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1. 发明授权

US5075444A Disodium salt of trimercapto-s-triazine hexahydrate, and method of its preparation 失效
标题翻译：三嗪硫青铜盐酸盐及其制备方法
公开(公告)号：US5075444A
公开(公告)日：1991-12-24
申请号：US569139
申请日：1990-08-17
申请人： Klaus Hentschel , Marc Samson , Marcel Vingerhoets , Karl-Ludwig Weber
发明人： Klaus Hentschel , Marc Samson , Marcel Vingerhoets , Karl-Ludwig Weber
IPC分类号： C02F1/52 , C02F1/62 , C07D251/38
CPC分类号： C02F1/5272 , C07D251/38
摘要： The disodium salt of trimercapto-s-triazine hexahydrate (TMT-Na.sub.2.6H.sub.2 O) which has a considerably higher water solubility than previously known TMT sodium salts. It is used for separating heavy metals from aqueous phase, especially from waste water.TMT-Na.sub.2.6H.sub.2 O is prepared by reacting TMT-Na.sub.3 .9H.sub.2 O, available from cyanuric chloride, with trimercapto-s-triazine (TMT-Ha.sub.3) in a molar ratio of 2-2.1 to 1 in aqueous medium with subsequent crystallization of the TMT-Na.sub.2 .6H.sub.2 O.
摘要翻译：三水合三钙六水合物的二钠盐（TMT-Na2.6H2O）具有比先前已知的TMT钠盐显着更高的水溶性。用于从水相中分离重金属，特别是废水。 TMT-Na2.6H2O是通过在水性介质中使得得自氰尿酰氯的TMT-Na 3·9H 2 O与三聚巯基-s-三嗪（TMT-Ha 3）的摩尔比为2-2.1〜1，随后TMT的结晶 -Na2.6H2O。

2. 发明授权

US5258515A Aqueous solutions of sodium salts of trimercapto-s-triazine, their preparation and use 失效
标题翻译：三巯基-s-三嗪的钠盐水溶液，其制备和用途
公开(公告)号：US5258515A
公开(公告)日：1993-11-02
申请号：US932745
申请日：1992-08-25
申请人： Klaus Hentschel , Marc Samson , Marcel Vingerhoets , Karl-Ludwig Weber
发明人： Klaus Hentschel , Marc Samson , Marcel Vingerhoets , Karl-Ludwig Weber
IPC分类号： C07D251/38
CPC分类号： C07D251/38
摘要： The invention relates to aqueous solutions of sodium salts of trimercapto-s-triazine whose molar saturation concentration at 0.degree. C. to 40.degree. C. is above the saturation concentration of trimercapto-s-triazine trisodium salt (TMT-Na.sub.3). More than two but less than three hydrogen atoms of the trimercapto-s-triazine are replaced by sodium ions. The solutions preferably contain trimercapto-s-triazine disodium salt (TMT-Na.sub.2) in addition to a little TMT-Na.sub.3. Surprisingly, the water solubility of TMT-Na.sub.2 is greater than that of TMT-Na.sub.3. The solutions represent a suitable supply form for the active substance trimercapto-s-triazine (TMT-H.sub.3) used in the separation of heavy metals The preparation takes place by means of reacting TMT-Na.sub.3 with TMT-H.sub.3 in a molar ratio of 1:greater than 0-less than 0.5, especially 1:0.1 to 1:
摘要翻译：本发明涉及三聚巯基三嗪的钠盐水溶液，其摩尔饱和浓度在0℃至40℃高于三巯基-s-三嗪三钠盐（TMT-Na 3）的饱和浓度。三聚巯基-s-三嗪的多于两个但少于三个的氢原子被钠离子代替。除了少量TMT-Na3之外，溶液优选含有三巯基-s-三嗪二钠盐（TMT-Na2）。令人惊讶的是，TMT-Na2的水溶性大于TMT-Na3的水溶性。该溶液代表用于分离重金属的活性物质三巯基-s-三嗪（TMT-H3）的合适供应形式。该制备通过使TMT-Na 3与TMT-H3以摩尔比1：大于0-小于0.5，特别是在水溶液中为1：0.1至1：<0.5。

