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1. 发明授权

US08779190B2 Process for producing sulfur-containing amino acid or salt thereof 有权
标题翻译：含硫氨基酸或其盐的制造方法
公开(公告)号：US08779190B2
公开(公告)日：2014-07-15
申请号：US13636238
申请日：2011-03-24
申请人： Kazuyasu Tani , Taro Hirose , Koji Hagiya
发明人： Kazuyasu Tani , Taro Hirose , Koji Hagiya
IPC分类号： C07C319/20
CPC分类号： C07C319/20 , C07C323/58
摘要： According to the present invention, a new process for producing a sulfur-containing amino acid without using of hydrogen cyanide or sodium azide which requires careful handling as a raw material can be provided. The present invention relates to a process for producing a sulfur-containing amino acid represented by the following formula (1) or a salt thereof: wherein R1 is an alkyl group having 1 to 12 carbon atoms and optionally having substituents or a cycloalkyl group having 3 to 12 carbon atoms and optionally having substituents, and n is an integral number of from 1 to 4, comprising a step of reacting a sulfur-containing 2-ketocarboxylic acid represented by the formula (2) or a salt thereof: wherein R1 and n mean the same as defined above, with ammonia and hydrogen in the presence of a transition metal catalyst.
摘要翻译：根据本发明，可以提供一种不使用需要小心处理作为原料的氰化氢或叠氮化钠来生产含硫氨基酸的新方法。本发明涉及一种由下式（1）表示的含硫氨基酸或其盐的制备方法：其中R1是具有1至12个碳原子并且任选具有取代基的烷基或具有3个至12个碳原子，并且任选地具有取代基，n为1至4的整数，包括使式（2）表示的含硫的2-酮羧酸或其盐：其中R1和n 表示与上述相同，在过渡金属催化剂存在下用氨和氢气。

2. 发明申请

US20130137897A1 PROCESS FOR PREPARING SULFUR-CONTAINING 2-KETOCARBOXYLATE COMPOUND 审中-公开
标题翻译：制备含硫酸2-羧基甲酸酯化合物的方法
公开(公告)号：US20130137897A1
公开(公告)日：2013-05-30
申请号：US13816123
申请日：2011-08-26
申请人： Kazuyasu Tani , Taro Hirose , Koji Hagiya
发明人： Kazuyasu Tani , Taro Hirose , Koji Hagiya
IPC分类号： C07C319/20
CPC分类号： C07C319/20 , B01J31/2243 , B01J2231/70 , B01J2531/0241 , B01J2531/0252 , B01J2531/56 , C07C323/52
摘要： The present invention provides a novel process for preparing a sulfur-containing 2-ketocarboxylate compound without using any enzyme. The process comprises a step of oxidizing a hydroxyacetate compound having an optionally-substituted sulfur-containing hydrocarbon group at 2-position in the presence of a vanadium compound. Preferably, the step is carried out further in the presence of oxygen, and more preferably, in the presence of an organic solvent.
摘要翻译：本发明提供了一种不使用任何酶制备含硫的2-酮羧酸盐化合物的新方法。该方法包括在钒化合物的存在下，在2-位氧化具有任选取代的含硫烃基的羟基乙酸酯化合物的步骤。优选地，该步骤在氧的存在下进一步进行，更优选在有机溶剂的存在下进行。

