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1. 发明授权

US08975084B2 Determination of cores or building blocks and reconstruction of parent molecules in heavy petroleums and other hydrocarbon resources 有权
标题翻译：核心或建筑物的测定以及重质石油和其他烃类资源中母体分子的重建
公开(公告)号：US08975084B2
公开(公告)日：2015-03-10
申请号：US13167841
申请日：2011-06-24
申请人： Kuangnan Qian , Kathleen E. Edwards , Anthony S. Mennito , Howard Freund
发明人： Kuangnan Qian , Kathleen E. Edwards , Anthony S. Mennito , Howard Freund
IPC分类号： G01N24/00 , H01J49/00
CPC分类号： H01J49/0045 , Y10T436/24
摘要： A method for the determination of the aromatic cores or building blocks of a vacuum resid by controlled fragmentation. Molecules can be generated from these building blocks.
摘要翻译：用于通过受控断裂测定真空残渣的芳香核心或结构单元的方法。可以从这些构建块生成分子。

2. 发明申请

US20120156798A1 DETERMINATION OF CORES OR BUILDING BLOCKS AND RECONSTRUCTION OF PARENT MOLECULES IN HEAVY PETROLEUMS AND OTHER HYDROCARBON RESOURCES 有权
标题翻译：确定重要石油和其他碳氢化合物资源中的核心或建筑物块和重新分配母体分子
公开(公告)号：US20120156798A1
公开(公告)日：2012-06-21
申请号：US13167841
申请日：2011-06-24
申请人： Kuangnan Qian , Kathleen E. Edwards , Anthony S. Mennito , Howard Freund
发明人： Kuangnan Qian , Kathleen E. Edwards , Anthony S. Mennito , Howard Freund
IPC分类号： G01N24/00
CPC分类号： H01J49/0045 , Y10T436/24
摘要： A method for the determination of the aromatic cores or building blocks of a vacuum resid by controlled fragmentation. Molecules can be generated from these building blocks.
摘要翻译：用于通过受控断裂测定真空残渣的芳香核心或结构单元的方法。可以从这些构建块生成分子。

3. 发明授权

US07344889B2 Chemical structural and compositional yields model for predicting hydrocarbon thermolysis products 有权
标题翻译：用于预测碳氢化合物热解产物的化学结构和组成产量模型
公开(公告)号：US07344889B2
公开(公告)日：2008-03-18
申请号：US10426356
申请日：2003-04-30
申请人： Simon R. Kelemen , Howard Freund , Michael Siskin , David J. Curry , Yitian Xiao , William N. Olmstead , Martin L. Gorbaty , A. E. Bence
发明人： Simon R. Kelemen , Howard Freund , Michael Siskin , David J. Curry , Yitian Xiao , William N. Olmstead , Martin L. Gorbaty , A. E. Bence
IPC分类号： G01N33/24
CPC分类号： G01N33/241 , G01N33/2823 , G06F19/702 , G06F19/703
摘要： A method of predicting the composition of hydrocarbon products of a complex carbonaceous material when exposed to specific time and temperature conditions is disclosed. In one embodiment, the material is characterized to obtain elemental, chemical and structural parameters. A representative chemical structure of the material is constructed based on the characterization information. The representative chemical structure is then stochastically expanded to a molecular ensemble chemical structural model that includes heteroatoms. The chemical structural model is coupled to a compositional yield model and the composition of the material products is determined using kinetic modeling. Methods are provided of constructing a chemical structural model of complex carbonaceous material, of coupling a molecular ensemble of chemical structures to a thermal chemical mechanism, of updating an ensemble of chemical structures during the kinetic modeling to reflect chemical reaction products and of eliminating molecules from the system.
摘要翻译：公开了当暴露于特定的时间和温度条件时预测复合碳质材料的烃产物的组成的方法。在一个实施方案中，该材料的特征在于获得元素，化学和结构参数。基于特征信息构建材料的代表性化学结构。然后将代表性的化学结构随机扩展到包括杂原子的分子整体化学结构模型。化学结构模型与组合产量模型耦合，并且使用动力学模型确定材料产物的组成。提供了构建复杂碳质材料的化学结构模型的方法，将化学结构的分子组合耦合到热化学机制，在动力学建模期间更新化学结构的集合以反映化学反应产物并从中消除分子系统。

4. 发明申请

US20090159500A1 Electrodesulfurization of heavy oils 有权
标题翻译：重油的电脱硫
公开(公告)号：US20090159500A1
公开(公告)日：2009-06-25
申请号：US12288564
申请日：2008-10-21
申请人： Mark A. Greaney , Chris A. Wright , Jonathan M. McConnachie , Howard Freund , Kun Wang
发明人： Mark A. Greaney , Chris A. Wright , Jonathan M. McConnachie , Howard Freund , Kun Wang
IPC分类号： C10G45/00
CPC分类号： C10G32/02
摘要： The electrodesulfurization of heavy oils wherein a feedstream comprised of bitumen or heavy oil is conducted, along with an effective amount of hydrogen, to an electrochemical cell. A current is applied to the cell wherein sulfur from the feedstream combines with hydrogen to form hydrogen sulfide which is removed.
摘要翻译：其中将由沥青或重油组成的原料流连同有效量的氢气一起进行到电化学电池的重油的硫化。将电流施加到电池，其中来自进料流的硫与氢结合以形成除去的硫化氢。

