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1. 发明授权

US08283508B2 Method for producing aromatic compound 失效
标题翻译：芳香族化合物的制备方法
公开(公告)号：US08283508B2
公开(公告)日：2012-10-09
申请号：US12671858
申请日：2008-08-01
申请人： Koji Abe , Yoshihiro Ushigoe , Yuichi Kotou , Ken Ikuno , Takashi Hosomi , Toyoaki Ihara
发明人： Koji Abe , Yoshihiro Ushigoe , Yuichi Kotou , Ken Ikuno , Takashi Hosomi , Toyoaki Ihara
IPC分类号： C07C1/32
CPC分类号： B01J31/04 , B01J21/18 , B01J23/42 , B01J23/44 , B01J2231/64 , C07C1/322 , C07C2523/44 , C07C2531/04 , C07C15/02
摘要： The present invention is a method for producing an aromatic compound by substituting the sulfonic acid group in a sulfonic acid aromatic-ester with a hydrogen atom in the presence of a platinum group metal catalyst, wherein an alkali metal carboxylate and/or an ammonium formate are made to coexist in the system. According to the present invention, an aromatic compound where the sulfonic acid group in a sulfonic acid aromatic-ester is substituted with a hydrogen atom, can be produced efficiently with good operability without using metal magnesium.
摘要翻译：本发明是通过在铂族金属催化剂的存在下用氢原子取代磺酸芳族酯中的磺酸基而制备芳族化合物的方法，其中碱金属羧酸盐和/或甲酸铵是在系统中共存。根据本发明，可以在不使用金属镁的情况下，以良好的可操作性有效地制备磺酸芳族酯中的磺酸基被氢原子取代的芳族化合物。

2. 发明申请

US20110230694A1 METHOD FOR PRODUCING AROMATIC COMPOUND 失效
标题翻译：生产芳香化合物的方法
公开(公告)号：US20110230694A1
公开(公告)日：2011-09-22
申请号：US12671858
申请日：2008-08-01
申请人： Koji Abe , Yoshihiro Ushigoe , Yuichi Kotou , Ken Ikuno , Takashi Hosomi , Toyoaki Ihara
发明人： Koji Abe , Yoshihiro Ushigoe , Yuichi Kotou , Ken Ikuno , Takashi Hosomi , Toyoaki Ihara
IPC分类号： C07C1/32
CPC分类号： B01J31/04 , B01J21/18 , B01J23/42 , B01J23/44 , B01J2231/64 , C07C1/322 , C07C2523/44 , C07C2531/04 , C07C15/02
摘要： The present invention is a method for producing an aromatic compound by substituting the sulfonic acid group in a sulfonic acid aromatic-ester with a hydrogen atom in the presence of a platinum group metal catalyst, wherein an alkali metal carboxylate and/or an ammonium formate are made to coexist in the system. According to the present invention, an aromatic compound where the sulfonic acid group in a sulfonic acid aromatic-ester is substituted with a hydrogen atom, can be produced efficiently with good operability without using metal magnesium.
摘要翻译：本发明是通过在铂族金属催化剂的存在下用氢原子取代磺酸芳族酯中的磺酸基而制备芳族化合物的方法，其中碱金属羧酸盐和/或甲酸铵是在系统中共存。根据本发明，可以在不使用金属镁的情况下，以良好的可操作性有效地制备磺酸芳族酯中的磺酸基被氢原子取代的芳族化合物。

