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    • 2. 发明授权
    • Magnetic recording medium having a specified binder system
    • 具有指定粘合剂体系的磁记录介质
    • US5607772A
    • 1997-03-04
    • US401705
    • 1995-03-10
    • Masahiro YamakawaKenji AkimotoKatsuya NakamuraFumio TakanoTakahiro Takasaki
    • Masahiro YamakawaKenji AkimotoKatsuya NakamuraFumio TakanoTakahiro Takasaki
    • C08G18/08C08G18/10C08G18/86G11B5/702
    • G11B5/7022C08G18/0804C08G18/10C08G18/86G11B5/7021Y10S428/90Y10T428/31609Y10T428/31935Y10T428/31938
    • A binder for coating materials containing dispersed inorganic powder comprises a polyurethane resin containing (a) 2.2 to 7.0 terminal epoxy groups in one molecule in average and (b) 0.1 to 5.0% by weight as SO.sub.3 -- of a sulfonic acid salt group, 0.05 to 3.0% by weight as COO-- of a carboxylic acid salt group, or 0.02 to 1.0% by weight as N.sup.+ of a quaternary ammonium salt group in the molecule, and having a number-average molecular weight of 2,000 to 10,000. A coating material containing dispersed inorganic powder and a magnetic recording medium both use this binder. In a recording medium comprising a magnetic layer placed on a non-magnetic substrate, the magnetic layer comprises polyurethane resin (A) as a binder, vinyl chloride polymer (B) containing 0.1 to 20% by weight of epoxy group and having an average degree of polymerization of 100 to 500, as another binder, (C) an alicylic acid anhydride as a crosslinking agent, and (E) a tertiary amine as a catalyst, and at least one of the binders is crosslinked between the epoxy groups therein by the reaction in which components (C) and (E) take part. The coating material containing fine inorganic powder dispersed with stability and having a low viscosity can be obtained by using, as the binder, the polyurethane resin having terminal epoxy groups and one of a sulfonic acid salt group, a carboxylic acid salt group, and a quaternary ammonium salt group. The magnetic recording material prepared by using magnetic powder as the inorganic powder and crosslinking the binder is excellent in dispersion of the magnetic powder and smoothness of the surface. Therefore, the magnetic recording medium is excellent in magnetic properties, durability, and running properties.
    • 含有分散无机粉末的涂料用粘合剂包含:(a)平均一分子中具有2.2〜7.0个末端环氧基的聚氨酯树脂,(b)0.1〜5.0重量%的磺酸盐基的SO 3,0.05〜 3.0重量%,作为羧酸盐基团的COO-,或作为分子中N +的季铵盐基团的0.02〜1.0重量%,数均分子量为2,000〜10000。 含有分散无机粉末和磁记录介质的涂料均使用该粘合剂。 在包含放置在非磁性基板上的磁性层的记录介质中,磁性层包含作为粘合剂的聚氨酯树脂(A),含有0.1-20重量%环氧基的氯乙烯聚合物(B),平均度 的聚合作为另一种粘合剂,(C)作为交联剂的丙烯酸酐,和(E)叔胺作为催化剂,并且至少一种粘合剂在其中的环氧基之间交联,由 组分(C)和(E)组成的反应。 通过使用具有末端环氧基和磺酸盐基团,羧酸盐基团和季铵盐之一的聚氨酯树脂作为粘合剂,可以获得稳定地分散且具有低粘度的无机细粉末的涂料 铵盐基团。 通过使用磁性粉末作为无机粉末并使粘合剂交联而制备的磁记录材料具有优异的磁性粉末分散性和表面平滑性。 因此,磁记录介质的磁特性,耐久性和运行性都优异。