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1. 发明授权

US4399306A Process for the preparation of 2,6-dialkyl-N-alkoxymethyl-2-chloro-acetanilides 失效
标题翻译：制备2,6-二烷基-N-烷氧基甲基-2-氯 - 乙酰苯胺的方法
公开(公告)号：US4399306A
公开(公告)日：1983-08-16
申请号：US104918
申请日：1979-12-18
申请人： Kornelia Domjan nee Pinter , Gyorgy Huszak , Zoltan Kolonics , Laszlo Lendvai , Jeno Pelyva , Endre Sumegi , Elemer Tomordi , Bela Gyorfi , Laszlo J. Szabo , Andras Haas , Miklos Kovacs , Taszlo Kulcsar , Miklos Nadasy , Balint Nagy , Andras Vass , Ervin Vertesi
发明人： Kornelia Domjan nee Pinter , Gyorgy Huszak , Zoltan Kolonics , Laszlo Lendvai , Jeno Pelyva , Endre Sumegi , Elemer Tomordi , Bela Gyorfi , Laszlo J. Szabo , Andras Haas , Miklos Kovacs , Taszlo Kulcsar , Miklos Nadasy , Balint Nagy , Andras Vass , Ervin Vertesi
IPC分类号： C07C231/00 , A01N20060101 , A01N37/18 , A01N37/22 , A01N37/26 , C07C20060101 , C07C67/00 , C07C231/12 , C07C231/14 , C07C233/25 , C07C233/88 , C07C103/375
摘要： The invention relates to an improved method for the preparation of a 2',6'-dialkyl-N-alkoxymethyl-2-chloro-acetanilide compound of the general formula (I), ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are identical or different and stand for straight-chained or branched C.sub.1-4 alkyl groups.According to the invention a dialkyl aniline of the general formula (II), ##STR2## wherein R.sub.1 and R.sub.2 are as defined above, is treated with aqueous formaldehyde solution in an apolar solvent at a temperature of 30.degree. to 80.degree. C., the solution of the resulting oxymethyl derivative formed with said apolar solvent is separated from the aqueous formaldehyde solution at an elevated temperature and then dehydrated, the resulting azomethine derivative is reacted with chloroacetyl chloride in the same apolar solvent medium, the resulting chloromethyl compound is reacted with an alcohol of the general formula (V),R.sub.3 -OH (V)wherein R.sub.3 is as defined above, in an amount sufficient to bind the hydrochloric acid liberated in the reaction, the reaction mixture is admixed with water, and the organic phase containing the required end-product is separated and optionally processed.
摘要翻译：本发明涉及一种制备通式（I），其中R1，R2和R3的通式（I）的2'，6'-二烷基-N-烷氧基甲基-2-氯 - 乙酰苯胺化合物的改进方法是相同或不同的，代表直链或支链C 1-4烷基。根据本发明，通式（II）的二烷基苯胺，其中R 1和R 2如上所定义，在甲醇溶液中，在非极性溶剂中，在30〜80℃的温度下进行处理将所得的非极性溶剂形成的氧甲基衍生物的溶液在升高的温度下从甲醛水溶液中分离出来然后脱水，所得的偶氮甲碱衍生物与氯乙酰氯在相同的非极性溶剂介质中反应，得到的氯甲基化合物为与其中R3如上所定义的通式（V）的醇，R3-OH（V）反应，其量足以与反应中释放的盐酸结合，将反应混合物与水混合，并将有机物包含所需最终产品的相分离并任选地处理。

