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1. 发明授权

US07943704B2 Method for producing emulsion polymers 有权
标题翻译：生产乳液聚合物的方法
公开(公告)号：US07943704B2
公开(公告)日：2011-05-17
申请号：US11994593
申请日：2006-07-10
申请人： Konrad Roschmann , Arno Tuchbreiter , Ekkehard Jahns , Joerg Leuninger , Bernhard Schuler , Oliver Wagner , Michaela Reinsch , Robert Wrazidlo
发明人： Konrad Roschmann , Arno Tuchbreiter , Ekkehard Jahns , Joerg Leuninger , Bernhard Schuler , Oliver Wagner , Michaela Reinsch , Robert Wrazidlo
IPC分类号： C08F285/00 , C08F265/04 , C08F2/22
CPC分类号： C08F2/22 , C08F265/00 , C08F265/04 , C08F265/06 , C08F285/00 , C08L51/003 , C09D151/003 , Y10S525/902 , C08L2666/02
摘要： The present invention provides a process for preparing emulsion polymer particles of a hollow core/shell structure in the presence of a monomer plasticizer having a ceiling temperature less than 181° C. wherein a polymerization inhibitor or reducing agent is not added to the aqueous emulsion of the core shell particles during the neutralization and swelling stage. The obtained core shell particles are useful in paints, paper coatings, foams, and cosmetics.
摘要翻译：本发明提供一种在上限温度低于181℃的单体增塑剂存在下制备中空核/壳结构的乳液聚合物颗粒的方法，其中不向聚合物颗粒中加入聚合抑制剂或还原剂核心壳颗粒在中和和膨胀阶段。所获得的核壳颗粒可用于油漆，纸涂料，泡沫和化妆品。

2. 发明申请

US20100063171A1 METHOD FOR PRODUCING EMULSION POLYMERS 有权
标题翻译：生产乳液聚合物的方法
公开(公告)号：US20100063171A1
公开(公告)日：2010-03-11
申请号：US11994593
申请日：2006-07-10
申请人： Konrad Roschmann , Arno Tuchbreiter , Ekkehard Jahns , Joerg Leuninger , Bernhard Schuler , Oliver Wagner , Michaela Reinsch , Robert Wrazidlo
发明人： Konrad Roschmann , Arno Tuchbreiter , Ekkehard Jahns , Joerg Leuninger , Bernhard Schuler , Oliver Wagner , Michaela Reinsch , Robert Wrazidlo
IPC分类号： C08J9/00 , C08K5/01 , C08K5/10 , C08K5/09 , C08K3/22 , C08K3/26 , C08K5/17 , C08K5/357
CPC分类号： C08F2/22 , C08F265/00 , C08F265/04 , C08F265/06 , C08F285/00 , C08L51/003 , C09D151/003 , Y10S525/902 , C08L2666/02
摘要： The present invention relates to a process for preparing emulsion polymer particles having a core/shell structure and also to their use in paints, paper coatings, foams, and cosmetics.
摘要翻译：本发明涉及一种制备具有核/壳结构的乳液聚合物颗粒的方法，还涉及它们在油漆，纸涂料，泡沫和化妆品中的应用。

