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1. 发明授权

US4364970A Method for improving surface properties of shaped articles of polyvinyl chloride resins 失效
标题翻译：改善聚氯乙烯树脂成型制品表面性能的方法
公开(公告)号：US4364970A
公开(公告)日：1982-12-21
申请号：US276485
申请日：1981-06-23
申请人： Kiyoshi Imada , Tokuji Abe , Susumu Ueno
发明人： Kiyoshi Imada , Tokuji Abe , Susumu Ueno
IPC分类号： C08J7/00 , B05D3/04 , B05D5/00 , B05D5/12 , B29C59/14 , B29C59/16 , B29D17/00 , C08J7/12 , C08L27/06 , G11B3/70 , G11B5/72 , B05D3/14
CPC分类号： C08J7/123 , B29C59/14 , G11B3/705 , C08J2327/06
摘要： A novel method is proposed for improving the surface properties or, in particular, for reducing accumulation of static electricity on the surface of a shaped article of a vinyl chloride-based resin.The inventive method comprises first exposing the surface of the shaped article to low temperature plasma of a gas having no polymerizability in plasma and then bringing the plasma-treated surface into contact with a liquid which is inert to the resin, e.g. water, or an aqueous solution containing a surface active agent. The effect of the inventive method is so strong and durable that the treated surface remains anti-static even after 12 months after the treatment.
摘要翻译：提出了一种用于改善表面性质，特别是减少氯乙烯类树脂成型体表面上的静电累积的新方法。本发明的方法包括首先将成形制品的表面暴露于等离子体中不具有聚合性的气体的低温等离子体，然后使等离子体处理的表面与对树脂呈惰性的液体接触。水或含有表面活性剂的水溶液。本发明方法的效果如此强烈和持久，即使在治疗后12个月后，处理过的表面也能保持抗静电。

2. 发明授权

US4302307A Method for the improvement of gramophone records 失效
标题翻译：提高留声机记录的方法
公开(公告)号：US4302307A
公开(公告)日：1981-11-24
申请号：US60502
申请日：1979-07-25
申请人： Kiyoshi Imada , Susumu Ueno , Tokuji Abe
发明人： Kiyoshi Imada , Susumu Ueno , Tokuji Abe
IPC分类号： C08J7/00 , B29C59/14 , B29D17/00 , C08J7/12 , C08L27/06 , G11B3/70 , C07C3/24
CPC分类号： C08J7/123 , B29C59/14 , G11B3/705 , B29K2027/06 , B29L2017/00 , C08J2327/06
摘要： Gramophone records made of a vinyl chloride based resin are subjected to a treatment with low temperature plasma of a gas having no polymerizability in the plasma condition. A markedly improved anti-static effect is imparted to the surface of the gramophone record which also becomes highly resistant to wearing so that the signal/noise ratio in playing of the gramophone record is remarkably improved even after many times of repeated playing of the record.
摘要翻译：由氯乙烯系树脂制造的留声机记录在等离子体条件下用低温等离子体处理不聚合的气体。赋予留声机记录表面的显着改善的抗静电效果，这也使得耐磨性变得非常高，从而即使在多次重复播放记录之后，留声机记录的播放中的信号/噪声比显着提高。

3. 发明授权

US4885333A Polyvinyl chloride resin composition having improved thermal stability and a method for the preparation thereof 失效
标题翻译：具有改进的热稳定性的聚氯乙烯树脂组合物及其制备方法
公开(公告)号：US4885333A
公开(公告)日：1989-12-05
申请号：US172338
申请日：1988-03-23
申请人： Tadashi Amano , Tokuji Abe
发明人： Tadashi Amano , Tokuji Abe
IPC分类号： C08K5/04 , C08F14/06 , C08K5/06 , C08L27/06
CPC分类号： C08F14/06 , C08K5/06
摘要： A polyvinyl chloride resin-based composition can be imparted with improved thermal stability of compounding the same with a polygylcerin in an amount of 0.01 to 0.5% by weight based on the resin even when the composition is compounded with a heat stabilizer having relatively low effectiveness although the use of such a heat stabilizer is desirable in respect of the physiological inertness. Similar improving effects on the thermal stability of a polyvinyl chloride resin-based composition can be obtained when the resin is prepared by suspension-polymerizing vinyl chloride monomer in an aqueous medium containing a polyglycerin.
摘要翻译：可以赋予聚氯乙烯树脂基组合物更好的热稳定性，其与基于树脂的0.01至0.5重量％的聚甘油的配混相同，即使当组合物与具有较低效力的热稳定剂配混时，关于生理惰性，需要使用这种热稳定剂。当通过将氯乙烯单体悬浮聚合在含有聚甘油的水性介质中制备树脂时，可以获得对聚氯乙烯树脂基组合物的热稳定性的类似改善效果。

