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1. 发明授权

US5442018A Ethylene polymerization using a titanium and vanadium catalyst system in staged reactors 失效
标题翻译：在分段反应器中使用钛和钒催化剂体系的乙烯聚合
公开(公告)号：US5442018A
公开(公告)日：1995-08-15
申请号：US221845
申请日：1994-04-01
申请人： Kevin J. Cann , James W. Nicoletti , Frederick J. Karol , Arthur E. Marcinkowsky , Thomas E. Spriggs , Mark C. Hwu
发明人： Kevin J. Cann , James W. Nicoletti , Frederick J. Karol , Arthur E. Marcinkowsky , Thomas E. Spriggs , Mark C. Hwu
IPC分类号： C08F2/34 , C08F10/02 , C08F210/16 , C08L23/04
CPC分类号： C08F10/02 , C08L23/04 , C08F210/16 , C08F2410/05
摘要： A process for producing polyethylene having a broad molecular weight distribution is provided, in which ethylene and optionally a comonomer are contacted in two reactors connected in series, one reactor containing a titanium-based catalyst and the other reactor containing a vanadium-based catalyst and a halohydrocarbon promoter, or alternatively, both reactors containing a mixed metal catalyst comprising both titanium and vanadium. In the latter case, the halohydrocarbon promoter is present in only one of the reactors to activate the vanadium sites of the catalyst and deactivate the titanium sites of the catalyst simultaneously.
摘要翻译：提供了一种制备具有宽分子量分布的聚乙烯的方法，其中乙烯和任选的共聚单体在串联连接的两个反应器中接触，一个包含钛基催化剂的反应器和另一个含有钒基催化剂的反应器和或者可选地，两个反应器都含有包含钛和钒的混合金属催化剂。在后一种情况下，卤代烃促进剂仅存在于一个反应器中以活化催化剂的钒位点并同时使催化剂的钛位点失活。

2. 发明授权

US4923938A Catalyst for regulating the molecular weight distribution of ethylene polymers 失效
标题翻译：用于调节乙烯聚合物分子量分布的催化剂
公开(公告)号：US4923938A
公开(公告)日：1990-05-08
申请号：US339590
申请日：1989-04-14
申请人： Sun-Chueh Kao , Kevin J. Cann , Frederick J. Karol , Arthur E. Marcinkowsky , Mark G. Goode , Eugene H. Theobald
发明人： Sun-Chueh Kao , Kevin J. Cann , Frederick J. Karol , Arthur E. Marcinkowsky , Mark G. Goode , Eugene H. Theobald
IPC分类号： C08F10/00
CPC分类号： C08F10/00
摘要： A vanadium-based catalyst is treated with certain oxygen-containing compounds as a means of narrowing and effectively regulating the molecular weight distribution of the polymers produced with the catalyst.
摘要翻译：用某些含氧化合物处理钒基催化剂作为缩小并有效调节用催化剂生产的聚合物的分子量分布的手段。

3. 发明授权

US4988783A Ethylene polymerization using supported vanadium catalyst 失效
标题翻译：使用负载型钒催化剂进行乙烯聚合
公开(公告)号：US4988783A
公开(公告)日：1991-01-29
申请号：US473104
申请日：1990-02-02
申请人： Debra L. Beran , Kevin J. Cann , Robert J. Jorgensen , Frederick J. Karol , Norma J. Maraschin , Arthur E. Marcinkowsky
发明人： Debra L. Beran , Kevin J. Cann , Robert J. Jorgensen , Frederick J. Karol , Norma J. Maraschin , Arthur E. Marcinkowsky
IPC分类号： C08F10/02 , C08F210/16
CPC分类号： C08F10/02 , C08F210/16 , Y10S526/901
摘要： An ethylene polymerization catalyst comprising a supported precursor of vanadium trihalide/electron donor complex and alkylaluminum or boron halides, when combined with alkylaluminum cocatalyst and alkyl halide promoter, provides enhanced polymerization and productivity plus superior polyethylene.
摘要翻译：当与烷基铝助催化剂和烷基卤促进剂组合时，包含三卤化钒/电子给体络合物和烷基铝或卤化硼的负载型前体的乙烯聚合催化剂提供增强的聚合和生产率以及优异的聚乙烯。