2. 发明授权

US4859772A Process for the preparation of 3-isopropyl-benzo-2-thia-1,3-diazinone-(4)-2,2-dioxide 失效
标题翻译：制备3-异丙基 - 苯并-2-硫杂-1,3-二嗪酮 - （4）-2,2-二氧化物的方法
公开(公告)号：US4859772A
公开(公告)日：1989-08-22
申请号：US105230
申请日：1987-07-15
申请人： Jeno Pelyva , K. Istvan Vecsey , Zoltan Kolonics , Laszlo Legradi , Lajos Nagy , Andras Horvath , Ferenc Fodor, deceased , Csaba Soptei , Dezso Sebok , Elemer Tomordi , Laszlo Lendvai , Bela Karacsonyi , Erzsebet Dioszegi
发明人： Jeno Pelyva , K. Istvan Vecsey , Zoltan Kolonics , Laszlo Legradi , Lajos Nagy , Andras Horvath , Ferenc Fodor, deceased , Csaba Soptei , Dezso Sebok , Elemer Tomordi , Laszlo Lendvai , Bela Karacsonyi , Erzsebet Dioszegi
IPC分类号： C07D285/16
CPC分类号： C07D285/16
摘要： The present invention relates to a process for the preparation of 3-isopropyl-benzo-2-thia-1,3-diazinone-(4)-2,2-dioxide which comprises preparing isopropyl sulfamoyl chloride in one step by reacting N,N'-diisopropyl-urea with phosphorus trichloride and chlorine in the presence of oleum and sulfuric acid and condensing the so obtained isopropyl sulfamoyl chloride at room temperature without any solvent in the presence of an excess of N,N-diethyl aniline with anthranylic acid methyl ester and subjecting the thus obtained N-isopropyl-N'-o-carbomethoxy-phenyl-sulfamide to cyclization in the presence of sodium methylate, extracting the obtained crude 3-isopropyl-benzo-2-thia-1,3-diazinone-(4)-2,2-dioxide with a mixture of methanol and water and after adding water to the aqueous-methanolic mixture and sedimenting the contaminations isolating a product of high purity.
摘要翻译： PCT No.PCT / HU86 / 00065 Sec。 371日期1987年7月15日 102（e）日期1987年7月15日PCT提交1986年12月3日PCT公布。第WO87 / 03588号公报日本6月18日，1987。本发明涉及3-异丙基 - 苯并-2-硫杂-1,3-二嗪酮 - （4）-2,2-二氧化物的制备方法，其包括制备异丙基氨磺酰氯在发烟硫酸和硫酸的存在下，使N，N'-二异丙基脲与三氯化磷和氯反应一步，在室温下将所得异丙基氨磺酰氯在没有任何溶剂的条件下，在过量的N，二乙基苯胺与苯甲酸甲酯反应，并将得到的N-异丙基-N'-邻甲氧基苯基磺酰胺在甲醇钠存在下环化，得到粗产物3-异丙基 - 苯并-2-硫杂-1- （4）-2,2-二氧化物与甲醇和水的混合物，并在向含水甲醇混合物中加入水并沉淀分离高纯度产物的污染物。

3. 发明授权

US5068424A Process for preparing arylsulphonyl-isocyanates and addition derivatives thereof 失效
标题翻译：芳基磺酰基异氰酸酯及其加成衍生物的制备方法
公开(公告)号：US5068424A
公开(公告)日：1991-11-26
申请号：US365790
申请日：1989-06-14
申请人： Gabor Besenyei , Sandor Nemeth , Laszlo Simandi , Maria Belak , Jozsef Dukai , Lajos Nagy , Elemer Tomordi , Csaba Soptei , Erzsebet E. Dioszegine
发明人： Gabor Besenyei , Sandor Nemeth , Laszlo Simandi , Maria Belak , Jozsef Dukai , Lajos Nagy , Elemer Tomordi , Csaba Soptei , Erzsebet E. Dioszegine
IPC分类号： C07D333/34 , A01N47/34 , A01N47/40 , B01J31/16 , C07B61/00 , C07C311/53 , C07C311/57 , C07C311/65
CPC分类号： C07C311/65
摘要： The invention relates to a process for preparing arylsulphonyl isocyanates of the general formula (I) ##STR1## and addition derivatives thereof--where in the formula the meaning of the substituents are as follows:Ar represents optionally substituted aryl, naphthyl- or thienyl group, andHX is a chemical bond or XZR.sub.1 stands for a group where Z is oxygen or sulphur,R.sub.1 is saturated or unsaturated alkyl, benzyl, cyclohexyl or substituted phenyl group orX is an NR.sub.2 R.sub.3 groupwherein R.sub.2 R.sub.3 is hydrogen, alkyl, unsubstituted alkyl, aryl, substituted aryl, aroyl or acyl group, and the essence of the process is that an N-halogen sulphonamidate is carbonylated in the presence of a carbonylating catalyst, in the presence or absence of alcohol, (thio) alcohol or amine reactants and the carbonylated compound obtained is reacted subsequently with the reactants.
摘要翻译：本发明涉及制备通式（I）的芳基磺酰基异氰酸酯及其加成衍生物的方法，其中在该式中取代基的含义如下：Ar表示任选取代的芳基，萘基或噻吩基，HX为化学键，X ZR1表示Z为氧或硫的基团，R1为饱和或不饱和的烷基，苄基，环己基或取代的苯基或X为NR2R3基团，其中R2R3为氢，烷基，未取代的烷基，芳基，取代的芳基，芳酰基或酰基，并且该方法的本质是在羰基化催化剂存在下，在醇，（硫）醇或胺的存在或不存在下羰基化N-卤代磺酰胺获得的反应物和羰基化的化合物随后与反应物反应。

