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    • 5. 发明申请
    • NONAQUEOUS ELECTROLYTE SECONDARY BATTERY
    • 非电解电解质二次电池
    • US20100255374A1
    • 2010-10-07
    • US12745856
    • 2008-12-04
    • Akiyoshi NemotoKazuyuki TaninoKenji Nakane
    • Akiyoshi NemotoKazuyuki TaninoKenji Nakane
    • H01M4/525
    • H01M4/505H01M2/1653H01M2/1686H01M4/131H01M4/525H01M6/164H01M10/0525H01M10/0569H01M2004/021H01M2004/028H01M2300/0025H01M2300/0034H01M2300/0037
    • A nonaqueous electrolyte secondary battery comprising a positive electrode containing a granular positive electrode active material composed of a mixed metal oxide and an M3-containing compound (M3 represents one or more elements selected from the group consisting of Group 3B elements in the periodic table, and the M3-containing compound is different from said mixed metal oxide) placed in the form of particles or a layer on the surface of the mixed metal oxide, wherein the positive electrode active material has M1 (M1 represents one or more elements selected from the group consisting of alkali metal elements), M2 (M2 represents one or more elements selected from the group consisting of Mn, Fe, Co and Ni), M3 (M3 has the same meaning as that described above) and O on its surface, and when the molar ratio (M3/M2) of the number of M3 atoms (mol) to the number of M2 atoms (mol) on the surface of the positive electrode active material is represented by A and the BET specific surface area of the positive electrode active material is represented by S (m2/g), A and S satisfy the following formula (1): A/S≧1  (1), a negative electrode, a separator, and a nonaqueous electrolyte.
    • 一种非水电解质二次电池,其包含含有由混合金属氧化物构成的粒状正极活性物质和含M3化合物的正极(M3表示选自周期表中的3B族元素的一种或多种元素,以及 含有M3的化合物不同于所述混合金属氧化物),其中所述正极活性物质具有M1(M1表示选自组中的一种或多种元素 由碱金属元素组成),M2(M2表示选自Mn,Fe,Co和Ni中的一种或多种元素),M3(M3具有与上述相同的含义)和O表面,当 正极活性物质表面的M3原子数(mol)与M2原子数(mol)的摩尔比(M3 / M2)由A表示,BET比表面积 正极活性物质由S(m2 / g)表示,A和S满足下式(1):A /S≥1(1),负极,隔膜和非水电解质。