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    • 4. 发明授权
    • Method of selectively reforming an inner part of an inorganic body
    • 选择性地重整无机体内部的方法
    • US06729161B1
    • 2004-05-04
    • US09600195
    • 2000-07-12
    • Kiyotaka MiuraJianrong QiuYuki KondoKazuyuki Hirao
    • Kiyotaka MiuraJianrong QiuYuki KondoKazuyuki Hirao
    • B01J1912
    • C03C23/0025B01J19/121
    • An inorganic body containing rare earth and/or transition metal ions that has been irradiated with a pulsed laser beam in the manner such that a focal point of the pulsed laser beam is adjusted to an inner part of the inorganic body is disclosed. The inorganic body may be a glass or crystal containing one or more of oxide, halide and chalcogenide. The rare earth ion may be one or more of Ce, Nd, Pr, Sm, Eu, Tb, Dy, Tm, Tb. The transition metal ion may be one or more of Ti, Mn, Cr, V, Fe, Cu, Mo and Ru. When the focal point is relatively shifted with respect to the inorganic body, an ionic valence-changed domain is formed with a predetermined pattern at the inner part of the inorganic body. The pulsed laser beam preferably has a pulse width under a picosecond. The ionic valence change occurs at the focal point and its vicinity, but the rare earth or transition metal ion keeps its original valence at all other parts, so as to form a reformed domain with a predetermined pattern in the inorganic body. Since optical properties are selectively changed at the reformed domain, the processed inorganic body is useful as a functional device such as a memory device or a light-emitting device using the differentiated optical properties.
    • 公开了一种含有以脉冲激光束的焦点调节为无机体的内部的脉冲激光束照射的稀土元素和/或过渡金属离子的无机体。 无机体可以是含有氧化物,卤化物和硫族化物中的一种或多种的玻璃或晶体。 稀土离子可以是Ce,Nd,Pr,Sm,Eu,Tb,Dy,Tm,Tb中的一种或多种。 过渡金属离子可以是Ti,Mn,Cr,V,Fe,Cu,Mo和Ru中的一种或多种。 当焦点相对于无机体相对移动时,在无机体的内部形成具有预定图案的离子价改变域。 脉冲激光束优选具有皮秒之下的脉冲宽度。 离子价态变化发生在焦点及其附近,但是稀土或过渡金属离子在其他部分保持其初始价态,从而在无机体中形成具有预定图案的重整畴。 由于光学特性在改性区域选择性地变化,所以经处理的无机体可用作诸如使用差分光学性质的存储器件或发光器件的功能器件。