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1. 发明授权

US4907038A Langmuir Blodgett ultrathin membrane of polyfumarate 失效
标题翻译： Langmuir Blodgett多功能富马酸超薄膜
公开(公告)号：US4907038A
公开(公告)日：1990-03-06
申请号：US47887
申请日：1987-05-08
申请人： Kiyotaka Shigehara , Akira Yamada , Masahiko Hara , Hidenari Nakahama , Seizo Miyata , Yoshishige Murata
发明人： Kiyotaka Shigehara , Akira Yamada , Masahiko Hara , Hidenari Nakahama , Seizo Miyata , Yoshishige Murata
IPC分类号： B01D69/12 , B05D1/20 , H01L21/28 , H01L21/312 , H01L29/51 , H01L51/30 , H01L51/50
CPC分类号： H01L51/5012 , B01D69/122 , B05D1/202 , B82Y30/00 , B82Y40/00 , H01L21/28167 , H01L21/28264 , H01L21/3128 , H01L29/51 , H01L29/518 , H01L51/0075 , Y10S428/91 , Y10T428/268
摘要： A Langmuir-Blodgett ultrathin membrane is constituted of polyfumarate having a degree of polymerization of 20 to 10,000. The polyfumarate is obtained by polymerizing fumarate represented by the general formula of: ##STR1## wherein at least one of R.sub.1 and R.sub.2 represents a bulky hydrocarbon group such as a branched alkyl group, a cycloalkyl group or a substituent thereof, a fluorine-substituted hydrocarbon group, a hetero atom-containing hydrocarbon group or a silicon-containing group.
摘要翻译： Langmuir-Blodgett超薄膜由聚合度为20〜10,000的聚富马酸盐构成。聚富马酸盐通过聚合由以下通式表示的富马酸盐获得：其中R 1和R 2中的至少一个表示大体积的烃基，例如支链烷基，环烷基或其取代基，氟取代的烃基团，含杂原子的烃基或含硅基团。

2. 发明授权

US4696838A Method of forming built-up film of fluorinated aliphatic compound on substrate surface 失效
标题翻译：在基材表面形成含氟脂肪族化合物的叠层膜的方法
公开(公告)号：US4696838A
公开(公告)日：1987-09-29
申请号：US874847
申请日：1986-06-16
申请人： Seizo Miyata , Hidenari Nakahama , Takeshi Kasuga
发明人： Seizo Miyata , Hidenari Nakahama , Takeshi Kasuga
IPC分类号： B32B15/082 , B05D1/20 , C08J7/06 , C09D127/12 , C09D127/16 , C09K3/00 , H01B17/60 , H01L21/312 , B05D1/36
CPC分类号： B82Y30/00 , B05D1/202 , B82Y40/00 , H01L21/3128
摘要： Using the Langmuir-Blodgett's technique and a compound represented by the general formula CF.sub.3 (CF.sub.2).sub.n (CH.sub.2).sub.m --X, wherein X is a hydrophilic group, preferably --COOH, n is from 5 to 20 and m is from 0 to 10, a firm built-up film having a desired number of monomolecular layers can surely be formed on a solid substrate surface by spreading a monomolecular film of the fluorinated compound on an aqueous phase containing trivalent metal ions. In the obtained built-up film the CF.sub.3 -terminated molecules are well oriented in the direction of the thickness of the film. The built-up film fully exhibits extreme hydrophobicity, high insulation, low refraction and other properties characteristic of the fluorine-containing compound.
摘要翻译：使用Langmuir-Blodgett技术和由通式CF 3（CF 2）n（CH 2）m X表示的化合物，其中X是亲水基团，优选-COOH，n为5至20，m为0至10，a 通过在含有三价金属离子的水相上涂布含氟化合物的单分子膜，可以可靠地在固体基材表面上形成具有所需数量的单分子层的固体成膜。在获得的积层膜中，CF 3封端的分子在膜的厚度方向上取向良好。该组合膜充分显示含氟化合物的极度疏水性，高绝缘性，低折射性等特性。

