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1. 发明授权

US06858678B2 Continuous bulk polymerization and esterification process and compositions including the polymeric product 有权
标题翻译：连续本体聚合和酯化方法以及包括聚合物产品的组合物
公开(公告)号：US06858678B2
公开(公告)日：2005-02-22
申请号：US10013752
申请日：2001-10-29
申请人： Kevin M. Andrist , John E. Blasko , Glenn C. Calhoun , Frederick C. Hansen , Dean R. Hellwig , Kurt A. Hessenius , Steven M. Hurley , D. Sunil Jayasuriya , Matthew G. Lee , Stephen J. Maccani , H. Thomas Mills, Jr. , Gregory R. Peterson , Paul E. Sandvick , Dennis M. Wilson , John P. Wiruth
发明人： Kevin M. Andrist , John E. Blasko , Glenn C. Calhoun , Frederick C. Hansen , Dean R. Hellwig , Kurt A. Hessenius , Steven M. Hurley , D. Sunil Jayasuriya , Matthew G. Lee , Stephen J. Maccani , H. Thomas Mills, Jr. , Gregory R. Peterson , Paul E. Sandvick , Dennis M. Wilson , John P. Wiruth
IPC分类号： C08L23/00 , B01F17/00 , C08F2/02 , C08F20/04 , C08F22/06 , C08F220/06 , C08F220/18 , C09D133/04 , C09G1/16 , C09J133/04 , D21H17/28 , D21H17/37 , D21H21/16 , C08F8/14
CPC分类号： B01F17/0085 , B01F17/0028 , B01F17/005 , C08F2/02 , C08F20/04 , C08F22/06 , C08F220/06 , C08F220/18 , C09G1/16 , D21H17/28 , D21H17/37 , D21H21/16
摘要： A continuous bulk polymerization and esterification process includes continuously charging into a reaction zone at least one ethylenically unsaturated acid-functional monomer and at least one linear or branched chain alkanol having greater than 11 carbon atoms. The process includes maintaining a flow rate through the reaction zone sufficient to provide an average residence time of less than 60 minutes and maintaining a temperature in the reaction zone sufficient to produce a polymeric product incorporating at least some of the alkanol as an ester of the polymerized ethylenically unsaturated acid-functional monomer. The polymeric product is used in various processes to produce water-based compositions including emulsions and dispersions such as oil emulsions, wax dispersions, pigment dispersions, surfactants and coatings which contain the polymeric product. A polymeric surfactant includes at least one ethylenically unsaturated acid-functional monomer which has been radically incorporated into the polymeric surfactant and at least one ester of the incorporated ethylenically unsaturated acid-functional monomer which has a linear or branched chain alkyl group with greater than 11 carbon atoms. The molar critical micelle concentration of the polymeric surfactant is less than 1.0×10−2 moles/liter. Aqueous 2 percent solutions of certain polymeric surfactants have a surface tension of less than 45 mN/m at 30° C. and exhibit a decrease in surface tension of at least 5 mN/m as the temperature warms from 30° C. to 50° C.
摘要翻译：连续本体聚合和酯化方法包括将至少一种烯属不饱和酸官能单体和至少一种具有大于11个碳原子的直链或支链链烷醇连续地加入到反应区中。该方法包括保持通过反应区的流速足以提供小于60分钟的平均停留时间，并保持反应区中的温度足以产生聚合产物，该聚合物与至少一些烷醇作为聚合的烯键式不饱和酸官能单体。聚合物产品用于各种工艺中以生产水性组合物，包括乳液和分散体，例如油乳剂，蜡分散体，颜料分散体，表面活性剂和含有聚合产物的涂料。聚合物表面活性剂包括至少一种烯键式不饱和酸官能单体，其已经自由地掺入聚合物表面活性剂和至少一种具有直链或支链烷基与大于11个碳的烯键式不饱和酸官能单体的酯原子聚合物表面活性剂的摩尔临界胶束浓度小于1.0×10 -2摩尔/升。某些聚合物表面活性剂的2％水溶液在30℃下的表面张力小于45mN / m，并且随着温度从30℃升温到50℃，表面张力降低至少5mN / m C。

