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1. 发明授权

US07682689B2 Successively biaxial-oriented porous polypropylene film and process for production thereof 有权
标题翻译：接着是双轴取向多孔聚丙烯薄膜及其生产方法
公开(公告)号：US07682689B2
公开(公告)日：2010-03-23
申请号：US11802122
申请日：2007-05-21
申请人： Kiyoshi Sadamitsu , Naoki Ikeda , Manabu Hoki , Kenichiro Nagata , Koichi Ogino
发明人： Kiyoshi Sadamitsu , Naoki Ikeda , Manabu Hoki , Kenichiro Nagata , Koichi Ogino
IPC分类号： B32B3/26
CPC分类号： C08J5/18 , B29C55/005 , B29C55/143 , B29K2023/12 , B29K2105/0005 , C08J2323/10 , H01M2/1653 , Y10T428/249978 , Y10T428/249979 , Y10T428/249986 , Y10T428/31909
摘要： Disclosed is a successively biaxially stretched film obtained by successive biaxial stretching method comprising extruding a melt of a β-crystal nucleating agent-containing polypropylene-based resin composition from a T-die, cooling the extruded resin on a chill roll, and stretching the resulting web sheet longitudinally and then transversely, wherein the longitudinally stretched sheet is made to have a degree of β-crystal orientation of less than 0.3 by the following method (I) and/or (II), optionally subjected to annealing treatment, and transversely stretched: method (I): melting the polypropylene-based resin composition containing needle crystals of a specific β-crystal nucleating agent at a temperature not lower than m.p. of the polypropylene-based resin and lower than dissolution temperature of the β-crystal nucleating agent in the polypropylene-based resin melt, and extruding the melt from the T-die at the same temperature, method (II): adjusting neck-in ratio during longitudinal stretching to 25 to 55%. The porous polypropylene film has good breakage resistance during manufacture, excellent thickness uniformity, high porosity and air-permeability, and is useful for battery separators.
摘要翻译：公开了通过连续双轴拉伸法获得的连续双轴拉伸膜，包括从T模挤出含有结晶成核剂的聚丙烯基树脂组合物的熔体，将冷却挤出的树脂冷却在冷却辊上，所得到的纤维网片纵向和横向，其中通过以下方法（I）和/或（II）使纵向拉伸的片材具有小于0.3的程度，任选进行退火处理，以及横向拉伸：方法（I）：在不低于mp的温度下熔化含有特定的结晶成核剂的针状结晶的聚丙烯类树脂组合物的聚丙烯类树脂，并且比聚丙烯类树脂熔体中的结晶成核剂的溶解温度低，并且在相同温度下从T模挤出熔体，方法（II）：调节颈缩纵向拉伸比为25〜55％。多孔聚丙烯膜在制造时具有良好的抗破坏性，优异的厚度均匀性，高孔隙率和透气性，并且可用于电池隔板。

2. 发明申请

US20070269719A1 Successively biaxial-oriented porous polypropylene film and process for production thereof 有权
公开(公告)号：US20070269719A1
公开(公告)日：2007-11-22
申请号：US11802122
申请日：2007-05-21
申请人： Kiyoshi Sadamitsu , Naoki Ikeda , Manabu Hoki , Kenichiro Nagata , Koichi Ogino
发明人： Kiyoshi Sadamitsu , Naoki Ikeda , Manabu Hoki , Kenichiro Nagata , Koichi Ogino
IPC分类号： H01M2/16
CPC分类号： C08J5/18 , B29C55/005 , B29C55/143 , B29K2023/12 , B29K2105/0005 , C08J2323/10 , H01M2/1653 , Y10T428/249978 , Y10T428/249979 , Y10T428/249986 , Y10T428/31909
摘要： Disclosed is a successively biaxially stretched film obtained by successive biaxial stretching method comprising extruding a melt of a β-crystal nucleating agent-containing polypropylene-based resin composition from a T-die, cooling the extruded resin on a chill roll, and stretching the resulting web sheet longitudinally and then transversely, wherein the longitudinally stretched sheet is made to have a degree of β-crystal orientation of less than 0.3 by the following method (I) and/or (II), optionally subjected to annealing treatment, and transversely stretched: method (I): melting the polypropylene-based resin composition containing needle crystals of a specific β-crystal nucleating agent at a temperature not lower than m.p. of the polypropylene-based resin and lower than dissolution temperature of the β-crystal nucleating agent in the polypropylene-based resin melt, and extruding the melt from the T-die at the same temperature, method (II): adjusting neck-in ratio during longitudinal stretching to 25 to 55%. The porous polypropylene film has good breakage resistance during manufacture, excellent thickness uniformity, high porosity and air-permeability, and is useful for battery separators.