3. 发明申请

US20140087289A1 PARTICULATE CARBON CATALYST AND METHOD FOR PRODUCING SAME 有权
标题翻译：颗粒碳催化剂及其生产方法
公开(公告)号：US20140087289A1
公开(公告)日：2014-03-27
申请号：US14119528
申请日：2012-05-21
申请人： Masayuki Chokai , Nobuaki Kido , Yuta Nabae , Masa-aki Kakimoto , Seizo Miyata
发明人： Masayuki Chokai , Nobuaki Kido , Yuta Nabae , Masa-aki Kakimoto , Seizo Miyata
IPC分类号： H01M4/90
CPC分类号： H01M4/9091 , B01J37/084 , B82Y30/00 , C01B32/336 , C01P2004/61 , C01P2004/62 , C01P2004/64 , H01M4/90 , H01M4/96 , H01M2004/8689 , H01M2008/1095
摘要： A particulate carbon catalyst in which particles having a particle diameter of 20 nm-1 μm account for a volume fraction of at least 45%, and the content of nitrogen atoms is 0.1-10 atomic % relative to the amount of carbon atoms.
摘要翻译：粒径为20nm〜1μm的粒子占体积分率至少为45％，氮原子数相对于碳原子数为0.1〜10原子％的粒状碳催化剂。

4. 发明申请

US20080210554A1 Method for treating the surface of object and apparatus thereof 失效
标题翻译：处理物体表面的方法及其装置
公开(公告)号：US20080210554A1
公开(公告)日：2008-09-04
申请号：US11981136
申请日：2007-10-31
申请人： Hideo Yoshida , Seizo Miyata , Masato Sone , Nobuyoshi Sato
发明人： Hideo Yoshida , Seizo Miyata , Masato Sone , Nobuyoshi Sato
IPC分类号： C25B9/00
CPC分类号： B08B3/14 , C25D5/00 , C25D5/08 , C25D17/00 , C25D21/04 , H01L21/02052 , H01L21/2885 , H01L21/32134
摘要： An apparatus for treating the surface of an object to be treated comprising introducing a surface treatment fluid into a reaction vessel (4) capable of receiving an object, introducing the surface treatment fluid into a separation vessel (14) after the object is subjected to surface treatment, and circulating the surface treatment fluid, from which a contaminant has already been removed, to the reaction vessel (4). At the time of treatment on the surface of the object, a circulation passage for the surface treatment fluid including the reaction vessel (4) is communicated and the surface treatment fluid is constantly circulated through the circulation passage.
摘要翻译：一种用于处理待处理物体的表面的装置，包括将表面处理流体引入到能够接收物体的反应容器（4）中，在物体经受表面之后将表面处理流体引入分离容器（14）处理，并且将已经从其中除去污染物的表面处理流体循环到反应容器（4）。在物体表面处理时，包括反应容器（4）的表面处理流体的循环通道连通，表面处理流体不断循环通过循环通道。

5. 发明授权

US5626797A Non linear optical material and method for orientation thereof 失效
标题翻译：非线性光学材料及其取向方法
公开(公告)号：US5626797A
公开(公告)日：1997-05-06
申请号：US387615
申请日：1995-02-13
申请人： Seizo Miyata , Kazuo Yoshinaga , Takeshi Miyazaki
发明人： Seizo Miyata , Kazuo Yoshinaga , Takeshi Miyazaki
IPC分类号： G02F1/361 , F21V9/00 , G02F1/35
CPC分类号： G02F1/3615
摘要： A nonlinear optical material comprises a solid solution of an organic guest compound having an electron donative group or an electron attractive group. The organic guest compound is contained in the nonlinear optical material preferably an oriented form through orientation under melting by application of a DC electric field. The guest compound is preferably a para-di-substituted benzene derivative represented by the formula: ##STR1## wherein A is an electron donative group and B is an electron attractive group.
摘要翻译：非线性光学材料包括具有给电子基团或吸电子基团的有机客体化合物的固溶体。非线性光学材料中的有机客体化合物优选通过施加直流电场在熔融下通过取向而定向。客体化合物优选为由下式表示的对二取代的苯衍生物：其中A是给电子基团，B是吸电子基团。

