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    • 4. 发明授权
    • Negative electrode for non-aqueous electrolyte secondary battery, method for producing the same, and non-aqueous electrolyte secondary battery
    • 非水电解质二次电池用负极及其制造方法以及非水电解质二次电池
    • US08389156B2
    • 2013-03-05
    • US12303854
    • 2007-08-22
    • Katsumi KashiwagiKazuyoshi HondaMasaki HasegawaMasaya UgajiYasutaka KogetsuShuji Ito
    • Katsumi KashiwagiKazuyoshi HondaMasaki HasegawaMasaya UgajiYasutaka KogetsuShuji Ito
    • H01M4/02
    • H01M4/13H01M4/386H01M4/40H01M4/70H01M10/0525H01M2004/025H01M2004/027
    • This invention provides a negative electrode and a non-aqueous electrolyte secondary battery including the negative electrode. The negative electrode includes a Li-absorbing element as a negative electrode active material, is free from deformation, separation of the negative electrode active material layer from the negative electrode current collector, and deposition of lithium on the negative electrode current collector, and is excellent in cycle characteristic, large-current discharge characteristic, and low-temperature discharge characteristic.The negative electrode of this invention includes: a current collector having depressions and protrusions on a surface in the thickness direction thereof; and a negative electrode active material layer that includes a plurality of columns containing a negative electrode active material that absorbs and releases lithium ions, the columns being grown outwardly from the surface of the current collector. The negative electrode of this invention is characterized in that the columns are grown at an inclination angle relative to the direction perpendicular to the surface of the current collector, and that the inclination angle of the columns changes reversibly depending on absorption and release of lithium ions by the negative electrode active material.
    • 本发明提供一种负极和含有负极的非水电解质二次电池。 负极包括作为负极活性物质的Li吸收元件,没有变形,负极活性物质层与负极集电体分离,并且在负极集电体上沉积锂,并且优异 循环特性,大电流放电特性和低温放电特性。 本发明的负极包括:在其厚度方向的表面上具有凹陷和突起的集电器; 以及包含吸收和释放锂离子的负极活性物质的多个列的负极活性物质层,所述列从集电体的表面向外生长。 本发明的负极的特征在于,柱相对于与集电体的表面垂直的方向以倾斜角度生长,并且柱的倾斜角随着锂离子的吸收和释放而可逆地变化 负极活性物质。
    • 9. 发明授权
    • Negative electrode active material and negative electrode using the same and lithium ion secondary battery
    • 负极活性物质和负极使用相同的锂离子二次电池
    • US08071237B2
    • 2011-12-06
    • US12095879
    • 2006-11-24
    • Kazuya IwamotoShuji Ito
    • Kazuya IwamotoShuji Ito
    • H01M4/13H01M4/48H01M10/02C01B33/113B05D5/12C23C16/00
    • H01M4/131H01M4/0423H01M4/1391H01M4/485H01M10/0525
    • In a negative electrode active material for a lithium ion secondary battery including a silicon oxide capable of absorbing and desorbing lithium ions, a silicon oxide having structural units each in the form of a tetrahedron in which a silicon atom is located at its center and silicon or oxygen atoms are located at its four vertices is used. The structural units are arranged randomly to form an amorphous structure. In the case that the number of oxygen atoms located at the four vertices in the structural units is represented by n (n=0, 1, 2, 3 or 4) and the structural units are represented by Si(n), the number of the structural units NSi(n) in the silicon oxide satisfies the following relations (1) to (3). [ Formula ⁢ ⁢ 1 ] NSi ⁡ ( 0 ) ∑ NSi ⁡ ( n ) ≥ 0.1 ( 1 ) Nsi ⁡ ( 4 ) ∑ NSi ⁡ ( n ) ≤ 0.1 ( 2 ) Nsi ⁡ ( 1 ) + NSi ⁡ ( 2 ) + Nsi ⁡ ( 3 ) ≠ 0 ( 3 )
    • 在包含能够吸收和解吸锂离子的氧化硅的锂离子二次电池用负极活性物质中,具有硅原子位于其中心的四面体形状的结构单元的氧化硅和硅 氧原子位于其四个顶点。 结构单元随机排列以形成非晶结构。 在结构单元中位于四个顶点的氧原子数由n(n = 0,1,2,3或4)表示,结构单元由Si(n)表示的情况下, 氧化硅中的结构单元NSi(n)满足关系式(1)〜(3)。 [公式1] NSi⁡(0)ΣNSi⁡(n)≥0.1(1)Nsi⁡(4)ΣNSi⁡(n)≤0.1(2)Nsi⁡(1)+ NSi⁡(2)+ Nsi⁡(3)≠0(3)