3. 发明授权

US08901237B2 Method to increase resistance against stain penetration of aqueous coating compositions 有权
标题翻译：提高耐水性涂料组合物渗透性的方法
公开(公告)号：US08901237B2
公开(公告)日：2014-12-02
申请号：US12066155
申请日：2006-09-11
申请人： Mubarik Mahmood Chowdhry , Hideki Yamashita , Cheeseng Yong , Gregory John Catterall , Jonathon Shane Allen , Roger Jan Van Sonsbeek , David Redfern , Bernhard Schuler , Oliver Wagner , David Christie
发明人： Mubarik Mahmood Chowdhry , Hideki Yamashita , Cheeseng Yong , Gregory John Catterall , Jonathon Shane Allen , Roger Jan Van Sonsbeek , David Redfern , Bernhard Schuler , Oliver Wagner , David Christie
IPC分类号： C08L31/00 , C08L31/02 , C08L33/00 , C08L33/02 , C09D7/12 , C09D135/06 , C09D133/08 , C09D133/12 , C08K5/41 , C08K5/521
CPC分类号： C09D7/1208 , C08K5/41 , C08K5/521 , C09D7/60 , C09D133/08 , C09D133/12 , C09D135/06
摘要： The invention also relates to a method to increase stain resistance and penetration resistance of aqueous coating compositions which method comprises providing a coating composition which contain at least one pigment, at least one film-forming polymer in the form of an aqueous polymer dispersion and at least one anionic surfactant, wherein the anionic surfactant comprises at least 85% by weight, preferably at least 90% by weight, more preferably at least 95% by weight, based on the total weight of anionic surfactant in the coating composition, of at least one anionic surfactant S, which is selected from semi-esters of sulfuric acid or phosphoric acid with an alcohol, which alcohol carries at least one alkyl radical having from 8 to 30 carbon atoms or an alkyl substituted phenyl radical wherein alkyl has from 4 to 30 carbon atoms and which alcohol may carry an oligo-C2-C3-alkylene-ether group provided that the number of repeating units in the oligo-C2-C3-alkylene-ether group is at most 15, or a salt thereof.
摘要翻译：本发明还涉及一种提高水性涂料组合物的抗污性和耐渗透性的方法，该方法包括提供一种涂料组合物，该组合物含有至少一种颜料，至少一种成膜聚合物，其形式为聚合物水分散体，至少一种阴离子表面活性剂，其中阴离子表面活性剂包含至少85重量％，优选至少90重量％，更优选至少95重量％，基于涂料组合物中阴离子表面活性剂的总重量，至少一种阴离子表面活性剂S，其选自硫酸或磷酸与醇的半酯，该醇含有至少一个具有8至30个碳原子的烷基或烷基取代的苯基，其中烷基具有4至30个碳原子，哪种醇可以携带低级C2-C3-亚烷基 - 醚基团，条件是低级C2-C3-亚烷基 - 醚基团中的重复单元数目最多为 15，或其盐。

4. 发明申请

US20080245259A1 Method to Increase Resistance Against Stain Penetration of Aqueous Coating Compositions 有权
标题翻译：提高水性涂料组合物渗透性的方法
公开(公告)号：US20080245259A1
公开(公告)日：2008-10-09
申请号：US12066155
申请日：2006-09-11
申请人： Mubarik Mahmood Chowdhry , Hideki Yamashita , Cheeseng Yong , Gregory John Catterall , Jonathon Shane Allen , Roger Jan Van Sonsbeek , David Redfern , Bernhard Schuler , Oliver Wagner , David Christie
发明人： Mubarik Mahmood Chowdhry , Hideki Yamashita , Cheeseng Yong , Gregory John Catterall , Jonathon Shane Allen , Roger Jan Van Sonsbeek , David Redfern , Bernhard Schuler , Oliver Wagner , David Christie
IPC分类号： C09D133/08
CPC分类号： C09D7/1208 , C08K5/41 , C08K5/521 , C09D7/60 , C09D133/08 , C09D133/12 , C09D135/06
摘要： The invention also relates to a method to increase stain resistance and penetration resistance of aqueous coating compositions which method comprises providing a coating composition which contain at least one pigment, at least one film-forming polymer in the form of an aqueous polymer dispersion and at least one anionic surfactant, wherein the anionic surfactant comprises at least 85% by weight, preferably at least 90% by weight, more preferably at least 95% by weight, based on the total weight of anionic surfactant in the coating composition, of at least one anionic surfactant S, which is selected from semi-esters of sulfuric acid or phosphoric acid with an alcohol, which alcohol carries at least one alkyl radical having from 8 to 30 carbon atoms or an alkyl substituted phenyl radical wherein alkyl has from 4 to 30 carbon atoms and which alcohol may carry an oligo-C2-C3-alkylene-ether group provided that the number of repeating units in the oligo-C2-C3-alkylene-ether group is at most 15, or a salt thereof.
摘要翻译：本发明还涉及一种提高水性涂料组合物的抗污性和耐渗透性的方法，该方法包括提供一种涂料组合物，该组合物含有至少一种颜料，至少一种成膜聚合物，其形式为聚合物水分散体，至少一种阴离子表面活性剂，其中阴离子表面活性剂包含至少85重量％，优选至少90重量％，更优选至少95重量％，基于涂料组合物中阴离子表面活性剂的总重量，至少一种阴离子表面活性剂S，其选自硫酸或磷酸与醇的半酯，该醇含有至少一个具有8至30个碳原子的烷基或烷基取代的苯基，其中烷基具有4至30个碳原子和哪些醇可以携带低级-C 2 -C 3 - 亚烷基 - 醚基团，条件是寡聚-C 2 - 亚烷基 - 醚基团中的重复单元的数目< / SUB> -C < 亚烷基 - 醚基最多为15，或其盐。