6. 发明授权

US5045239A Non-linear optical material 失效
标题翻译：非线性光学材料
公开(公告)号：US5045239A
公开(公告)日：1991-09-03
申请号：US362464
申请日：1989-03-17
申请人： Seizo Miyata , Toshiyuki Watanabe , Yoshitaka Goto , Akio Hayashi , Masaharu Nakayama
发明人： Seizo Miyata , Toshiyuki Watanabe , Yoshitaka Goto , Akio Hayashi , Masaharu Nakayama
IPC分类号： G02F1/361
CPC分类号： G02F1/3613
摘要： A non-linear optical material comprises a derivative of chalcone represented by the following general formulae (I) or (II) of: ##STR1## wherein R.sub.1 and R.sub.2 each represent a halogen atom, a hydroxyl group, an amino group, a dimethylamino group, a nitro group, a cyano group, a phenyl group, an acetyl group, an alkyl group having 1 to 18 carbon atoms or an alkyloxy group having 1 to 22 carbon atoms; n.sub.1 and n.sub.2 each represent an interger of from 0 to 21; and m.sub.1 and m.sub.2 each represent an integer of from 0 to 5.
摘要翻译： PCT No.PCT / JP88 / 00740 Sec。 371日期：1989年3月17日 102（e）日期1989年3月17日PCT提交1988年7月22日PCT公布。出版物WO89 / 01181 日期：1989年2月9日。非线性光学材料包含由以下通式（I）或（II）表示的查耳酮衍生物：其中R 1和R 2各自表示卤素原子，羟基，氨基，二甲基氨基，硝基，氰基，苯基，乙酰基，碳原子数1〜18的烷基或具有1〜22个的烷氧基的烷基碳原子 n1和n2分别表示从0到21的整数; m1和m2各自表示0〜5的整数。

7. 发明授权

US4981614A Solid solution 失效
标题翻译：固体溶液
公开(公告)号：US4981614A
公开(公告)日：1991-01-01
申请号：US245643
申请日：1988-09-16
申请人： Takeshi Miyazaki , Seizo Miyata
发明人： Takeshi Miyazaki , Seizo Miyata
IPC分类号： G02F1/361
CPC分类号： G02F1/3615
摘要： An organic guest compound having both an electron attractive group and an electron donative group is blended with a host polymer selected from a lactone polymer and a copolymer nylon to form a solid solution. The solid solution shows good mechanical strength and processability and may be suitably formed into a nonlinear optical device. Even if the guest compound is a compound, such as p-nitroaniline, which has a large non-linearity but is by itself liable to form a centrosymmetrical crystal thus showing no SHG activity, the solid solution obtained by blending it with the host polymer can show a uniform and large SHG activity.

8. 发明申请

US20100000872A1 ELECTROPLATING METHOD 审中-公开
标题翻译：电镀方法
公开(公告)号：US20100000872A1
公开(公告)日：2010-01-07
申请号：US12443766
申请日：2007-04-02
申请人： Tetsuya Shimizu , Hisayoshi Tajima , Seizo Miyata , Masato Sone
发明人： Tetsuya Shimizu , Hisayoshi Tajima , Seizo Miyata , Masato Sone
IPC分类号： C25D21/14
CPC分类号： C25D15/02 , C25D3/38 , C25D5/003 , H01L21/2885 , H01L21/76877
摘要： The surface of a metal base is electroplated by utilizing an induction codeposition phenomenon using at least one of carbon dioxide and inert gas, an electroplating liquid containing a metal powder dispersed therein, and a surfactant in a supercritical state or a subcritical state. The concentration of the metal in the electroplating liquid is in a saturated or supersaturated state. Accordingly, the dissolution speed of the metal base can be suppressed, and, at the same time, a plating layer having a smooth surface can be formed in a short time by utilizing an induction codeposition phenomenon. The electroplating method can be applied even when the metal base is formed of a metallic thin film provided on a surface of an insulating film provided on the substrate, or even when the metal is copper, zinc, iron, nickel, or cobalt. The above constitution can provide an electroplating method which, in electroplating on the surface of a metal base, can prevent the dissolution of the metal base to realize normal electroplating even in the case of a very thin metal base.
摘要翻译：使用二氧化碳和惰性气体中的至少一种，含有分散在其中的金属粉末的电镀液体和超临界状态或亚临界状态的表面活性剂，利用感应共沉淀现象对金属基体的表面进行电镀。电镀液中金属的浓度处于饱和或过饱和状态。因此，可以抑制金属基体的溶解速度，并且同时可以通过利用感应共沉积现象在短时间内形成具有光滑表面的镀层。即使当金属基底由设置在基板上的绝缘膜的表面上设置的金属薄膜形成时，或甚至当金属为铜，锌，铁，镍或钴时，也可以应用电镀方法。上述结构可以提供一种电镀方法，即使在非常薄的金属基底的情况下，在金属基体表面的电镀中也能够防止金属基体的溶解，从而实现正常的电镀。

