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    • 5. 发明授权
    • Active energy ray curable composition comprised of a maleimide derivative and a method for curing the said curable composition
    • 由马来酰亚胺衍生物和固化所述固化性组合物的方法组成的活性能量射线固化性组合物
    • US06410611B1
    • 2002-06-25
    • US09079523
    • 1998-05-15
    • Yoshinobu SakuraiAtsushi MiyakawaHisatomo YoneharaHidenobu IshikawaKatsuji Takahashi
    • Yoshinobu SakuraiAtsushi MiyakawaHisatomo YoneharaHidenobu IshikawaKatsuji Takahashi
    • C07D207448
    • C09D167/00C08F2/48C08F22/40C08F290/00C08F290/06C08F290/14C08F290/142C08F290/145C08F291/00C08G65/20C08G65/3328C08G65/33317C08G65/33337C08G73/12C08L33/04C08L67/07C08L71/02C09D11/101C09D167/07C08L2666/02
    • Objects of the present invention are the provision of an active energy ray curable composition which can be cured in the absence of a photoinitiator, and which can also be cured at practical light intensities and irradiating energy, and a method for curing the said curable composition; in which the composition comprises a maleimide derivative represented by formula (1): wherein m and n each represent an integer of 1 to 5, and the total of m and n is 6 or smaller, R11 and R12 each represent a linking group selected from the group consisting of {circle around (1)} an alkylene group, {circle around (2)} an alicyclic group, {circle around (3)} an arylalkylene group, and {circle around (4)} a cycloalkylalkyene group, G1 and G2 each represent an ester linkage selected from the group consisting of —COO— and —OCO—, R2 represents a linking chain having an average molecular weight of 100 to 100,000 selected from the group consisting of (A) a (poly)ether linking chain and (B) a (poly)ester linking chain, in which at least one organic group selected from the group consisting of {circle around (1)} a straight chain alkylene group, {circle around (2)} a branched alkylene group, {circle around (3)} an alkylene group having a hydroxyl group, {circle around (4)} an alicyclic group, {circle around (5)} an aryl group, and {circle around (6)} an arylalkylene group is connected via at least one linkage selected from the group consisting of (a) an ether linkage and (b) an ester linkage.
    • 本发明的目的是提供一种活性能量射线固化性组合物,其可以在不存在光引发剂的情况下固化,并且还可以在实际的光强度和照射能量下固化,以及固化所述可固化组合物的方法; 其中组合物包含由式(1)表示的马来酰亚胺衍生物:其中m和n各自表示1至5的整数,m和n的总数为6或更小,R 11和R 12各自表示选自 由(1)个亚烷基,(2)周期的脂环族基团,(3)周围的芳基亚烷基和{(4)周围的环)烷基亚烷基组成的组,G1和 G2各自表示选自-COO-和-OCO-的酯键,R2表示平均分子量为100至100,000的连接链,其选自(A)(聚)醚连接链 和(B)(多)酯连接链,其中至少一种选自{(1)}直链亚烷基周围的圆环,(2)周围的支链亚烷基, (3周围)具有羟基的亚烷基,(4周围的脂环族基),环状 (5)}芳基和(8)周围的芳基亚烷基经由至少一个选自(a)醚键和(b)酯键的键连接。