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1. 发明申请

US20050143546A1 Processes based on atom (or group) transfer radical polymerization and novel (co)polymers having useful structures and properties 失效
标题翻译：基于原子（或基团）转移自由基聚合的方法和具有有用结构和性质的新型（共）聚合物
公开(公告)号：US20050143546A1
公开(公告)日：2005-06-30
申请号：US11059217
申请日：2005-02-16
申请人： Krzysztof Matyjaszewski , Simion Coca , Scott Gaynor , Dorota Greszta , Timothy Patten , Jin-Shan Wang , Jianhui Xia
发明人： Krzysztof Matyjaszewski , Simion Coca , Scott Gaynor , Dorota Greszta , Timothy Patten , Jin-Shan Wang , Jianhui Xia
IPC分类号： C08F4/00 , C08F4/06 , C08F4/40 , C08F4/44 , C08F4/50 , C08F12/08 , C08F16/18 , C08F20/00 , C08F110/10 , C08F257/02 , C08F265/00 , C08F265/04 , C08F271/02 , C08F291/00 , C08F293/00 , C08F297/00 , C08F210/00 , C08F212/06
CPC分类号： C08F271/02 , C08F4/00 , C08F4/40 , C08F110/10 , C08F257/02 , C08F265/00 , C08F265/04 , C08F291/00 , C08F293/005 , C08F2438/01
摘要： Improved processes for atom (or group) transfer radical polymerization (ATRP) and novel polymers have been developed and are described. In certain embodiments, novel copolymers comprising a least one polymeric branch or polymeric block with a predominantly alternating monomer sequence are described. Novel copolymers comprising a least one polymeric branch or polymeric block with a gradient monomer structure are described. Additionally, novel copolymers comprising a least one polymeric branch or polymeric block with a predominantly periodic monomer sequence are also described. Novel copolymers having a water soluble backbone and at least two hydrophobic polymeric branches grafted to the water soluble backbone are also described.
摘要翻译：已经开发并描述了原子（或基团）转移自由基聚合（ATRP）和新型聚合物的改进方法。在某些实施方案中，描述了包含具有主要交替的单体序列的至少一个聚合物分支或聚合物嵌段的新型共聚物。描述了包含具有梯度单体结构的至少一个聚合物分支或聚合物嵌段的新型共聚物。此外，还描述了包含具有主要为周期性单体序列的至少一个聚合物分支或聚合物嵌段的新型共聚物。还描述了具有水溶性主链和接枝到水溶性主链上的至少两个疏水性聚合物分子的新型共聚物。

