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1. 发明申请

US20110111944A1 MgO-A12O3-SiO2-Based Crystallizable Glass and Crystallized Glass, and Manufacturing Method Thereof 有权
标题翻译： MgO-A12O3-SiO2基可结晶玻璃和结晶玻璃及其制造方法
公开(公告)号：US20110111944A1
公开(公告)日：2011-05-12
申请号：US12911664
申请日：2010-10-25
申请人： Kuo-Chuan Hsu , Chao Qu
发明人： Kuo-Chuan Hsu , Chao Qu
IPC分类号： C03C3/112 , C03C10/16
CPC分类号： C03C3/112 , C03C1/002 , C03C10/0045 , C03C10/0063
摘要： The invention provides a crystallizable glass, a crystallized glass, and manufacturing methods thereof. The crystallizable glass can be crystallized in a short period of time, and can maintain its glass shape and its surface condition during a crystallization process. The crystallized glass has good mechanical strength, an adequate thermal expansion coefficient that allows the crystallized glass to be used as a construction material, less content of alkali-metal oxides, and good chemical durability. The MgO—Al2O3—SiO2-based crystallizable glass and crystallized glass contain, by mass percent, 55.0-65.0% SiO2, 8.0-14.0% Al2O3, 10.0-20.0% MgO, 1.5-6.0% CaO, 1.0-2.2% Li2O, 0.7-3.0% Na2O, 2.5-4.0% K2O, and 1.5-3.0% F.
摘要翻译：本发明提供一种可结晶玻璃，结晶玻璃及其制造方法。可结晶玻璃可以在短时间内结晶，并且可以在结晶过程中保持其玻璃形状和表面状态。结晶化玻璃具有良好的机械强度，足够的热膨胀系数，允许结晶化玻璃用作构造材料，较少的碱金属氧化物含量和良好的化学耐久性。 MgO-Al 2 O 3 -SiO 2系的可结晶玻璃和结晶化玻璃以质量％计含有55.0-65.0％的SiO 2，8.0〜14.0％的Al 2 O 3，10.0〜2.0％的MgO，1.5〜6.0％的CaO，1.0〜2.2％的Li 2 O，0.7 -3.0％Na2O，2.5-4.0％K2O和1.5-3.0％F。

2. 发明授权

US08431498B2 MgO—Al2O3—SiO2-based crystallizable glass and crystallized glass, and manufacturing method thereof 有权
标题翻译： MgO-Al2O3-SiO2系可结晶玻璃和结晶玻璃及其制造方法
公开(公告)号：US08431498B2
公开(公告)日：2013-04-30
申请号：US12911664
申请日：2010-10-25
申请人： Kuo-Chuan Hsu , Chao Qu
发明人： Kuo-Chuan Hsu , Chao Qu
IPC分类号： C03C10/04
CPC分类号： C03C3/112 , C03C1/002 , C03C10/0045 , C03C10/0063
摘要： The invention provides a crystallizable glass, a crystallized glass, and manufacturing methods thereof. The crystallizable glass can be crystallized in a short period of time, and can maintain its glass shape and its surface condition during a crystallization process. The crystallized glass has good mechanical strength, an adequate thermal expansion coefficient that allows the crystallized glass to be used as a construction material, less content of alkali-metal oxides, and good chemical durability. The MgO—Al2O3—SiO2-based crystallizable glass and crystallized glass contain, by mass percent, 55.0-65.0% SiO2, 8.0-14.0% Al2O3, 10.0-20.0% MgO, 1.5-6.0% CaO, 1.0-2.2% Li2O, 0.7-3.0% Na2O, 2.5-4.0% K2O, and 1.5-3.0% F.
摘要翻译：本发明提供一种可结晶玻璃，结晶玻璃及其制造方法。可结晶玻璃可以在短时间内结晶，并且可以在结晶过程中保持其玻璃形状和表面状态。结晶化玻璃具有良好的机械强度，足够的热膨胀系数，允许结晶化玻璃用作构造材料，较少的碱金属氧化物含量和良好的化学耐久性。 MgO-Al 2 O 3 -SiO 2系的可结晶玻璃和结晶化玻璃以质量％计含有55.0-65.0％的SiO 2，8.0〜14.0％的Al 2 O 3，10.0〜2.0％的MgO，1.5〜6.0％的CaO，1.0〜2.2％的Li 2 O，0.7 -3.0％Na2O，2.5-4.0％K2O和1.5-3.0％F。

