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1. 发明授权

US4460514A Method for the preparation of poly (carbonyl fluoride) oligomers 失效
标题翻译：聚（碳酰氟）低聚物的制备方法
公开(公告)号：US4460514A
公开(公告)日：1984-07-17
申请号：US418951
申请日：1982-09-16
申请人： Keith B. Baucom , Burrell N. Hamon
发明人： Keith B. Baucom , Burrell N. Hamon
IPC分类号： C07C51/58
CPC分类号： C07C51/58
摘要： An improved method for synthesizing poly (carbonyl fluoride) oligomers by using bis(trifluoromethyl)trioxide as a reaction initiator in the photo-oxidation of F-3 methylbutene-1.
摘要翻译：在F-3甲基丁烯-1的光氧化中，通过使用双（三氟甲基）三氧化物作为反应引发剂来合成聚（碳酰氟）低聚物的改进方法。

2. 发明授权

US4374715A Method for the preparation of poly (carbonoyl fluoride) oligomers 失效
标题翻译：制备聚（碳酰氟）低聚物的方法
公开(公告)号：US4374715A
公开(公告)日：1983-02-22
申请号：US274697
申请日：1981-06-17
申请人： Keith B. Baucom , Burrell N. Hamon
发明人： Keith B. Baucom , Burrell N. Hamon
IPC分类号： C07C51/58 , B01J19/12
CPC分类号： C07C51/58 , Y10S204/912
摘要： An improved method for synthesizing poly (carbonyl fluoride) oligomers by using bis(trifluoromethyl)trioxide as a reaction initiator in the photo-oxidation of F-3 methylbutene-1.
摘要翻译：在F-3甲基丁烯-1的光氧化中，通过使用双（三氟甲基）三氧化物作为反应引发剂来合成聚（碳酰氟）低聚物的改进方法。

3. 发明授权

US3933831A Perfluorinated tertiary amines 失效
标题翻译：全氟化叔胺
公开(公告)号：US3933831A
公开(公告)日：1976-01-20
申请号：US413440
申请日：1973-11-07
申请人： Ralph J. De Pasquale , Keith B. Baucom
发明人： Ralph J. De Pasquale , Keith B. Baucom
IPC分类号： C07D211/18 , C07D211/88 , C07D251/06 , C07D251/34 , C07D211/00
CPC分类号： C07D251/34 , C07D211/18 , C07D211/88 , C07D251/06
摘要： Thermally and oxidatively stable perfluorinated tertiary amines of the formula: ##EQU1## ARE DISCLOSED, AS WELL AS THE PROCESS FOR MAKING THESE AND OTHER COMPOUNDS. The carbonyl group of imides or amides is reduced with SF.sub.4 using HF as the reaction solvent at a reaction temperature of 25.degree.-300.degree.C. Cyclic imides can be used as starting compounds, and tertiary amines containing unsaturated moieties can be produced.The perfluorinated tertiary amines have various uses in view of their high degree of thermal and oxidative stability, including uses as hydraulic fluids or transformer dielectric fluids.
摘要翻译：耐热和氧化稳定的下式为：R7fN-R1f的全氟化叔胺也被公开，作为制备这些和其它化合物的方法。在25〜300℃的反应温度下，使用HF作为反应溶剂，用SF4还原酰亚胺或酰胺的羰基。可以使用环状酰亚胺作为起始化合物，并且可以制备含有不饱和部分的叔胺。

4. 发明授权

US5177275A Reaction of substrate compounds with fluorine in an eductor 失效
标题翻译：基质化合物与荧光素在反应器中的反应
公开(公告)号：US5177275A
公开(公告)日：1993-01-05
申请号：US345588
申请日：1989-05-01
申请人： Keith B. Baucom , Adam C. Alty , Earl J. Kimmel
发明人： Keith B. Baucom , Adam C. Alty , Earl J. Kimmel
IPC分类号： C07B39/00 , C07C17/04 , C07C17/21 , C07C17/281 , C07C19/08
CPC分类号： C07C17/281 , C07B39/00 , C07C17/04 , C07C17/21
摘要： Substrate compounds are reacted by passing them through an eductor with fluorine gas optionally in the presence of a liquid medium and preferably in a loop reactor with cooling means thereby providing rapid but controlled reaction suitable for industrial scale production. Vinylidene chloride, for example, smoothly produces dichlorodifluoroethane and dichlorotrifluoroethane in good yield.