3. 发明授权

US09362595B2 Nonaqueous electrolytic solution and energy storage device using same 有权
标题翻译：非水电解液及储能装置使用
公开(公告)号：US09362595B2
公开(公告)日：2016-06-07
申请号：US14111451
申请日：2012-03-26
申请人： Koji Abe , Kazuhiro Miyoshi , Yuichi Kotou
发明人： Koji Abe , Kazuhiro Miyoshi , Yuichi Kotou
IPC分类号： H01M10/056 , H01M10/0567 , H01M10/0569 , H01M10/0525 , H01G11/06 , H01G11/60 , H01M10/48 , H01G11/64
CPC分类号： H01M10/0569 , H01G11/06 , H01G11/60 , H01G11/64 , H01M10/0525 , H01M10/0567 , H01M10/48 , H01M2200/20 , H01M2220/20 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： The present invention is to provide a nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, wherein the nonaqueous solvent includes 0.01 to 40% by volume of an ester having two alkyl groups at the α-position carbon of the carbonyl group and being represented by the following general formula (I), and an energy storage device. (in the above formula, R1 is an alkyl group, an alkenyl group or an alkynyl group in which at least one of the hydrogen atoms may be substituted with a halogen atom, R2 and R3 are an alkyl group in which at least one of the hydrogen atoms may be substituted with a halogen atom, and R2 and R3 may be linked to each other to form a ring. However, when R2 and R3 do not form a ring, R3 is an alkyl group in which at least one of the hydrogen atoms may be substituted with a halogen atom.).
摘要翻译：本发明提供一种通过将电解质盐溶解在非水溶剂中制备的非水电解液，其中非水溶剂包括0.01至40体积％的在羰基的α-位碳上具有两个烷基的酯，由以下通式（I）表示，以及储能装置。（在上式中，R 1是其中至少一个氢原子可以被卤素原子取代的烷基，烯基或炔基，R 2和R 3是烷基，其中至少一个氢原子可以被卤素原子取代，R2和R3可以彼此连接形成环，但是当R2和R3不形成环时，R3是烷基，其中至少一个氢原子可以被卤素原子取代）。

4. 发明申请

US20140030609A1 NONAQUEOUS ELECTROLYTIC SOLUTION AND ENERGY STORAGE DEVICE USING SAME 有权
标题翻译：非电解电解质和使用相同的能量储存装置
公开(公告)号：US20140030609A1
公开(公告)日：2014-01-30
申请号：US14111451
申请日：2012-03-26
申请人： Koji Abe , Kazuhiro Miyoshi , Yuichi Kotou
发明人： Koji Abe , Kazuhiro Miyoshi , Yuichi Kotou
IPC分类号： H01M10/0569 , H01M10/0525
CPC分类号： H01M10/0569 , H01G11/06 , H01G11/60 , H01G11/64 , H01M10/0525 , H01M10/0567 , H01M10/48 , H01M2200/20 , H01M2220/20 , Y02E60/122 , Y02E60/13 , Y02T10/7011 , Y02T10/7022
摘要： The present invention is to provide a nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, wherein the nonaqueous solvent includes 0.01 to 40% by volume of an ester having two alkyl groups at the α-position carbon of the carbonyl group and being represented by the following general formula (I), and an energy storage device. (in the above formula, R1 is an alkyl group, an alkenyl group or an alkynyl group in which at least one of the hydrogen atoms may be substituted with a halogen atom, R2 and R3 are an alkyl group in which at least one of the hydrogen atoms may be substituted with a halogen atom, and R2 and R3 may be linked to each other to form a ring. However, when R2 and R3 do not form a ring, R3 is an alkyl group in which at least one of the hydrogen atoms may be substituted with a halogen atom.)
摘要翻译：本发明提供一种通过将电解质盐溶解在非水溶剂中制备的非水电解液，其中非水溶剂包括0.01至40体积％的在羰基的α位碳上具有两个烷基的酯，和由以下通式（I）表示，以及储能装置。（在上式中，R 1是其中至少一个氢原子可以被卤素原子取代的烷基，烯基或炔基，R 2和R 3是烷基，其中至少一个氢原子可以被卤素原子取代，R2和R3可以彼此连接形成环，但是当R2和R3不形成环时，R3是烷基，其中至少一个氢原子可以被卤原子取代。）