4. 发明授权

US4954628A Process for preparing N-sulphonyl-ureas 失效
标题翻译：制备N-磺酰脲的方法
公开(公告)号：US4954628A
公开(公告)日：1990-09-04
申请号：US317769
申请日：1989-03-02
申请人： Gabor Besenyei , Sandor Nemeth , Laszlo Simandi , Maria Belak , Maria Szabo , Jozsef Dukai , Lajos Nagy , Elemer Tomordi , Csaba Soptei , Erzsebet E. Dioszegine
发明人： Gabor Besenyei , Sandor Nemeth , Laszlo Simandi , Maria Belak , Maria Szabo , Jozsef Dukai , Lajos Nagy , Elemer Tomordi , Csaba Soptei , Erzsebet E. Dioszegine
IPC分类号： C07D251/16 , B01J27/13 , B01J31/16 , C07B61/00 , C07C311/60 , C07D213/75 , C07D239/42 , C07D251/18 , C07D251/22 , C07D251/46 , C07D333/34 , C07D521/00
CPC分类号： C07D521/00 , C07C311/60
摘要： The invention relates to a process for preparing sulphonyl-ureas of the general formula (I) ##STR1## wherein Ar.sub.1 represents a phenyl, naphthyl or thienyl group, the derivatives thereof substituted by C.sub.1-4 alkyl, C.sub.1-4 haloalkyl, (halo)alkoxycarbonyl, (halo)alkyloxy, nitro, cyano groups as well as by halogen atoms,Ar.sub.2 represents a phenyl, pyridyl, pirimidinyl or triazinyl group and the derivatives thereof substituted by C.sub.1-4 (halo)alkyl, C.sub.1-4 (halo)alkyloxy, amino, O-acyl, O-arylsulphonyl, O-(substituted carbamoyl) groups as well as by halogen atoms.According to the invention N-halogen aryl sulphonamidate is reacted in the presence of a carbonylating catalyst, carbon monoxide and an aromatic amine, optionally in the presence of a phase transfer catalyst, or N-halogen aryl sulphonamidate is reacted with carbon monoxide in the presence of a carbonylating catalyst, and optionally in the presence of a phase transfer catalyst, then the obtained reaction mixture is further reacted with an aromatic amine or an N-halogen-arylamine-alkali metal salt is reacted with aryl-sulphonamid in the presence of a carbonylating catalyst, carbon monoxide and optionally in the presence of a phase transfer catalyst or an amine, amine dihalogenid, aryl sulphonamid are reacted in the presence of a carbonylating catalyst and carbon monoxide and the obtained reaction mixture is worked up in a known manner.The thus prepared sulphonyl-ureas are biologically active compounds, which are used in the pharmaceutical industry and for regulating plant growth.
摘要翻译：本发明涉及一种制备通式（I）的磺酰脲的方法，其中Ar 1表示苯基，萘基或噻吩基，其衍生物被C 1-4烷基，C 1-4卤代烷基，（卤代）烷氧基羰基，（卤代）烷氧基，硝基，氰基以及卤素原子，Ar 2表示苯基，吡啶基，吡啶基或三嗪基，其衍生物被C 1-4（卤代）烷基，卤代）烷氧基，氨基，O-酰基，O-芳基磺酰基，O-（取代的氨基甲酰基）基团以及卤素原子。根据本发明，N-卤素芳基磺酰胺酸酯在羰基化催化剂，一氧化碳和芳族胺的存在下，任选地在相转移催化剂存在下反应，或N-卤素芳基磺酰胺盐与一氧化碳在存在下反应的羰基化催化剂，并且任选地在相转移催化剂存在下，然后将所得反应混合物进一步与芳族胺反应或N-卤素 - 芳基胺 - 碱金属盐在芳基 - 磺酰胺存在下与羰基化催化剂，一氧化碳和任选在相转移催化剂或胺，胺二卤代芳基磺酰胺存在下，在羰基化催化剂和一氧化碳的存在下反应，并将所得反应混合物以已知方式处理。如此制备的磺酰脲是生物活性化合物，其用于制药工业和调节植物生长。