2. 发明授权

US06355727B1 Continuous bulk polymerization and esterification process 有权
标题翻译：连续本体聚合和酯化过程
公开(公告)号：US06355727B1
公开(公告)日：2002-03-12
申请号：US09347035
申请日：1999-07-02
申请人： Kevin M. Andrist , John E. Blasko , Glenn C. Calhoun , Frederick C. Hansen , Dean R. Hellwig , Kurt A. Hessenius , Steven M. Hurley , D. Sunil Jayasuriya , Matthew G. Lee , Stephen J. Maccani , H. Thomas Mills, Jr. , Gregory R. Peterson , Paul E. Sandvick , Dennis M. Wilson , John P. Wiruth
发明人： Kevin M. Andrist , John E. Blasko , Glenn C. Calhoun , Frederick C. Hansen , Dean R. Hellwig , Kurt A. Hessenius , Steven M. Hurley , D. Sunil Jayasuriya , Matthew G. Lee , Stephen J. Maccani , H. Thomas Mills, Jr. , Gregory R. Peterson , Paul E. Sandvick , Dennis M. Wilson , John P. Wiruth
IPC分类号： C08F2004
CPC分类号： B01F17/0085 , B01F17/0028 , B01F17/005 , C08F2/02 , C08F20/04 , C08F22/06 , C08F220/06 , C08F220/18 , C09G1/16 , D21H17/28 , D21H17/37 , D21H21/16
摘要： A continuous bulk polymerization and esterification process includes continuously charging into a reaction zone at least one ethylenically unsaturated acid-functional monomer and at least one linear or branched chain alkanol having greater than 11 carbon atoms. The process includes including maintaining a flow rate through the reaction zone sufficient to provide an average residence time of less than 60 minutes and maintaining a temperature in the reaction zone sufficient to produce a polymeric product incorporating at least some of the alkanol as an ester of the polymerized ethylenically unsaturated acid-functional monomer. The polymeric product is used in various processes to produce water-based compositions including emulsions and dispersions such as oil emulsions, wax dispersions, pigment dispersions, surfactants and coatings which contain the polymeric product. A polymeric surfactant includes at least one ethylenically unsaturated acid-functional monomer which has been radically incorporated into the polymeric surfactant and at least one ester of the incorporated ethylenically unsaturated acid-functional monomer which has a linear or branched chain alkyl group with greater than 11 carbon atoms. The molar critical micelle concentration of the polymeric surfactant is less than 1.0×10−2 moles/liter. Aqueous 2 percent neutralized solutions of certain polymeric surfactants have a surface tension of less than 45 mN/m at 30° C. and exhibit a decrease in surface tension of at least 5 mN/m as the temperature warms from 30° C. to 50° C.
摘要翻译：连续本体聚合和酯化方法包括将至少一种烯属不饱和酸官能单体和至少一种具有大于11个碳原子的直链或支链链烷醇连续地加入到反应区中。该方法包括保持通过反应区的流速足以提供小于60分钟的平均停留时间，并保持反应区中的温度足以产生聚合产物，该聚合物与至少一些烷醇作为聚合的烯键式不饱和酸官能单体。聚合物产品用于各种工艺中以生产水性组合物，包括乳液和分散体，例如油乳剂，蜡分散体，颜料分散体，表面活性剂和含有聚合产物的涂料。聚合物表面活性剂包括至少一种烯键式不饱和酸官能单体，其已经自由地掺入聚合物表面活性剂和至少一种具有直链或支链烷基与大于11个碳的烯键式不饱和酸官能单体的酯原子聚合物表面活性剂的摩尔临界胶束浓度小于1.0×10 -2摩尔/升。某些聚合物表面活性剂的2％中和水溶液的表面张力在30℃时的表面张力小于45mN / m，并且随着温度从30℃升至50℃，表面张力降低至少5mN / m C。

