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1. 发明授权

US07678954B2 Olefin oligomerization to produce hydrocarbon compositions useful as fuels 有权
标题翻译：烯烃低聚产生用作燃料的烃组合物
公开(公告)号：US07678954B2
公开(公告)日：2010-03-16
申请号：US11342385
申请日：2006-01-27
申请人： Keith H. Kuechler , Stephen Harold Brown , Helge Jaensch , Georges M. Mathys , Shifang Luo , Jane C. Cheng
发明人： Keith H. Kuechler , Stephen Harold Brown , Helge Jaensch , Georges M. Mathys , Shifang Luo , Jane C. Cheng
IPC分类号： C07C2/02
CPC分类号： C10G50/00 , C09K8/32
摘要： In a process for producing a hydrocarbon composition, a feed comprising at least one C3 to C8 olefin and an olefinic recycle stream rich in C9− hydrocarbons is contacted with a crystalline molecular sieve catalyst having an average crystal size no greater than 0.05 micron and an alpha value between about 100 and about 600 in at least one reaction zone under olefin oligomerization conditions including an inlet temperature between about 150° C. and about 350° C., a pressure of at least 2,860 kPa and a recycle to feed weight ratio of about 0.1 to about 3.0. The contacting produces an oligomerization effluent stream, which is separated into at least a hydrocarbon product stream rich in C9+ hydrocarbons and the olefinic recycle stream.
摘要翻译：在制备烃组合物的方法中，将包含至少一种C 3 -C 8烯烃和富含C 9烃的烯烃循环料的进料与平均晶体尺寸不大于0.05微米的结晶分子筛催化剂和α 在至少一个反应区中在约100至约600之间的烯烃低聚条件下，包括入口温度为约150℃至约350℃，压力至少为2,860kPa，循环至进料重量比为约 0.1至约3.0。接触产生低聚流出物流，其被分离成至少一种富含C9 +烃的烃产物流和烯烃再循环流。

2. 发明授权

US08481796B2 Olefin oligomerization and compositions therefrom 有权
标题翻译：烯烃低聚及其组合物
公开(公告)号：US08481796B2
公开(公告)日：2013-07-09
申请号：US11342386
申请日：2006-01-27
申请人： Keith H. Kuechler , Stephen Harold Brown , An Amandine Verberckmoes , Steven E. Silverberg , Marc P. Puttemans , Mark R. Welford , John S. Godsmark
发明人： Keith H. Kuechler , Stephen Harold Brown , An Amandine Verberckmoes , Steven E. Silverberg , Marc P. Puttemans , Mark R. Welford , John S. Godsmark
IPC分类号： C07C2/02 , C07C2/08
CPC分类号： C10L1/04 , C10G50/00 , C10M177/00 , C10M2203/003 , C10N2220/028 , C10N2230/40 , C10N2270/00
摘要： A hydrocarbon composition that comprises species of at least 3 different carbon numbers, at least about 95 wt % non-normal hydrocarbons, no greater than 1000 wppm aromatics, no greater than 10 wt % naphthenes, and also has a certain boiling point range; and a process for making the hydrocarbon composition.
摘要翻译：烃组合物，其包含至少3种不同碳数的物质，至少约95重量％的非正常烃，不大于1000wppm芳族化合物，不大于10重量％的环烷烃，并且还具有一定的沸点范围; 以及制备烃组合物的方法。

3. 发明授权

US07692049B2 Hydrocarbon compositions useful for producing fuels and methods of producing the same 有权
标题翻译：用于生产燃料的烃组合物及其制备方法
公开(公告)号：US07692049B2
公开(公告)日：2010-04-06
申请号：US11342374
申请日：2006-01-27
申请人： Keith H. Kuechler , Stephen Harold Brown , An Amandine Verberckmoes , Marc P. Puttemans , Steven E. Silverberg
发明人： Keith H. Kuechler , Stephen Harold Brown , An Amandine Verberckmoes , Marc P. Puttemans , Steven E. Silverberg
IPC分类号： C10M105/04
CPC分类号： C10G50/00 , C10G2400/02 , C10G2400/04
摘要： A hydrocarbon composition comprises at least 90 wt. % of C9 to C20 non-normal olefins, non-normal saturates or combinations thereof based on the weight of the hydrocarbon composition, at least 2 wt. % and not greater than 25 wt. % of C9 hydrocarbons based on the weight of the hydrocarbon composition, and less than 15 wt. % of C17+ hydrocarbons based on the weight of the hydrocarbon composition, wherein said hydrocarbon composition has a specific gravity at 15° C. of at least 0.730 and less than 0.775. The composition is produced by oligomerization of at least one C3 to C8 olefin and an olefinic recycle stream containing no more than 10 wt. % of C10+ non-normal olefins. The composition is useful in producing fuel blends, such as jet fuel and diesel fuel.
摘要翻译：烃组合物包含至少90wt。至少2重量％的C9至C20非正构烯烃的％，非正常饱和物或其组合，基于烃组合物的重量计，％且不大于25wt。基于烃组合物重量的C 9烃的％，小于15wt。基于烃组合物重量的C17 +烃的％，其中所述烃组合物在15℃下的比重为至少0.730且小于0.775。该组合物是通过使至少一种C 3至C 8烯烃和含有不超过10wt。％的C10 +非正常烯烃。该组合物可用于生产燃料混合物，例如喷气燃料和柴油燃料。

