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1. 发明授权

US07615284B2 Crystallized glass article having patterns and method of producing the same 有权
标题翻译：具有图案的结晶玻璃制品及其制造方法
公开(公告)号：US07615284B2
公开(公告)日：2009-11-10
申请号：US11498463
申请日：2006-08-02
申请人： Kuo-Chuan Hsu
发明人： Kuo-Chuan Hsu
IPC分类号： B32B17/06 , C03C10/04
CPC分类号： C03C10/0036 , C03B19/09 , C03B23/20 , C03B32/02 , C03C10/0045 , C03C2218/345 , Y10T428/24942
摘要： A crystalline glass with a characteristic of precipitating crystals from the surface of the crystalline glass to the interior thereof when it is being heated at a temperature higher than the softening point is used in the invention. A plurality of small crystalline glass masses 12 are accumulated and leveled in a fireproof mold coated with a mold release agent, and two crystalline glass plates 14A and 14B cut in an S shape are placed on the accumulated surface of the small crystalline glass masses 12 with the cut faces tightly bonded. A heat treatment is then performed to obtain a crystallized glass article having patterns. The crystalline glass plate can be cut into any shape to tightly bond the cut faces, and therefore the obtained crystallized glass articles have different patterns like natural-marble-like patterns, human figure patterns, animal patterns, etc. The invention also discloses a method of producing crystallized articles having patterns.
摘要翻译：在本发明中使用具有从结晶玻璃表面析出结晶到其内部的特性的结晶玻璃，当其在高于软化点的温度下被加热时。多个小晶粒玻璃块12在涂有脱模剂的防火模具中堆积并平整，并且将两个切割成S形的晶体玻璃板14A和14B放置在小结晶玻璃块12的积聚表面上，切面紧贴。然后进行热处理以获得具有图案的结晶玻璃制品。结晶玻璃板可以切割成任何形状以紧密地结合切割面，因此所获得的结晶玻璃制品具有不同的图案，如天然大理石样图案，人形图案，动物图案等。本发明还公开了一种方法生产具有图案的结晶物品。

2. 发明申请

US20070048529A1 Crystallized glass article having patterns and method of producing the same 有权
标题翻译：具有图案的结晶玻璃制品及其制造方法
公开(公告)号：US20070048529A1
公开(公告)日：2007-03-01
申请号：US11498463
申请日：2006-08-02
申请人： Kuo-Chuan Hsu
发明人： Kuo-Chuan Hsu
IPC分类号： C03C10/04 , B32B17/06
CPC分类号： C03C10/0036 , C03B19/09 , C03B23/20 , C03B32/02 , C03C10/0045 , C03C2218/345 , Y10T428/24942
摘要： A crystalline glass with a characteristic of precipitating crystals from the surface of the crystalline glass to the interior thereof when it is being heated at a temperature higher than the softening point is used in the invention. A plurality of small crystalline glass masses 12 are accumulated and leveled in a fireproof mold coated with a mold release agent, and two crystalline glass plates 14A and 14B cut in an S shape are placed on the accumulated surface of the small crystalline glass masses 12 with the cut faces tightly bonded. A heat treatment is then performed to obtain a crystallized glass article having patterns. The crystalline glass plate can be cut into any shape to tightly bond the cut faces, and therefore the obtained crystallized glass articles have different patterns like natural-marble-like patterns, human figure patterns, animal patterns, etc. The invention also discloses a method of producing crystallized articles having patterns.
摘要翻译：在本发明中使用具有从结晶玻璃表面析出结晶到其内部的特性的结晶玻璃，当其在高于软化点的温度下被加热时。多个小晶状玻璃块12在涂有脱模剂的防火模具中堆积并平整，并且将两个S形切割的晶体玻璃板14A和14B放置在小晶状玻璃块的积聚表面上 12切割面紧紧贴合。然后进行热处理以获得具有图案的结晶玻璃制品。结晶玻璃板可以切割成任何形状以紧密地结合切割面，因此所获得的结晶玻璃制品具有不同的图案，如天然大理石样图案，人形图案，动物图案等。本发明还公开了一种方法生产具有图案的结晶物品。

