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    • 4. 发明授权
    • Process for the preparation of ethanol and higher alcohols
    • 乙醇和高级醇的制备方法
    • US08637580B2
    • 2014-01-28
    • US13808240
    • 2011-05-17
    • Poul Erik Højlund NielsenBurcin TemelPablo Beato
    • Poul Erik Højlund NielsenBurcin TemelPablo Beato
    • C07C27/00
    • C07C29/1516C07C29/1512C07C29/32C07C31/08C07C31/10C07C31/12C07C31/125
    • Process for the preparation of ethanol and/or higher alcohols comprising the steps of: (a) providing an alcohol synthesis gas comprising carbon monoxide and hydrogen in a molar ratio of higher than 0.5; (c) adding an amount of methanol and/or higher alcohols to the synthesis gas to obtain a synthesis gas mixture. (d) converting the synthesis gas mixture from step (c) in presence of one or more catalysts catalysing the conversion of the synthesis gas mixture into a ethanol and/or higher alcohols containing product; and (e) withdrawing the product from step (d), wherein the synthesis gas is purified by removing iron and nickel carbonyl compounds prior or after the addition methanol and/or higher alcohols to the synthesis gas and optionally (I) cooling the withdrawn product in step (e); and (g) contacting the cooled product with a hydrogenation catalyst.
    • 制备乙醇和/或高级醇的方法包括以下步骤:(a)提供摩尔比高于0.5的一氧化碳和氢气的醇合成气; (c)向合成气中加入一定量的甲醇和/或高级醇以得到合成气体混合物。 (d)在催化合成气混合物转化为乙醇和/或高级醇的产物的一种或多种催化剂的存在下,转化来自步骤(c)的合成气混合物; 和(e)从步骤(d)中取出产物,其中通过在向合成气中加入甲醇和/或高级醇之前或之后除去铁和镍羰基化合物来纯化合成气,并且任选地(I)冷却所提取的产物 在步骤(e)中; 和(g)使冷却的产物与氢化催化剂接触。
    • 6. 发明申请
    • PROCESS FOR THE PREPARATION OF ETHANOL AND HIGHER ALCOHOLS
    • 制备乙醇和高级醇的方法
    • US20130123377A1
    • 2013-05-16
    • US13808240
    • 2011-05-17
    • Poul Erik Højlund NielsenBurcin TemelPablo Beato
    • Poul Erik Højlund NielsenBurcin TemelPablo Beato
    • C07C29/151
    • C07C29/1516C07C29/1512C07C29/32C07C31/08C07C31/10C07C31/12C07C31/125
    • Process for the preparation of ethanol and/or higher alcohols comprising the steps of: (a) providing an alcohol synthesis gas comprising carbon monoxide and hydrogen in a molar ratio of higher than 0.5; (c) adding an amount of methanol and/or higher alcohols to the synthesis gas to obtain a synthesis gas mixture. (d) converting the synthesis gas mixture from step (c) in presence of one or more catalysts catalysing the conversion of the synthesis gas mixture into a ethanol and/or higher alcohols containing product; and (e) withdrawing the product from step (d), wherein the synthesis gas is purified by removing iron and nickel carbonyl compounds prior or after the addition methanol and/or higher alcohols to the synthesis gas and optionally (I) cooling the withdrawn product in step (e); and (g) contacting the cooled product with a hydrogenation catalyst.
    • 制备乙醇和/或高级醇的方法包括以下步骤:(a)提供摩尔比高于0.5的一氧化碳和氢气的醇合成气; (c)向合成气中加入一定量的甲醇和/或高级醇以得到合成气体混合物。 (d)在催化合成气混合物转化为乙醇和/或高级醇的产物的一种或多种催化剂的存在下,转化来自步骤(c)的合成气混合物; 和(e)从步骤(d)中取出产物,其中通过在向合成气中加入甲醇和/或高级醇之前或之后除去铁和镍羰基化合物来纯化合成气,并且任选地(I)冷却所提取的产物 在步骤(e)中; 和(g)使冷却的产物与氢化催化剂接触。