2. 发明授权

US5763548A (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization 失效
标题翻译：（Co）聚合物和基于原子（或基团）转移自由基聚合的新型聚合方法
公开(公告)号：US5763548A
公开(公告)日：1998-06-09
申请号：US414415
申请日：1995-03-31
申请人： Krzysztof Matyjaszewski , Jin-Shan Wang
发明人： Krzysztof Matyjaszewski , Jin-Shan Wang
IPC分类号： C08F2/38 , C08F4/00 , C08F4/06 , C08F4/40 , C08F12/08 , C08F20/10 , C08F136/08 , C08F291/00 , C08F293/00 , C08F297/00 , C08L51/00 , C08L53/00 , C09D151/00 , C09D153/00 , C09J151/00 , C09J153/00
CPC分类号： C08F4/40 , C08F136/08 , C08F2/38 , C08F291/00 , C08F293/00 , C08F293/005 , C08F297/00 , C08F4/00 , C08L51/003 , C08L53/00 , C09D151/003 , C09D153/00 , C09J151/003 , C09J153/00 , C08F2438/01 , Y10S526/901
摘要： A new polymerization process (atom transfer radical polymerization, or ATRP) based on a redox reaction between a transition metal (e.g., Cu(I)/Cu(II), provides "living" or controlled radical polymerization of styrene, (meth)acrylates, and other radically polymerizable monomers. Using various simple organic halides as model halogen atom transfer precursors (initiators) and transition metal complexes as a model halogen atom transfer promoters (catalysts), a "living" radical polymerization affords (co)polymers having the predetermined number average molecular weight by .DELTA.�M!/�I!.sub.0 (up to M.sub.n >10.sup.5) and a surprisingly narrow molecular weight distribution (M.sub.w /M.sub.n), as low as 1.15. The participation of free radical intermediates in ATRP is supported by end-group analysis and stereochemistry of the polymerization. In addition, polymers with various topologies (e.g., block, random, star, graft, hyperbranched, dendritic end-functional and in-chain functional copolymers �for example, of styrene and methyl (meth)acrylate!) have been synthesized using the present process. The Polymeric products encompassed by the present invention can be widely used as plastics, elastomers, adhesives, emulsifiers, thermoplastic elastomers, etc.
摘要翻译：基于过渡金属（例如Cu（I）/ Cu（II））之间的氧化还原反应的新的聚合方法（原子转移自由基聚合或ATRP）提供苯乙烯，（甲基）丙烯酸酯的“活性”或受控自由基聚合使用各种简单的有机卤化物作为模型卤素原子转移前体（引发剂）和过渡金属络合物作为模型卤素原子转移促进剂（催化剂），“活性”自由基聚合提供具有预定的数均分子量由DELTA [M] / [I] 0（高达Mn> 105）和惊人的窄分子量分布（Mw / Mn）低至1.15。自由基中间体在ATRP中的参与由此外，具有各种拓扑结构的聚合物（例如嵌段，无规，星形，接枝，超支化，树枝状末端官能团和链内官能团共聚物[例如苯乙烯a nd甲基（甲基）丙烯酸甲酯]）。本发明包括的聚合物可广泛用作塑料，弹性体，粘合剂，乳化剂，热塑性弹性体等。

3. 发明授权

US06624263B2 (Co) polymers and a novel polymerization process based on atom (or group) transfer radical polymerization 失效
标题翻译：（Co）聚合物和基于原子（或基团）转移自由基聚合的新型聚合方法
公开(公告)号：US06624263B2
公开(公告)日：2003-09-23
申请号：US10098052
申请日：2002-03-13
申请人： Krzysztof Matyjaszewski , Jin-Shan Wang
发明人： Krzysztof Matyjaszewski , Jin-Shan Wang
IPC分类号： C08F442
CPC分类号： C08F4/40 , C08F2/38 , C08F4/00 , C08F136/08 , C08F291/00 , C08F293/00 , C08F293/005 , C08F297/00 , C08F2438/01 , C08L51/003 , C08L53/00 , C09D151/003 , C09D153/00 , C09J151/003 , C09J153/00 , Y10S526/901 , C08F4/10
摘要： A new polymerization process (atom transfer radical polymerization, or ATRP) based on a redox reaction between a transition metal (e.g., Cu(I)/Cu(II), provides “living” or controlled radical polymerization of styrene, (meth)acrylates, and other radically polymerizable monomers. Using various simple organic halides as model halogen atom transfer precursors (initiators) and transition metal complexes as a model halogen atom transfer promoters (catalysts), a “living” radical polymerization affords (co)polymers having the predetermined number average molecular weight by &Dgr;[M]/[I]0 (up to Mn>105) and a surprisingly narrow molecular weight distribution (Mw/Mn), as low as 1.15. The participation of free radical intermediates in ATRP is supported by end-group analysis and stereochemistry of the polymerization. In addition, polymers with various topologies (e.g., block, random, star, end-functional and in-chain functional copolymers [for example, of styrene and methyl (meth)acrylate]) have been synthesized using the present process. The polymeric products encompassed by the present invention can be widely used as plastics, elastomers, adhesives, emulsifiers, thermoplastic elastomers, etc.
摘要翻译：基于过渡金属（例如Cu（I）/ Cu（II））之间的氧化还原反应的新的聚合方法（原子转移自由基聚合或ATRP）提供苯乙烯，（甲基）丙烯酸酯的“活性”或受控自由基聚合使用各种简单的有机卤化物作为模型卤素原子转移前体（引发剂）和过渡金属络合物作为模型卤素原子转移促进剂（催化剂），“活性”自由基聚合提供具有预定的数均分子量为Delta [M] / [I] 0（达到Mn> 10 5），令人惊讶的窄分子量分布（Mw / Mn）低至1.15。自由基中间体参与ATRP 此外，具有各种拓扑结构的聚合物（例如嵌段，无规，星形，末端官能和链内官能团共聚物[例如苯乙烯和（甲基）丙烯酸甲酯） ]）使用本方法合成。本发明包括的聚合物可广泛用作塑料，弹性体，粘合剂，乳化剂，热塑性弹性体等。