3. 发明申请

US20120177893A1 CRYSTALLIZED GLASS ARTICLE HAVING PATTERNS 审中-公开
标题翻译：具有图案的结晶玻璃制品
公开(公告)号：US20120177893A1
公开(公告)日：2012-07-12
申请号：US13310556
申请日：2011-12-02
申请人： Kuo-Chuan Hsu
发明人： Kuo-Chuan Hsu
IPC分类号： B32B3/00
CPC分类号： C03B19/09 , C03B23/203 , C03B32/02 , C03C10/0036 , Y10T428/24802
摘要： A crystallized glass article having patterns outwardly expressing a spotted pattern through precipitating one or more spherical crystallized glass inside a crystallized glass layer. The crystallized glass article having patterns includes a crystallized glass layer A containing at least one main crystal selected from β-wollastonite and diopside crystals, and having a thickness more than 6 mm and less than or equal to 18 mm, and one or more spherical crystallized glass precipitating inside the crystallized glass layer A; and a glass layer B provided in a manner of fusion-bonding on at least a part of at least one surface selected from one horizontal surface and lateral surfaces of the crystallized glass layer A.
摘要翻译：一种结晶玻璃制品，其具有通过在结晶化玻璃层内沉淀一个或多个球形结晶玻璃而向外表示斑点图案的图案。具有图案的结晶化玻璃制品包括含有选自硅砂石和透辉石晶体中的至少一种主晶体并且具有大于6mm且小于或等于18mm的厚度的结晶玻璃层A和一个或多个球形在结晶化玻璃层A内析出的结晶化玻璃; 以及在从结晶化玻璃层A的一个水平面和侧面的至少一个表面的至少一部分表面的至少一部分上进行熔接而形成的玻璃层B.

4. 发明授权

US07913516B2 Crystallized glass article having patterns and method of producing the same 有权
标题翻译：具有图案的结晶玻璃制品及其制造方法
公开(公告)号：US07913516B2
公开(公告)日：2011-03-29
申请号：US12564021
申请日：2009-09-21
申请人： Kuo-Chuan Hsu
发明人： Kuo-Chuan Hsu
IPC分类号： C03B32/00 , B32B17/06 , C03C10/04
CPC分类号： C03C10/0036 , C03B19/09 , C03B23/20 , C03B32/02 , C03C10/0045 , C03C2218/345 , Y10T428/24942
摘要： A crystalline glass with a characteristic of precipitating crystals from the surface of the crystalline glass to the interior thereof when it is being heated at a temperature higher than the softening point is used in the invention. A plurality of small crystalline glass masses 12 are accumulated and leveled in a fireproof mold coated with a mold release agent, and two crystalline glass plates 14A and 14B cut in an S shape are placed on the accumulated surface of the small crystalline glass masses 12 with the cut faces tightly bonded. A heat treatment is then performed to obtain a crystallized glass article having patterns. The crystalline glass plate can be cut into any shape to tightly bond the cut faces, and therefore the obtained crystallized glass articles have different patterns like natural-marble-like patterns, human figure patterns, animal patterns, etc. The invention also discloses a method of producing crystallized articles having patterns.
摘要翻译：在本发明中使用具有从结晶玻璃表面析出结晶到其内部的特性的结晶玻璃，当其在高于软化点的温度下被加热时。多个小晶粒玻璃块12在涂有脱模剂的防火模具中堆积并平整，并且将两个切割成S形的晶体玻璃板14A和14B放置在小结晶玻璃块12的积聚表面上，切面紧贴。然后进行热处理以获得具有图案的结晶玻璃制品。结晶玻璃板可以切割成任何形状以紧密地结合切割面，因此所获得的结晶玻璃制品具有不同的图案，如天然大理石样图案，人体图案，动物图案等。本发明还公开了一种方法生产具有图案的结晶物品。