3. 发明申请

US20130137896A1 PROCESS FOR PREPARING SULFUR-CONTAINING 2-KETOCARBOXYLATE COMPOUND 审中-公开
标题翻译：制备含硫酸2-羧基甲酸酯化合物的方法
公开(公告)号：US20130137896A1
公开(公告)日：2013-05-30
申请号：US13814988
申请日：2011-08-26
申请人： Kazuyasu Tani , Taro Hirose , Koji Hagiya
发明人： Kazuyasu Tani , Taro Hirose , Koji Hagiya
IPC分类号： C07C319/20
CPC分类号： C07C319/20 , B01J23/462 , B01J37/0201 , B01J37/03 , B01J37/035 , B01J37/16 , C07C323/52
摘要： The present invention provides a novel process for preparing a sulfur-containing 2-ketocarboxylate compound without using any enzyme. The process comprises a step of oxidizing a hydroxyacetate compound having an optionally-substituted sulfur-containing hydrocarbon group at 2-position in the presence of ruthenium metal or a ruthenium compound. Preferably, the step is carried out under pressurized condition, and more preferably, in the presence of at least one typical metal selected from the group consisting of an alkali metal compound and an alkaline earth metal compound.
摘要翻译：本发明提供了一种不使用任何酶制备含硫的2-酮羧酸盐化合物的新方法。该方法包括在钌金属或钌化合物的存在下，在2-位氧化具有任选取代的含硫烃基的羟基乙酸酯化合物的步骤。优选地，该步骤在加压条件下进行，更优选在至少一种选自碱金属化合物和碱土金属化合物的典型金属的存在下进行。

4. 发明申请

US20130012737A1 PROCESS FOR PRODUCING SULFUR-CONTAINING AMINO ACID OR SALT THEREOF 有权
标题翻译：生产含有氨基酸或其盐的硫酸盐的方法
公开(公告)号：US20130012737A1
公开(公告)日：2013-01-10
申请号：US13636238
申请日：2011-03-24
申请人： Kazuyasu Tani , Taro Hirose , Koji Hagiya
发明人： Kazuyasu Tani , Taro Hirose , Koji Hagiya
IPC分类号： C07C319/20
CPC分类号： C07C319/20 , C07C323/58
摘要： According to the present invention, a new process for producing a sulfur-containing amino acid without using of hydrogen cyanide or sodium azide which requires careful handling as a raw material can be provided.The present invention relates to a process for producing a sulfur-containing amino acid represented by the following formula (1) or a salt thereof: wherein R1 is an alkyl group having 1 to 12 carbon atoms and optionally having substituents or a cycloalkyl group having 3 to 12 carbon atoms and optionally having substituents, and n is an integral number of from 1 to 4, comprising a step of reacting a sulfur-containing 2-ketocarboxylic acid represented by the formula (2) or a salt thereof: wherein R1 and n mean the same as defined above, with ammonia and hydrogen in the presence of a transition metal catalyst.
摘要翻译：根据本发明，可以提供一种不使用需要小心处理作为原料的氰化氢或叠氮化钠来生产含硫氨基酸的新方法。本发明涉及一种由下式（1）表示的含硫氨基酸或其盐的制备方法：其中R1是具有1至12个碳原子并且任选具有取代基的烷基或具有3个至12个碳原子，并且任选地具有取代基，n为1至4的整数，包括使式（2）表示的含硫的2-酮羧酸或其盐：其中R1和n 表示与上述相同，在过渡金属催化剂存在下用氨和氢气。

5. 发明授权

US5556867A Oxazoline derivative, its production and its use 失效
标题翻译：恶唑啉衍生物，其生产及其用途
公开(公告)号：US5556867A
公开(公告)日：1996-09-17
申请号：US341215
申请日：1994-12-05
申请人： Taro Hirose , Hirosi Kisida , Shigeru Saito , Hiroaki Fujimoto
发明人： Taro Hirose , Hirosi Kisida , Shigeru Saito , Hiroaki Fujimoto
IPC分类号： A01N43/76 , C07D263/14 , C07D413/12
CPC分类号： C07D413/10 , A01N43/76 , C07D263/14 , C07D413/12
摘要： An oxazoline derivative having the formula: ##STR1## which is useful for control of insects, mites and/or ticks.
摘要翻译：具有下式的恶唑啉衍生物：其可用于防治昆虫，螨虫和/或蜱。