4. 发明授权

US06407187B1 (Co)polymers and a novel polymerization process based on atom (or group) transfer radical polymerization 失效
标题翻译：（Co）聚合物和基于原子（或基团）转移自由基聚合的新型聚合方法
公开(公告)号：US06407187B1
公开(公告)日：2002-06-18
申请号：US09034187
申请日：1998-03-03
申请人： Krzysztof Matyjaszewski , Jin-Shan Wang
发明人： Krzysztof Matyjaszewski , Jin-Shan Wang
IPC分类号： C08F238
CPC分类号： C08F4/40 , C08F2/38 , C08F4/00 , C08F136/08 , C08F291/00 , C08F293/00 , C08F293/005 , C08F297/00 , C08F2438/01 , C08L51/003 , C08L53/00 , C09D151/003 , C09D153/00 , C09J151/003 , C09J153/00 , Y10S526/901 , C08F4/10
摘要： A new polymerization process (atom transfer radical polymerization, or ATRP) based on a redox reaction between a transition metal (e.g., Cu(I)/Cu(II), provides “living” or controlled radical polymerization of styrene, (meth)acrylates, and other radically polymerizable monomers. Using various simple organic halides as model halogen atom transfer precursors (initiators) and transition metal complexes as a model halogen atom transfer promoters (catalysts), a “living” radical polymerization affords (co)polymers having the predetermined number average molecular weight by &Dgr;[M]/[I]0 (up to Mn>105) and a surprisingly narrow molecular weight distribution (Mw/Mn), as low as 1.15. The participation of free radical intermediates in ATRP is supported by end-group analysis and stereochemistry of the polymerization. In addition, polymers with various topologies (e.g., block, random, star, end-functional and in-chain functional copolymers [for example, of styrene and methyl (meth)acrylate]) have been synthesized using the present process. The polymeric products encompassed by the present invention can be widely used as plastics, elastomers, adhesives, emulsifiers, thermoplastic elastomers, etc.
摘要翻译：基于过渡金属（例如Cu（I）/ Cu（II））之间的氧化还原反应的新的聚合方法（原子转移自由基聚合或ATRP）提供苯乙烯，（甲基）丙烯酸酯的“活性”或受控自由基聚合使用各种简单的有机卤化物作为模型卤素原子转移前体（引发剂）和过渡金属络合物作为模型卤素原子转移促进剂（催化剂），“活性”自由基聚合提供具有预定的数均分子量由DELTA [M] / [I] 0（高达Mn> 105）和惊人的窄分子量分布（Mw / Mn）低至1.15。自由基中间体在ATRP中的参与由此外，具有各种拓扑结构的聚合物（例如嵌段，无规，星形，末端官能和链内功能性共聚物[例如苯乙烯和（甲基）丙烯酸甲酯]）具有 b 使用本方法合成een。本发明包括的聚合物可广泛用作塑料，弹性体，粘合剂，乳化剂，热塑性弹性体等。