3. 发明授权

US07235203B2 Successively biaxial-oriented porous polypropylene film and process for production thereof 有权
标题翻译：接着是双轴取向多孔聚丙烯薄膜及其生产方法
公开(公告)号：US07235203B2
公开(公告)日：2007-06-26
申请号：US10468005
申请日：2002-02-15
申请人： Kiyoshi Sadamitsu , Naoki Ikeda , Manabu Hoki , Kenichiro Nagata , Koichi Ogino
发明人： Kiyoshi Sadamitsu , Naoki Ikeda , Manabu Hoki , Kenichiro Nagata , Koichi Ogino
IPC分类号： B29C55/14
CPC分类号： C08J5/18 , B29C55/005 , B29C55/143 , B29K2023/12 , B29K2105/0005 , C08J2323/10 , H01M2/1653 , Y10T428/249978 , Y10T428/249979 , Y10T428/249986 , Y10T428/31909
摘要： Disclosed is a successively biaxially stretched film obtained by successive biaxial stretching method comprising extruding a melt of a β-crystal nucleating agent-containing polypropylene-based resin composition from a T-die, cooling the extruded resin on a chill roll, and stretching the resulting web sheet longitudinally and then transversely, wherein the longitudinally stretched sheet is made to have a degree of β-crystal orientation of less than 0.3 by the following method (I) and/or (II), optionally subjected to annealing treatment, and transversely stretched: method (I): melting the polypropylene-based resin composition containing needle crystals of a specific β-crystal nucleating agent at a temperature not lower than m.p. of the polypropylene-based resin and lower than dissolution temperature of the β-crystal nucleating agent in the polypropylene-based resin melt, and extruding the melt from the T-die at the same temperature, method (II): adjusting neck-in ratio during longitudinal stretching to 25 to 55%. The porous polypropylene film has good breakage resistance during manufacture, excellent thickness uniformity, high porosity and air-permeability, and is useful for battery separators.
摘要翻译：公开了通过连续双轴拉伸法获得的连续双轴拉伸膜，包括从T模挤出含β-结晶成核剂的聚丙烯基树脂组合物的熔体，将挤出的树脂冷却在冷却辊上，并拉伸所得的网片纵向和横向，其中通过以下方法（I）和/或（II）使纵向拉伸的片材具有小于0.3的β晶取向度，任选进行退火处理，横向拉伸：方法（I）：在不低于mp的温度下熔化含有特定β-晶体成核剂的针状结晶的聚丙烯类树脂组合物的聚丙烯类树脂，低于聚丙烯类树脂熔融体中的β晶形成核剂的溶解温度，在相同温度下从T模挤出熔融物，方法（II）：调节镦粗比在纵向拉伸至25至55％。多孔聚丙烯膜在制造时具有良好的抗破坏性，优异的厚度均匀性，高孔隙率和透气性，并且可用于电池隔板。

