas and an aluminum catalyst is disclosed. Using aluminum to catalyze the hydrogenation allows the reaction to proceed at a lower temperature and pressure while reducing the amount of hydrogen chloride present in the reactor thus reducing the corrosiveness and cost of the aluminum chloride recovery. Methods for batch, batchwise continuous, and continuous aluminum chloride recovery are disclosed.
摘要翻译：公开了通过使用氢气和铝催化剂的氢化从失活的烷基化催化剂络合物中回收氯化铝。使用铝催化氢化使得反应在较低的温度和压力下进行，同时减少反应器中存在的氯化氢的量，从而降低氯化铝回收的腐蚀性和成本。公开了批次间歇连续氯化铝回收方法。

2. 发明授权

US5510561A Homogenous catalyst and processes for fluid phase alkylation 失效
标题翻译：均相催化剂和流化相烷基化方法
公开(公告)号：US5510561A
公开(公告)日：1996-04-23
申请号：US399405
申请日：1995-03-06
申请人： Larry G. Sherman , William A. Yuill
发明人： Larry G. Sherman , William A. Yuill
IPC分类号： C07C2/62 , C07C5/27
CPC分类号： C07C2/62 , C07C5/2794 , C07C2527/08 , C07C2527/11 , C07C2527/126 , C07C2531/02 , C07C2531/12
摘要： A discrete catalyst and processes for the alkylation of isoalkanes with alkenes under homogenous fluid conditions. The catalyst is formed by contacting, under fluid conditions, a homogenous fluid containing a paraffin hydrocarbon having from 4 to 12 carbon atoms with a Lewis acid/protic Bronsted acid pair to produce a discrete catalytic complex that is soluble in the fluid. The discrete catalyst is the reaction product of the acid pair and alkanes and includes hydrocarbon ligands of limited chain length rendering it soluble in the fluid. The catalyst is active for the alkylation of isoalkanes, under homogenous fluid conditions.
摘要翻译：离子催化剂和在均相流体条件下用烯烃烷基化异烷烃的方法。催化剂通过在流体条件下使含有4-12个碳原子的链烷烃的均匀流体与路易斯酸/质子布朗斯台德酸对接触来形成，以产生可溶于流体的离散催化络合物。离散催化剂是酸对和烷烃的反应产物，包括有限链长度的烃配体，使其溶于流体。在均匀的流体条件下，催化剂对于异烷烃的烷基化是有活性的。

3. 发明授权

US08651113B2 Magnetically responsive nanoparticle therapeutic constructs and methods of making and using 有权
标题翻译：磁响应纳米颗粒治疗结构及其制备和使用方法
公开(公告)号：US08651113B2
公开(公告)日：2014-02-18
申请号：US12505111
申请日：2009-07-17
申请人： Charles E. Seeney , Jim Klostergaard , William A. Yuill , Donald D. Gibson
发明人： Charles E. Seeney , Jim Klostergaard , William A. Yuill , Donald D. Gibson
IPC分类号： A61B19/00
CPC分类号： A61N2/12 , A61K9/1641 , A61K9/1676 , A61K9/5094
摘要： Magnetically responsive therapeutic carriers comprise nanoparticles including single-domain nanoparticles comprising magnetite and having an average particle size ranging between 1 and 50 nanometers, clusters of the single-domain nanoparticles, the clusters having an average cluster size ranging between 5 and 1000 nanometers, and mixtures of the two. The single-domain nanoparticles are encapsulated with a silica coating. A silane coupling agent is bonded to the silica coating and has a specific pendant functional group capable of selectively binding with the therapeutic. Preferably, the bond between the specific pendant functional group and the therapeutic is a covalent bond. The movement of magnetically responsive nanoparticle therapeutic constructs, with concentration and extravasation/endocytosis at a target site, such as cancerous tumors, uses a controllable magnetic field generator adapted to move the therapeutic constructs in three dimensions, and is enhanced using a repetitively-varying magnetic field. A method for treating cancer comprises administering and magnetically guiding a therapeutic construct comprising paclitaxel.
摘要翻译：磁响应治疗载体包括纳米颗粒，其包括包含磁铁矿并且具有1至50纳米的平均粒度范围的单畴纳米颗粒，单畴纳米颗粒的簇，簇的平均簇尺寸为5至1000纳米，混合物的两个。单畴纳米颗粒用二氧化硅涂层包封。硅烷偶联剂与二氧化硅涂层结合，并具有能够与治疗剂选择性结合的特异性侧链官能团。优选地，特定侧基官能团与治疗剂之间的键是共价键。磁性反应性纳米颗粒治疗构建体的运动，在靶位点（如癌性肿瘤）上具有浓度和外渗/内吞作用，使用可控磁场发生器，其适于在三维中移动治疗构建体，并且使用重复变化的磁领域。用于治疗癌症的方法包括施用和磁性引导包含紫杉醇的治疗构建体。