4. 发明授权

US07678953B2 Olefin oligomerization 有权
标题翻译：烯烃低聚
公开(公告)号：US07678953B2
公开(公告)日：2010-03-16
申请号：US11342000
申请日：2006-01-27
申请人： Keith H. Kuechler , Stephen Harold Brown , An Amandine Verberckmoes , Marc P. Puttemans , Steven E. Silverberg
发明人： Keith H. Kuechler , Stephen Harold Brown , An Amandine Verberckmoes , Marc P. Puttemans , Steven E. Silverberg
IPC分类号： C07C2/02
CPC分类号： C10G50/00 , C07C2/12 , C07C11/02
摘要： A process for producing a hydrocarbon composition that comprises contacting a feed stream, that comprises at least one C3 to C8 olefin, and an olefinic recycle stream, that comprises a first olefinic recycle stream and no more than 10 wt % of C10+ non-normal olefins, with a molecular sieve catalyst in a reaction zone under olefin oligomerization conditions producing an oligomerization effluent stream; separating the oligomerization effluent stream to produce a first olefinic stream, that has a weight ratio of C4−/(C5-C8) molecules from about 0.8 to about 1.2 times the weight ratio of C4−/(C5-C8) molecules found in the oligomerization effluent stream, and a first hydrocarbon product stream, that comprises at least 1 wt % and no more than 30 wt % of C9 non-normal olefin; and splitting the first olefinic stream to produce the first olefinic recycle stream and a first purge stream.
摘要翻译：一种用于生产烃组合物的方法，其包括使包含至少一种C 3至C 8烯烃的进料流和烯烃循环料流接触，所述进料流包含第一烯烃循环料流和不超过10重量％的C 10+非正烯烃在烯烃低聚条件下在反应区中分子筛催化剂生成低聚流出物流; 分离低聚流出物流以产生第一烯烃流，其具有C4- /（C5-C8）分子的重量比约为所述C4- /（C5-C8）分子的重量比的约0.8至约1.2倍。低聚流出物流和第一烃产物流，其包含至少1重量％且不超过30重量％的C 9非正构烯烃; 和分裂第一烯烃流以产生第一烯烃再循环流和第一吹扫流。

5. 发明授权

US08932451B2 Integrated crude refining with reduced coke formation 有权
标题翻译：综合原油精炼与焦炭形成减少
公开(公告)号：US08932451B2
公开(公告)日：2015-01-13
申请号：US13597504
申请日：2012-08-29
申请人： Ramon A. Strauss , Stephen Harold Brown , Donald E. Stratton , Stefan Maria Willy Ceulemans
发明人： Ramon A. Strauss , Stephen Harold Brown , Donald E. Stratton , Stefan Maria Willy Ceulemans
IPC分类号： C10G65/14 , C10G65/00 , C10G65/12 , B01D3/06 , C10G7/00 , B01J37/02 , C10G49/02 , B01J37/20 , C10G49/22 , C10G67/04 , C10G45/04 , B01J23/74 , B01J35/02 , C10G47/02 , B01J35/10 , B01J23/883 , B01J23/888
CPC分类号： C10G65/12 , B01J23/74 , B01J23/883 , B01J23/8885 , B01J35/023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0201 , B01J37/0207 , B01J37/20 , C10G35/00 , C10G45/00 , C10G45/02 , C10G45/04 , C10G45/32 , C10G45/44 , C10G45/58 , C10G47/00 , C10G47/02 , C10G49/02 , C10G49/22 , C10G65/00 , C10G65/14 , C10G67/00 , C10G67/0454 , C10G2300/1037 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2300/205 , C10G2300/206 , C10G2300/301 , C10G2300/305 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/10 , C10G2400/26 , C10G2400/28
摘要： Methods are provided for processing crude oil feeds with reduced or minimized energy usage, reduced or minimized numbers of processing steps, improved allocation of hydrogen, and reduced or minimized formation of low value products. The methods reduce or minimize the use of vacuum distillation, and in many aspects reduce or minimize the use of both atmospheric and vacuum distillation. The methods also reduce or minimize the use of coking and fluid catalytic cracking processes.
摘要翻译：提供了用于以减少或最小化的能量使用来处理原油进料的方法，减少或最少数量的处理步骤，改善氢的分配，以及减少或最小化低价值产物的形成。该方法减少或最小化真空蒸馏的使用，并且在许多方面减少或最小化大气压和真空蒸馏的使用。该方法还减少或最小化焦化和流化催化裂化过程的使用。