5. 发明申请

US20100018253A1 CRYSTALLIZED GLASS ARTICLE HAVING PATTERNS AND METHOD OF PRODUCING THE SAME 有权
标题翻译：具有图案的结晶玻璃制品及其制造方法
公开(公告)号：US20100018253A1
公开(公告)日：2010-01-28
申请号：US12564021
申请日：2009-09-21
申请人： Kuo-Chuan Hsu
发明人： Kuo-Chuan Hsu
IPC分类号： C03B32/00
CPC分类号： C03C10/0036 , C03B19/09 , C03B23/20 , C03B32/02 , C03C10/0045 , C03C2218/345 , Y10T428/24942
摘要： A crystalline glass with a characteristic of precipitating crystals from the surface of the crystalline glass to the interior thereof when it is being heated at a temperature higher than the softening point is used in the invention. A plurality of small crystalline glass masses 12 are accumulated and leveled in a fireproof mold coated with a mold release agent, and two crystalline glass plates 14A and 14B cut in an S shape are placed on the accumulated surface of the small crystalline glass masses 12 with the cut faces tightly bonded. A heat treatment is then performed to obtain a crystallized glass article having patterns. The crystalline glass plate can be cut into any shape to tightly bond the cut faces, and therefore the obtained crystallized glass articles have different patterns like natural-marble-like patterns, human figure patterns, animal patterns, etc. The invention also discloses a method of producing crystallized articles having patterns.
摘要翻译：在本发明中使用具有从结晶玻璃表面析出结晶到其内部的特性的结晶玻璃，当其在高于软化点的温度下被加热时。多个小晶粒玻璃块12在涂有脱模剂的防火模具中堆积并平整，并且将两个切割成S形的晶体玻璃板14A和14B放置在小结晶玻璃块12的积聚表面上，切面紧贴。然后进行热处理以获得具有图案的结晶玻璃制品。结晶玻璃板可以切割成任何形状以紧密地结合切割面，因此所获得的结晶玻璃制品具有不同的图案，如天然大理石样图案，人体图案，动物图案等。本发明还公开了一种方法生产具有图案的结晶物品。

6. 发明申请

US20070149379A1 Crystallizable glass and crystallized glass of Li2O-A12O3-SiO2 system and method for producing crystallized glass fo Li2O-A12O3-SiO2 system 审中-公开
标题翻译： Li2O-A12O3-SiO2体系的结晶玻璃和结晶玻璃及其制备Li2O-Al2O3-SiO2体系结晶玻璃的方法
公开(公告)号：US20070149379A1
公开(公告)日：2007-06-28
申请号：US11713322
申请日：2007-03-02
申请人： Kuo-Chuan Hsu , Gan-Cheng Zhang , Chien-Liang Tseng , Zheng-Li Zhang
发明人： Kuo-Chuan Hsu , Gan-Cheng Zhang , Chien-Liang Tseng , Zheng-Li Zhang
IPC分类号： C03C10/14 , C03C10/12
CPC分类号： C03C10/0027 , C03C3/085 , C03C3/097 , C03C3/11 , C03C10/0009
摘要： A crystallizable glass of Li2O—Al2O3—SiO2 system is provided, which can be crystallized by a crystallization process at a lower temperature to produce crystallized glass of Li2O-Al2O3—SiO2 system with excellent thermal characteristics. The crystallizable glass of Li2O—Al2O3—SiO2 system which consists essentially of, by weight percentages, SiO2—58.0˜66.0 wt %; Al2O3—18.0˜26.0 wt %; Li2O—3.5˜5.5 wt %; TiO2—0.5-4.0 wt %; ZrO2—0.5˜3.0 wt % P2O5—0.5˜3.0 wt %; F—0.1˜1.0 wt %; B2O3—0˜2.5 wt %; Na2O—0˜2.0 wt %; K2O—0˜2.0 wt %; MgO—0˜1.0 wt %; ZnO—0.5˜3.0 wt %; BaO—0˜2.5 wt %; SrO—0.3˜3.0 wt % As2O3—0.4˜1.5 wt %; and Sb2O3—0˜1.5 wt %.
摘要翻译：提供了一种Li 2 O 2 Al 3 O 3 -SiO 2系统的可结晶玻璃，其可以是通过在较低温度下的结晶过程结晶以产生Li 2 O 3 Al 2 O 3 -SiO 2的结晶玻璃， / SUB>系统具有优异的热特性。 Li 2 O-Al 2 O 3 -SiO 2体系的可结晶玻璃，其基本上由重量百分比，SiO 2 -58.0〜66.0重量％; Al 2 O 3 -18.0〜26.0重量％; Li 2 O-3.5〜5.5重量％; TiO 2 -0.5-4.0重量％; ZrO 2 -0.5〜3.0重量％P 2 O 5〜0.5〜3.0重量％; F-0.1〜1.0重量％ B 2 O 3 -0-2.5wt％; Na 2 O-0〜2.0重量％; K 2 O-0〜2.0重量％; MgO-0〜1.0重量％ ZnO-0.5〜3.0重量％ BaO-0〜2.5wt％; SrO-0.3〜3.0重量％As 2 N 3 O 3〜0.4〜1.5重量％和Sb 2 O 3 -0〜1.5重量％。