4. 发明授权

US4543382A Plastic magnets impregnated with a dye-coated magnet alloy powder 失效
标题翻译：浸渍有染料涂覆的磁铁合金粉末的塑料磁体
公开(公告)号：US4543382A
公开(公告)日：1985-09-24
申请号：US561552
申请日：1983-12-14
申请人： Michinori Tsuchida , Toshihide Shimizu , Ichiro Kaneko , Tokuji Abe
发明人： Michinori Tsuchida , Toshihide Shimizu , Ichiro Kaneko , Tokuji Abe
IPC分类号： C08K9/04 , B22F1/02 , H01F1/06 , H01F1/08 , H01F7/02
CPC分类号： B22F1/02 , H01F1/061 , H01F1/083 , Y10S428/90 , Y10T428/2991
摘要： The invention provides a very simple but effective means for preventing surface oxidation of fine metal powders by coating the metal powder with an organic dye. This method of surface-oxidation prevention is particularly useful for the preparation of a so-called plastic magnet which is prepared by uniformly blending a dye-coated fine powder of a magnetic alloy such as a rare earth-cobalt based permanent magnet with a thermoplastic resin such as a nylon or polyphenylene sulfide resin followed by molding the resin-powder blend into a magnet form. In addition to the remarkably improved magnetic properties of the thus prepared plastic magnets as a result of high loading and absence of degradation by oxidation, the danger of spontaneous ignition of the magnet powder in molding can be eliminated almost completely. Surface treatment of the dye-coated magnet powder with a silicone fluid gives further improved results.
摘要翻译：本发明提供了通过用有机染料涂覆金属粉末来防止细金属粉末的表面氧化的非常简单但有效的手段。这种表面氧化防止方法对于制备所谓的塑料磁体是特别有用的，该塑料磁体是通过将诸如稀土 - 钴基永磁体的磁性合金的染料包覆的细粉与热塑性树脂例如尼龙或聚苯硫醚树脂，随后将树脂 - 粉末混合物模塑成磁体形式。除了由于高负载和氧化劣化而导致的如此制备的塑料磁体的显着改善的磁性能之外，几乎完全可以消除在成型中磁粉的自发点火的危险。用硅氧烷流体对染料涂覆的磁体粉末进行表面处理，可以进一步提高结果。

5. 发明授权

US4497722A Composition for plastic magnets 失效
标题翻译：塑料磁铁的组成
公开(公告)号：US4497722A
公开(公告)日：1985-02-05
申请号：US626742
申请日：1984-07-02
申请人： Michinori Tsuchida , Tokuji Abe , Hajime Kitamura
发明人： Michinori Tsuchida , Tokuji Abe , Hajime Kitamura
IPC分类号： H01F1/06 , H01F1/08
CPC分类号： H01F1/061 , H01F1/0552 , H01F1/0558 , Y10S428/90
摘要： The plastic magnet composition provided by the invention comprises a thermoplastic resin as a binder and a powder of a metallic or alloy-type magnet which is coated on the particle surface with a phosphorus-containing compound having at least one phosphorus-to-oxygen linkage in a molecule such as phosphoric acid and related compounds. By virtue of the surface coating, the magnet powder is freed from the degradation by air oxidation and the danger of ignition in the molding process so that plastic magnets of high performance can be readily manufactured with safety. The advantages of the coating layer are further increased when the coating layer is formed of a combination of the phosphorus-containing compound and an organic dye compound. An overcoating on the thus coated magnet powder with an organopolysiloxane has an effect of increased lubricity.
摘要翻译：由本发明提供的塑料磁体组合物包括作为粘合剂的热塑性树脂和金属或合金型磁体的粉末，其在具有至少一个磷 - 氧键的含磷化合物的颗粒表面上涂覆分子如磷酸和相关化合物。借助于表面涂层，可以通过空气氧化降低磁体粉末和模制过程中点燃的危险，从而可以安全地制造高性能的塑料磁体。当涂层由含磷化合物和有机染料化合物的组合形成时，涂层的优点进一步增加。这样涂覆的磁体粉末与有机聚硅氧烷的外涂层具有提高的润滑性的效果。

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