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1. 发明授权

US07837774B2 Biocide compositions for use in coatings 有权
标题翻译：用于涂料的杀生物剂组合物
公开(公告)号：US07837774B2
公开(公告)日：2010-11-23
申请号：US12331932
申请日：2008-12-10
申请人： Kenneth Breindel , Shailesh Shah , Ayaz A. Khan
发明人： Kenneth Breindel , Shailesh Shah , Ayaz A. Khan
IPC分类号： A01N33/00 , A01N29/00
CPC分类号： A01N37/34 , A01N59/16 , C09D5/14 , A01N25/04 , A01N25/34 , A01N2300/00
摘要： Biocide compositions capable of increasing the fading resistance of a coating material, which compositions preferably comprise a nano-sized halogenated benzonitrile and a nano-sized zinc oxide, are disclosed. Coating compositions, which comprise the biocide compositions, binders, and pigments are disclosed. The biocide compositions are particularly suitable for use in paints. Methods for reducing the fading of pigmented coating compositions upon exposure to light are also disclosed.
摘要翻译：公开了能够提高涂料的抗褪色性的杀生物剂组合物，该组合物优选包含纳米尺度的卤代苄腈和纳米尺寸的氧化锌。公开了包含杀生物剂组合物，粘合剂和颜料的涂料组合物。杀生物剂组合物特别适用于涂料。还公开了降低着色涂料组合物在光照下的褪色的方法。

2. 发明申请

US20090145327A1 Biocide Compositions for Use in Coatings 有权
标题翻译：用于涂料的杀菌剂组合物
公开(公告)号：US20090145327A1
公开(公告)日：2009-06-11
申请号：US12331932
申请日：2008-12-10
申请人： Kenneth Breindel , Shailesh Shah , Ayaz A. Khan
发明人： Kenneth Breindel , Shailesh Shah , Ayaz A. Khan
IPC分类号： A01N59/16 , C09D7/00 , A01N25/08
CPC分类号： A01N37/34 , A01N59/16 , C09D5/14 , A01N25/04 , A01N25/34 , A01N2300/00
摘要： Biocide compositions capable of increasing the fading resistance of a coating material, which compositions preferably comprise a nano-sized halogenated benzonitrile and a nano-sized zinc oxide, are disclosed. Coating compositions, which comprise the biocide compositions, binders, and pigments are disclosed. The biocide compositions are particularly suitable for use in paints. Methods for reducing the fading of pigmented coating compositions upon exposure to light are also disclosed.
摘要翻译：公开了能够提高涂料的抗褪色性的杀生物剂组合物，该组合物优选包含纳米尺度的卤代苄腈和纳米尺寸的氧化锌。公开了包含杀生物剂组合物，粘合剂和颜料的涂料组合物。杀生物剂组合物特别适用于涂料。还公开了降低着色涂料组合物在光照下的褪色的方法。

3. 发明申请

US20100288644A1 Coating for metal containers, metalworking lubricant compositions, compositions for electroplating and electrowinning, latex compositions and processes therefor 审中-公开
标题翻译：金属容器涂层，金属加工润滑剂组合物，用于电镀和电解沉积的组合物，胶乳组合物及其工艺
公开(公告)号：US20100288644A1
公开(公告)日：2010-11-18
申请号：US12803263
申请日：2009-11-12
申请人： David W. Brown , Kenneth Breindel , Michael S. Wiggins , Ronald W. Broadbent , Shailesh Shah
发明人： David W. Brown , Kenneth Breindel , Michael S. Wiggins , Ronald W. Broadbent , Shailesh Shah
IPC分类号： C25D3/02 , B21B45/02
CPC分类号： C25D3/02 , C10M159/12 , C10M173/00 , C10M2207/042 , C10M2207/046 , C10M2209/103 , C10M2209/104 , C10M2209/105 , C10N2260/06
摘要： Coatings for metal containers, metalworking lubricant compositions, compositions for electroplating and electrowinning, and latex compositions comprising a base-catalyzed reaction product of (a) at least one compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and (b) at least one compound having the formula II R2X(AO)nY (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or —NR3— where R3 is hydrogen or a C1-C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number from 0 to 200; and Y is hydrogen, or Y can be a mercapto group or an amino group or a C1-C6 alkylamino group in place of a terminal —OH group, provided that when Y is mercapto or an amino group, or a C1-C6 alkylamino group, n is at least 1; wherein the mole ratio of component a) to b) is from 0.1:1 to 5:1; are described.
摘要翻译：用于金属容器，金属加工润滑剂组合物，用于电镀和电解提取的组合物的涂料，以及包含（a）至少一种式I的化合物R1（X）3（I）的碱催化的反应产物的胶乳组合物，其中每个X基团为卤素原子或一个X基团是卤素原子，两个X基团表示环氧氧原子，其与R1基团中的两个相邻的碳原子连接以形成环氧基，并且R 1是含有3至10个碳的烷基三原子和（b）至少一种具有式II R2X（AO）nY（II）的化合物，其中R2是具有1至36个碳原子的取代或未取代的饱和或不饱和的有机基团; X是-O - ， - S-或-NR 3 - ，其中R 3是氢或C 1 -C 18烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; Y为氢原子，Y为巯基或氨基或C1-C6烷基氨基而不是端基-OH，条件是当Y为巯基或氨基时，或为C1-C6烷基氨基，n至少为1; 其中组分a）至b）的摩尔比为0.1:1至5:1; 被描述。