4. 发明授权

US4508842A Ethylene polymerization using supported vanadium catalyst 失效
标题翻译：使用负载型钒催化剂进行乙烯聚合
公开(公告)号：US4508842A
公开(公告)日：1985-04-02
申请号：US480297
申请日：1983-03-29
申请人： Debra L. Beran , Kevin J. Cann , Robert J. Jorgensen , Frederick J. Karol , Norma J. Maraschin , Arthur E. Marcinkowsky
发明人： Debra L. Beran , Kevin J. Cann , Robert J. Jorgensen , Frederick J. Karol , Norma J. Maraschin , Arthur E. Marcinkowsky
IPC分类号： C08F2/00 , C08F2/34 , C08F4/00 , C08F4/60 , C08F4/68 , C08F10/02 , C08F210/16
CPC分类号： C08F10/02 , C08F210/16
摘要： An ethylene polymerization catalyst comprising a supported precursor of vanadium trihalide/electron donor complex and alkylaluminum or boron halides, when combined with alkylaluminum cocatalyst and alkyl halide promoter provides enhanced polymerization and productivity plus superior polyethylene.
摘要翻译：包含三卤化钒/电子给体络合物和烷基铝或卤化硼的负载型前体的乙烯聚合催化剂当与烷基铝助催化剂和烷基卤助催化剂组合时，提供增强的聚合和生产率以及优异的聚乙烯。

5. 发明授权

US5070057A Simplified polyethylene catalyst system 失效
标题翻译：简化聚乙烯催化剂体系
公开(公告)号：US5070057A
公开(公告)日：1991-12-03
申请号：US502678
申请日：1990-04-02
申请人： Kevin J. Cann , Frederick J. Karol , Arthur E. Marcinkowsky
发明人： Kevin J. Cann , Frederick J. Karol , Arthur E. Marcinkowsky
IPC分类号： C08F4/60 , C08F4/68 , C08F10/00
CPC分类号： C08F10/00
摘要： An improved support vanadium catalyst, especially an improved Beran et al. catalyst system and ethylene polymerization process in which the improvement derives from fixing the promoter to a component of the catalyst composition such that it is a molecularly structural component of the catalyst and thus is not separately fed to the polymerization reaction, but instead is part of the catalyst composition fed to the reaction.
摘要翻译：改进的载体钒催化剂，特别是改进的Beran等催化剂体系和乙烯聚合方法，其中改进来自于将催化剂固定到催化剂组合物的组分，使得其是催化剂的分子结构组分，因此不分别进料到聚合反应中，而是部分催化剂组合物进料到反应中。

6. 发明授权

US4892853A Ethylene polymerization catalyst 失效
标题翻译：乙烯聚合催化剂
公开(公告)号：US4892853A
公开(公告)日：1990-01-09
申请号：US251360
申请日：1988-09-30
申请人： Kevin J. Cann , Frederick J. Karol , Kiu H. Lee , Arthur E. Marcinkowsky
发明人： Kevin J. Cann , Frederick J. Karol , Kiu H. Lee , Arthur E. Marcinkowsky
IPC分类号： C08F4/60 , C08F4/68 , C08F10/02
CPC分类号： C08F10/02
摘要： A vanadium catalyst composition comprising:(i) the reaction product of a vanadium compound and an electron donor, which is a liquid, organic Lewis base in which the vanadium compound is soluble;(ii) a hydrocarbyl aluminum cocatalyst; and(iii) a promoter having the following formula:C.sub.3 (X).sub.a (F).sub.b (H).sub.cwherein X is chlorine, bromine, or iodine, and each X can be alike or differenta=an integer from 6 to 8b=an integer from 0 to 2c=an integer from 0 to 2a+b+c=8

7. 发明授权

US4845067A Catalyst for regulating the molecular weight distribution of ethylene polymers 失效
公开(公告)号：US4845067A
公开(公告)日：1989-07-04
申请号：US214587
申请日：1988-07-01
申请人： Sun-Chueh Kao , Kevin J. Cann , Frederick J. Karol , Arthur E. Marcinkowsky , Mark G. Goode , Eugene H. Theobald
发明人： Sun-Chueh Kao , Kevin J. Cann , Frederick J. Karol , Arthur E. Marcinkowsky , Mark G. Goode , Eugene H. Theobald
IPC分类号： C08F4/60 , C08F4/68 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/901
摘要： A vanadium-based catalyst is treated with certain oxygen-containing compounds as a means of narrowing and effectively regulating the molecular weight distribution of the polymers produced with the catalyst.