5. 发明授权

US07572874B2 Processes based on atom (or group) transfer radical polymerization and novel (co)polymers having useful structures and properties 失效
标题翻译：基于原子（或基团）转移自由基聚合的方法和具有有用结构和性质的新型（共）聚合物
公开(公告)号：US07572874B2
公开(公告)日：2009-08-11
申请号：US11059217
申请日：2005-02-16
申请人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Dorota Greszta , Timothy E. Patten , Jin-Shan Wang , Jianhui Xia
发明人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Dorota Greszta , Timothy E. Patten , Jin-Shan Wang , Jianhui Xia
IPC分类号： C08F210/00 , C08F210/10 , C08F216/12 , C08F216/36 , C08F220/02 , C08F220/42
CPC分类号： C08F271/02 , C08F4/00 , C08F4/40 , C08F110/10 , C08F257/02 , C08F265/00 , C08F265/04 , C08F291/00 , C08F293/005 , C08F2438/01
摘要： Improved processes for atom (or group) transfer radical polymerization (ATRP) and novel polymers have been developed and are described. In certain embodiments, novel copolymers comprising a least one polymeric branch or polymeric block with a predominantly alternating monomer sequence are described. Novel copolymers comprising a least one polymeric branch or polymeric block with a gradient monomer structure are described. Additionally, novel copolymers comprising a least one polymeric branch or polymeric block with a predominantly periodic monomer sequence are also described. Novel copolymers having a water soluble backbone and at least two hydrophobic polymeric branches grafted to the water soluble backbone are also described.
摘要翻译：已经开发并描述了原子（或基团）转移自由基聚合（ATRP）和新型聚合物的改进方法。在某些实施方案中，描述了包含具有主要交替的单体序列的至少一个聚合物分支或聚合物嵌段的新型共聚物。描述了包含具有梯度单体结构的至少一个聚合物分支或聚合物嵌段的新型共聚物。此外，还描述了包含具有主要为周期性单体序列的至少一个聚合物分支或聚合物嵌段的新型共聚物。还描述了具有水溶性主链和接枝到水溶性主链上的至少两个疏水性聚合物分子的新型共聚物。

6. 发明授权

US5807937A Processes based on atom (or group) transfer radical polymerization and novel (co) polymers having useful structures and properties 失效
标题翻译：基于原子（或基团）转移自由基聚合的方法和具有有用结构和性质的新型（共）聚合物
公开(公告)号：US5807937A
公开(公告)日：1998-09-15
申请号：US559309
申请日：1995-11-15
申请人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Dorota Greszta , Timothy E. Patten , Jin-Shan Wang , Jianhui Xia
发明人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Dorota Greszta , Timothy E. Patten , Jin-Shan Wang , Jianhui Xia
IPC分类号： C08F4/00 , C08F4/06 , C08F4/40 , C08F4/44 , C08F4/50 , C08F12/08 , C08F16/18 , C08F20/00 , C08F110/10 , C08F257/02 , C08F265/00 , C08F265/04 , C08F271/02 , C08F291/00 , C08F293/00 , C08F297/00
CPC分类号： C08F271/02 , C08F110/10 , C08F257/02 , C08F265/00 , C08F265/04 , C08F291/00 , C08F293/005 , C08F4/00 , C08F4/40 , C08F2438/01
摘要： Improved processes have been developed for atom (or group) transfer radical polymerization (ATRP). In one improvement, the ATRP process involves polymerizing in the presence of a (partially) free radical-deactivating amount of the corresponding reduced or oxidized transition metal compound. In a further improvement, the ATRP process involves polymerizing in a homogeneous system or in the presence of a solubilized initiating/catalytic system. The present invention also concerns end-functional, site-specific functional and telechelic homopolymers and copolymers; block, random, graft, alternating and tapered (or "gradient") copolymers which may have certain properties or a certain novel structure; star, comb and "hyperbranched" polymers and copolymers; multi-functional hyperbranched, end-functional polymers; cross-linked polymers and gels; water-soluble polymers and hydrogels (e.g., a copolymer prepared by radical copolymerization of a water-soluble monomer and a divinyl monomer); and an ATRP process using water as a medium.
摘要翻译：已经开发了用于原子（或基团）转移自由基聚合（ATRP）的改进方法。在一个改进中，ATRP方法包括在（部分）游离基失活量的相应还原或氧化的过渡金属化合物的存在下聚合。在进一步的改进中，ATRP方法包括在均相体系中或在溶解的引发/催化体系存在下进行聚合。本发明还涉及终端功能，位点特异性功能和遥爪均聚物和共聚物; 嵌段，随机，接枝，交替和渐缩（或“梯度”）共聚物，其可以具有某些性质或某种新颖结构; 星形，梳状和“超支化”聚合物和共聚物; 多功能超支化，末端官能聚合物; 交联聚合物和凝胶; 水溶性聚合物和水凝胶（例如，通过水溶性单体和二乙烯基单体的自由基共聚制备的共聚物）; 和使用水作为介质的ATRP方法。