5. 发明授权

US4407206A Partial combustion process for coal 失效
标题翻译：煤的部分燃烧过程
公开(公告)号：US4407206A
公开(公告)日：1983-10-04
申请号：US376725
申请日：1982-05-10
申请人： William Bartok , Howard Freund
发明人： William Bartok , Howard Freund
IPC分类号： F23C6/04 , F23D1/00
CPC分类号： F23C6/04 , F23B5/04
摘要： Disclosed is a process for combusting coal containing more than 1 wt. % sulfur which process comprises (a) providing a coal containing more than 1 wt. % sulfur and containing an organically bound calcium to sulfur ratio of at least about 0.8 to 1, (b) burning the coal to about 80% to 95% carbon conversion at temperatures greater than about 1,100.degree. C. in a first combustion zone in the presence of an oxidizing agent but under reducing conditions such that the equivalence ratio of coal to oxidizing agent is less than 1.5 but greater than or equal to 1.0, (c) separating the resulting solid effluent from the gaseous effluent from the first combustion zone, and (d) burning the gaseous effluent at a temperature from about 1,000.degree. C. to about 1,500.degree. C. in a second combustion zone under oxidizing conditions. A substantial amount of the sulfur of the coal is captured in the resulting solid effluent.
摘要翻译：公开了一种燃烧含有大于1wt。％硫，该方法包括（a）提供含有大于1重量％％硫并且含有至少约0.8至1的有机结合的钙与硫的比例，（b）在第一燃烧区中在大于约1100℃的温度下将煤燃烧至约80％至95％的碳转化率存在氧化剂但在还原条件下使得煤与氧化剂的当量比小于1.5但大于或等于1.0，（c）将得到的固体流出物与来自第一燃烧区的气态流出物分离，以及（d）在氧化条件下，在第二燃烧区，在约1000℃至约1500℃的温度下燃烧气态流出物。在生成的固体流出物中捕获大量的硫。

6. 发明授权

US08361311B2 Integrated vacuum resid to chemicals conversion process 失效
公开(公告)号：US08361311B2
公开(公告)日：2013-01-29
申请号：US12833485
申请日：2010-07-09
申请人： S. Mark Davis , Larry Lee Iaccino , Richard C. Stell , Steven E. Silverberg , Jiunn-Shyan Liou , Howard Freund
发明人： S. Mark Davis , Larry Lee Iaccino , Richard C. Stell , Steven E. Silverberg , Jiunn-Shyan Liou , Howard Freund
IPC分类号： C10G9/28
CPC分类号： B01J19/0053 , C10B55/10 , C10B57/04 , C10B57/06 , C10G9/36 , C10G11/18 , C10G2300/1077 , C10G2300/203 , C10G2300/206 , C10G2300/301 , C10G2300/4006 , C10G2300/807 , C10G2400/20 , C10J3/463 , C10J3/482 , C10J2300/0943 , C10J2300/0956 , C10J2300/0973
摘要： A process and apparatus for cracking a hydrocarbon feed containing resid, comprising: heating a hydrocarbon feedstock containing resid; passing said heated hydrocarbon feedstock to a vapor/liquid separator; flashing said heated hydrocarbon feedstock in said vapor/liquid separator to form a vapor phase and a liquid phase containing said resid; passing at least a portion of said resid-containing liquid phase from said vapor/liquid separator to a thermal conversion reactor operating at 649° C. or more, wherein the thermal conversion reactor contains coke particles; and converting at least a portion of said resid into olefins.

7. 发明授权

US08613852B2 Process for producing a high stability desulfurized heavy oils stream 有权
标题翻译：生产高稳定性脱硫重油料流的方法
公开(公告)号：US08613852B2
公开(公告)日：2013-12-24
申请号：US12967437
申请日：2010-12-14
申请人： Daniel P. Leta , Walter D. Vann , David T. Ferrughelli , Eric B. Sirota , Howard Freund
发明人： Daniel P. Leta , Walter D. Vann , David T. Ferrughelli , Eric B. Sirota , Howard Freund
IPC分类号： C10G19/00 , C10G19/073 , C10G19/08
CPC分类号： C10G29/06 , C10G9/00 , C10G19/02 , C10G31/08
摘要： Self-compatible heavy oil streams are produced from converted and/or desulfurized fractions. In a preferred embodiment, an incompatibility stream is added to the converted and/or desulfurized stream to reduce the solubility number of the stream. After using a water wash to remove incompatible material, a lighter fraction is removed from the stream to increase the solubility number.
摘要翻译：自相容重油流由转化和/或脱硫馏分生产。在优选的实施方案中，将不相容物流加入转化和/或脱硫的流中以降低流的溶解度。在使用水洗以除去不相容材料后，从流中除去较轻馏分以增加溶解度数。