3. 发明申请

US20120291493A1 CONSECUTIVE MOLDING METHOD FOR CRYSTALLIZED GLASS AND DEVICE THEREOF 审中-公开
标题翻译：用于结晶玻璃的配套成型方法及其装置
公开(公告)号：US20120291493A1
公开(公告)日：2012-11-22
申请号：US13417045
申请日：2012-03-09
申请人： Kuo-Chuan Hsu , Yan-Bin Jiang , Chao Qu
发明人： Kuo-Chuan Hsu , Yan-Bin Jiang , Chao Qu
IPC分类号： C03B20/00 , C03B13/00
CPC分类号： C03B25/08 , C03B5/245 , C03B5/265 , C03B13/04 , C03B32/02 , C03C3/097 , C03C10/0027 , Y02P40/57
摘要： A consecutive molding method for crystallized glass comprises: a process to obtain molten glass by melting glass raw materials; a process to obtain a band-shaped plate glass by roll forming the molten glass; a crystallization process to obtain a band-shaped crystallized glass plate by conducting thermal treatment on the band-shaped plate glass to crystallize it; and a process to cut the band-shaped crystallized glass plate, wherein the crystallization process includes: a process to form crystal nuclei in the band-shaped plate glass by disposing it in the atmosphere of a crystal nucleus-formation temperature and retaining it at the temperature; a process to raise the temperature of the band-shaped plate glass with crystal nuclei to a crystal-growth temperature; a process to retain the band-shaped plate glass with crystal nuclei at the crystal-growth temperature to produce a band-shaped crystallized glass plate; and a process to slowly cool down the band-shaped crystallized glass plate.
摘要翻译：结晶玻璃的连续成型方法包括：通过熔化玻璃原料获得熔融玻璃的方法; 通过辊压成形熔融玻璃获得带状平板玻璃的方法; 通过对带状平板玻璃进行热处理以使其结晶化而获得带状结晶化玻璃板的结晶化方法; 以及切割带状结晶玻璃板的方法，其中结晶方法包括：在带状平板玻璃中通过将其设置在晶核形成温度的气氛中形成晶核的工艺，并将其保持在温度; 将具有晶核的带状平板玻璃的温度升高至晶体生长温度的工序; 在结晶生长温度下保持具有晶核的带状平板玻璃以产生带状结晶玻璃板的工艺; 以及缓慢冷却带状结晶化玻璃板的工序。

4. 发明申请

US20120291492A1 CONSECUTIVE MOLDING METHOD FOR CRYSTALLIZED GLASS AND DEVICE THEREOF 审中-公开
标题翻译：用于结晶玻璃的配套成型方法及其装置
公开(公告)号：US20120291492A1
公开(公告)日：2012-11-22
申请号：US13417036
申请日：2012-03-09
申请人： Kuo-Chuan Hsu , Yan-Bin Jiang , Chao Qu
发明人： Kuo-Chuan Hsu , Yan-Bin Jiang , Chao Qu
IPC分类号： C03B27/012 , C03B13/00
CPC分类号： C03B13/04 , C03B5/245 , C03B5/265 , C03B25/08 , C03B32/02 , C03C3/097 , C03C10/0027 , Y02P40/57
摘要： A consecutive molding method for crystallized glass comprises: a melting process to obtain molten glass by melting glass raw materials; a molding process to obtain a band-shaped plate glass by roll forming the molten glass to become band-shaped; a crystallization process to obtain a band-shaped crystallized glass plate by conducting thermal treatment on the band-shaped plate glass to crystallize it; and a cutting process to cut the band-shaped crystallized glass plate, wherein the crystallization process includes: a temperature-raising process to produce the band-shaped crystallized glass plate by disposing the band-shaped plate glass obtained in the molding process, in the atmosphere of a crystal nucleus-formation temperature and raising the temperature to a crystal-growth temperature or above to grow crystals as well as form crystal nuclei; and a slow-cooling process to slowly cool down the band-shaped crystallized glass plate.
摘要翻译：结晶玻璃的连续成型方法包括：通过熔化玻璃原料获得熔融玻璃的熔融过程; 通过将熔融玻璃辊成型为带状而获得带状平板玻璃的成型方法; 通过对带状平板玻璃进行热处理以使其结晶化而获得带状结晶化玻璃板的结晶化方法; 以及切割带状结晶玻璃板的切割工序，其中结晶工艺包括：通过将在模塑工艺中获得的带状平板玻璃设置在该方法中来生产带状结晶玻璃板的升温过程晶体生成温度的气氛，将温度升高至晶体生长温度以上，生长晶体，形成晶核; 以及缓慢冷却带状结晶玻璃板的缓慢冷却过程。