9. 发明授权

US07528905B2 Light polarizing film, a method of continuously fabricating same, and reflective optical devices using same 失效
标题翻译：光偏振膜，其连续制造方法和使用其的反射光学器件
公开(公告)号：US07528905B2
公开(公告)日：2009-05-05
申请号：US10986081
申请日：2004-11-12
申请人： Seizo Miyata
发明人： Seizo Miyata
IPC分类号： G02F1/1335
CPC分类号： G02B5/3033
摘要： There are provided a light polarizing film of a grid type, usable for light at a wavelength in a range of a visible light region to an infrared region, and a method of continuously fabricating the same. A PET film 12 was fed via rolls 13, and a mixed liquid containing poly (vinyl alcohol), formaldehyde, ZnO whiskers after metal treatment, and water was applied to the surface of the PET film to a predetermined thickness with the use of a T-die 14, subsequently executing coating while applying shearing stress by varying peripheral velocity of an upper roll 16 of biaxial rolls from that of a lower roll 16′ thereof, whereupon the ZnO whiskers were oriented in the longitudinal direction of the film. Thereafter, the film was dried and cured through a constant temperature cell 17 kept at a predetermined temperature, and rolls 18 to be subsequently taken up by a take-up roll 19. The light polarizing film obtained was found very high in polarized light reflection property in an infrared region of a wavelength in a range of 1 to 10 μm, and upon measurement of reflectance for two sheets of the light polarizing films crossed at right angles, infrared light reflectance thereof was found at 99%.
摘要翻译：提供了可用于在可见光区域到红外区域的范围内的波长的光栅的光偏振膜及其连续制造方法。通过辊13供给PET膜12，将金属处理后的含有聚（乙烯醇），甲醛，ZnO晶须的金属和水的混合液用T形涂布在PET膜的表面上至规定的厚度随后，通过改变双辊辊的上辊16的圆周速度与下辊16'的周向速度同时施加剪切应力，随后在膜的纵向方向上取向ZnO晶须。然后，通过保持在规定温度下的恒温槽17将该膜干燥固化，然后将辊18卷取成卷绕辊19，得到的偏光膜的偏振光反射率非常高在1〜10μm范围的波长的红外线区域中，在测定两片直角交叉的偏光膜的反射率的情况下，其红外光反射率为99％。

10. 发明申请

US20050106769A1 Light polarizing film, a method of continuously fabricating same, and reflective optical film using same 失效
标题翻译：光偏振膜，其连续制造方法和使用其的反射型光学膜
公开(公告)号：US20050106769A1
公开(公告)日：2005-05-19
申请号：US10986080
申请日：2004-11-12
申请人： Seizo Miyata
发明人： Seizo Miyata
IPC分类号： C08J5/18 , G02B1/11 , G02B5/30 , G02F1/1333
CPC分类号： C08J5/18 , G02B5/3058
摘要： There are provided a light polarizing film of a grid type, usable for light at a wavelength in a range of a visible light region to an infrared region, a method of continuously fabricating the same, and a reflective optical film using the light polarizing film. A polypropylene film is passed through rolls 12, a first constant temperature cell 13, and rolls 12′ to thereby undergo uniaxial drawing by 4-fold. Thereafter, an aluminum metal is vapor-deposited to a thickness of 100 nm in a vacuum deposition cell 14 to be subsequently passed through rolls 15, a second constant temperature cell 16, and rolls 15′, undergoing uniaxial drawing by 2-fold again while partially crystallizing the polypropylene film. At this point in time, the aluminum metal undergoes substantially uniform cracking in a direction orthogonal to a drawing direction. Thereafter, heat treatment is applied to the film in a third constant temperature cell 17, and the film is subsequently taken out by take-up rolls 18. The film-like light polarizing film obtained had a degree of polarization at 99.5%, and light transmittance at 90%, in a region of infrared wavelength in a range of 1 to 10 μm. With two sheets of the films crossed at right angles, reflectance thereof for infrared rays was measured and was found at not less than 99.9%.
摘要翻译：提供了可用于可见光区域与红外区域的波长范围内的光的栅格型偏光膜，其连续制造方法和使用该偏光膜的反射型光学膜。聚丙烯膜通过辊12，第一恒温槽13和辊12'，由此进行单轴拉伸4倍。此后，在真空沉积池14中将铝金属气相沉积至厚度为100nm，随后通过辊15，第二恒温槽16和辊15'，再次进行2倍的单轴拉伸，同时部分结晶聚丙烯薄膜。在这个时间点上，铝金属在与拉拔方向正交的方向上经历基本均匀的开裂。此后，在第三恒温槽17中对膜进行热处理，然后通过卷取辊18将膜取出。获得的膜状光偏振膜在红外波长为1〜10μm范围内的偏振度为99.5％，透光率为90％。用两片膜直角交叉，测定红外线的反射率，结果为99.9％以上。

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