7. 发明授权

US06887962B2 Processes based on atom (or group) transfer radical polymerization and novel (co)polymers having useful structures and properties 失效
公开(公告)号：US06887962B2
公开(公告)日：2005-05-03
申请号：US10289545
申请日：2002-11-07
申请人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Dorota Greszta , Timothy E. Patten , Jin-Shan Wang , Jianhui Xia
发明人： Krzysztof Matyjaszewski , Simion Coca , Scott G. Gaynor , Dorota Greszta , Timothy E. Patten , Jin-Shan Wang , Jianhui Xia
IPC分类号： C08F4/00 , C08F4/06 , C08F4/40 , C08F4/44 , C08F4/50 , C08F12/08 , C08F16/18 , C08F20/00 , C08F110/10 , C08F257/02 , C08F265/00 , C08F265/04 , C08F271/02 , C08F291/00 , C08F293/00 , C08F297/00 , C08F210/10 , C08F212/08 , C08F220/12 , C08F220/44
CPC分类号： C08F271/02 , C08F4/00 , C08F4/40 , C08F110/10 , C08F257/02 , C08F265/00 , C08F265/04 , C08F291/00 , C08F293/005 , C08F2438/01
摘要： Improved processes for atom (or group) transfer radical polymerization (ATRP) and novel polymers have been developed and are described. In certain embodiments, novel copolymers comprising a least one polymeric branch or polymeric block with a predominantly alternating monomer sequence are described. Novel copolymers comprising a least one polymeric branch or polymeric block with a gradient monomer structure are described. Additionally, novel copolymers comprising a least one polymeric branch or polymeric block with a predominantly periodic monomer sequence are also described. Novel copolymers having a water soluble backbone and at least two hydrophobic polymeric branches grafted to the water soluble backbone are also described.

8. 发明申请

US20050090632A1 Noel (co) polymers and a novel polymerization process based on atom (or group) transfer radical polymerization 审中-公开
标题翻译： Noel（共）聚合物和基于原子（或基团）转移自由基聚合的新型聚合方法
公开(公告)号：US20050090632A1
公开(公告)日：2005-04-28
申请号：US10992249
申请日：2004-11-18
申请人： Krzysztof Matyjaszewski , Jin-Shan Wang
发明人： Krzysztof Matyjaszewski , Jin-Shan Wang
IPC分类号： C08F4/00 , C08F136/08 , C08F293/00 , C08L51/00 , C08L53/00 , C09D151/00 , C09D153/00 , C09J151/00 , C09J153/00
CPC分类号： C09J153/00 , C08F4/00 , C08F136/08 , C08F293/005 , C08F2438/01 , C08L51/003 , C08L53/00 , C09D151/003 , C09D153/00 , C09J151/003 , C08F4/10
摘要： A new polymerization process (atom transfer radical polymerization, or ATRP) based on a redox reaction between a transition metal (e.g., Cu(I)/Cu(II), provides “living” or controlled radical polymerization of styrene, (meth)acrylates, and other radically polymerizable monomers. Using various simple organic halides as model halogen atom transfer precursors (initiators) and transition metal complexes as a model halogen atom transfer promoters (catalysts), a “living” radical polymerization affords (co)polymers having the predetermined number average molecular weight by Δ[M]/[I]0 (up to Mn>105) and a surprisingly narrow molecular weight distribution (Mw/Mn), as low as 1.15. The participation of free radical intermediates in ATRP is supported by end-group analysis and stereochemistry of the polymerization. In addition, polymers with various topologies (e.g., block, random, star, end-functional and in-chain functional copolymers [for example, of styrene and methyl (meth)acrylate]) have been synthesized using the present process. The polymeric products encompassed by the present invention can be widely used as plastics, elastomers, adhesives, emulsifiers, thermoplastic elastomers, etc.
摘要翻译：基于过渡金属（例如Cu（I）/ Cu（II））之间的氧化还原反应的新的聚合方法（原子转移自由基聚合或ATRP）提供苯乙烯，（甲基）丙烯酸酯的“活性”或受控自由基聚合使用各种简单的有机卤化物作为模型卤素原子转移前体（引发剂）和过渡金属络合物作为模型卤素原子转移促进剂（催化剂），“活性”自由基聚合提供具有预定的数均分子量为Δ[M] / [I] <0>（至多为M <10> 5），令人惊奇的分子量自由基中间体在ATRP中的参与由聚合的端基分析和立体化学支持而得到支持，其中，分子量分布（M> / M>>）低至1.15。此外，具有各种拓扑结构的聚合物（例如嵌段，无规，星形，末端官能和链内官能团共聚物[ 或者例如苯乙烯和（甲基）丙烯酸甲酯]）。本发明包括的聚合物可广泛用作塑料，弹性体，粘合剂，乳化剂，热塑性弹性体等。