6. 发明申请

US20140078655A1 WATERPROOF STRUCTURE, ELECTRONIC DEVICE, AND WATERPROOFING METHOD 有权
标题翻译：防水结构，电子设备和防水方法
公开(公告)号：US20140078655A1
公开(公告)日：2014-03-20
申请号：US14114871
申请日：2012-04-25
申请人： Taro Hirose
发明人： Taro Hirose
IPC分类号： H05K5/06
CPC分类号： H05K5/061 , H01M2/1066 , H01M2220/30 , H05K5/06
摘要： A waterproof structure includes a package having an opening; a lid part which is slidable between a first position that makes the opening be open and a second position that is located closer to the innermost of the opening than the first position and closes the opening; and an elastic member provided on a surface of the lid part, said surface facing an inner side of the opening, in a manner such that the elastic member is incapable of contacting the package when the lid part is positioned at the first position, and that the elastic member is pressed into the opening when the lid part is positioned at the second position. It is possible to prevent insufficient pressing of the elastic member into the opening, and thereby the relevant waterproof performance can be improved
摘要翻译：防水结构包括具有开口的包装; 盖部，其在使开口打开的第一位置与位于比第一位置更靠近开口最内侧的第二位置之间滑动并封闭开口; 以及弹性构件，其设置在所述盖部的表面上，所述表面面向所述开口的内侧，使得当所述盖部位于所述第一位置时所述弹性构件不能接触所述包装，并且所述弹性构件当盖部分位于第二位置时，弹性构件被压入开口中。可以防止弹性部件压入开口部的压力不足，能够提高防水性能

7. 发明申请

US20120029772A1 STEERING CONTROL APPARATUS 有权
标题翻译：转向控制装置
公开(公告)号：US20120029772A1
公开(公告)日：2012-02-02
申请号：US13001928
申请日：2009-08-25
申请人： Yoshitaka Fujita , Taro Hirose , Theerawat Limpibunterng
发明人： Yoshitaka Fujita , Taro Hirose , Theerawat Limpibunterng
IPC分类号： B62D6/00
CPC分类号： B62D6/002 , B62D7/159
摘要： A steering control apparatus (100) controls a steering mechanism to limit a behavior of a vehicle in the vehicle (10) equipped with the steering mechanism (200) which can independently steer front wheels and rear wheels. The steering control apparatus is provided with: a controlling device for controlling the steering mechanism such that a rudder angle of the front wheels and a rudder angle of the rear wheels are reverse-phased and such that a rudder angle speed of the front wheels is higher than a rudder angle speed of the rear wheels.
摘要翻译：转向控制装置（100）控制转向机构以限制配备有能够独立地转向前轮和后轮的转向机构（200）的车辆（10）中的车辆的行为。转向控制装置设置有：用于控制转向机构的控制装置，使得前轮的舵角和后轮的舵角相反，并且前轮的舵角速度更高比后轮的方向舵角速度快。

8. 发明授权

US06339176B2 Method for producing 4-methoxymethyl-2,3,5,6-tetrafluorobenzenemethanol 有权
标题翻译： 4-甲氧基甲基-2,3,5,6-四氟苯甲醇的制备方法
公开(公告)号：US06339176B2
公开(公告)日：2002-01-15
申请号：US09725472
申请日：2000-11-30
申请人： Taro Hirose , Tatsuya Mori
发明人： Taro Hirose , Tatsuya Mori
IPC分类号： C07C4101
CPC分类号： C07C41/16 , C07C43/1786
摘要： It provides a production method of 4-methoxymethyl-2,3,5,6-tetrafluorobenzenemethanol to allow 2,3,5,6-tetrafluoro-1,4-benzenedimethanol to react with an inorganic base in water, and then add dimethyl sulfate and a water-immiscible organic solvent selected from the group consisting of hydrocarbons and ethers to the reaction mixture, or to allow 2,3,5,6-tetrafluoro-1,4-benzenedimethanol to react with an inorganic base in water and said water-immiscible organic solvent, and then to add dimethyl sulfate to the reaction mixture.
摘要翻译：提供4-甲氧基甲基-2,3,5,6-四氟苯甲醇的制造方法，使2,3,5,6-四氟-1,4-苯二甲醇与水中的无机碱反应，然后加入硫酸二甲酯和与反应混合物中选自烃和醚的水不混溶的有机溶剂，或使2,3,5,6-四氟-1,4-苯二甲醇与水中的无机碱反应，所述水可混溶的有机溶剂，然后向反应混合物中加入硫酸二甲酯。