5. 发明授权

US4769495A Perfluoro-keto-ylids as precursors of polychloroketones, 1,2-diketones and quinoxalines 失效
标题翻译：全氟酮基作为多氯代酮，1,2-二酮和喹喔啉的前体
公开(公告)号：US4769495A
公开(公告)日：1988-09-06
申请号：US935955
申请日：1986-11-28
申请人： Keith B. Baucom
发明人： Keith B. Baucom
IPC分类号： C07C45/30 , C07C45/32 , C07C45/67 , C07C49/255 , C07C49/84 , C07C59/135 , C07C59/315 , C07D241/42 , C07D307/30 , C07F9/54 , C07C45/27
CPC分类号： C07C45/673 , C07C45/30 , C07C45/32 , C07C49/255 , C07C49/84 , C07C59/135 , C07C59/315 , C07D241/42 , C07D307/30 , C07F9/5456
摘要： The invention relates to a novel fluorinated pre-polymer and novel process steps in producing the same. The pre-polymers are quinoxaline materials derived by reaction of diketone linkage containing perfluoro-compounds with an aromatic diamine. The diketone is produced by a bis-ketone. The polychloroketone is produced by reacting a keto-ylid with a chlorinating agent, e.g., chlorine. The keto-ylid is produced by oxidatively dechlorinating a polychloroketone which may be a monoketone or reacting a phosphorane with an acid halide of a polyoxy-perfluoroalkylene oxide wherein the perfluoro-oxyalkylene group contains two or three carbon atoms, and there are present from two or twenty perfluoro-oxyalkylene units in the oligomer. The quinoxalines, the polychloroketones and the diketones hereof are novel products. Cross-linking may be effected with a free radical generator.
摘要翻译：本发明涉及一种新的氟化预聚物及其制备方法。预聚物是通过含有全氟化合物的二酮键与芳族二胺反应得到的喹喔啉物质。二酮由双酮制成。多氯代酮通过酮基 - 里地与氯化剂例如氯反应来制备。通过氧化脱氯多氯代酮（其可以是单酮或使磷烷与聚氧全氟环氧烷的酰卤反应，其中全氟氧化烯基含有两个或三个碳原子）而产生酮基，其存在于两个或多个低聚物中有二十个全氟氧化烯单元。喹喔啉，多氯酮和二酮是新产品。交联可以用自由基发生剂进行。

6. 发明授权

US4546184A Perfluoro-keto-ylids as precursors of polychloroketones, 1,2-diketones and quinoxalines 失效
公开(公告)号：US4546184A
公开(公告)日：1985-10-08
申请号：US497006
申请日：1983-05-23
申请人： Keith B. Baucom
发明人： Keith B. Baucom
IPC分类号： C07C45/30 , C07C45/67 , C07C49/255 , C07C49/84 , C07C59/135 , C07C59/315 , C07D241/42 , C07D307/30 , C07F9/54 , C07D403/04
CPC分类号： C07C49/255 , C07C45/30 , C07C45/673 , C07C49/84 , C07C59/135 , C07C59/315 , C07D241/42 , C07D307/30 , C07F9/5456
摘要： The invention relates to a novel fluorinated pre-polymer and novel process steps in producing the same. The pre-polymers are quinoxaline materials derived by reaction of diketone linkage containing perfluoro-compounds with an aromatic diamine. The diketone is produced by oxidatively dechlorinating a polychloroketone which may be a monoketone or a bis-ketone. The polychloroketone is produced by reacting a keto-ylid with a chlorinating agent, e.g., chlorine. The keto-ylid is produced by reacting a phosphorane with an acid halide of a polyoxy-perfluoroalkylene oxide wherein the perfluoro-oxyalkylene group contains two or three carbon atoms, and there are present from two to twenty perfluoro-oxyalkylene units in the oligomer. The quinoxalines, the polychloroketones and the diketones hereof are novel products. Cross-linking may be effected with a free radical generator.

7. 发明授权

US5334788A Reaction of substrate compounds with fluorine in an eductor 失效
标题翻译：底物化合物与氟在喷射器中的反应
公开(公告)号：US5334788A
公开(公告)日：1994-08-02
申请号：US876978
申请日：1992-05-01
申请人： Keith B. Baucom , Adam C. Alty , Earl J. Kimmel
发明人： Keith B. Baucom , Adam C. Alty , Earl J. Kimmel
IPC分类号： C07B39/00 , C07C17/04 , C07C17/21 , C07C17/281 , C07C19/08 , C07C17/20 , C07C22/00
CPC分类号： C07C17/281 , C07B39/00 , C07C17/04 , C07C17/21
摘要： Substrate compounds are reacted by passing them through an eductor with fluorine gas optionally in the presence of a liquid medium and preferably in a loop reactor with cooling means thereby providing rapid but controlled reaction suitable for industrial scale production. Vinylidene chloride, for example, smoothly produces dichlorodifluoroethane and dichlorotrifluoroethane in good yield.
摘要翻译：底物化合物通过使其通过具有氟气的喷射器，任选地在液体介质存在下，优选在具有冷却装置的环管反应器中进行反应，由此提供适用于工业规模生产的快速但受控制的反应。例如，偏二氯乙烯以良好的产率平稳地产生二氯二氟乙烷和二氯三氟乙烷。