5. 发明授权

US07615284B2 Crystallized glass article having patterns and method of producing the same 有权
标题翻译：具有图案的结晶玻璃制品及其制造方法
公开(公告)号：US07615284B2
公开(公告)日：2009-11-10
申请号：US11498463
申请日：2006-08-02
申请人： Kuo-Chuan Hsu
发明人： Kuo-Chuan Hsu
IPC分类号： B32B17/06 , C03C10/04
CPC分类号： C03C10/0036 , C03B19/09 , C03B23/20 , C03B32/02 , C03C10/0045 , C03C2218/345 , Y10T428/24942
摘要： A crystalline glass with a characteristic of precipitating crystals from the surface of the crystalline glass to the interior thereof when it is being heated at a temperature higher than the softening point is used in the invention. A plurality of small crystalline glass masses 12 are accumulated and leveled in a fireproof mold coated with a mold release agent, and two crystalline glass plates 14A and 14B cut in an S shape are placed on the accumulated surface of the small crystalline glass masses 12 with the cut faces tightly bonded. A heat treatment is then performed to obtain a crystallized glass article having patterns. The crystalline glass plate can be cut into any shape to tightly bond the cut faces, and therefore the obtained crystallized glass articles have different patterns like natural-marble-like patterns, human figure patterns, animal patterns, etc. The invention also discloses a method of producing crystallized articles having patterns.
摘要翻译：在本发明中使用具有从结晶玻璃表面析出结晶到其内部的特性的结晶玻璃，当其在高于软化点的温度下被加热时。多个小晶粒玻璃块12在涂有脱模剂的防火模具中堆积并平整，并且将两个切割成S形的晶体玻璃板14A和14B放置在小结晶玻璃块12的积聚表面上，切面紧贴。然后进行热处理以获得具有图案的结晶玻璃制品。结晶玻璃板可以切割成任何形状以紧密地结合切割面，因此所获得的结晶玻璃制品具有不同的图案，如天然大理石样图案，人形图案，动物图案等。本发明还公开了一种方法生产具有图案的结晶物品。