9. 发明授权

US09321480B2 Vehicle steering control apparatus 有权
标题翻译：车辆转向控制装置
公开(公告)号：US09321480B2
公开(公告)日：2016-04-26
申请号：US13811697
申请日：2011-06-01
申请人： Yoshiaki Suzuki , Theerawat Limpibunterng , Toru Takashima , Takahiro Kojo , Taro Hirose , Yoshiaki Tsuchiya , Masahiro Miyata , Susumu Fujii
发明人： Yoshiaki Suzuki , Theerawat Limpibunterng , Toru Takashima , Takahiro Kojo , Taro Hirose , Yoshiaki Tsuchiya , Masahiro Miyata , Susumu Fujii
IPC分类号： B62D6/00 , B62D5/00 , B62D5/04 , B62D7/15
CPC分类号： B62D6/00 , B62D5/008 , B62D5/0481 , B62D7/159
摘要： A vehicle steering control apparatus (100) in a vehicle (10), which is provided with: a steering system including at least a rudder angle varying device (400, 700) capable of changing a relation between a steering angle, which is a rotation angle of a steering wheel (12), and a rudder angle of steered wheels and a steering torque assisting device (500) capable of assisting a driver steering torque; and a power supply source (800) for supplying electric power to the steering system, is provided with: a limiting device for limiting electric current consumption of the steering torque assisting device if a consumption current value of the steering system is greater than a maximum allowable current value in a case where supply capacity of supplying an electric current in the power supply source is reduced with respect to a reference; and a controlling device for matching a neutral position of the steering wheel with a neutral position of the steered wheels in a situation in which the electric current consumption of the steering torque assisting device is limited.
摘要翻译：一种车辆（10）中的车辆转向控制装置（100），其设置有：至少包括舵角变化装置（400,700）的转向系统，其能够改变作为旋转的转向角方向盘（12）的角度以及转向轮的方向舵角度和能够辅助驾驶员转向转矩的转向转矩辅助装置（500）; 以及用于向转向系统供电的供电源（800）设置有限制装置，用于限制转向系统的消耗电流值大于最大允许值的转向助力装置的电流消耗在供电源供给电力相对于基准的情况下减小电流值的电流值; 以及用于在转向转矩辅助装置的电流消耗受到限制的情况下将方向盘的空档位置与转向轮的空档位置相匹配的控制装置。

10. 发明授权

US08594888B2 Steering control apparatus 有权
标题翻译：转向控制装置
公开(公告)号：US08594888B2
公开(公告)日：2013-11-26
申请号：US13001928
申请日：2009-08-25
申请人： Yoshitaka Fujita , Taro Hirose , Theerawat Limpibunterng
发明人： Yoshitaka Fujita , Taro Hirose , Theerawat Limpibunterng
IPC分类号： G06F7/00
CPC分类号： B62D6/002 , B62D7/159
摘要： A steering control apparatus (100) controls a steering mechanism to limit a behavior of a vehicle in the vehicle (10) equipped with the steering mechanism (200) which can independently steer front wheels and rear wheels. The steering control apparatus is provided with: a controlling device for controlling the steering mechanism such that a rudder angle of the front wheels and a rudder angle of the rear wheels are reverse-phased and such that a rudder angle speed of the front wheels is higher than a rudder angle speed of the rear wheels.
摘要翻译：转向控制装置（100）控制转向机构以限制配备有能够独立地转向前轮和后轮的转向机构（200）的车辆（10）中的车辆的行为。转向控制装置设置有：用于控制转向机构的控制装置，使得前轮的舵角和后轮的舵角相反，并且前轮的舵角速度更高比后轮的方向舵角速度快。

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