8. 发明授权

US4633020A Perfluoro-keto-ylids as precursors of polychloroketones, 1,2-diketones and quinoxalines 失效
标题翻译：全氟酮基作为多氯代酮，1,2-二酮和喹喔啉的前体
公开(公告)号：US4633020A
公开(公告)日：1986-12-30
申请号：US783178
申请日：1985-10-02
申请人： Keith B. Baucom
发明人： Keith B. Baucom
IPC分类号： C07C45/30 , C07C45/32 , C07C45/67 , C07C49/255 , C07C49/84 , C07C59/135 , C07C59/315 , C07D241/42 , C07D307/30 , C07F9/54 , C07F9/50
CPC分类号： C07C59/135 , C07C45/30 , C07C45/32 , C07C45/673 , C07C49/255 , C07C49/84 , C07C59/315 , C07D241/42 , C07D307/30 , C07F9/5456
摘要： The invention relates to a novel fluorinated pre-polymer and novel process steps in producing the same. The pre-polymers are quinoxaline materials derived by reaction of diketone linkage containing perfluoro-compounds with an aromatic diamine. The diketone is produced by oxidatively dechlorinating a polychloroketone which may be a monoketone or a bis-ketone. The polychloroketone is produced by reacting a keto-ylid with a chlorinating agent, e.g., chlorine. The keto-ylid is produced by reacting a phosphorane with an acid halide of a polyoxy-perfluoroalkylene oxide wherein the perfluoro-oxyalkylene group contains two or three carbon atoms, and there are present from two to twenty perfluoro-oxyalkylene units in the oligomer. The quinoxalines, the polychloroketones and the diketones hereof are novel products. Cross-linking may be effected with a free radical generator.
摘要翻译：本发明涉及一种新的氟化预聚物及其制备方法。预聚物是通过含有全氟化合物的二酮键与芳族二胺反应得到的喹喔啉物质。二酮通过氧化脱氯可以是单酮或双酮的多氯代酮来制备。多氯代酮通过酮基 - 里地与氯化剂例如氯反应来制备。通过使正膦与聚氧全氟环氧烷的酰卤反应生成酮基，其中全氟氧化烯基含有2或3个碳原子，低聚物中存在2至20个全氟氧化烯单元。喹喔啉，多氯酮和二酮是新产品。交联可以用自由基发生剂进行。

9. 发明授权

US4356070A Method for synthesizing poly(carbonyl fluoride) oligomers 失效
标题翻译：聚（碳酰氟）低聚物的合成方法
公开(公告)号：US4356070A
公开(公告)日：1982-10-26
申请号：US274574
申请日：1981-06-17
申请人： Keith B. Baucom
发明人： Keith B. Baucom
IPC分类号： B01J19/12 , C07C51/58 , C07D251/24
CPC分类号： C07D251/24 , B01J19/123 , C07C51/58
摘要： F-3-Methylbutene-1 has been oxidized using oxygen and ultraviolet radiation to form poly(carbonyl fluoride) oligomers. The formation of fluoroformate terminated material is insignificant. This is in sharp contrast to the products derived from the prior art oxidation of F-propene (HFP) in which up to 60% fluoroformate terminated material was produced. F-Ethylene (TFE) can be added to the F-3-methylbutene-1 reaction gas stream without adversely affecting the product composition. The fluoride oligomers, after addition of one unit of hexafluoropropylene oxide, can be converted to s-triazines which have excellent properties as hydrualic fluids.
摘要翻译：使用氧和紫外线辐射使F-3-甲基丁烯-1氧化形成聚（碳酰氟）低聚物。氟甲酸酯封端材料的形成是微不足道的。这与来自现有技术的F-丙烯（HFP）的氧化产物产生鲜明的对比，其中产生高达60％的氟甲酸酯封端的材料。可以将F-乙烯（TFE）加入到F-3-甲基丁烯-1反应气流中，而不会不利地影响产物组成。加入一单位的六氟环氧丙烷之后，氟化物低聚物可以转化为具有优异性能的水溶液的s-三嗪。

10. 发明授权

US4241223A F-Phenylalkylene oxide diacetylenes 失效
标题翻译： F-苯基环氧烷二乙炔
公开(公告)号：US4241223A
公开(公告)日：1980-12-23
申请号：US70473
申请日：1979-08-28
申请人： Keith B. Baucom
发明人： Keith B. Baucom
IPC分类号： C07C41/30 , C07C43/176 , C07C59/315 , C07C43/166
CPC分类号： C07C59/315 , C07C41/30 , C07C43/176
摘要： F-phenylalkylene oxide acetylenes having the formula C.sub.6 F.sub.5 C.tbd.C(CF.sub.2 OCF.sub.2).sub.n C.tbd.CC.sub.6 F.sub.5, where n ranges from 3 to 8, inclusive. The diacetylenes are useful as monomers for preparing fluorinated polyether elastomers.
摘要翻译：具有式C 6 F 5 C 3 CF（CF 2 OCF 2）n C 3BOND CC 6 F 5的F-苯基亚烷基氧基炔烃，其中n为3至8，包括3和8。二乙炔可用作制备氟化聚醚弹性体的单体。

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