6. 发明申请

US20070048529A1 Crystallized glass article having patterns and method of producing the same 有权
标题翻译：具有图案的结晶玻璃制品及其制造方法
公开(公告)号：US20070048529A1
公开(公告)日：2007-03-01
申请号：US11498463
申请日：2006-08-02
申请人： Kuo-Chuan Hsu
发明人： Kuo-Chuan Hsu
IPC分类号： C03C10/04 , B32B17/06
CPC分类号： C03C10/0036 , C03B19/09 , C03B23/20 , C03B32/02 , C03C10/0045 , C03C2218/345 , Y10T428/24942
摘要： A crystalline glass with a characteristic of precipitating crystals from the surface of the crystalline glass to the interior thereof when it is being heated at a temperature higher than the softening point is used in the invention. A plurality of small crystalline glass masses 12 are accumulated and leveled in a fireproof mold coated with a mold release agent, and two crystalline glass plates 14A and 14B cut in an S shape are placed on the accumulated surface of the small crystalline glass masses 12 with the cut faces tightly bonded. A heat treatment is then performed to obtain a crystallized glass article having patterns. The crystalline glass plate can be cut into any shape to tightly bond the cut faces, and therefore the obtained crystallized glass articles have different patterns like natural-marble-like patterns, human figure patterns, animal patterns, etc. The invention also discloses a method of producing crystallized articles having patterns.
摘要翻译：在本发明中使用具有从结晶玻璃表面析出结晶到其内部的特性的结晶玻璃，当其在高于软化点的温度下被加热时。多个小晶状玻璃块12在涂有脱模剂的防火模具中堆积并平整，并且将两个S形切割的晶体玻璃板14A和14B放置在小晶状玻璃块的积聚表面上 12切割面紧紧贴合。然后进行热处理以获得具有图案的结晶玻璃制品。结晶玻璃板可以切割成任何形状以紧密地结合切割面，因此所获得的结晶玻璃制品具有不同的图案，如天然大理石样图案，人形图案，动物图案等。本发明还公开了一种方法生产具有图案的结晶物品。

7. 发明申请

US20080041107A1 Continuous method and system for manufacturing a crystallized glass plate 审中-公开
标题翻译：用于制造结晶玻璃板的连续方法和系统
公开(公告)号：US20080041107A1
公开(公告)日：2008-02-21
申请号：US11975029
申请日：2007-10-16
申请人： Kuo-Chuan Hsu , Chien-Liang Tseng , Xun-Geng Wang
发明人： Kuo-Chuan Hsu , Chien-Liang Tseng , Xun-Geng Wang
IPC分类号： C03C10/00
CPC分类号： C03B33/0235 , C03B13/04 , C03B32/02
摘要： A continuous method for manufacturing crystallized glass plates includes the steps of melting a raw crystallizable glass material to form molten glass, adjusting the molten glass to have a predetermined viscosity, rolling the molten glass to form a belt of crystallizable glass, and passing the belt of crystallizable glass through a crystallization tunnel so as to form a belt of crystallized glass.
摘要翻译：用于制造结晶玻璃板的连续方法包括以下步骤：将原始可结晶玻璃材料熔化以形成熔融玻璃，调节熔融玻璃以具有预定粘度，滚动熔融玻璃以形成可结晶玻璃带，并使可结晶玻璃通过结晶隧道，形成结晶玻璃带。

8. 发明授权

US6080454A Process for producing stained crystallized glass and its articles 失效
标题翻译：生产染色结晶玻璃及其制品的方法
公开(公告)号：US6080454A
公开(公告)日：2000-06-27
申请号：US934650
申请日：1997-09-22
申请人： Kuo-Chuan Hsu , Ching-Hsi Lin , Hsien-Chung Tsai
发明人： Kuo-Chuan Hsu , Ching-Hsi Lin , Hsien-Chung Tsai
IPC分类号： C03B19/06 , C03B32/02 , C03C14/00 , C03B19/09
CPC分类号： C03C14/004 , C03B19/06 , C03B32/02 , C03C2214/08 , C03C2214/20
摘要： A process for producing stained crystallized glass and its articles is provided where crystallized glass is obtained with patterns and colors like that of granites, marble, and other natural stones. The process includes the heat-treatment of a prepared batch of crystallizable glass granules, colored powder and water, at a temperature higher than the softening point of the glass granules resulting in fusion bonding of the glass granules. The colored powder is compounded by an inorganic pigment, a suspension stabilizing agent, an agglomerate, a deflocculant agent, and a crystallizable glass powder. The surface pattern is formed by the grain boundary region of the crystallizable glass granules, and part of the inorganic pigment in the colored powder moving with the crystallizable glass powder.
摘要翻译：提供了一种生产结晶化玻璃及其制品的方法，其中获得了具有花岗岩，大理石和其它天然石材的图案和颜色的结晶玻璃。该方法包括在高于玻璃颗粒的软化点的温度下对制备的可结晶玻璃颗粒，着色粉末和水的批处理进行热处理，导致玻璃颗粒的熔合。着色粉末由无机颜料，悬浮稳定剂，附聚物，抗絮凝剂和可结晶玻璃粉末组成。表面图案由可结晶玻璃颗粒的晶界区域形成，着色粉末中的无机颜料的一部分与可结晶玻璃粉末一起移动。