4. 发明授权

US06861132B2 Porous polypropylene film, process for producing the same, and absorbent article employing the film 有权
标题翻译：多孔聚丙烯薄膜，其制造方法和使用该薄膜的吸收制品
公开(公告)号：US06861132B2
公开(公告)日：2005-03-01
申请号：US10275987
申请日：2001-06-01
申请人： Naoki Ikeda , Kiyoshi Sadamitsu , Manabu Hoki , Kenichiro Nagata , Toshiaki Kobayashi
发明人： Naoki Ikeda , Kiyoshi Sadamitsu , Manabu Hoki , Kenichiro Nagata , Toshiaki Kobayashi
IPC分类号： A61F13/49 , A61F5/44 , A61F13/15 , A61F13/514 , A61L15/22 , A61L15/24 , A61L15/42 , B29C67/20 , C08J5/18 , C08J9/00 , C08K5/20 , C08L23/16 , B32B5/22 , B32B31/00
CPC分类号： C08J5/18 , A61F13/51462 , A61F2013/15552 , A61F2013/51411 , A61L15/225 , A61L15/24 , A61L15/425 , C08J2323/16 , Y10T428/249953 , Y10T428/249958 , Y10T428/249986 , C08L23/16
摘要： Disclosed is a porous film made of a resin composition containing (I) (i) a propylene-ethylene copolymer or (ii) a polypropylene-based resin mixture containing a propylene-ethylene copolymer, each having an ethylene content of 3.0 to 7.0 wt. % and an MFR measured at 230° C. of 2.0 to 4.0 g/10 min and (II) a β-crystal nucleating agent; the film having a porosity of 20 to 80%, a Gurley air permeability of 5,000 sec/100 cc or lower as measured according to JIS P-8117, a water vapor permeability of 2,000 g/m2·24 h or higher as measured according to JIS Z-0208 and a water pressure resistance of 75 kPa or higher as measured according to JIS L-1092 using an aqueous surfactant solution; a process for producing the same; and an absorbent article employing the porous film as a backsheet.
摘要翻译：公开了一种由含有（I）（i）丙烯 - 乙烯共聚物或（ii）含丙烯 - 乙烯共聚物的聚丙烯类树脂混合物的树脂组合物制成的多孔膜，它们各自具有3.0至7.0重量％的乙烯含量。％，在230℃下测定的MFR为2.0〜4.0g / 10分钟，（II）β-晶体成核剂; 该膜的孔隙率为20〜80％，Gurley透气度为5000秒/ 100cc以下，根据JIS P-8117测定，水蒸气透过度为2000g / m 2·24h以上，为24h以上使用表面活性剂水溶液，根据JIS Z-0208测定，耐水压为75kPa以上，根据JIS L-1092测定; 其制造方法; 以及使用多孔膜作为底片的吸收制品。

5. 发明申请

US20060091581A1 Polypropylene-based resin molded article and process for producing the same 审中-公开
标题翻译：聚丙烯系树脂成形体及其制造方法
公开(公告)号：US20060091581A1
公开(公告)日：2006-05-04
申请号：US11302329
申请日：2005-12-14
申请人： Kiyoshi Sadamitsu , Manabu Hoki , Naoki Ikeda , Koichi Ogino
发明人： Kiyoshi Sadamitsu , Manabu Hoki , Naoki Ikeda , Koichi Ogino
IPC分类号： D01F1/02
CPC分类号： C08J5/00 , C08J2323/12 , C08K5/20 , C08L23/10
摘要： The present invention provides a crystalline polypropylene-based resin molded article having an excellent impact resistance, in particular a remarkably high Izod impact strength, and a process for producing the molded article. A polypropylene-based resin molded article with an excellent impact resistance in which the β crystals of the polypropylene-based resin are unoriented can be produced by a process comprising the steps of: adding 0.01 to 0.1 parts by weight of at least one amide compound to 100 parts by weight of a polypropylene-based resin; kneading the resulting mixture at a temperature not lower than the dissolution temperature of the amide compound in the molten polypropylene-based resin until the compound dissolves in the molten polypropylene-based resin; and injecting and/or extruding the resulting melt in such a state that the amide compound has dissolved in the molten polypropylene-based resin.
摘要翻译：本发明提供具有优异的耐冲击性，特别是高度悬臂梁式冲击强度的结晶性聚丙烯系树脂成形体及其制造方法。聚丙烯类树脂的β晶体为非取向性的耐冲击性优异的聚丙烯系树脂成形体可以通过以下工序来制备，该方法包括：将0.01〜0.1重量份的至少一种酰胺化合物加入到 100重量份的聚丙烯类树脂; 在不低于熔融聚丙烯类树脂中的酰胺化合物的溶解温度的温度下捏合所得混合物，直到化合物溶解在熔融的聚丙烯类树脂中; 并且以使得酰胺化合物溶解在熔融的聚丙烯类树脂中的状态注入和/或挤出所得到的熔体。

