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    • 1. 发明授权
    • Living polymers, the preparation thereof and the use thereof for
preparing telechelic polymers
    • 活性聚合物,其制备方法及其制备远电子聚合物的用途
    • US5321093A
    • 1994-06-14
    • US764870
    • 1991-09-24
    • Klaus BronstertKonrad KnollErich Haedicke
    • Klaus BronstertKonrad KnollErich Haedicke
    • C08C19/44C08F4/48C08F36/04C08F297/04C08F297/94
    • C08F297/042C08C19/44C08F36/04
    • A process for preparing bifunctional living polymers which are able to forth bifunctional telechelic polymers or block copolymers with at least 3 blocks of conjugated dienes and/or vinylaromatics with molecular weights of from 1,500 to 500,000, by bifunctional initiators whose anionic centers are aliphatic carbon atoms which are substituted by lithium and an aliphatic hydrocarbon radical as well as by either 2 aryl radicals or by one aryl radical and one hydrogen radical, where one of the aryl radicals can also be part of the two anionic centers, in a first stage being reacted in the presence of not more than 2.5 moles of an aliphatic ether or a tertiary amine per mole of lithium and not less than 2 mol/l of a conjugated diene at from -40.degree. to +35.degree. C. with not less than two moles of diene, resulting in the formation of low molecular weight diene oligomers which in turn act as bifunctional initiators, and using the latter in a second reaction stage in a conventional manner at above 40.degree. C., with or without the addition of other monomers, to obtain polymers of the required molecular weight.
    • 制备双官能活性聚合物的方法,其能够通过双官能引发剂(其阴离子中心是脂族碳原子)与分子量为1,500至500,000的至少3个共轭二烯和/或乙烯基芳香族嵌段的双官能遥爪聚合物或嵌段共聚物 被锂和脂族烃基以及2个芳基或一个芳基和一个氢基取代,其中一个芳基也可以是两个阴离子中心的一部分,在第一阶段中被反应 在-40℃至+ 35℃下每摩尔锂和不小于2mol / l共轭二烯的摩尔数不超过2.5摩尔的脂族醚或叔胺的存在,不少于2摩尔的 二烯,导致形成低分子量二烯低聚物,其又作为双官能引发剂,并在上述常规方式的第二反应阶段中使用后者 40℃,加入或不加入其它单体,得到所需分子量的聚合物。