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    • 5. 发明申请
    • NONAQUEOUS ELECTROLYTE SOLUTION AND LITHIUM SECONDARY BATTERY USING SAME
    • 非电解电解液和锂二次电池使用相同
    • US20090280404A1
    • 2009-11-12
    • US12064337
    • 2006-08-11
    • Koji AbeKazuhiro MiyoshiMasahide KondoManabu Takase
    • Koji AbeKazuhiro MiyoshiMasahide KondoManabu Takase
    • H01M6/14H01M6/16
    • H01M10/0525H01M10/0567H01M10/0569H01M2300/004
    • The present invention provides a nonaqueous electrolytic solution exhibiting excellent electrical capacity, long-term cycle property, and storage property in a charged state; and a lithium secondary battery using the nonaqueous electrolytic solution.The nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, comprises 0.001% to 5% by weight of a tin compound represented by the following general formula (I) and/or (II), on the basis of the weight of the nonaqueous electrolytic solution: R1R2R3Sn-MR4R5R6  (I) where R1 to R3 each represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or an aryloxy group; R4 to R6 each represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, or an aryl group; M represents Si or Ge; and SnX2  (II) where X represents β-diketonate.
    • 本发明提供一种在充电状态下显示出优异的电容,长期循环性能和储存性能的非水电解液。 以及使用非水电解液的锂二次电池。 其中电解质盐溶解在非水溶剂中的非水电解液包含0.001重量%至5重量%的由以下通式(I)和/或(II)表示的锡化合物,基于重量 的非水电解液:R1R2R3Sn-MR4R5R6(I)其中R1至R3各自表示氢原子,卤素原子,烷基,烯基,炔基,芳基或芳氧基; R4至R6各自表示氢原子,卤素原子,烷基,烯基,炔基或芳基; M表示Si或Ge; 和SnX 2(II),其中X代表β-二酮。
    • 6. 发明授权
    • Nonaqueous electrolyte solution and lithium secondary battery using same
    • 非水电解液和锂二次电池使用相同
    • US08124273B2
    • 2012-02-28
    • US12064337
    • 2006-08-11
    • Koji AbeKazuhiro MiyoshiMasahide KondoManabu Takase
    • Koji AbeKazuhiro MiyoshiMasahide KondoManabu Takase
    • H01M4/36
    • H01M10/0525H01M10/0567H01M10/0569H01M2300/004
    • The present invention provides a nonaqueous electrolytic solution exhibiting excellent electrical capacity, long-term cycle property, and storage property in a charged state; and a lithium secondary battery using the nonaqueous electrolytic solution.The nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, comprises 0.001% to 5% by weight of a tin compound represented by the following general formula (I) and/or (II), on the basis of the weight of the nonaqueous electrolytic solution: R1R2R3Sn-MR4R5R6  (I) where R1 to R3 each represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or an aryloxy group; R4 to R6 each represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, or an aryl group; M represents Si or Ge; and SnX2  (II) where X represents β-diketonate.
    • 本发明提供一种在充电状态下显示出优异的电容,长期循环性能和储存性能的非水电解液。 以及使用非水电解液的锂二次电池。 其中电解质盐溶解在非水溶剂中的非水电解液包含0.001重量%至5重量%的由以下通式(I)和/或(II)表示的锡化合物,基于重量 的非水电解液:R1R2R3Sn-MR4R5R6(I)其中R1至R3各自表示氢原子,卤素原子,烷基,烯基,炔基,芳基或芳氧基; R4至R6各自表示氢原子,卤素原子,烷基,烯基,炔基或芳基; M表示Si或Ge; 和SnX2(II),其中X表示&bgr; - 酮。
    • 8. 发明授权
    • Phenyl sulfonate compound, nonaqueous electrolyte solution using the same, and lithium battery
    • 苯磺酸盐化合物,使用其的非水电解质溶液和锂电池
    • US08512897B2
    • 2013-08-20
    • US12740122
    • 2008-10-24
    • Koji AbeKazuhiro Miyoshi
    • Koji AbeKazuhiro Miyoshi
    • H01M6/14
    • H01M10/0567C07C309/65C07C309/66H01M4/131H01M4/133H01M10/0525H01M2300/004Y02T10/7011
    • Provided are (1) a novel phenyl sulfonate compound, (2) a nonaqueous electrolytic solution comprising an electrolyte salt dissolved in a nonaqueous solvent and containing a phenyl sulfonate compound of the following general formula (II) in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution, and (3) a lithium battery containing the nonaqueous electrolytic solution and excellent in low-temperature cycle property. (wherein X1 to X5 each independently represents a fluorine atom or a hydrogen atom, and from one to four of these are fluorine atoms; R2 represents a linear or branched alkyl group having from 1 to 6 carbon atoms, a linear or branched alkyl group having from 1 to 6 carbon atoms in which at least one hydrogen atom is substituted with a halogen atom, or an aryl group having from 6 to 9 carbon atoms).
    • 提供了(1)一种新的苯基磺酸盐化合物,(2)一种非水电解液,其包含溶解在非水溶剂中的电解质盐,并含有0.01至10%的下列通式(II)的苯基磺酸盐化合物: 的非水电解液,(3)含有非水电解液的锂电池,低温循环性优异。 (其中X1至X5各自独立地表示氟原子或氢原子,并且其中1至4个为氟原子; R2表示具有1至6个碳原子的直链或支链烷基,直链或支链烷基具有 1至6个碳原子,其中至少一个氢原子被卤素原子取代,或具有6至9个碳原子的芳基)。