4. 发明授权

US06465605B2 Branched polymeric surfactant reaction products, methods for their preparation, and uses therefor 有权
标题翻译：支化聚合物表面活性剂反应产物，其制备方法及用途
公开(公告)号：US06465605B2
公开(公告)日：2002-10-15
申请号：US09783855
申请日：2001-02-15
申请人： Kenneth Breindel , Ronald W. Broadbent , Michael S. Wiggins , Marcie Natale
发明人： Kenneth Breindel , Ronald W. Broadbent , Michael S. Wiggins , Marcie Natale
IPC分类号： C08G5900
CPC分类号： C08G65/337 , B01D19/0427 , C08G65/33306 , C08G2650/06 , C08G2650/50 , C08L71/02 , C08L71/03 , C08L79/02 , C09D5/024 , C09D7/65
摘要： Polymeric compounds useful as low foaming surfactants and defoaming and stabilizing agents for aqueous-and nonaqueous-based compositions, and to processes for the preparation of the polymeric compounds, wherein the polymeric compounds are the reaction products of reactants comprising A) at least one linking compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and B) compounds of formula 11 R2(OA)nX (II) wherein R2 is an organic group containing from 4 to 36 carbon atoms, n is a number of from 0 to 200, X is —OH, —NHR′, or —SH and each OA group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group.
摘要翻译：可用作低泡表面活性剂的聚合化合物和用于水基和非水基组合物的消泡和稳定剂以及制备聚合物的方法，其中聚合物是反应物的反应产物，其包含：A）至少一种连接化合物式I其中X基团为卤素原子或一个X基团为卤素原子，两个X基团表示环氧氧原子，其与R1基团中两个相邻的碳原子连接形成环氧基团，R1为烷基三含3至10个碳原子的基团; 和B）式11的化合物，其中R2是含有4至36个碳原子的有机基团，n是0-200的数，X是-OH，-NHR'或-SH，各个OA基团独立地是亚乙基氧基， 1,2-亚丙氧基或1,2-亚丁氧基。

5. 发明授权

US06409809B1 Pigmented coatings exhibiting reduced fading 失效
标题翻译：显色减少的着色涂料
公开(公告)号：US06409809B1
公开(公告)日：2002-06-25
申请号：US09500336
申请日：2000-02-08
申请人： Kenneth Breindel , Samuel A. Firman
发明人： Kenneth Breindel , Samuel A. Firman
IPC分类号： A01N43647
CPC分类号： C09D5/025 , A01N37/34 , A01N43/653 , A01N25/24 , A01N25/22 , A01N2300/00
摘要： A method for preventing the fading of pigmented coatings, especially water based acrylic paints, includes incorporating therein a biocide containing a mixture of from about 1% to about 99% by weight of a halogenated benzonitrile compound and from about 1% to about 99% by weight of a conazole compound.
摘要翻译：防止着色涂料，特别是水基丙烯酸涂料的褪色的方法包括在其中加入含有约1％至约99％重量的卤化苄腈化合物和约1％至约99％的混合物的杀生物剂，重唑化合物。