5. 发明授权

US4776874A 2-chloro-ethyl phosphonic acid esters and plant growth regulating agents containing same as active ingredient 失效
标题翻译： 2-氯乙基膦酸酯和含有活性成分的植物生长调节剂
公开(公告)号：US4776874A
公开(公告)日：1988-10-11
申请号：US839498
申请日：1986-03-13
申请人： Sandor Balint , Judit Benczik nee Pasztor , Jozsef Fodor , Andras Horvath , Elemer Tomordi , Csaba Soptei , Jozsef Karsai , Endre Sebestyen , Sandor Gaal , Ivan Gardi , Gyorgy Kiss , Andras Papp , Imre Csatlos
发明人： Sandor Balint , Judit Benczik nee Pasztor , Jozsef Fodor , Andras Horvath , Elemer Tomordi , Csaba Soptei , Jozsef Karsai , Endre Sebestyen , Sandor Gaal , Ivan Gardi , Gyorgy Kiss , Andras Papp , Imre Csatlos
IPC分类号： A01N57/24 , C07F9/40 , C07F9/655
CPC分类号： C07F9/65522 , A01N57/24 , C07F9/65517
摘要： The present invention relates to new compounds of the general formula (I) ##STR1## wherein R stands for hydrogen, C.sub.1-8 straight or branched chained alkyl, C.sub.1-4 haloalkyl, C.sub.1-4 alkoxy-C.sub.1-2 alkyl,R.sup.1 stands for 2,3-dihydro-2,2-dimethyl-benzofuran-7-yl, 4-methyl-coumarin-7-yl, 2,2,4-trimethyl-(2H)-chromen-5-yl or 2,2,4-trimethyl-(2H)-chromen-7-yl and Me stands for a monovalent cation and represents the salt of the acid.The new compounds show plant growth regulating activity and can be used as active ingredient of plant growth regulators.
摘要翻译： PCT No.PCT / HU85 / 00043 Sec。 371日期：1986年3月13日 102（e）1986年3月13日PCT PCT。1985年7月17日PCT公布。出版物WO86 / 00903 1986年2月13日。本发明涉及通式（I）的新化合物。其中R代表氢，C1-8直链或支链烷基，C1-4卤代烷基，C1-4 烷氧基-C 1-2烷基，R1代表2,3-二氢-2,2-二甲基 - 苯并呋喃-7-基，4-甲基 - 香豆素-7-基，2,2,4-三甲基 - （2H） - 色烯-5-基或2,2,4-三甲基 - （2H） - 色烯-7-基，Me表示一价阳离子，代表酸的盐。新化合物显示植物生长调节活性，可用作植物生长调节剂的活性成分。