6. 发明授权

US08741129B2 Use of low boiling point aromatic solvent in hydroprocessing heavy hydrocarbons 有权
标题翻译：在加氢处理重质烃中使用低沸点芳香族溶剂
公开(公告)号：US08741129B2
公开(公告)日：2014-06-03
申请号：US13597582
申请日：2012-08-29
申请人： Stephen Harold Brown , Teh C. Ho , Jane Chi-Ya Cheng , Hyung Suk Woo
发明人： Stephen Harold Brown , Teh C. Ho , Jane Chi-Ya Cheng , Hyung Suk Woo
IPC分类号： C10G45/00 , C10G47/00 , C10G45/02 , C10G45/32 , C10G45/44
CPC分类号： C10G45/00 , C10G45/02 , C10G45/32 , C10G45/44 , C10G45/58 , C10G47/00 , C10G2300/1037 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2300/205 , C10G2300/206 , C10G2300/44
摘要： This invention is directed to a process for producing a hydroprocessed product. The invention is particularly advantageous in that substantially less hydrogen is absorbed during the process relative to conventional hydroprocessing methods. This benefit is achieved by using a particular solvent as a co-feed component. In particular, the solvent component contains at least one single ring aromatic compound and has a relatively low boiling point range compared to the heavy hydrocarbon oil component used as another co-feed component.
摘要翻译：本发明涉及一种加氢处理产物的生产方法。本发明特别有利的是，相对于常规的加氢处理方法，在该方法中吸收相对较少的氢。通过使用特定溶剂作为共进料组分来实现该益处。特别地，溶剂组分含有至少一种单环芳族化合物，并且与用作另一种共进料组分的重质烃油组分相比具有相对较低的沸点范围。

7. 发明申请

US20130081979A1 USE OF SUPERCRITICAL FLUID IN HYDROPROCESSING HEAVY HYDROCARBONS 审中-公开
标题翻译：超临界流体在氢化重油中的应用
公开(公告)号：US20130081979A1
公开(公告)日：2013-04-04
申请号：US13597616
申请日：2012-08-29
申请人： Stephen Harold Brown , Teh C. Ho , Jane Chi-ya Cheng , Hyung Suk Woo
发明人： Stephen Harold Brown , Teh C. Ho , Jane Chi-ya Cheng , Hyung Suk Woo
IPC分类号： C10G47/34
CPC分类号： C10G47/34 , C10G45/02 , C10G47/00 , C10G2300/205 , C10G2300/206 , C10G2300/301 , C10G2300/308 , C10G2300/44
摘要： This invention is directed to a process for producing a hydroprocessed product. The invention is particularly advantageous in that substantially longer run length can be attained relative to conventional hydroprocessing methods. This benefit is achieved by using a particular solvent as a co-feed component. In particular, the solvent component is comprised of at least one or more supercritical solvent compounds.
摘要翻译：本发明涉及一种加氢处理产物的生产方法。本发明特别有利的是，相对于常规的加氢处理方法可以实现更长的运行长度。通过使用特定溶剂作为共进料组分来实现该益处。特别地，溶剂组分由至少一种或多种超临界溶剂化合物组成。