6. 发明授权

US07169858B2 Polyfluorinated compounds useful as surfactants, foam control agents and/or rheology modifiers 失效
标题翻译：可用作表面活性剂，泡沫控制剂和/或流变改性剂的多氟化合物
公开(公告)号：US07169858B2
公开(公告)日：2007-01-30
申请号：US10788136
申请日：2004-02-26
申请人： David W. Brown , Kenneth Breindel , Ronald W. Broadbent , Michael S. Wiggins
发明人： David W. Brown , Kenneth Breindel , Ronald W. Broadbent , Michael S. Wiggins
IPC分类号： C08G65/22 , C08G65/24
CPC分类号： C07C41/03 , C07C43/11 , C08G65/2639 , C08G65/337 , C08L71/03 , C09D5/024 , C09D7/65 , Y10T428/25 , C07C43/23
摘要： Reaction products prepared by processes which comprise reacting: A) at least one compound having the general formula I: R1(X)3 (I) wherein each X group independently represents a halogen atom or one X group represents a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group having from 3 to 10 carbon atoms; and B) at least one compound having the general formula II R2X(AO)nY (II) wherein R2 represents a polyfluorinated organic group having from 1 to 36 carbon atoms and at least two fluorine atoms; X represents —O—, —S—, or NR3— where R3 is hydrogen or a C1–C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200; and Y represents hydrogen, a mercapto group, an amino group or a C1–C6 alkylamino group in place of a terminal —OH group, with the proviso that when Y is a mercapto, amino, or a C1–C6 alkylamino group, n is at least 1; are described.
摘要翻译：通过以下方法制备的反应产物：A）至少一种具有通式I的化合物：<？in-line-formula description =“In-line formula”end =“lead”→> R 1> （X）3（I）<？in-line-formula description =“In-line formula”end =“tail”？>其中每个X基团独立地表示卤素原子或一个X 基团表示卤素原子，两个X基团表示环氧氧原子，其与R 1基团中的两个相邻的碳原子连接以形成环氧基，并且R 1 >是具有3至10个碳原子的烷基三胺基; 和B）至少一种具有通式II的化合物<？in-line-formula description =“In-line Formulas”end =“lead”？> R 2 X（AO） Y（II）<？在线公式描述=“在线式”end =“tail”？>其中R 2表示多氟化有机基团，其具有1至 36个碳原子和至少两个氟原子; X表示-O-，-S-或NR 3 - ，其中R 3是氢或C 1 -C 18 烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; Y表示氢，巯基，氨基或C 1 -C 6烷基氨基代替末端-OH基团，条件是当Y 是巯基，氨基或C 1 -C 6烷基氨基，n为至少1; 被描述。

7. 发明授权

US07017490B1 Lithographic fountain solutions 失效
标题翻译：平版喷泉解决方案
公开(公告)号：US07017490B1
公开(公告)日：2006-03-28
申请号：US10436587
申请日：2003-05-13
申请人： David W. Brown , Kenneth Breindel , Ronald W. Broadbent , Michael S. Wiggins
发明人： David W. Brown , Kenneth Breindel , Ronald W. Broadbent , Michael S. Wiggins
IPC分类号： B41F1/18 , C09K3/00 , G03F7/00 , C08L63/00
CPC分类号： B41N3/08
摘要： Lithographic fountain solutions containing a surfactant-effective quantity of at least one reaction product comprising the following reactants: (A) at least one compound of formula I R1(X)3 (I) wherein each X group is a halogen atom or one X group is a halogen atom and two X groups represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R1 group to form an epoxy group, and R1 is an alkanetriyl group containing from 3 to 10 carbon atoms; and (B) at least one compound having formula II R2X(AO)nY (II) wherein R2 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 1 to 36 carbon atoms; X is —O—, —S—, or NR3— where R3 is hydrogen or a C1–C18 alkyl group; each AO group is independently an ethyleneoxy, 1,2-propyleneoxy, or 1,2-butyleneoxy group, n is a number of from 0 to 200; and Y is hydrogen, or Y can be a mercapto group or an amino group or a C1–C6 alkylamino group in place of a terminal —OH group, provided that when Y is mercapto or an amino group or a C1–C6 alkylamino group, n is at least 1.
摘要翻译：含有表面活性剂有效量的至少一种包含以下反应物的反应产物的平版印刷喷泉溶液：（A）至少一种式I的化合物<？in-line-formula description =“In-line Formulas”end =“lead” （X）3（I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中每个X 基团是卤素原子或一个X基团是卤素原子，两个X基团表示环氧氧原子，其与R 1基团中的两个相邻碳原子连接以形成环氧基团，并且 R 1是含有3至10个碳原子的烷基三烷基; 和（B）至少一种具有式II的化合物<？in-line-formula description =“In-line Formulas”end =“lead”？> R 2 X（AO）n Y（II）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 2是取代或未取代的饱和或不饱和的，具有1至36个碳原子的有机基团; X是-O-，-S-或NR 3 - ，其中R 3是氢或C 1 -C 18 烷基; 每个AO基团独立地为亚乙氧基，1,2-亚丙氧基或1,2-亚丁氧基，n为0至200的数; 并且Y是氢，或Y可以是巯基或氨基或C 1 -C 6烷基氨基代替末端-OH基团，条件是当Y是巯基或氨基或C 1 -C 6烷基氨基时，n至少为1。

