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    • 6. 发明授权
    • Low resistance collector frame for electroconductive organic, carbon and
graphitic materials
    • 用于导电有机,碳和石墨材料的低电阻收集器框架
    • US4631118A
    • 1986-12-23
    • US729702
    • 1985-05-02
    • Francis P. McCulloughRoy V. Snelgrove
    • Francis P. McCulloughRoy V. Snelgrove
    • C23C28/00C25D5/00C25D7/00H01R4/22C25D5/48
    • H01R4/22C23C28/00C25D5/48C25D5/54C25D5/56C25D7/00
    • A low resistance electrical connection is disclosed to connect two dissimilar electroconductive materials, one of which is a fiber, bundle of fibers or a film of an electroconductive polymer, carbon or graphite to an electroconductive metal collector. The connection is achieved by electroplating at an initial low current density the edge ends of a fiber or bundle of fibers or the edges of a cloth or film with an electroconductive metal, e.g. copper, silver and the like; thereafter crimping a fine electroconductive wire mesh onto said plated area and then continuing the said plating process until the wire mesh or gauze is substantially encapsulated with said electroplated metal. Alternative, the electroplated fiber ends may be joined by solder, as by dipping the ends or edges into a molten solder bath or laying a bead of solder substantially onto the copper plated edge of the fiber, bundle, cloth or film. Such practice ensures the electroconductive polymer, carbon or graphite end or edge will be intimately bound to the electroconductive metal forming the collector or frame.In many instances it is necessary that the collector metal and/or frame be insulated both electrically and chemically from contact with the environment into which the electroconductive polymer, graphite, carbon and the like is to be used. A procedure is described for protecting the collector frame when placed in hostile environment service.
    • 公开了一种低电阻电连接,以连接两种不同的导电材料,其中一种是纤维,纤维束或导电聚合物膜,碳或石墨到导电金属收集器。 该连接通过以初始低电流密度电镀在纤维或纤维束的边缘端部或通过导电金属的布或膜的边缘例如电镀来实现。 铜,银等; 然后将精细的导电丝网压接到所述电镀区域上,然后继续所述电镀工艺,直到丝网或纱布基本上被所述电镀金属包封。 另一方面,电镀纤维端部可以通过焊料接合,如将端部或边缘浸入熔融焊料槽或将焊料珠基本上铺在纤维,束,布或膜的镀铜边缘上。 这种做法确保导电聚合物,碳或石墨端或边缘将紧密地结合到形成收集器或框架的导电金属。 在许多情况下,集电器金属和/或框架必须以电气和化学方式绝缘以与将要使用导电聚合物,石墨,碳等的环境接触。 描述了当放置在恶劣环境服务中时保护收集器框架的过程。
    • 7. 发明授权
    • Flexible carbon fiber electrode with low modulus and high electrical
conductivity, battery employing the carbon fiber electrode, and method
of manufacture
    • 具有低模量和高导电性的柔性碳纤维电极,采用碳纤维电极的电池及其制造方法
    • US5532083A
    • 1996-07-02
    • US280708
    • 1994-07-26
    • Francis P. McCullough
    • Francis P. McCullough
    • H01B1/04H01M4/58H01M4/66H01M4/96H01M6/42H01M6/48
    • H01M4/583H01B1/04H01M4/663H01M4/96
    • A novel flexible carbon article for an electrode is disclosed for use in an electrical storage device in which the flexible carbon article, such as a planar sheet of a plurality of substantially parallel fibers or ribbons, and in which the fibers or ribbons have a Young's modulus of less than 1 MM psi (6.89 Gpa). The invention also resides in an electrical energy storage device, such as a secondary battery, comprising a water impermeable housing having at least one and preferably more than two cells in series, wherein a battery containing at least two cells also contains at least one shared bipolar electrode made of the flexible carbon article. Each cell has a foraminous separator between each pair of electrodes and contains an electrolyte comprising an ionizable salt in a non-aqueous fluid. Also disclosed are methods of making the electrode from an unfiltered precursor polymer and from a sub-acrylic polymer.
    • 公开了一种用于电极的新颖的柔性碳制品,用于电气存储装置中,其中柔性碳制品例如多个基本上平行的纤维或带状物的平面片,并且其中纤维或带具有杨氏模量 小于1 MM psi(6.89 Gpa)。 本发明还涉及一种诸如二次电池的电能存储装置,其包括具有至少一个且优选多于两个的串联的电池的不透水壳体,其中包含至少两个电池的电池还包含至少一个共同的双极 由柔性碳制品制成的电极。 每个电池在每对电极之间具有多孔分离器,并且包含在非水溶液中包含可电离盐的电解质。 还公开了从未过滤的前体聚合物和亚丙烯酸类聚合物制备电极的方法。