8. 发明授权

US08075762B2 Electrodesulfurization of heavy oils 有权
标题翻译：重油的电脱硫
公开(公告)号：US08075762B2
公开(公告)日：2011-12-13
申请号：US12288564
申请日：2008-10-21
申请人： Mark A. Greaney , Chris A. Wright , Jonathan M. McConnachie , Howard Freund , Kun Wang
发明人： Mark A. Greaney , Chris A. Wright , Jonathan M. McConnachie , Howard Freund , Kun Wang
IPC分类号： C10G45/00
CPC分类号： C10G32/02
摘要： The electrodesulfurization of heavy oils wherein a feedstream comprised of bitumen or heavy oil is conducted, along with an effective amount of hydrogen, to an electrochemical cell. A current is applied to the cell wherein sulfur from the feedstream combines with hydrogen to form hydrogen sulfide which is removed.
摘要翻译：其中将由沥青或重油组成的原料流连同有效量的氢气一起进行到电化学电池的重油的硫化。将电流施加到电池，其中来自进料流的硫与氢结合以形成除去的硫化氢。

9. 发明授权

US4468231A Cation ion exchange of coal 失效
标题翻译：阳离子交换煤
公开(公告)号：US4468231A
公开(公告)日：1984-08-28
申请号：US373883
申请日：1982-05-03
申请人： William Bartok , Howard Freund , Ronald Liotta
发明人： William Bartok , Howard Freund , Ronald Liotta
IPC分类号： C10L9/02 , C10L9/06
CPC分类号： C10L9/02 , Y10S44/905
摘要： Disclosed is a one-step ion-exchange method for organically bonding alkali and alkaline-earth metals onto coal. The method comprises contacting the coal, at a temperature from about 20.degree. C. to about 100.degree. C. with, (a) an aqueous solution containing cations of one or more metals selected from the group consisting of alkali and alkaline-earth metals, and (b) an oxidizing gas.
摘要翻译：公开了一种用于将碱金属和碱土金属有机结合到煤上的一步离子交换方法。该方法包括在约20℃至约100℃的温度下接触煤，（a）含有一种或多种选自碱金属和碱土金属的金属的阳离子的水溶液，和（b）氧化气体。

10. 发明授权

US09056297B2 Integrated vacuum resid to chemicals conversion process 有权
标题翻译：集成减压渣油到化学品转化过程中
公开(公告)号：US09056297B2
公开(公告)日：2015-06-16
申请号：US13723591
申请日：2012-12-21
申请人： S. Mark Davis , Larry L. Iaccino , Richard C. Stell , Steven E. Silverberg , Jiunn-Shyan Liou , Howard Freund
发明人： S. Mark Davis , Larry L. Iaccino , Richard C. Stell , Steven E. Silverberg , Jiunn-Shyan Liou , Howard Freund
IPC分类号： B01J19/00 , C10B55/10 , C10B57/04 , C10B57/06 , C10G11/18 , C10J3/48 , B01J19/24 , B01J8/18 , C10G9/34 , C10G9/36 , C10J3/46
CPC分类号： B01J19/0053 , C10B55/10 , C10B57/04 , C10B57/06 , C10G9/36 , C10G11/18 , C10G2300/1077 , C10G2300/203 , C10G2300/206 , C10G2300/301 , C10G2300/4006 , C10G2300/807 , C10G2400/20 , C10J3/463 , C10J3/482 , C10J2300/0943 , C10J2300/0956 , C10J2300/0973
摘要： A process and apparatus for cracking a hydrocarbon feed containing resid, comprising: heating a hydrocarbon feedstock containing resid; passing said heated hydrocarbon feedstock to a vapor/liquid separator; flashing said heated hydrocarbon feedstock in said vapor/liquid separator to form a vapor phase and a liquid phase containing said resid; passing at least a portion of said resid-containing liquid phase from said vapor/liquid separator to a thermal conversion reactor operating at 649° C. or more, wherein the thermal conversion reactor contains coke particles; and converting at least a portion of said resid into olefins.
摘要翻译：一种用于裂化含有渣油的烃进料的方法和装置，包括：加热含有残渣的烃原料; 将所述加热的烃原料通入气/液分离器; 在所述气/液分离器中闪蒸所述加热的烃原料以形成含有所述残渣的气相和液相; 将来自所述蒸汽/液体分离器的至少一部分所述残留液体相转移到在649℃或更高温度下操作的热转化反应器，其中所述热转化反应器含有焦炭颗粒; 以及将所述残留物的至少一部分转化为烯烃。

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