4. 发明申请

US20090180976A1 SINGLE STEP MILLING AND SURFACE COATING PROCESS FOR PREPARING STABLE NANODISPERSIONS 有权
标题翻译：单步铣削和表面涂装工艺，用于制备稳定的纳米尺寸
公开(公告)号：US20090180976A1
公开(公告)日：2009-07-16
申请号：US12267400
申请日：2008-11-07
申请人： Charles E. Seeney , William A. Yuill , Donald D. Gibson
发明人： Charles E. Seeney , William A. Yuill , Donald D. Gibson
IPC分类号： A61K8/04 , B05D7/00 , A61Q17/04 , C09C1/36
CPC分类号： B05D3/12 , A61K8/11 , A61K8/29 , A61K2800/413 , A61Q17/04 , B01J2/006 , B82Y30/00 , C01G9/02 , C01G23/047 , C01P2004/51 , C01P2004/52 , C01P2004/62 , C01P2004/64 , C01P2004/84 , C01P2006/12 , C09C1/3623 , C09C1/3661 , C09C1/3676 , C09C1/3692
摘要： A single step milling and surface coating process allows for production of a stable dispersion of surface coated nanoparticles in an efficient manner. The process comprises providing feed particles, providing a coating agent, and generating the stable dispersion of surface coated nanoparticles by milling the feed particles in an aqueous medium containing the coating agent such that the coating agent bonds to surfaces of the feed particles as the feed particles are milled to an average particle size of less than about 100 nm.
摘要翻译：单步研磨和表面涂覆工艺允许以有效的方式生产表面包被的纳米颗粒的稳定分散体。该方法包括提供进料颗粒，提供涂层剂，以及通过在含有涂层剂的水性介质中研磨进料颗粒而产生表面包被的纳米颗粒的稳定分散体，使得涂覆剂与进料颗粒的表面作为进料颗粒被研磨成小于约100nm的平均粒度。

5. 发明申请

US20110130616A1 Magnetically Responsive Nanoparticle Therapeutic Constructs and Methods of Making and Using 有权
标题翻译：磁响应纳米颗粒治疗结构及其使用方法
公开(公告)号：US20110130616A1
公开(公告)日：2011-06-02
申请号：US12505111
申请日：2009-07-17
申请人： Charles E. Seeney , Jim Klostergaard , William A. Yuill , Donald D. Gibson
发明人： Charles E. Seeney , Jim Klostergaard , William A. Yuill , Donald D. Gibson
IPC分类号： A61N2/04 , A61N2/00 , A61N2/02 , A61K9/16 , A61K31/335 , A61K9/14 , B82Y5/00
CPC分类号： A61N2/12 , A61K9/1641 , A61K9/1676 , A61K9/5094
摘要： Magnetically responsive therapeutic carriers comprise nanoparticles including single-domain nanoparticles comprising magnetite and having an average particle size ranging between 1 and 50 nanometers, clusters of the single-domain nanoparticles, the clusters having an average cluster size ranging between 5 and 1000 nanometers, and mixtures of the two. The single-domain nanoparticles are encapsulated with a silica coating. A silane coupling agent is bonded to the silica coating and has a specific pendant functional group capable of selectively binding with the therapeutic. Preferably, the bond between the specific pendant functional group and the therapeutic is a covalent bond. The movement of magnetically responsive nanoparticle therapeutic constructs, with concentration and extravasation/endocytosis at a target site, such as cancerous tumors, uses a controllable magnetic field generator adapted to move the therapeutic constructs in three dimensions, and is enhanced using a repetitively-varying magnetic field. A method for treating cancer comprises administering and magnetically guiding a therapeutic construct comprising paclitaxel.
摘要翻译：磁响应治疗载体包括纳米颗粒，其包括包含磁铁矿并且具有1至50纳米的平均粒度范围的单畴纳米颗粒，单畴纳米颗粒的簇，簇的平均簇尺寸为5至1000纳米，混合物的两个。单畴纳米颗粒用二氧化硅涂层包封。硅烷偶联剂与二氧化硅涂层结合，并具有能够与治疗剂选择性结合的特异性侧链官能团。优选地，特定侧基官能团与治疗剂之间的键是共价键。磁性反应性纳米颗粒治疗构建体的运动，在靶位点（如癌性肿瘤）上具有浓度和外渗/内吞作用，使用可控磁场发生器，其适于在三维中移动治疗构建体，并且使用重复变化的磁领域。用于治疗癌症的方法包括施用和磁性引导包含紫杉醇的治疗构建体。