9. 发明授权

US08969498B2 Compositions and method of inhibiting polymerization of vinyl-aryl monomers 有权
标题翻译：抑制乙烯基 - 芳基单体聚合的组合物和方法
公开(公告)号：US08969498B2
公开(公告)日：2015-03-03
申请号：US13811574
申请日：2011-07-27
申请人： Nathan T. Kendall , Kishore K. Kar , Mark H. McAdon , Krzysztof Matyjaszewski , Laura Mueller , Charles D. Dukes
发明人： Nathan T. Kendall , Kishore K. Kar , Mark H. McAdon , Krzysztof Matyjaszewski , Laura Mueller , Charles D. Dukes
IPC分类号： C07C7/20 , C08F2/40 , C08F2/00 , C08F12/08 , C08F12/36
CPC分类号： C07C7/20 , C08F2/00 , C08F12/08 , C08F12/36 , C08F2/40 , C07C15/46 , C07C15/44
摘要： The invention generally relates to a method of inhibiting polymerization of vinyl aryl monomers, a process for increasing number average molecular weight of a polystyrene, and to an inhibitor composition useful therein.
摘要翻译：本发明一般涉及一种抑制乙烯基芳基单体的聚合的方法，一种增加聚苯乙烯的数均分子量的方法以及其中可用的抑制剂组合物。

10. 发明申请

US20140275420A1 ATOM TRANSFER RADICAL POLYMERIZATION UNDER BIOLOGICALLY COMPATIBLE CONDITIONS 审中-公开
标题翻译：在生物兼容条件下进行原子转移自由基聚合
公开(公告)号：US20140275420A1
公开(公告)日：2014-09-18
申请号：US14239181
申请日：2012-08-22
申请人： Krzysztof Matyjaszewski , Saadyah E. Averick , Antonina Simakova
发明人： Krzysztof Matyjaszewski , Saadyah E. Averick , Antonina Simakova
IPC分类号： C08F289/00
CPC分类号： C07K1/1077 , A61K47/60 , C07K14/43595 , C07K14/765 , C08F283/06 , C08F289/00 , C08G81/025
摘要： Methods for conducting controlled grafting-from radical polymerizations from biomolecules under conditions that are biologically compatible are described. The methods provide biomolecule-polymer conjugates with highly controlled structures and narrow polydispersities under aqueous reaction conditions and biological temperatures. Biomolecules, such as proteins and nucleotides can be conjugated to polymers with high levels of control.
摘要翻译：描述了在生物相容性条件下从生物分子的自由基聚合进行受控接枝的方法。该方法在水性反应条件和生物温度下提供具有高度受控结构和窄多分散性的生物分子 - 聚合物共轭物。生物分子，如蛋白质和核苷酸可以与高度控制的聚合物缀合。

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