5. 发明授权

US06209360B1 Latch needle having a latch supported on a pin 有权
标题翻译：具有支撑在销上的闩锁的闩锁针
公开(公告)号：US06209360B1
公开(公告)日：2001-04-03
申请号：US09537545
申请日：2000-03-30
申请人： Sigmar Majer , Bernhard Schuler
发明人： Sigmar Majer , Bernhard Schuler
IPC分类号： D04B3504
CPC分类号： D04B35/04
摘要： A latch needle includes a head; a cheek having two facing side walls each having an inner wall face and an outer wall face; a sawslot defined by the inner wall faces of the side walls; and a pivot pin being formed at least on one of the side walls by plastically deforming the side wall. The pivot pin extends from the inner wall face of the side wall into the sawslot. The latch needle further has a first depression provided in the outer wall face of the side wall in alignment with the pivot pin. The first depression includes a bottom having a peripheral region in which a second depression is provided. A needle latch cooperates with the head and has a latch shank accommodated in the sawslot. The latch shank has a hole into which the pivot pin extends for forming a bearing support for the needle latch.
摘要翻译：闩锁针包括头部; 具有两个具有内壁面和外壁面的面对侧壁的面颊; 由侧壁的内壁面限定的锯槽; 以及通过使侧壁塑性变形而形成在至少一个侧壁上的枢轴销。枢轴销从侧壁的内壁面延伸到锯槽。闩锁针还具有设置在与枢轴销对准的侧壁的外壁面中的第一凹部。第一凹部包括具有设置有第二凹部的周边区域的底部。针头与头部配合并具有容纳在锯槽中的闩锁柄。闩锁柄具有孔，枢轴销延伸到该孔中以形成用于针闩的轴承支撑。

6. 发明授权

US5354724A Heat sensitive recording materials with polymer enrobed sensitizer 失效
标题翻译：热敏记录材料与聚合物加入敏化剂
公开(公告)号：US5354724A
公开(公告)日：1994-10-11
申请号：US99008
申请日：1993-07-29
申请人： Dietrich Hoffmann , Bernhard Schuler
发明人： Dietrich Hoffmann , Bernhard Schuler
IPC分类号： B41M5/323 , B41M5/333 , B41M5/337 , B41M5/26
CPC分类号： B41M5/3375
摘要： Recording materials which contain one or more optionally polymer-enrobed dye precursors, one or more optionally polymer-enrobed developers and one or more polymer-enrobed sensitizers are described.
摘要翻译：描述了含有一种或多种任选的聚合物引发的染料前体，一种或多种任选的聚合物引发的显影剂和一种或多种聚合物引发的敏化剂的记录材料。

7. 发明授权

US5097683A Tool for stitch forming machines, particularly knitting machines 失效
标题翻译：缝纫机，特殊针织机工具
公开(公告)号：US5097683A
公开(公告)日：1992-03-24
申请号：US546937
申请日：1990-07-02
申请人： Bernhard Schuler , Kurt Wiedenhofer
发明人： Bernhard Schuler , Kurt Wiedenhofer
IPC分类号： D04B15/68 , D04B35/02
CPC分类号： D04B35/02
摘要： A tool for a stitch forming machine which includes a bed and a plurality of guide grooves disposed in the bed, the tool including a shank slidably disposed in one of the guide grooves. The shank includes an end having a stitch forming device, and has a butt and at least two bends spaced from one another along a longitudinal direction of the shank. The bends are oriented toward the same side of the shank and are disposed in a region of the shank which, during sliding movement of the shank during operation of the knitting machine, remains within the guide groove.
摘要翻译：一种用于缝合成型机的工具，其包括床和设置在床中的多个引导槽，该工具包括可滑动地设置在一个引导槽中的柄。柄包括具有线圈形成装置的端部，并且具有沿着柄部的纵向方向彼此间隔开的对接和至少两个弯曲部。弯曲部朝向柄的同一侧，并且设置在柄的区域中，在针织机的操作期间在柄的滑动运动期间保持在引导槽内。