8. 发明授权

US06509395B2 Defoamers for pigment dispersants 有权
标题翻译：消泡剂用于颜料分散剂
公开(公告)号：US06509395B2
公开(公告)日：2003-01-21
申请号：US09801509
申请日：2001-03-08
申请人： Kenneth Breindel , David W. Brown
发明人： Kenneth Breindel , David W. Brown
IPC分类号： C08L6300
CPC分类号： C08G65/24 , C08G65/337
摘要： Branched polymer defoamers for pigment dispersants. The branched polymers are the reaction products of a linking agent defined by formula (I): R(Y)3 (I) wherein each Y group is a halogen atom or one Y group is a halogen atom and two Y groups together represent an epoxy oxygen atom, which is attached to two adjacent carbon atoms in the R group to form an epoxy group, and R is an alkanetriyl group containing from 3 to 10 carbon atoms, and b) at least one compound having the formula (II) R1X(EO)n(PO)m(BO)pZ (II) wherein R1 is a substituted or unsubstituted, saturated or unsaturated, organic group having from 4 to 36 carbon atoms; x is —O—, —S—, or —NR2—where R2 is hydrogen or a C1-C4 alkyl group; Z is hydrogen, —NHR2 in place of a terminal —O— group wherein R2 has the meaning given above, or —SH, in which the —SH group is present in place of a terminal —O— group; n is a number of from 0 to 100, e.g., from 1 to 100; m is a number of from 0 to 50 e.g., from 1 to 50; and p is a number of from 0 to 50 e.g., from 1 to 50; provided that the sum of n, m, and p is at least 1; and wherein EO, PO and BO groups when present can be in random and/or block distribution and can be in any order with respect to the X group.
摘要翻译：用于颜料分散剂的分支聚合物消泡剂。支链聚合物是由式（I）定义的连接剂的反应产物：其中每个Y基团是卤素原子或一个Y基团是卤素原子，两个Y基团一起表示环氧氧原子，其连接到两个 R基中的相邻碳原子形成环氧基，R是含有3至10个碳原子的烷三基，和b）至少一种具有式（II）的化合物，其中R 1是取代或未取代的饱和或不饱和的，具有4至36个碳原子的有机基团; x是-O-，-S-或-NR 2 - ，其中R 2是氢或C 1 -C 4烷基; Z是氢，-NHR 2代替其中R2具有上述含义的末端-O-基团或-SH，其中-SH基团代替末端-O-基团; n为0至100，例如1至100的数; m为0至50，例如1至50; 并且p为0至50，例如1至50的数; 条件是n，m和p的和为至少1; 并且当存在时，EO，PO和BO基团可以是随机和/或嵌段分布，并且可以相对于X基团以任何顺序。

9. 发明授权

US06251958B1 Defoamer process 失效
标题翻译：消泡剂工艺
公开(公告)号：US06251958B1
公开(公告)日：2001-06-26
申请号：US09288593
申请日：1999-04-08
申请人： Puvin Pichai , Kenneth Breindel
发明人： Puvin Pichai , Kenneth Breindel
IPC分类号： B01F312
CPC分类号： B01D19/0413 , B01D19/0404 , Y10S516/928 , B01D19/0409
摘要： A process for preparing a defoamer composition by providing a high-shear, in-line mixer having a rotor-stator assembly with at least one concentric set of shearing teeth which rotate at a tip speed of up to about 25 meters per second and feeding to said mixer a melt of a hydrophobic defoaming agent along with a functional carrier liquid at a controlled mass flow rate and temperature. After mixing, the mixture is cooled and discharged into a receiving vessel.
摘要翻译：一种制备消泡剂组合物的方法，该方法通过提供一种具有转子 - 定子组件的高剪切的在线混合器，所述转子 - 定子组件具有至少一个同心的一组剪切齿，其以最高约25米/秒的速度旋转，所述混合器是以受控的质量流率和温度与疏水消泡剂一起的功能载体液体的熔体。混合后，将混合物冷却并排放到接收容器中。