5. 发明授权

US09203113B2 Nonaqueous electrolyte solution, electrochemical element using same, and 1,2-dioxypropane compound used in same 有权
标题翻译：非水电解液，使用该电解液的电化学元件，及其中使用的1,2-二氧代丙烷化合物
公开(公告)号：US09203113B2
公开(公告)日：2015-12-01
申请号：US13634006
申请日：2011-03-24
申请人： Kazuhiro Miyoshi , Yuichi Kotou , Shoji Shikita
发明人： Kazuhiro Miyoshi , Yuichi Kotou , Shoji Shikita
IPC分类号： H01M10/0567 , H01M4/131 , H01M4/52 , H01M4/58 , H01M4/587 , H01M4/38 , C07D327/10 , H01M10/052 , C07D317/18 , C07D317/38 , C07D497/04 , H01M10/0569 , C07F9/6574
CPC分类号： H01M10/0567 , C07D317/18 , C07D317/38 , C07D327/10 , C07D497/04 , C07F9/65742 , H01M4/131 , H01M4/386 , H01M4/387 , H01M4/52 , H01M4/5825 , H01M4/587 , H01M10/052 , H01M10/0569 , H01M2300/0037 , Y02E60/122 , Y02T10/7011
摘要： An object of the present invention is to provide a nonaqueous electrolytic solution capable of improving low-temperature load characteristics after high temperature charging storage, an electrochemical element using it, and a 1,2-dioxypropane compound used for it.The nonaqueous electrolytic solution of the present invention comprises an electrolyte salt dissolved in a nonaqueous solvent, and contains a 1,2-dioxypropane compound represented by the above-mentioned general formula (I). (wherein R1 and R2 each represent a hydrogen atom, or an alkyl group having from 1 to 6 carbon atoms; X1 represents a group selected from —S(═O)—, —S(═O)2—, —C(═O)—, —CR3R4—, —P(═O)(OR5)— and —SiR6R7—; R3 and R4 each represent a hydrogen atom, or an alkyl group having from 1 to 6 carbon atoms; R5 to R7 each represent an alkyl group having from 1 to 6 carbon atoms. Y1 represents an alkylsulfinyl group, an alkenylsulfinyl group, an alkynylsulfinyl group, an arylsulfinyl group, an alkylsulfonyl group, an alkenylsulfonyl group, an alkynylsulfonyl group, or an arylsulfonyl group; Z1 represents a hydrogen atom, an alkyl group, an alkylsulfinylmethyl group, an alkenylsulfinylmethyl group, an alkynylsulfinylmethyl group, an arylsulfinylmethyl group, an alkylsulfonylmethyl group, an alkenylsulfonylmethyl group, an alkynylsulfonylmethyl group, or an arylsulfonylmethyl group; provided that at least one hydrogen atom on the carbon atom of X1, Y1 and Z1 may be substituted with a halogen atom).
摘要翻译：本发明的目的是提供一种能够提高高温充电保存后的低温负荷特性的非水电解液，使用它的电化学元件和用于其的1,2-二氧代丙烷化合物。本发明的非水电解液包含溶解在非水溶剂中的电解质盐，并含有上述通式（I）表示的1,2-二氧代丙烷化合物。（其中R 1和R 2各自表示氢原子或具有1至6个碳原子的烷基; X 1表示选自-S（= O） - ， - S（= O）2 - ， - C（= O） - ， - CR 3 R 4 - ， - P（= O）（OR 5） - 和-SiR 6 R 7 - ; R 3和R 4各自表示氢原子或具有1至6个碳原子的烷基; 具有1至6个碳原子的烷基，Y1表示烷基亚磺酰基，烯基亚磺酰基，炔基亚磺酰基，芳基亚磺酰基，烷基磺酰基，链烯基磺酰基，炔基磺酰基或芳基磺酰基; Z1表示氢原子烷基，烷基亚磺酰基甲基，烯基亚磺酰基甲基，炔基亚磺酰基甲基，芳基亚磺酰基甲基，烷基磺酰基甲基，链烯基磺酰基甲基，炔基磺酰基甲基或芳基磺酰基甲基;条件是：至少一个碳原子上的氢原子 X1，Y1和Z1可以是不同的用卤素原子）。

