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    • 7. 发明授权
    • High corrosion resistance hot dip galvanized steel material
    • 高耐腐蚀热浸镀锌钢材
    • US08663818B2
    • 2014-03-04
    • US12224967
    • 2007-03-14
    • Koichi NoseKohei TokudaYuichi SatoMakoto Nakazawa
    • Koichi NoseKohei TokudaYuichi SatoMakoto Nakazawa
    • B32B15/00B32B15/01
    • C23C2/06B32B15/013C22C18/00C22C18/04C22C21/06C22C21/08C22C23/02C22C23/04C22C30/06C22C45/00C22C45/005C23C2/28Y10T428/12757Y10T428/12771Y10T428/12792Y10T428/12799Y10T428/12951
    • The present invention provides a high corrosion resistance hot dip galvannealed steel material comprised of a Zn-based hot dip plated steel material achieving both a higher corrosion resistance of the plated layer itself by the added elements and sacrificial protection of iron metal by the plated layer or workability free of degradation caused of formation of intermetallic compounds by added elements, that is, a high corrosion resistance hot dip Zn plated steel material characterized in that an alloy plated layer containing Zn: 35 mass % or more, preferably 40 mass % or more, contains a non-equilibrium phase having a heat capacity by differential scanning calorimetry of 1 J/g or more. Furthermore, 5% or more, preferably 50% or more in terms of vol % is an amorphous phase. The alloy layer may contain, by mass %, Mg: 1 to 60% and Al: 0.07 to 59%, may further contain one or more elements selected from Cr, Mn, Fe, Co, Ni, and Cu in a total of 0.1 to 10%, and may in addition contain one or more elements of 0.1 to 10% of La, 0.1 to 10% of Ce, 0.1 to 10% of Ca, 0.1 to 10% of Sn, 0.005 to 2% of P, and 0.02 to 7% of Si.
    • 本发明提供一种耐腐蚀性高的浸镀热镀锌钢材,其由Zn基热浸镀钢材组成,通过添加的元素实现镀层本身的较高的耐腐蚀性,并通过镀层牺牲铁金属的牺牲保护,或 不含添加元素形成金属间化合物的劣化的可加工性,即耐腐蚀性高的镀锌钢材,其特征在于,含有Zn:35质量%以上,优选为40质量%以上的合金镀层, 含有通过差示扫描量热法测定的热容量为1J / g以上的非平衡相。 此外,以体积%计为5%以上,优选为50%以上是非晶相。 合金层可以以质量%计含有Mg:1〜60%,Al:0.07〜59%,还可以含有选自Cr,Mn,Fe,Co,Ni和Cu中的一种或多种元素,总计0.1 〜10%,另外可以含有0.1〜10%的La,0.1〜10%的Ce,0.1〜10%的Ca,0.1〜10%的Sn,0.005〜2%的P,以及 0.02〜7%的Si。
    • 8. 发明申请
    • High Corrosion Resistance Hot dip Galvanized Steel Material
    • 耐腐蚀性高浸镀锌钢材料
    • US20090053555A1
    • 2009-02-26
    • US12224967
    • 2007-03-14
    • Koichi NoseKohei TokudaYuichi SatoMakoto Nakazawa
    • Koichi NoseKohei TokudaYuichi SatoMakoto Nakazawa
    • B32B15/20B32B15/01B32B15/18
    • C23C2/06B32B15/013C22C18/00C22C18/04C22C21/06C22C21/08C22C23/02C22C23/04C22C30/06C22C45/00C22C45/005C23C2/28Y10T428/12757Y10T428/12771Y10T428/12792Y10T428/12799Y10T428/12951
    • The present invention provides a high corrosion resistance hot dip galvannealed steel material comprised of a Zn-based hot dip plated steel material achieving both a higher corrosion resistance of the plated layer itself by the added elements and sacrificial protection of iron metal by the plated layer or workability free of degradation caused of formation of intermetallic compounds by added elements, that is, a high corrosion resistance hot dip Zn plated steel material characterized in that an alloy plated layer containing Zn: 35 mass % or more, preferably 40 mass % or more, contains a non-equilibrium phase having a heat capacity by differential scanning calorimetry of 1 J/g or more. Furthermore, 5% or more, preferably 50% or more in terms of vol % is an amorphous phase. The alloy layer may contain, by mass %, Mg: 1 to 60% and Al: 0.07 to 59%, may further contain one or more elements selected from Cr, Mn, Fe, Co, Ni, and Cu in a total of 0.1 to 10%, and may in addition contain one or more elements of 0.1 to 10% of La, 0.1 to 10% of Ce, 0.1 to 10% of Ca, 0.1 to 10% of Sn, 0.005 to 2% of P, and 0.02 to 7% of Si.
    • 本发明提供一种耐腐蚀性高的浸镀热镀锌钢材,其由Zn基热浸镀钢材组成,通过添加的元素实现镀层本身的较高的耐腐蚀性,并通过镀层牺牲铁金属的牺牲保护,或 不含添加元素形成金属间化合物的劣化的可加工性,即耐腐蚀性高的镀锌钢材,其特征在于,含有Zn:35质量%以上,优选为40质量%以上的合金镀层, 含有通过差示扫描量热法测定的热容量为1J / g以上的非平衡相。 此外,以体积%计为5%以上,优选为50%以上是非晶相。 合金层可以以质量%计含有Mg:1〜60%,Al:0.07〜59%,还可以含有选自Cr,Mn,Fe,Co,Ni和Cu中的一种或多种元素,总计0.1 〜10%,另外可以含有0.1〜10%的La,0.1〜10%的Ce,0.1〜10%的Ca,0.1〜10%的Sn,0.005〜2%的P,以及 0.02〜7%的Si。