6. 发明授权

US06207131B1 Method and apparatus for producing titanium dioxide 失效
标题翻译：用于生产二氧化钛的方法和设备
公开(公告)号：US06207131B1
公开(公告)日：2001-03-27
申请号：US08887649
申请日：1997-07-03
申请人： John C. Magyar , Alan J. Morris , Glenn D. Wootten , William A. Yuill
发明人： John C. Magyar , Alan J. Morris , Glenn D. Wootten , William A. Yuill
IPC分类号： C01G23047
CPC分类号： C01G23/07
摘要： A process for reacting titanium tetrachloride vapors with oxygen to produce titanium dioxide wherein the oxygen is introduced into the reactor in at least two points. The process has the ability to control properties, such as particle size, of the raw pigment produced. The temperature of the oxygen introduced to the reactor at the further inlet point is above, below, or at the same temperature of the oxygen introduced at the first inlet point. The further inlet point can be located before or after the all the titanium tetrachloride has been introduced into the reactor. The titanium tetrachloride is introduced at a relatively low temperature, below about 427° C., and the reaction temperature in the reactor is at least about 700° C. The process includes the use of an auxilary fuel such as carbon monoxide, methane, propane, butane, pentane, hexane, benzene, xylene, toluene, or combinations thereof for increasing the temperature in the reactor. Still further, the process for producing titanium dioxide provides for the addition of aluminum chloride to the reactor. Advantageously, the process allows the pressure in the reactor to be above atmospheric pressure and range between about 0.15 MPa and 4.0 MPa above atmospheric pressure during the production of titanium dioxide. A reactor is also provided with an aluminum chloride generator for heating the titanium tetrachloride and delivering aluminum chloride to the reactor.
摘要翻译：一种使四氯化钛蒸气与氧反应产生二氧化钛的方法，其中氧气至少在两个点被引入反应器中。该方法具有控制生产的原料颜料的性质，例如粒度的能力。在另一入口点处引入反应器的氧的温度高于，低于或在与在第一入口点处引入的氧的相同温度下。进一步的入口点可以位于将四氯化钛全部引入反应器之前或之后。四氯化钛在相对较低的温度下引入，低于约427℃，反应器中的反应温度至少为约700℃。该方法包括使用辅助燃料如一氧化碳，甲烷，丙烷，丁烷，戊烷，己烷，苯，二甲苯，甲苯或其组合，以提高反应器中的温度。此外，制备二氧化钛的方法提供了向反应器中加入氯化铝。有利地，该方法允许反应器中的压力高于大气压力，并且在二氧化钛生产期间在大气压力之间的约0.15MPa和4.0MPa之间的范围。反应器还设有用于加热四氯化钛并将氯化铝输送到反应器的氯化铝发生器。

7. 发明授权

US4551312A Process for converting molybdenite to molybdenum oxide 失效
标题翻译：将辉钼矿转化为氧化钼的工艺
公开(公告)号：US4551312A
公开(公告)日：1985-11-05
申请号：US670244
申请日：1984-11-13
申请人： William A. Yuill
发明人： William A. Yuill
IPC分类号： C01G39/02 , C22B1/02 , C22B34/34
CPC分类号： C22B1/02 , C01G39/02 , C22B34/34 , C01P2006/80
摘要： A process for converting molybdenite to molybdenum oxide by a flash roasting process wherein the molybdenum calcine produced in the flash roasting process is subsequently treated with a free chlorine-containing aqueous solution.
摘要翻译：通过闪蒸焙烧方法将辉钼矿转化为氧化钼的方法，其中在闪蒸焙烧过程中产生的钼煅烧物随后用游离的含氯水溶液处理。