3. 发明授权

US06090884A Starch degradation/graft polymerization composition, process, and uses thereof 失效
标题翻译：淀粉降解/接枝聚合组合物，方法及其用途
公开(公告)号：US06090884A
公开(公告)日：2000-07-18
申请号：US74536
申请日：1998-05-07
申请人： Steven M. Hurley , Florence L. Todd , Paul E. Sandvick , Steve E. Danley
发明人： Steven M. Hurley , Florence L. Todd , Paul E. Sandvick , Steve E. Danley
IPC分类号： C08L33/00 , C08F251/00 , C09D5/02 , C09D11/10 , C09D11/14 , C09D103/02 , C09D133/06 , C09D151/02 , C08K3/30 , C08L3/02 , C09D11/00 , C09D103/04
CPC分类号： C09D11/106 , C08F251/00 , C09D151/02
摘要： Disclosed herein are starch stabilized polymeric emulsions. Persulfate salts degrade starch to give it suitable characteristics, and then also, essentially simultaneously, initiate polymerization with monomers. This permits a single reaction condition to be used for both the degradation step and the polymerization step, and avoids the need for use of metallic ions such as iron.
摘要翻译：本文公开了淀粉稳定的聚合物乳液。过硫酸盐降解淀粉以赋予其合适的特性，然后基本上同时引发与单体的聚合。这允许单独的反应条件用于降解步骤和聚合步骤，并且避免使用诸如铁的金属离子。

4. 发明授权

US4810407A Non-homogenized multi-surface polish compositions 失效
标题翻译：非均质化多表面抛光组合物
公开(公告)号：US4810407A
公开(公告)日：1989-03-07
申请号：US094064
申请日：1987-09-02
申请人： Paul E. Sandvick
发明人： Paul E. Sandvick
IPC分类号： C09G1/04 , C09G1/16 , C09G1/14 , C11D3/37
CPC分类号： C09G1/04 , C09G1/16 , Y10S516/01
摘要： A non-homogenized oil-in-water, essentially wax free emulsion cleaner polisher composition that resists phase separation. The composition comprises from about 75 to 99% water, 0.5 to 12% film former, 0.1 to 5% nonionic emulsifier and 0.01 to 0.3% thickener. The composition may be dispensed from pump, trigger or squeeze sprayers. Various methods are also disclosed to formulate the composition.
摘要翻译：非均质化的水包油，基本上不含蜡的乳液清洁剂抛光剂组合物，可抵抗相分离。该组合物包含约75至99％的水，0.5至12％的成膜剂，0.1至5％的非离子乳化剂和0.01至0.3％的增稠剂。组合物可以从泵，触发器或挤压喷雾器分配。还公开了各种方法来配制组合物。