6. 发明申请

US20130004862A1 NONAQUEOUS ELECTROLYTE SOLUTION, ELECTROCHEMICAL ELEMENT USING SAME, AND 1,2-DIOXYPROPANE COMPOUND USED IN SAME 有权
标题翻译：非电解电解质溶液，使用它们的电化学元素和使用于其中的1,2-二氧戊环化合物
公开(公告)号：US20130004862A1
公开(公告)日：2013-01-03
申请号：US13634006
申请日：2011-03-24
申请人： Kazuhiro Miyoshi , Yuichi Kotou , Shoji Shikita
发明人： Kazuhiro Miyoshi , Yuichi Kotou , Shoji Shikita
IPC分类号： H01M10/056 , H01G9/00 , C07D327/10 , C07D317/36 , H01G9/035 , H01G9/038
CPC分类号： H01M10/0567 , C07D317/18 , C07D317/38 , C07D327/10 , C07D497/04 , C07F9/65742 , H01M4/131 , H01M4/386 , H01M4/387 , H01M4/52 , H01M4/5825 , H01M4/587 , H01M10/052 , H01M10/0569 , H01M2300/0037 , Y02E60/122 , Y02T10/7011
摘要： An object of the present invention is to provide a nonaqueous electrolytic solution capable of improving low-temperature load characteristics after high temperature charging storage, an electrochemical element using it, and a 1,2-dioxypropane compound used for it.The nonaqueous electrolytic solution of the present invention comprises an electrolyte salt dissolved in a nonaqueous solvent, and contains a 1,2-dioxypropane compound represented by the above-mentioned general formula (I). (wherein R1 and R2 each represent a hydrogen atom, or an alkyl group having from 1 to 6 carbon atoms; X1 represents a group selected from —S(═O)—, —S(═O)2—, —C(═O)—, —CR3R4—, —P(═O)(OR5)— and —SiR6R7—; R3 and R4 each represent a hydrogen atom, or an alkyl group having from 1 to 6 carbon atoms; R5 to R7 each represent an alkyl group having from 1 to 6 carbon atoms. Y1 represents an alkylsulfinyl group, an alkenylsulfinyl group, an alkynylsulfinyl group, an arylsulfinyl group, an alkylsulfonyl group, an alkenylsulfonyl group, an alkynylsulfonyl group, or an arylsulfonyl group; Z1 represents a hydrogen atom, an alkyl group, an alkylsulfinylmethyl group, an alkenylsulfinylmethyl group, an alkynylsulfinylmethyl group, an arylsulfinylmethyl group, an alkylsulfonylmethyl group, an alkenylsulfonylmethyl group, an alkynylsulfonylmethyl group, or an arylsulfonylmethyl group; provided that at least one hydrogen atom on the carbon atom of X1, Y1 and Z1 may be substituted with a halogen atom).
摘要翻译：本发明的目的是提供一种能够提高高温充电保存后的低温负荷特性的非水电解液，使用它的电化学元件和用于其的1,2-二氧代丙烷化合物。本发明的非水电解液包含溶解在非水溶剂中的电解质盐，并含有上述通式（I）表示的1,2-二氧代丙烷化合物。（其中R 1和R 2各自表示氢原子或具有1至6个碳原子的烷基; X 1表示选自-S（= O） - ， - S（= O）2 - ， - C（= O） - ， - CR 3 R 4 - ， - P（= O）（OR 5） - 和-SiR 6 R 7 - ; R 3和R 4各自表示氢原子或具有1至6个碳原子的烷基; 具有1至6个碳原子的烷基，Y1表示烷基亚磺酰基，烯基亚磺酰基，炔基亚磺酰基，芳基亚磺酰基，烷基磺酰基，链烯基磺酰基，炔基磺酰基或芳基磺酰基; Z1表示氢原子烷基，烷基亚磺酰基甲基，烯基亚磺酰基甲基，炔基亚磺酰基甲基，芳基亚磺酰基甲基，烷基磺酰基甲基，链烯基磺酰基甲基，炔基磺酰基甲基或芳基磺酰基甲基;条件是：至少一个碳原子上的氢原子 X1，Y1和Z1可以是不同的用卤素原子）。

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