3. 发明授权

US5852217A Process for the production of primary and/or secondary amines from oxo compounds 失效
标题翻译：从氧代化合物生产伯胺和/或仲胺的方法
公开(公告)号：US5852217A
公开(公告)日：1998-12-22
申请号：US888394
申请日：1997-07-07
申请人： Thomas Haas , Dietrich Arntz , Karl-Ludwig Weber , Willi Hofen , Stefan Wieland
发明人： Thomas Haas , Dietrich Arntz , Karl-Ludwig Weber , Willi Hofen , Stefan Wieland
IPC分类号： C07C209/24 , C07B61/00 , C07C209/26 , C07C209/48 , C07C209/52 , C07C211/01 , C07C211/33 , C07C211/36 , C07C211/43
CPC分类号： C07C209/26 , C07C209/48 , C07C211/36 , C07C2101/14
摘要： This invention relates to a process for the production of primary and/or secondary amines from oxo compounds by catalytic imination of the oxo compound with ammonia or a primary amine and subsequent hydrogenation. Imination proceeds according to the invention in the presence of a novel imination catalyst, namely an organopolysiloxane containing sulphonate groups. This imination catalyst is distinguished by elevated activity. The process is in particular suitable for the production of isophorone diamine from isophorone nitrile, wherein it has proved possible to reduce the content of secondary products and to increase yield.
摘要翻译：本发明涉及通过氧化合物与氨或伯胺的催化模拟和随后的氢化从氧代化合物制备伯胺和/或仲胺的方法。根据本发明，在新型酰化催化剂，即含有磺酸酯基团的有机聚硅氧烷的存在下进行本发明。该仿制催化剂的活性升高。该方法特别适用于从异佛尔酮腈生产异佛尔酮二胺，其中证明可以减少二次产物的含量并提高产率。

4. 发明授权

US5679860A Process for the production of 3-aminoethyl-3,5,5-trimethylcyclohexyl amine 失效
标题翻译： 3-氨基乙基-3,5,5-三甲基环己胺的制备方法
公开(公告)号：US5679860A
公开(公告)日：1997-10-21
申请号：US739044
申请日：1996-10-28
申请人： Thomas Haas , Roland Burmeister , Dietrich Arntz , Karl-Ludwig Weber , Monika Berweiler
发明人： Thomas Haas , Roland Burmeister , Dietrich Arntz , Karl-Ludwig Weber , Monika Berweiler
IPC分类号： B01J21/06 , C07B61/00 , C07C209/48 , C07C209/52 , C07C211/36 , C07C209/32
CPC分类号： C07C211/36 , C07C209/48 , C07C209/52 , C07C2101/14
摘要： A process for producing 3-aminomethyl-3,5,5-trimethylcyclohexyl amine (isophorone diamine) from isophorone nitrile. Isophorone nitrile is iminated in a first stage and then the reaction mixture is subjected to aminating hydrogenation in a second stage in the presence of a fixed bed hydrogenation catalyst based on Raney cobalt. The fixed bed hydrogenation catalyst is produced in a special manner by mixing a powdery Co--containing Raney alloy with powdery cobalt, sintering the powdery mixture to shaped moldings and then activating by leaching with alkali hydroxide solution. The yield and/or space-time yield in isophorone diamine production can be increased.
摘要翻译：由异佛尔酮腈生产3-氨基甲基-3,5,5-三甲基环己胺（异佛尔酮二胺）的方法。在第一阶段中将异佛尔酮腈进行酰化，然后在基于阮内钴的固定床氢化催化剂的存在下，将反应混合物在第二阶段进行氨化氢化。固定床加氢催化剂以特殊的方式通过将粉末状含钴阮内合金与粉末状钴混合，将粉末状混合物烧结成型成形体，然后通过用碱金属氢氧化物溶液浸出而活化。可以增加异佛尔酮二胺生产中的产率和/或时空产率。

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