8. 发明授权

US07989668B2 Lowering nitrogen-containing Lewis bases in molecular sieve oligomerisation 有权
标题翻译：降低分子筛低聚中的含氮路易斯碱
公开(公告)号：US07989668B2
公开(公告)日：2011-08-02
申请号：US11700979
申请日：2007-02-01
申请人： John Stephen Godsmark , Georges Marie Karel Mathys , Hubertus Joseph Beckers , Charles Morris Yarbrough , Stephen Harold Brown , Yeo-Meng Lim
发明人： John Stephen Godsmark , Georges Marie Karel Mathys , Hubertus Joseph Beckers , Charles Morris Yarbrough , Stephen Harold Brown , Yeo-Meng Lim
IPC分类号： C07C2/12
CPC分类号： C07C2/12 , C07C7/10 , C07C29/141 , C07C29/16 , C07C45/50 , C07C51/235 , C07C67/08 , C07C2529/70 , C07C2601/14 , C10G21/00 , C10G25/00 , C10G50/00 , C10L1/06 , C12C11/02 , C07C11/02 , C07C31/02 , C07C31/12 , C07C63/15 , C07C69/76 , C07C69/80 , C07C69/82 , C07C69/78 , C07C69/75 , C07C47/02
摘要： Nitrogen-containing Lewis bases act as poisons for molecular sieve catalysts used in oligomerisation reactions. A lowering of their presence in the feed prior to the contacting thereof with the molecular sieve brings a significant extension of catalyst life. Excessive elimination of these poisons may be disadvantageous. Lowering the levels of these catalyst poisons to more manageable concentrations is therefore preferred.
摘要翻译：含氮路易斯碱作为低聚反应中使用的分子筛催化剂的毒物。在与分子筛接触之前，它们在进料中的存在降低导致催化剂寿命的显着延长。过度消除这些毒素可能是不利的。因此优选将这些催化剂毒物的水平降低到更易于控制的浓度。

9. 发明申请

US20100282641A1 Process for Reducing Bromine Index of Hydrocarbon Feedstocks 有权
标题翻译：降低碳氢化合物原料溴指数的方法
公开(公告)号：US20100282641A1
公开(公告)日：2010-11-11
申请号：US12766372
申请日：2010-04-23
申请人： Stephen Harold Brown , Gary David Mohr , Michael Christopher Clark , Selma Lawrence
发明人： Stephen Harold Brown , Gary David Mohr , Michael Christopher Clark , Selma Lawrence
IPC分类号： C10G17/00
CPC分类号： C10G29/16 , C10G25/003 , C10G25/03 , C10G53/02 , C10G53/08 , C10G67/06 , C10G67/14 , C10G69/12 , C10G2300/4018 , C10G2300/4056 , C10G2300/701
摘要： A process for reducing the Bromine Index of a hydrocarbon feedstock, the process comprising the step of contacting the hydrocarbon feedstock with a catalyst at conversion conditions, wherein the catalyst includes at least one molecular sieve and at least one clay, and wherein said catalyst is sufficient to reduce more than 50% of the Bromine Index of a hydrocarbon feedstock.
摘要翻译：一种用于降低烃原料的溴指数的方法，该方法包括在转化条件下使烃原料与催化剂接触的步骤，其中催化剂包括至少一种分子筛和至少一种粘土，并且其中所述催化剂是足够的以减少烃原料的溴指数的50％以上。

10. 发明授权

US07683228B2 Production of high purity cumene from non-extracted feed and hydrocarbon composition useful therein 有权
标题翻译：从非提取的原料和可用于其中的烃组合物生产高纯度枯烯
公开(公告)号：US07683228B2
公开(公告)日：2010-03-23
申请号：US11705323
申请日：2007-02-12
申请人： Stephen Harold Brown
发明人： Stephen Harold Brown
IPC分类号： C07C15/085 , C07C2/66
CPC分类号： C07C15/085 , C07C2/66 , C07C2529/70
摘要： A process for producing an cumene product having a purity of at least 99.50 percent based on the weight of cumene present in the product by the propylation of the benzene present in non-extracted hydrocarbon composition feed, e.g., non-extracted reformate. The non-extracted hydrocarbon composition feed is substantially free of both C4− hydrocarbons and the C7+ aromatic hydrocarbons and contains benzene and benzene coboilers. The process is carried out in the liquid phase, in the presence of an acid-active catalyst containing MCM-22 family molecular sieve, and under specified conditions.
摘要翻译：基于存在于产物中的异丙苯的重量，通过非萃取的烃组合物进料例如未提取的重整油中存在的苯的丙基，生产纯度至少为99.50％的异丙基苯产品的方法。未提取的烃组合物进料基本上不含C 4烃和C 7+芳烃，并且含有苯和苯共沸混合物。该方法在液相中，在含有MCM-22族分子筛的酸活性催化剂存在下，并在规定的条件下进行。

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