6. 发明授权

US06235823B1 Crystalline polypropylene resin composition and amide compounds 失效
标题翻译：结晶聚丙烯树脂组合物和酰胺化合物
公开(公告)号：US06235823B1
公开(公告)日：2001-05-22
申请号：US08003659
申请日：1993-01-13
申请人： Naoki Ikeda , Masafumi Yoshimura , Kazuaki Mizoguchi , Hiroshi Kitagawa , Yuji Kawashima , Kiyoshi Sadamitsu , Yasuyuki Kawahara
发明人： Naoki Ikeda , Masafumi Yoshimura , Kazuaki Mizoguchi , Hiroshi Kitagawa , Yuji Kawashima , Kiyoshi Sadamitsu , Yasuyuki Kawahara
IPC分类号： C08K520
CPC分类号： C08K5/0083 , C07C233/65 , C07C2601/08 , C07C2601/14 , C07C2601/18 , C07C2601/20 , C08K5/0008 , C08K5/20 , C08L23/12
摘要： Disclosed are a crystalline polypropylene resin composition comprising a crystalline polyproplylene resin and a &bgr;-nucleating agent, and a method of increasing the proportion of &bgr;-form crystals in a crystalline polypropylene resin molding comprising molding the composition, the &bgr;-nucleating agent being a diamide compound.
摘要翻译：公开了包含结晶聚丙烯树脂和β-成核剂的结晶聚丙烯树脂组合物，以及增加结晶聚丙烯树脂成型体中β型晶体的比例的方法，包括模塑该组合物，β-成核剂为二酰胺复合。

7. 发明授权

US06593427B2 Orientated gel molding method of polyolefin-based resin composition and molded article obtainable by the method 失效
标题翻译：聚烯烃类树脂组合物的定向凝胶成型方法和通过该方法得到的成型体
公开(公告)号：US06593427B2
公开(公告)日：2003-07-15
申请号：US09818731
申请日：2001-03-28
申请人： Toshiaki Kobayashi , Kiyoshi Sadamitsu
发明人： Toshiaki Kobayashi , Kiyoshi Sadamitsu
IPC分类号： C08R515
CPC分类号： C08J5/00 , C08J2323/02 , C08K5/1575 , C08L23/02
摘要： The present invention provides a method of molding a polyolefin-based resin comprising the steps of dissolving at least one dibenzylidene sorbitol compound in a molten polyolefin resin, cooling the molten resin to a temperature not higher than the sol-gel transition temperature during the cooling cycle to form network-like crystals of the dibenzylidene sorbitol compound, and molding the resulting resin composition at a temperature not lower than the melting temperature of the polyolefin-based resin but not higher than the sol-gel transition temperature during the heating cycle; and a polyolefin resin molded article obtainable by this molding method.
摘要翻译：本发明提供了一种聚烯烃类树脂的成型方法，包括以下步骤：将至少一种二亚苄基山梨醇化合物溶解在熔融聚烯烃树脂中，在冷却循环期间将熔融树脂冷却至不高于溶胶 - 凝胶转变温度的温度以形成二亚苄基山梨糖醇化合物的网状晶体，并且在不低于聚烯烃类树脂的熔融温度的温度下成型所得树脂组合物，但不高于加热循环期间的溶胶 - 凝胶转变温度; 和通过该成型方法得到的聚烯烃树脂成形品。