7. 发明授权

US08431498B2 MgO—Al2O3—SiO2-based crystallizable glass and crystallized glass, and manufacturing method thereof 有权
标题翻译： MgO-Al2O3-SiO2系可结晶玻璃和结晶玻璃及其制造方法
公开(公告)号：US08431498B2
公开(公告)日：2013-04-30
申请号：US12911664
申请日：2010-10-25
申请人： Kuo-Chuan Hsu , Chao Qu
发明人： Kuo-Chuan Hsu , Chao Qu
IPC分类号： C03C10/04
CPC分类号： C03C3/112 , C03C1/002 , C03C10/0045 , C03C10/0063
摘要： The invention provides a crystallizable glass, a crystallized glass, and manufacturing methods thereof. The crystallizable glass can be crystallized in a short period of time, and can maintain its glass shape and its surface condition during a crystallization process. The crystallized glass has good mechanical strength, an adequate thermal expansion coefficient that allows the crystallized glass to be used as a construction material, less content of alkali-metal oxides, and good chemical durability. The MgO—Al2O3—SiO2-based crystallizable glass and crystallized glass contain, by mass percent, 55.0-65.0% SiO2, 8.0-14.0% Al2O3, 10.0-20.0% MgO, 1.5-6.0% CaO, 1.0-2.2% Li2O, 0.7-3.0% Na2O, 2.5-4.0% K2O, and 1.5-3.0% F.
摘要翻译：本发明提供一种可结晶玻璃，结晶玻璃及其制造方法。可结晶玻璃可以在短时间内结晶，并且可以在结晶过程中保持其玻璃形状和表面状态。结晶化玻璃具有良好的机械强度，足够的热膨胀系数，允许结晶化玻璃用作构造材料，较少的碱金属氧化物含量和良好的化学耐久性。 MgO-Al 2 O 3 -SiO 2系的可结晶玻璃和结晶化玻璃以质量％计含有55.0-65.0％的SiO 2，8.0〜14.0％的Al 2 O 3，10.0〜2.0％的MgO，1.5〜6.0％的CaO，1.0〜2.2％的Li 2 O，0.7 -3.0％Na2O，2.5-4.0％K2O和1.5-3.0％F。