8. 发明申请

US20120053260A1 AQUEOUS EMULSION POLYMERS, THEIR PREPARATION AND USE 有权
标题翻译：水性乳液聚合物，其制备和使用
公开(公告)号：US20120053260A1
公开(公告)日：2012-03-01
申请号：US13221021
申请日：2011-08-30
申请人： Roelof BALK , Rolf Dersch , Sebastian Roller , Bernhard Schuler
发明人： Roelof BALK , Rolf Dersch , Sebastian Roller , Bernhard Schuler
IPC分类号： C09D5/02 , C08F2/46 , C09D4/02
CPC分类号： C09D5/022 , C08F2/24 , C08F2/46 , C08F220/18 , C08F220/40 , C08F2220/1825 , C09D4/00 , C09D133/066 , C08F212/08 , C08F220/06 , C08F220/56 , C08F2220/283
摘要： The present invention provides aqueous emulsion polymers comprising (A) monomers A (B) at least one (meth)acrylate with olefinically unsaturated side groups (monomers B), and (C) at least one photoinitiator, and also the use thereof in coating materials, more particularly in exterior architectural paints.
摘要翻译：本发明提供包含（A）单体A（B）至少一种具有烯属不饱和侧基（单体B）的（甲基）丙烯酸酯和（C）至少一种光引发剂的水性乳液聚合物，以及其在涂料中的用途，更具体地在外部建筑涂料中。

9. 发明授权

US06620870B1 Contact bonding adhesives 有权
标题翻译：接触粘合剂
公开(公告)号：US06620870B1
公开(公告)日：2003-09-16
申请号：US09926449
申请日：2001-11-06
申请人： Matthias Gerst , Gerhard Auchter , Bernhard Schuler
发明人： Matthias Gerst , Gerhard Auchter , Bernhard Schuler
IPC分类号： C09J13308
CPC分类号： C09J133/066 , C09J7/385 , Y10S526/911 , Y10S526/932
摘要： Pressure-sensitive adhesives comprising an aqueous polymer dispersions wherein the polymer is composed of from 50 to 99.9% by weight of at least one C1-C12 alkyl (meth)acrylate (monomers a) from 0.05 to 20% by weight of at least one vinylaromatic compound (monomers b) from 0.05 to 10% by weight of at least one ethylenically unsaturated hydroxy compound (monomers c) from 0 to 10% by weight of an ethylenically unsaturated acid or an acid anhydride (monomers d) and from 0 to 30% by weight of other ethylenically unsaturated compounds (monomers e) the weight percentages being based on the polymer, and the polymer dispersion comprising an emulsifier consisting to the extent of at least 5% by weight of aromatic carbon atoms (and called aromatic emulsifier for short) or an emulsifier mixture consisting to the extent of at least 10% by weight of an aromatic emulsifier.
摘要翻译：包含聚合物水分散体的压敏粘合剂，其中所述聚合物由50至99.9重量％的至少一种（甲基）丙烯酸C 1 -C 12烷基酯（单体a）组成，0.05至20重量％的至少一种乙烯基芳族化合物（单体b）0.05至10重量％的至少一种烯属不饱和羟基化合物（单体c），0至10重量％的烯属不饱和酸或酸酐（单体d）和0至30重量％的其它烯键式不饱和化合物（单体e），其重量百分比基于聚合物，并且包含乳化剂的聚合物分散体包含至少5重量％的芳族碳原子的程度（简称为芳族乳化剂）或乳化剂混合物的含量至少为10重量％的芳族乳化剂。

10. 发明授权

US06605662B2 Multistage aqueous dispersion of polymer particles having a soft core and hard shell 失效
标题翻译：具有软核和硬壳的聚合物颗粒的多级水分散体
公开(公告)号：US06605662B2
公开(公告)日：2003-08-12
申请号：US09854751
申请日：2001-05-15
申请人： Cheng-Le Zhao , Joachim Roser , Eckehardt Wistuba , Bernhard Schuler , Klemens Mathauer
发明人： Cheng-Le Zhao , Joachim Roser , Eckehardt Wistuba , Bernhard Schuler , Klemens Mathauer
IPC分类号： C08F224
CPC分类号： D21H19/58 , C08F265/06 , C08F285/00 , C08F291/00 , C09D151/003 , C09J151/003 , Y10S525/902 , Y10S526/902 , C08F2/22
摘要： A process for preparing aqueous polymer dispersions comprises first of all subjecting ethylenically unsaturated monomers to free-radical aqueous emulsion polymerization to prepare an aqueous dispersion of a polymer 1 having a glass transition temperature Tg1, then dissolving further, comparatively hard monomers in the dispersed particles of the polymer 1, and subsequently carrying out free-radical polymerization of said monomers dissolved in said particles.
摘要翻译：制备聚合物水分散体的方法首先将烯属不饱和单体进行自由基水乳液聚合，以制备具有玻璃化转变温度Tg1的聚合物1的水分散体，然后将较硬的单体进一步溶解在聚合物1，随后进行溶解在所述颗粒中的所述单体的自由基聚合。

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