6. 发明授权

US5116402A Herbicidal composition containing dioxolane, dioxane, or dioxepane derivatives as antidote 失效
标题翻译：含有二恶烷，二氧化物或二氧化硫衍生物的除草组合物作为抗氧化剂
公开(公告)号：US5116402A
公开(公告)日：1992-05-26
申请号：US333737
申请日：1989-03-31
申请人： Ferenc Dutka , Tamas Komives , Katalin Fodor, nee Csorba , Attila Marton , Aniko Csikos, nee Gluck , Eva Osztheimer , Karoly Henger , Robert Laborczy , Zsuzsanna Reti, nee Bosnyak , Dezso Sebok , Jozsef Szabolcs , Elemer Tomordi
发明人： Ferenc Dutka , Tamas Komives , Katalin Fodor, nee Csorba , Attila Marton , Aniko Csikos, nee Gluck , Eva Osztheimer , Karoly Henger , Robert Laborczy , Zsuzsanna Reti, nee Bosnyak , Dezso Sebok , Jozsef Szabolcs , Elemer Tomordi
IPC分类号： A01N47/10 , A01C1/06 , A01N25/32 , A01N35/00 , A01N35/02 , A01N37/42 , A01N43/08 , A01N43/24 , A01N43/48 , A01N43/74 , A01N47/12 , A01N47/28 , A01P13/00 , C07C43/313 , C07C43/315 , C07C43/317 , C07D233/02 , C07D235/10 , C07D239/04 , C07D263/04 , C07D307/46 , C07D317/16 , C07D317/20 , C07D319/06 , C07D321/06 , C07D327/04 , C07H9/04 , C09K17/00
CPC分类号： C07D263/04 , A01N25/32 , C07C323/00 , C07C43/313 , C07C43/315 , C07C43/317 , C07D233/02 , C07D235/10 , C07D239/04 , C07D307/46 , C07D317/16 , C07D317/20 , C07D319/06 , C07D321/06 , C07D327/04 , C07H9/04
摘要： The invention relates to a herbicidal composition which contains, besides binding, wetting, dispersing, emulsifying agents, solvents and/or surface-active substances, herbicides as active agent of thiocarbamate, carbamate, acid amide or urea type alone or in a combination, furthermore as antidote a compound of the general formula I ##STR1## wherein R.sup.1 and R.sup.2, independently of each other, are hydrogen, C.sub.1-6 alkyl, C.sub.2-6 alkenyl, C.sub.1-4 cyanoalkyl, C.sub.1-6 haloalkyl, phenyl-C.sub.1-4 -haloalkyl, phenyl, halogenphenyl, C.sub.1-4 -alkyl-phenyl, C.sub.1-4 -alkoxyphenyl, furfuryl;R.sup.3 and R.sup.4, independently of each other, are hydrogen, C.sub.1-18 -alkyl, C.sub.2-4 -haloalkyl, C.sub.2-4 -cyanoalkyl, C.sub.1-4 -alkoxy-C.sub.2-4 -alkyl, C.sub.5-6 -cycloalkyl, phenyl-C.sub.1-4 -alkyl, C.sub.3-4 -alkenyl, phenyl-C.sub.3-4 -alkenyl, di-C.sub.1-4 -alkylamino-C.sub.2-4 -alkyl, hydroxy-C.sub.2-6 -alkyl, furfuryl, tetrahydrofurfuryl, C.sub.1-4 -alkoxy-C.sub.2-4 -alkoxy-C.sub.2-4 -alkyl;R.sup.3 and R.sup.4, together, are C.sub.2-4 -alkylene, C.sub.4 -alkenylene, glucofuranosylene, acetoxy-C.sub.3 -alkylene, C.sub.1-4 -alkoxy-C.sub.3 -alkylene, hydroxy-C.sub.3 -alkylene, halogen-C.sub.3 -alkylene; wherein the quantity of the antidote lies between 0.01 and 15 parts by weight referred to 1 part by weight of herbicidal agent, furthermore the composition contains altogether 0.1 to 95 percent by weight of the herbicidal agents and the antidote.
摘要翻译：本发明涉及一种除草剂除了结合之外还含有除了作为硫代氨基甲酸酯，氨基甲酸酯，酰胺或尿素的单独或组合的活性剂之外的其它润湿剂，分散剂，乳化剂，溶剂和/或表面活性物质，除此之外作为解毒剂，通式I的化合物其中R 1和R 2彼此独立地为氢，C 1-6烷基，C 2-6烯基，C 1-4氰基烷基，C 1-6卤代烷基，苯基-C 1-4 - 卤代烷基，苯基，卤素苯基，C 1-4 - 烷基 - 苯基，C 1-4烷氧基苯基，糠基; R 3和R 4彼此独立地是氢，C 1-18 - 烷基，C 2-4 - 卤代烷基，C 2-4 - 氰基烷基，C 1-4 - 烷氧基-C 2-4 - 烷基，C 5-6 - 环烷基， C 1-4 - 烷基，C 3-8 - 烯基，苯基-C 3-4 - 烯基，二-C 1-4 - 烷基氨基-C 2-4 - 烷基，羟基-C 2-6 - 烷基，糠基，四氢糠基，烷氧基-C 2-4的烷氧基-C 2-4的烷基; R 3和R 4一起是C 2-4亚烷基，C 4 - 亚烯基，呋喃糖基，乙酰氧基-C 3 - 亚烷基，C 1-4 - 烷氧基-C 3 - 亚烷基，羟基-C 3 - 亚烷基，卤素-C 3 - 亚烷基; 其中解毒剂的量介于0.01至15重量份之间，称为除草剂1重量份，此外该组合物含有除草剂和解毒剂重量的0.1-95重量％。

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