8. 发明申请

US20120291493A1 CONSECUTIVE MOLDING METHOD FOR CRYSTALLIZED GLASS AND DEVICE THEREOF 审中-公开
标题翻译：用于结晶玻璃的配套成型方法及其装置
公开(公告)号：US20120291493A1
公开(公告)日：2012-11-22
申请号：US13417045
申请日：2012-03-09
申请人： Kuo-Chuan Hsu , Yan-Bin Jiang , Chao Qu
发明人： Kuo-Chuan Hsu , Yan-Bin Jiang , Chao Qu
IPC分类号： C03B20/00 , C03B13/00
CPC分类号： C03B25/08 , C03B5/245 , C03B5/265 , C03B13/04 , C03B32/02 , C03C3/097 , C03C10/0027 , Y02P40/57
摘要： A consecutive molding method for crystallized glass comprises: a process to obtain molten glass by melting glass raw materials; a process to obtain a band-shaped plate glass by roll forming the molten glass; a crystallization process to obtain a band-shaped crystallized glass plate by conducting thermal treatment on the band-shaped plate glass to crystallize it; and a process to cut the band-shaped crystallized glass plate, wherein the crystallization process includes: a process to form crystal nuclei in the band-shaped plate glass by disposing it in the atmosphere of a crystal nucleus-formation temperature and retaining it at the temperature; a process to raise the temperature of the band-shaped plate glass with crystal nuclei to a crystal-growth temperature; a process to retain the band-shaped plate glass with crystal nuclei at the crystal-growth temperature to produce a band-shaped crystallized glass plate; and a process to slowly cool down the band-shaped crystallized glass plate.
摘要翻译：结晶玻璃的连续成型方法包括：通过熔化玻璃原料获得熔融玻璃的方法; 通过辊压成形熔融玻璃获得带状平板玻璃的方法; 通过对带状平板玻璃进行热处理以使其结晶化而获得带状结晶化玻璃板的结晶化方法; 以及切割带状结晶玻璃板的方法，其中结晶方法包括：在带状平板玻璃中通过将其设置在晶核形成温度的气氛中形成晶核的工艺，并将其保持在温度; 将具有晶核的带状平板玻璃的温度升高至晶体生长温度的工序; 在结晶生长温度下保持具有晶核的带状平板玻璃以产生带状结晶玻璃板的工艺; 以及缓慢冷却带状结晶化玻璃板的工序。

9. 发明申请

US20120291492A1 CONSECUTIVE MOLDING METHOD FOR CRYSTALLIZED GLASS AND DEVICE THEREOF 审中-公开
标题翻译：用于结晶玻璃的配套成型方法及其装置
公开(公告)号：US20120291492A1
公开(公告)日：2012-11-22
申请号：US13417036
申请日：2012-03-09
申请人： Kuo-Chuan Hsu , Yan-Bin Jiang , Chao Qu
发明人： Kuo-Chuan Hsu , Yan-Bin Jiang , Chao Qu
IPC分类号： C03B27/012 , C03B13/00
CPC分类号： C03B13/04 , C03B5/245 , C03B5/265 , C03B25/08 , C03B32/02 , C03C3/097 , C03C10/0027 , Y02P40/57
摘要： A consecutive molding method for crystallized glass comprises: a melting process to obtain molten glass by melting glass raw materials; a molding process to obtain a band-shaped plate glass by roll forming the molten glass to become band-shaped; a crystallization process to obtain a band-shaped crystallized glass plate by conducting thermal treatment on the band-shaped plate glass to crystallize it; and a cutting process to cut the band-shaped crystallized glass plate, wherein the crystallization process includes: a temperature-raising process to produce the band-shaped crystallized glass plate by disposing the band-shaped plate glass obtained in the molding process, in the atmosphere of a crystal nucleus-formation temperature and raising the temperature to a crystal-growth temperature or above to grow crystals as well as form crystal nuclei; and a slow-cooling process to slowly cool down the band-shaped crystallized glass plate.
摘要翻译：结晶玻璃的连续成型方法包括：通过熔化玻璃原料获得熔融玻璃的熔融过程; 通过将熔融玻璃辊成型为带状而获得带状平板玻璃的成型方法; 通过对带状平板玻璃进行热处理以使其结晶化而获得带状结晶化玻璃板的结晶化方法; 以及切割带状结晶玻璃板的切割工序，其中结晶工艺包括：通过将在模塑工艺中获得的带状平板玻璃设置在该方法中来生产带状结晶玻璃板的升温过程晶体生成温度的气氛，将温度升高至晶体生长温度以上，生长晶体，形成晶核; 以及缓慢冷却带状结晶玻璃板的缓慢冷却过程。