5. 发明授权

US5700516A Repulpable hot melt polymer/wax compositions for fibrous products 失效
标题翻译：用于纤维制品的可再热熔融聚合物/蜡组合物
公开(公告)号：US5700516A
公开(公告)日：1997-12-23
申请号：US733534
申请日：1996-10-18
申请人： Paul E. Sandvick , Calvin J. Verbrugge
发明人： Paul E. Sandvick , Calvin J. Verbrugge
IPC分类号： C08L91/06 , D21H19/14 , D21H19/18 , D21H19/20 , D21H21/16 , D21H19/00
CPC分类号： D21H21/16 , C08L91/06 , D21H19/14 , D21H19/18 , D21H19/20
摘要： Hot melt wax compositions are described that render fibrous products such as paper, paperboard and corrugated paper containers water-resistant at room temperature, but enable such articles to be repulped and recycled when the coated articles are repulped in a heated nearly neutral to alkaline aqueous medium. The compositions comprise from about 20% to 97.5% by weight of a water-repellent wax that is a solid at 20.degree. C.; from about 2.5% to 50% by weight of an addition polymer of from about 50 to 95 mole percent of an ethylene-1,2-dicarboxylic acid or anhydride and from about 5 to 50 mole percent of at least one additional ethylenically unsaturated monomer selected from the group consisting of 1-alkenes having from about 4 to 60 carbon atoms wherein the polymer is dispersible in the water-repellent wax; optionally from about 1 to 90 mole percent of the carboxyl groups in the polymer may be further modified by reaction with a substituted or unsubstituted monoalcohol or monoamine; and optionally, from about 5% to 75% by weight of at least one fatty acid selected from the group consisting of fatty acids containing from about 12 to 48 carbon atoms. The compositions are solid at 20.degree. C., but start to become fluid between about 50.degree. C. to 95.degree. C.
摘要翻译：描述了在室温下使纤维产品如纸，纸板和瓦楞纸容器耐水性的热熔蜡组合物，但是当涂覆的制品在加热的近似中性至碱性水性介质中再次重新制备时，可使这些制品再次再循环。该组合物包含约20％至97.5％重量的在20℃下为固体的防水蜡。约2.5％至50％重量的约50至95％摩尔的乙烯-1,2-二羧酸或酸酐和约5至50摩尔％的至少一种另外的烯键式不饱和单体的加成聚合物由具有约4至60个碳原子的1-烯烃组成的组，其中该聚合物可分散在拒水蜡中; 可以通过与取代或未取代的一元醇或单胺反应来进一步修饰聚合物中约1至90摩尔％的羧基; 和任选的约5％至75％重量的至少一种选自含有约12至48个碳原子的脂肪酸的脂肪酸。组合物在20℃下为固体，但在约50℃至95℃之间开始变成流体。

6. 发明授权

US5587202A Repulpable hot melt polymer/fatty acid compositions for fibrous products 失效
标题翻译：用于纤维制品的可再热熔融聚合物/脂肪酸组合物
公开(公告)号：US5587202A
公开(公告)日：1996-12-24
申请号：US572404
申请日：1995-12-14
申请人： Paul E. Sandvick , Calvin J. Verbrugge
发明人： Paul E. Sandvick , Calvin J. Verbrugge
IPC分类号： C08K5/09 , D21H19/20 , D21H19/00
CPC分类号： D21H19/20 , C08K5/09 , Y10T428/1303 , Y10T428/1307 , Y10T428/24669 , Y10T428/24694 , Y10T428/3188
摘要： Hot melt polymer/fatty acid compositions are described that render fibrous products such as paper, paperboard and corrugated paper containers water-resistant at room temperature, but enable such articles to be repulped and recycled when the coated articles are repulped in a heated nearly neutral to alkaline pH aqueous medium. The compositions comprise from about 5% to 50% by weight of an addition polymer of from about 5 to 95 mole percent of an ethylenically unsaturated monocarboxylic acid or 50 to 95 mole percent of an ethylene-1,2-dicarboxylic acid or anhydride and the balance to a total of 100 mole percent of at least one additional ethylenically unsaturated monomer selected from the group consisting of 1-alkenes having from about 4 to 60 carbon atoms; alkyl vinyl ethers having an ether alkyl, group of from about 8 to 60 carbon atoms, and alkyl acrylates or alkyl methacrylates having an alkyl group of from about 8 to 60 carbon atoms; optionally from about 1 to 90 mole percent of the carboxyl groups in the polymer may be further modified by reaction with a substituted or unsubstituted monoalcohol or monoamine; and from about 50% to 95% by weight of at least one fatty acid selected from the group consisting of natural or synthetic fatty acids containing from about 12 to 48 carbon atoms, wherein the fatty acid is compatible with the polymer and the composition is a solid at 20.degree. C., but starts to become fluid between about 50.degree. C. to 95.degree. C.
摘要翻译：描述了在室温下使纤维制品如纸，纸板和瓦楞纸容器具有耐水性的热熔聚合物/脂肪酸组合物，但是当涂覆的制品在加热的几乎中立至碱性pH水介质。组合物包含约5％至50％重量的约5至95摩尔％的烯属不饱和单羧酸或50至95摩尔％的乙烯-1,2-二羧酸或酸酐的加成聚合物，平衡至总共100摩尔％的至少一种另外的选自具有约4至60个碳原子的1-烯烃的烯属不饱和单体; 具有醚烷基，约8至60个碳原子的烷基乙烯基醚和具有约8至60个碳原子的烷基的丙烯酸烷基酯或甲基丙烯酸烷基酯; 可以通过与取代或未取代的一元醇或单胺反应来进一步修饰聚合物中约1至90摩尔％的羧基; 和约50％至95％重量的至少一种选自含有约12至48个碳原子的天然或合成脂肪酸的脂肪酸，其中脂肪酸与聚合物相容，组合物为在20℃固体，但在约50℃至95℃之间开始变成流体。