8. 发明授权

US5998576A Rosin-based molecular crystals, nucleating agent for polyolefin and polyolefin resins composition and moldings thereof 失效
标题翻译：基于松香的分子晶体，聚烯烃成核剂和聚烯烃树脂组合物及其模制品
公开(公告)号：US5998576A
公开(公告)日：1999-12-07
申请号：US51317
申请日：1998-04-08
申请人： Kiyoshi Sadamitsu , Masahide Ishikawa , Toshiaki Kobayashi
发明人： Kiyoshi Sadamitsu , Masahide Ishikawa , Toshiaki Kobayashi
IPC分类号： C08L23/02 , C08L23/12 , C08L23/14 , C08L93/04 , C08K5/09 , C08L23/00
CPC分类号： C08L23/142 , C08L23/02 , C08L93/04 , C08L2205/02 , C08L2205/03
摘要： This invention provides a rosin-based molecular crystal formed from the following component A and component B:Component A: dehydroabietic acid or a rosin-based resin acid containing dehydroabietic acid as an essential constituentComponent B: at least one rosin-based resin acid alkali metal salt selected from the class consisting of lithium, sodium and potassium salts of said component A,a polyolefin resin nucleating agent comprising the rosin-based molecular crystal, a polyolefin resin composition comprising the nucleating agent and if desired a calcium compound, and a molded article obtainable by molding the resin composition.
摘要翻译： PCT No.PCT / JP97 / 02740 Sec。 371日期：1998年4月8日 102（e）1998年4月8日PCT PCT 1997年8月7日PCT公布。公开号WO98 / 06784 日本特开1998年2月19日本发明提供由以下成分A和成分B形成的松香基分子晶体：成分A：脱氢松香酸或含脱氢枞酸作为必需成分的松香系树脂酸成分B：至少1种松香的选自所述组分A的锂，钠和钾盐类的树脂酸性碱金属盐，包含所述松香基分子晶体的聚烯烃树脂成核剂，包含所述成核剂的聚烯烃树脂组合物和如果需要，钙化合物和通过模塑该树脂组合物可获得的模塑制品。

9. 发明授权

US06238615B1 Orientated gel molding method of polyolefin based resin composition 失效
标题翻译：聚烯烃基树脂组合物定向凝胶成型方法
公开(公告)号：US06238615B1
公开(公告)日：2001-05-29
申请号：US09341186
申请日：1999-07-06
申请人： Toshiaki Kobayashi , Kiyoshi Sadamitsu
发明人： Toshiaki Kobayashi , Kiyoshi Sadamitsu
IPC分类号： B29B1304
CPC分类号： C08J5/00 , C08J2323/02 , C08K5/1575 , C08L23/02
摘要： The present invention provides method of molding a polyolefin-based resin comprising the steps of dissolving at least one dibenzylidene sorbitol compound in a molten polyolefin resin, cooling the molten resin to a temperature not higher than the sol-gel transition temperature during the cooling cycle to form network-like crystals of the dibenzylidene sorbitol compound, and molding the resulting resin composition at a temperature not lower than the melting temperature of the polyolefin-based resin but not higher than the sol-gel transition temperature during the heating cycle; and a polyolefin resin molded article obtainable by this molding method.
摘要翻译：本发明提供了一种聚烯烃类树脂的成型方法，包括以下步骤：将至少一种二亚苄基山梨糖醇化合物溶解在熔融聚烯烃树脂中，在冷却循环期间将熔融树脂冷却至不高于溶胶 - 凝胶转变温度的温度，形成二亚苄基山梨糖醇化合物的网状晶体，并且在不低于聚烯烃类树脂的熔融温度的温度下成型所得树脂组合物，但不高于加热循环期间的溶胶 - 凝胶转变温度; 和通过该成型方法得到的聚烯烃树脂成形品。

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