10. 发明申请

US20060160689A1 Crystallizable glass and crystallized glass of Li2O-A12O3-SiO2 system and method for producing crystallized glass of Li2O-A12O3-SiO2 system 审中-公开
标题翻译： Li2O-A12O3-SiO2体系的结晶玻璃和结晶玻璃以及Li2O-A12O3-SiO2体系结晶玻璃的制备方法
公开(公告)号：US20060160689A1
公开(公告)日：2006-07-20
申请号：US11122891
申请日：2005-05-04
申请人： Kuo-Chuan Hsu , Gan-Cheng Zhang , Chien-Liang Tseng , Zheng-Li Zhang
发明人： Kuo-Chuan Hsu , Gan-Cheng Zhang , Chien-Liang Tseng , Zheng-Li Zhang
IPC分类号： C03C10/12
CPC分类号： C03C10/0027 , C03C3/085 , C03C3/097 , C03C3/11 , C03C10/0009
摘要： A crystallizable glass of Li2O—Al2O3—SiO2 system is provided, which can be crystallized by a crystallization process at a lower temperature to produce crystallized glass of Li2O—Al2O3—SiO2 system with excellent thermal characteristics. The crystallizable glass and crystallized glass of Li2O—Al2O3—SiO2 system consist essentially of, by weight percentages, SiO2 - - - 58.0˜66.0 wt % Al2O3 - - - 18.0˜26.0 wt % ; Li2O - - - 3.5˜5.5 wt %; TiO2 - - - 0.5˜4.0 wt % ; ZrO2 - - - 0.5˜3.0 wt %; P2O5 - - - 0.5˜3.0 wt %; F - - - 0.1˜1.0 wt %; B2O3 - - - 0˜2.5 wt %; Na2O - - - 0˜2.0 wt %; K2O - - - 0˜2.0 wt %; MgO - - - 0˜1.0 wt %; ZnO - - - 0.5˜3.0 wt % ; BaO - - - 0˜2.5 wt % ; SrO - - - 0.3˜3.0 wt % As2O3 - - - 0.4˜1.5 wt % ; and Sb2O3- - - 0˜1.5 wt %. A method for producing a crystallized glass of Li2O—Al2O3—SiO2 system is also provided.
摘要翻译：提供了一种Li 2 O 2 Al 3 O 3 -SiO 2系统的可结晶玻璃，其可以是通过在较低温度下的结晶过程结晶以产生Li 2 O 3 Al 2 O 3 -SiO 2的结晶玻璃， / SUB>系统具有优异的热特性。 Li 2 O 2 Al 3 O 3 Al 2 O 3系统的可结晶玻璃和结晶化玻璃基本上由，重量百分比，SiO 2 - - - 58.0〜66.0％（重量）Al 2 O 3 - - - 18.0〜26.0％（重量）％。 Li 2 O - - 3.5〜5.5wt％; TiO 2 - - - 0.5〜4.0wt％; ZrO 2 - - - 0.5〜3.0wt％; P 2 O 5 - - - 0.5〜3.0wt％; F - - - 0.1〜1.0 wt％; B 2 O 3 - - - 0 - 2.5 wt％; Na 2 O - - - 0〜2.0wt％; K 2 O - - - 0〜2.0wt％; MgO - - - 0〜1.0wt％; ZnO - - - 0.5〜3.0 wt％; BaO - - - 0〜2.5 wt％; SrO - - - 0.3〜3.0％（重量）As 2 O 3 3 - - - 0.4〜1.5％（重量）和Sb 2 O 3 - 0 - 1.5wt％。一种制备Li 2 O 2 Al 2 O 3 -SiO 2系结晶玻璃的方法也是提供。

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