7. 发明授权

US5491190A Repulpable hot melt polymer/fatty acid compositions for fibrous products 失效
标题翻译：用于纤维制品的可再热熔融聚合物/脂肪酸组合物
公开(公告)号：US5491190A
公开(公告)日：1996-02-13
申请号：US96523
申请日：1993-07-22
申请人： Paul E. Sandvick , Calvin J. Verbrugge
发明人： Paul E. Sandvick , Calvin J. Verbrugge
IPC分类号： C08K5/09 , D21H19/20 , C08J3/20 , C08L33/00
CPC分类号： D21H19/20 , C08K5/09 , Y10T428/1303 , Y10T428/1307 , Y10T428/24669 , Y10T428/24694 , Y10T428/3188
摘要： Hot melt polymer/fatty acid compositions are described that render fibrous products such as paper, paperboard and corrugated paper containers water-resistant at room temperature, but enable such articles to be repulped and recycled when the coated articles are repulped in a heated nearly neutral to alkaline pH aqueous medium. The compositions comprise from about 5% to 50% by weight of an addition polymer of from about 5 to 95 mole percent of an ethylenically unsaturated monocarboxylic acid or 50 to 95 mole percent of an ethylene-1,2-dicarboxylic acid or anhydride and the balance to a total of 100 mole percent of at least one additional ethylenically unsaturated monomer selected from the group consisting of 1-alkenes having from about 4 to 60 carbon atoms; alkyl vinyl ethers having an ether alkyl group of from about 8 to 60 carbon atoms, and alkyl acrylates or alkyl methacrylates having an alkyl group of from about 8 to 60 carbon atoms; optionally from about 1 to 90 mole percent of the carboxyl groups in the polymer may be further modified by reaction with a substituted or unsubstituted monoalcohol or monoamine; and from about 50% to 95% by weight of at least one fatty acid selected from the group consisting of natural or synthetic fatty acids containing from about 12 to 48 carbon atoms, wherein the fatty acid is compatible with the polymer and the composition is a solid at 20.degree. C., but starts to become fluid between about 50.degree. C. to 95.degree. C.
摘要翻译：描述了在室温下使纤维制品如纸，纸板和瓦楞纸容器具有耐水性的热熔聚合物/脂肪酸组合物，但是当涂覆的制品在加热的几乎中立至碱性pH水介质。组合物包含约5％至50％重量的约5至95摩尔％的烯属不饱和单羧酸或50至95摩尔％的乙烯-1,2-二羧酸或酸酐的加成聚合物，平衡至总共100摩尔％的至少一种另外的选自具有约4至60个碳原子的1-烯烃的烯属不饱和单体; 具有约8至60个碳原子的醚烷基的烷基乙烯基醚和具有约8至60个碳原子的烷基的丙烯酸烷基酯或甲基丙烯酸烷基酯; 可以通过与取代或未取代的一元醇或单胺反应来进一步修饰聚合物中约1至90摩尔％的羧基; 和约50％至95％重量的至少一种选自含有约12至48个碳原子的天然或合成脂肪酸的脂肪酸，其中脂肪酸与聚合物相容，组合物为在20℃固体，但在约50℃至95℃之间开始变成流体。