10. 发明授权

US6107394A Polymeric thickeners for aqueous compositions 有权
标题翻译：含水组合物的聚合增稠剂
公开(公告)号：US6107394A
公开(公告)日：2000-08-22
申请号：US91064
申请日：1999-01-11
申请人： Ronald W. Broadbent , Kenneth Breindel
发明人： Ronald W. Broadbent , Kenneth Breindel
IPC分类号： C08G65/329 , C08L71/02 , C08J3/00 , C08K3/20 , C08L51/00 , C08L75/00 , C08L77/00
CPC分类号： C08G65/329 , C08L71/02
摘要： Latexes are thicknened by a blend of a urethane compound effective as an associative thickener and a non-urethane compound of the formula: R.sup.1 --(O--A).sub.a --B.sup.1 --R.sup.2 --(B.sup.2 --R.sup.3).sub.d --(B.sup.3 --(A'--O).sub.b-f --(A'--B.sup.4).sub.f --R.sup.4 --(B.sup.5 --R.sup.5).sub.e).sub.n --B.sup.6 --(A"O).sub.c --R.sup.6, wherein R.sup.1 and R.sup.6 are monovalent hydrophobic groups independently selected from the group consisting of an aliphatic group, a substituted aliphatic group, an aromatic group, and a substituted aromatic group; R.sup.2 and R.sup.4 are independently selected from the group consisting of aliphatic, substituted aliphatic, aromatic, or substituted aromatic radicals, each radical being divalent or trivalent; R.sup.3 and R.sup.5 are independently selected from hydrogen, lower alkyl and lower aralkyl; B.sup.1, B.sup.2, B.sup.3, B.sup.4, B.sup.5 and B.sup.6 are linking groups independently selected from the group consisting of an oxygen atom (to form the ether linkage --O--), a carboxylated group (to form an ester linkage R.sup.2 --C(O)--O-- and/or R.sup.4 --C(O)--O--, an amino group to form the amine linkage R.sup.2 --N(R)-- and/or R.sup.4 --N(R)--, wherein R is hydrogen, lower alkyl, lower aralkyl, or lower acyl), and an amido group (to form the amide linkage R.sup.2 --N(R)--C(O)-- and or R.sup.4 --N(R)--C(O)--, wherein R is hydrogen, lower alkyl, lower aralkyl, or lower acyl); each of a, b, c, d, e, f and n are integers, wherein each of a and c are independently any integer from greater than 20 to about 200; b is any integer from greater than 20 to about 450; d, e, and f are zero or 1; and n is any integer from 1 to about 5; and each of A, A' and A" is independently an ethylene, 1,2-propylene, 1,2-butylene unit or combinations thereof.
摘要翻译： PCT No.PCT / US96 / 19136 Sec。 371日期1999年1月11日 102（e）1999年1月11日PCT PCT 1996年12月4日PCT公布。出版物WO97 / 21743 日期：1997年6月19日通过作为缔合增稠剂和下式的非氨基甲酸酯化合物的共混物，将化合物加成：R1-（OA）a-B1-R2-（B2-R3）d-（B3 - （A'-O）bf-（A'-B4）f-R4-（B5-R5）e）n-B6-（A''O）c-R6，其中R1和R6是独立选择的一价疏水基团由脂肪族基团，取代脂肪族基团，芳香族基团和取代芳香族基团组成的组; R2和R4独立地选自脂族，取代的脂族，芳族或取代的芳族基团，每个基团是二价或三价的; R3和R5独立地选自氢，低级烷基和低级芳烷基; B1，B2，B3，B4，B5和B6是独立地选自氧原子（形成醚键-O-）的连接基团，羧基（形成酯键R2-C（O） -O-和/或R 4 -C（O）-O-，形成胺键R2-N（R） - 和/或R4-N（R） - 的氨基，其中R是氢，低级烷基，低级芳烷基或低级酰基）和酰氨基（形成酰胺键R2-N（R）-C（O） - 和/或R4-N（R）-C（O） - ，其中R是氢，低级烷基，低级芳烷基或低级酰基）; a，b，c，d，e，f和n各自为整数，其中a和c各自独立地为大于20至约200的任何整数; b是大于20至约450的任何整数; d，e和f为零或1; n为1〜5的整数; 并且A，A'和A“各自独立地为乙烯，1,2-亚丙基，1,2-亚丁基单元或其组合。

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