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    • 3. 发明授权
    • Process for exposing a photosensitive resin composition to light
    • 将光敏树脂组合物曝光的方法
    • US5330882A
    • 1994-07-19
    • US709964
    • 1991-06-04
    • Chitoshi KawaguchiSeiji ArimatsuKatsuji KonishiKazunori Kanda
    • Chitoshi KawaguchiSeiji ArimatsuKatsuji KonishiKazunori Kanda
    • G03F7/20G03C5/00
    • G03F7/2022Y10S522/913
    • The present invention provides an improved process by which dissolved oxygen is effectively removed from a photosensitive resin layer of a photosensitive resin plate. The process comprises preliminarily exposing the photosensitive resin to light to quench oxygen dissolved in said photosensitive resin layer before conducting a main exposure. The photosensitive resin layer is prepared from a photosensitive resin composition which comprises:(a) a polymer binder,(b) a radically polymerizable monomer,(c) a sensitizing dye, and(d) a photopolymerization initiator which is excited by a light of a different wave length from a light exciting the sensitizing dye.The preliminary exposure is conducted with a light only exciting the sensitizing dye and the main exposure is conducted with a light exciting the photopolymerization initiator.
    • 本发明提供了一种改进的方法,通过该方法可以有效地从感光性树脂板的感光性树脂层除去溶解氧。 该方法包括在进行主曝光之前,将感光性树脂预先曝光,以使溶解在所述感光性树脂层中的氧气骤冷。 感光性树脂层由感光性树脂组合物制成,该感光性树脂组合物包含:(a)聚合物粘合剂,(b)自由基聚合性单体,(c)敏化染料,(d)光聚合引发剂, 来自激发敏化染料的光的不同波长。 用仅激发敏化染料的光进行初步曝光,并且通过光激发光聚合引发剂进行主曝光。
    • 5. 发明授权
    • Photosensitive resin composition
    • 感光树脂组合物
    • US5073477A
    • 1991-12-17
    • US621435
    • 1990-12-04
    • Hidefumi KusudaKatsuji KonishiKoichi Ueda
    • Hidefumi KusudaKatsuji KonishiKoichi Ueda
    • G03F7/032G03F7/027G03F7/028G03F7/031G03F7/033G03F7/038
    • G03F7/033Y10S430/108Y10S430/111
    • Disclosed is a photosensitive resin composition for flexographic printing which has high water developability and good mechanical strength. The resin composition comprises (A) a partially crosslinked copolymer prepared by a radical emulsion polymerization of a specific monomer mixture (B) a linear polymer having a molecular weight of at least 5,000, which has at least 30 mol % of a conjugated diene unit, (C) a basic nitrogen atom-containing compound, (D) a photopolymerizable ethylenically unsaturated monomer, and (E) a photopolymerization inhitiator. The present invention also provides a resin plate for flexographic printing obtained from the above mentioned resin composition and a process for preparing it. The present invention further provides a printing plate obtained from the resin plate and a process for preparing it.
    • 公开了一种用于柔性版印刷的感光性树脂组合物,其具有高水显影性和良好的机械强度。 树脂组合物包含(A)通过特定单体混合物(B)的自由基乳液聚合制备的部分交联共聚物(B)分子量至少为5,000的直链聚合物,其具有至少30mol%的共轭二烯单元, (C)含碱性氮原子的化合物,(D)可光聚合的烯属不饱和单体,和(E)光聚合吸附剂。 本发明还提供了由上述树脂组合物获得的用于柔性版印刷的树脂板及其制备方法。 本发明还提供从树脂板获得的印版及其制备方法。
    • 7. 发明授权
    • Water-developable photosensitive composition for producing relief plates
    • 用于生产浮雕板的水显影光敏组合物
    • US5175076A
    • 1992-12-29
    • US805671
    • 1991-12-17
    • Katsukiyo IshikawaHidefumi KusudaKatsuji Konishi
    • Katsukiyo IshikawaHidefumi KusudaKatsuji Konishi
    • G03F7/033
    • G03F7/033Y10S430/111Y10S430/12Y10S430/121
    • A water-developable photosensitive resin plate suitable for the manufacture of a relief printing plate having high resistance to water-based inks, high resilience and excellent form stability, which comprises:(A) a copolymer comprising units of (i) an aliphatic conjugated diene monomer (ii) and .alpha., .beta.-ethylenically unsaturated carboxylic acid and (iii) a polyfunctional vinyl monomer, optionally with (iv) a monofunctional vinyl monomer, the content of the aliphatic conjugated diene monomer (i), the .alpha., .beta.-ethylenically unsaturated carboxylic acid (ii), the polyfunctional vinyl monomer (iii) and the monofunctional vinyl monomer (iv) being respectively from about 5 to 95 mol %, from about 1 to 30 mol %, from about 0.1 to 10 mol % and 0 to 70 mol % based on the combination of those monomeric components;(B) a basic nitrogen atom-containing compound;(C) an ethylenically unsaturated monomer; and(D) a photopolymerization initiator.
    • PCT No.PCT / US87 / 02372 Sec。 371日期1990年7月12日 102(e)日期1990年7月12日PCT提交1987年9月22日PCT公布。 出版物WO88 / 02135 日本,1988年3月24日。适用于制造具有高耐水性油墨,高回弹性和优异形状稳定性的凸版印刷版的水显影感光性树脂板,其包含:(A)包含 (i)脂族共轭二烯单体(ii)和α,β-烯属不饱和羧酸和(iii)多官能乙烯基单体,任选具有(iv)单官能乙烯基单体,脂族共轭二烯单体(i) ,α,β-烯属不饱和羧酸(ii),多官能乙烯基单体(iii)和单官能乙烯基单体(iv)分别为约5至95摩尔%,约1至30摩尔%,约0.1 〜10摩尔%,0〜70摩尔%。 (B)含碱性氮原子的化合物; (C)烯属不饱和单体; 和(D)光聚合引发剂。