9. 发明申请

US20120111058A1 Method and Apparatus of Continuously Forming Crystallized Glass 审中-公开
标题翻译：连续形成结晶玻璃的方法和装置
公开(公告)号：US20120111058A1
公开(公告)日：2012-05-10
申请号：US13237855
申请日：2011-09-20
申请人： Kuo-Chuan Hsu , Yanbin Jiang
发明人： Kuo-Chuan Hsu , Yanbin Jiang
IPC分类号： C03B32/02 , C03B21/02 , C03B13/00
CPC分类号： C03B13/04 , C03B25/08 , C03B32/02 , C03C3/097 , C03C10/0027 , Y02P40/57
摘要： One objective of the present invention was to provide a method of continuously forming crystallized glass, so as to reduce the thermal treatment time necessary for crystallizing a belt-shaped glass plate; and to provide an apparatus of continuously forming crystallized glass, so as to shorten the thermal treatment zone necessary for crystallizing a belt-shaped glass plate. A method of continuously forming crystallized glass according to the present invention includes: a melting step of melting a raw glass material to obtain molten glass; a shaping step of rolling the molten glass to form a belt-shaped glass plate; a crystallizing step of retaining the belt-shaped glass plate at a temperature necessary for nuclei formation and crystal growth, thereby forming nuclei and crystallizing the belt-shaped glass plate to a belt-shaped crystallized glass plate, and then slowly cooling the belt-shaped crystallized glass plate; and a cutting step of cutting the belt-shaped crystallized glass plate.
摘要翻译：本发明的一个目的是提供一种连续地形成结晶玻璃的方法，以减少结晶带状玻璃板所需的热处理时间; 并且提供连续地形成结晶化玻璃的装置，以缩短结晶带状玻璃板所需的热处理区域。根据本发明的连续形成结晶玻璃的方法包括：熔化原料玻璃材料以获得熔融玻璃的熔融步骤; 成形步骤，轧制熔融玻璃以形成带状玻璃板; 将带状玻璃板保持在成核和晶体生长所需的温度的结晶步骤，从而形成核并将带状玻璃板结晶成带状结晶玻璃板，然后缓慢冷却带状结晶玻璃板; 以及切割带状结晶玻璃板的切割步骤。

10. 发明申请

US20050016214A1 Continuous method and system for manufacturing a crystallized glass plate 审中-公开
标题翻译：用于制造结晶玻璃板的连续方法和系统
公开(公告)号：US20050016214A1
公开(公告)日：2005-01-27
申请号：US10850124
申请日：2004-05-19
申请人： Kuo-Chuan Hsu , Chien-Liang Tseng , Xun-Geng Wang
发明人： Kuo-Chuan Hsu , Chien-Liang Tseng , Xun-Geng Wang
IPC分类号： C03B17/06 , C03B13/04 , C03B32/02 , C03B33/023 , C03B21/02 , C03C10/00
CPC分类号： C03B33/0235 , C03B13/04 , C03B32/02
摘要： A continuous method for manufacturing crystallized glass plates includes the steps of melting a raw crystallizable glass material to form molten glass, adjusting the molten glass to have a predetermined viscosity, rolling the molten glass to form a belt of crystallizable glass, and passing the belt of crystallizable glass through a crystallization tunnel so as to form a belt of crystallized glass.
摘要翻译：用于制造结晶玻璃板的连续方法包括以下步骤：将原始可结晶玻璃材料熔化以形成熔融玻璃，调节熔融玻璃以具有预定粘度，滚动熔融玻璃以形成可结晶玻璃带，并使可结晶玻璃通过结晶通道形成结晶玻璃带。

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