8. 发明授权

US06835361B2 Processes and apparatus for reacting gaseous reactants containing solid particles 有权
标题翻译：用于使含有固体颗粒的气态反应物反应的方法和装置
公开(公告)号：US06835361B2
公开(公告)日：2004-12-28
申请号：US09822565
申请日：2001-03-30
申请人： William A. Yuill , Charles A. Natalie
发明人： William A. Yuill , Charles A. Natalie
IPC分类号： B01D500
CPC分类号： B01J4/001 , B01J12/02 , B01J19/2405 , B01J19/2415 , B01J2219/00094 , B01J2219/00155 , B01J2219/00159 , B01J2219/00164 , C01G23/07
摘要： The present invention provides improved processes and apparatus for reacting high flow rates of one or more gaseous reactants in tubular reactors. The improved processes and apparatus allow such reactions to be carried out with a low pressure drop across the reactor and without excessive erosion due to solid particles carried with or picked up by the gaseous reactants. A process of this invention is basically comprised of the steps of swirling a gaseous reactant which may contain or pick up solid particles in a first annular plenum chamber followed by a second larger diameter annular plenum chamber and then introducing the gaseous reactant and solid particles into a reactor by way of two or more radial slots whereby said gaseous reactant and solid particles are caused to flow into said reactor and are uniformly distributed therein.
摘要翻译：本发明提供用于使管流反应器中一种或多种气态反应物的高流速反应的改进方法和装置。改进的方法和装置允许这样的反应在反应器的低压降下进行，并且由于由气态反应物携带或拾取的固体颗粒而没有过度的侵蚀。本发明的方法基本上包括以下步骤：旋转气态反应物，所述气态反应物可以在第一环形增压室中紧随着第二较大直径的环形增压室容纳或吸收固体颗粒，然后将气态反应物和固体颗粒引入反应器通过两个或更多个径向槽，由此使所述气态反应物和固体颗粒流入所述反应器并均匀分布在其中。

9. 发明授权

US4549959A Process for separating molybdenite from a molybdenite-containing copper sulfide concentrate 失效
标题翻译：从含辉钼矿的硫化铜精矿中分离辉钼矿的方法
公开(公告)号：US4549959A
公开(公告)日：1985-10-29
申请号：US656201
申请日：1984-10-01
申请人： Raynor O. Armstrong , Daniel A. Norrgran , William A. Yuill
发明人： Raynor O. Armstrong , Daniel A. Norrgran , William A. Yuill
IPC分类号： B03D1/001 , B03D1/002 , B03D1/02 , B03D1/14
CPC分类号： B03D1/02 , B03D1/002 , B03D2201/06 , B03D2203/02
摘要： A process for selectively separating molybdenum from a molybdenite-containing copper sulfide concentrate by a flotation process wherein the molybdenite is selectively floated by the use of a sulfite or bisulfite compound as a copper sulfide depressant.
摘要翻译：通过浮选方法从含辉钼矿的硫化铜精矿中选择性分离钼的方法，其中通过使用亚硫酸盐或亚硫酸氢盐化合物作为硫化铜抑制剂选择性地漂浮辉钼矿。

10. 发明授权

US08001977B2 Device for moving magnetic nanoparticles through tissue 失效
标题翻译：通过组织移动磁性纳米粒子的装置
公开(公告)号：US08001977B2
公开(公告)日：2011-08-23
申请号：US11400620
申请日：2006-04-06
申请人： Charles E. Seeney , William A. Yuill
发明人： Charles E. Seeney , William A. Yuill
IPC分类号： A61B19/00
CPC分类号： A61N2/12
摘要： The movement of magnetically responsive nanoparticles through a membrane is significantly enhanced by using a varying magnetic field gradient. The magnetic field varies in intensity and/or direction and can be achieved by mechanically varying the position of a magnet with respect to the membrane, or by oscillating the strength of one or more electromagnets.
摘要翻译：通过使用变化的磁场梯度，通过膜的磁响应纳米颗粒的运动被显着增强。磁场在强度和/或方向上变化，并且可以通过机械地改变磁体相对于膜的位置，或通过振荡一个或多个电磁体的强度来实现。

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