8. 发明授权

US5599596A Repulpable hot melt polymer/fatty acid compositions for fibrous products 失效
标题翻译：用于纤维制品的可再热熔融聚合物/脂肪酸组合物
公开(公告)号：US5599596A
公开(公告)日：1997-02-04
申请号：US572455
申请日：1995-12-14
申请人： Paul E. Sandvick , Calvin J. Verbrugge
发明人： Paul E. Sandvick , Calvin J. Verbrugge
IPC分类号： C08K5/09 , D21H19/20 , B27N3/00 , B29D22/00 , B29D23/00 , B32B1/08 , B65D1/00
CPC分类号： D21H19/20 , C08K5/09 , Y10T428/1303 , Y10T428/1307 , Y10T428/24669 , Y10T428/24694 , Y10T428/3188
摘要： Hot melt polymer/fatty acid compositions are described that render fibrous products such as paper, paperboard and corrugated paper containers water-resistant at room temperature, but enable such articles to be repulped and recycled when the coated articles are repulped in a heated nearly neutral to alkaline pH aqueous medium. The compositions comprise from about 5% to 50% by weight of an addition polymer of from about 5 to 95 mole percent of an ethylenically unsaturated monocarboxylic acid or 50 to 95 mole percent of an ethylene-1,2-dicarboxylic acid or anhydride and the balance to a total of 100 mole percent of at least one additional ethylenically unsaturated monomer selected from the group consisting of 1-alkenes having from about 4 to 60 carbon atoms; alkyl vinyl ethers having an ether alkyl, group of from about 8 to 60 carbon atoms, and alkyl acrylates or alkyl methacrylates having an alkyl group of from about 8 to 60 carbon atoms; optionally from about 1 to 90 mole percent of the carboxyl groups in the polymer may be further modified by reaction with a substituted or unsubstituted monoalcohol or monoamine; and from about 50% to 95% by weight of at least one fatty acid selected from the group consisting of natural or synthetic fatty acids containing from about 12 to 48 carbon atoms, wherein the fatty acid is compatible with the polymer and the composition is a solid at 20.degree. C., but starts to become fluid between about 50.degree. C. to 95.degree. C.
摘要翻译：描述了在室温下使纤维制品如纸，纸板和瓦楞纸容器具有耐水性的热熔聚合物/脂肪酸组合物，但是当涂覆的制品在加热的几乎中立至碱性pH水介质。组合物包含约5％至50％重量的约5至95摩尔％的烯属不饱和单羧酸或50至95摩尔％的乙烯-1,2-二羧酸或酸酐的加成聚合物，平衡至总共100摩尔％的至少一种另外的选自具有约4至60个碳原子的1-烯烃的烯属不饱和单体; 具有醚烷基，约8至60个碳原子的烷基乙烯基醚和具有约8至60个碳原子的烷基的丙烯酸烷基酯或甲基丙烯酸烷基酯; 可以通过与取代或未取代的一元醇或单胺反应来进一步修饰聚合物中约1至90摩尔％的羧基; 和约50％至95％重量的至少一种选自含有约12至48个碳原子的天然或合成脂肪酸的脂肪酸，其中脂肪酸与聚合物相容，组合物为在20℃固体，但在约50℃至95℃之间开始变成流体。

9. 发明授权

US4613646A Cleaning and polishing compositions 失效
标题翻译：清洁和抛光组合物
公开(公告)号：US4613646A
公开(公告)日：1986-09-23
申请号：US723021
申请日：1985-04-15
申请人： Paul E. Sandvick
发明人： Paul E. Sandvick
IPC分类号： C09G1/16 , C11D3/37 , C11D3/43 , C08K5/01
CPC分类号： C09G1/16 , C11D3/3765 , C11D3/43
摘要： A surface-treating water-in-oil emulsion composition, which is essentially wax-free, comprising water, hydrocarbon solvent, film-former, nonionic emulsifier and an alpha-olefin/maleic anhydride polymer.
摘要翻译：基本上无蜡的表面处理油包水乳液组合物包含水，烃溶剂，成膜剂，非离子乳化剂和α-烯烃/马来酸酐聚合物。

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