8. 发明授权

US4670526A Process for activation of titanium and vanadium catalysts useful in ethylene polymerization 失效
公开(公告)号：US4670526A
公开(公告)日：1987-06-02
申请号：US833148
申请日：1986-02-27
申请人： Kevin J. Cann , David L. Miles , Frederick J. Karol
发明人： Kevin J. Cann , David L. Miles , Frederick J. Karol
IPC分类号： C08F4/62 , C08F4/60 , C08F4/639 , C08F4/64 , C08F10/00 , C08F10/02 , C08F4/68
CPC分类号： C08F10/00
摘要： A process for activating a titanium or vanadium compound and producing polyethylene comprising (i) dissolving a divalent magnesium halide and a Lewis acid having the formula R.sub.m A1X.sub.n or R.sub.m BX.sub.n wherein R is an alkyl or aromatic radical, each radical having 1 to 12 carbon atoms and each R being alike or different; X is a halogen atom; m is an integer from 0 to 3; n is an integer from 0 to 3; and m+n equals 3, in an excess of electron donor compound selected from the group consisting of alkyl esters of alkyl and aromatic carboxylic acids and alkyl and cycloalkyl ethers, each compound having 2 to 12 carbon atoms, in such a manner that a magnesium halide/Lewis acid/electron donor complex is formed; (ii) separating the complex from excess electron donor compound; and (iii) introducing (a) the complex, the titanium or vanadium compound, and a hydrocarbyl aluminum compound and (b) ethylene into a reactor in such a manner that the titanium or vanadium compound is activated and polyethylene is produced.

9. 发明授权

US4861846A Process for simultaneously dimerizing ethylene and copolymerizing ethylene with the dimerized product 失效
标题翻译：同时使乙烯二聚并使乙烯与二聚产物共聚的方法
公开(公告)号：US4861846A
公开(公告)日：1989-08-29
申请号：US714828
申请日：1985-03-22
申请人： Kevin J. Cann , Michael W. Chen , Frederick J. Karol
发明人： Kevin J. Cann , Michael W. Chen , Frederick J. Karol
IPC分类号： C08F4/64 , C07C2/00 , C07C2/08 , C07C2/30 , C07C11/08 , C08F20060101 , C08F2/34 , C08F4/60 , C08F4/658 , C08F4/659 , C08F10/00 , C08F10/02 , C08F210/00 , C08F210/02 , C08F210/06 , C08F210/08 , C08F210/16
CPC分类号： C08F210/16 , Y10S526/901
摘要： A process for producing copolymers of ethylene and butene-1 wherein the butene-1 comonomer is generated in situ within the polymerization reactor by a separately catalyzed ethylene dimerization reaction.
摘要翻译：一种制备乙烯和丁烯-1的共聚物的方法，其中丁烯-1共聚单体在聚合反应器内原位通过单独催化的乙烯二聚反应产生。

10. 发明授权

US4755495A Process for activation of titanium and vanadium catalysts useful in ethylene polymerization 失效
标题翻译：活化用于乙烯聚合的钛和钒催化剂的方法
公开(公告)号：US4755495A
公开(公告)日：1988-07-05
申请号：US941363
申请日：1986-12-15
申请人： Kevin J. Cann , David L. Miles , Frederick J. Karol
发明人： Kevin J. Cann , David L. Miles , Frederick J. Karol
IPC分类号： C08F10/00 , C08F4/64
CPC分类号： C08F10/00
摘要： A process for activating a titanium or vanadium compound and producing polyethylene comprising (i) dissolving a divalent magnesium halide and a Lewis acid having the formula R.sub.m A1X.sub.n or R.sub.m BX.sub.n wherein R is an alkyl or aromatic radical, each radical having 1 to 12 carbon atoms and each R being alike or different; X is a halogen atom; m is an integer from 0 to 3; n is an integer from 0 to 3; and m+n equals 3, in an excess of electron donor compound selected from the group consisting of alkyl esters of alkyl and aromatic carboxylic acids and alkyl and cycloalkyl ethers, each compound having 2 to 12 carbon atoms, in such a manner that a magnesium halide/Lewis acid/electron donor complex is formed; (ii) separating the complex from excess electron donor compound; and (iii) introducing (a) the complex, the titanium or vanadium compound, and a hydrocarbyl aluminum compound and (b) ethylene into a reactor in such a manner that the titanium or vanadium compound is activated and polyethylene is produced.
摘要翻译：一种用于活化钛或钒化合物并生产聚乙烯的方法，包括（i）溶解二价卤化镁和具有式RmA1Xn或RmBXn的路易斯酸，其中R是烷基或芳基，每个基团具有1至12个碳原子， R相同或不同; X是卤原子; m是0至3的整数; n为0〜3的整数。并且m + n等于3，过量的选自烷基和芳族羧酸的烷基酯和烷基和环烷基醚的电子给体化合物，每个化合物具有2至12个碳原子，以使镁形成卤化物/路易斯酸/电子给体络合物; （ii）将复合物与过量的电子给体化合物分离; 和（iii）将复合物，钛或钒化合物和烃基铝化合物和（b）乙烯以使得钛或钒化合物活化并且生产聚乙烯的方式引入反应器中。

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