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    • 4. 发明授权
    • Alkenyl compound, liquid crystal composition, and liquid crystal display device
    • 烯基化合物,液晶组合物和液晶显示装置
    • US06231934B1
    • 2001-05-15
    • US09155348
    • 1998-09-28
    • Tomoyuki KondoShuichi MatsuiKazutoshi MiyazawaYasuko SekiguchiEtsuo Nakagawa
    • Tomoyuki KondoShuichi MatsuiKazutoshi MiyazawaYasuko SekiguchiEtsuo Nakagawa
    • C09K1934
    • C07C43/225C07C43/176C07C43/188C07C69/753C07C69/76C09K19/04C09K19/16C09K19/3001C09K19/3048C09K19/3059C09K19/3402C09K19/42C09K19/44C09K19/46C09K2019/0448C09K2019/0451C09K2019/3422Y10T428/10
    • The liquid crystalline compound is expressed by the general formula (1) Ra-A1-Z1-A2-Z2-A3-Z3-A4-Rb   (1) wherein Ra represents an alkenyl group having 2 to 20 carbon atoms or an alkyl group having 1 to 20 carbon atoms any methylene group (—CH2—) in the alkenylene or alkyl group may be replaced by —O—, —S—, —CO—, —CH═CH—, or —C≡C—, but in no case —O— and/or —S— continues, and any hydrogen atom in Ra may be replaced by a halogen atom; Rb represents Ra, a halogen atom, or cyano group provided that at least one of Ra and Rb represents a group having double bond; A1, A2, A3, and A4 independently represent trans-1,4-cyclohexylene group, 1,4-phenylene group any hydrogen atom on the ring may be replaced by fluorine atom or cyano group, cyclohexenediyl group, pyridine-2,5-diyl group, pyrimidine-2,5-diyl group, or 1,3-dioxane-2,5-diyl group; and Z1, Z2, and Z3 independently represent an alkenylene group having 2 to 4 carbon atoms, —(CH2)2—, —COO—, —OCO—, —C≡C—, —CH2O—, —OCH2—, or single bond any hydrogen atom in the groups may be replaced by a halogen atom provided that at least one of Z1, Z2, and Z3 represents an alkenylene group having 2 to 4 carbon atoms.
    • 液晶化合物由通式(1)表示,其中R a表示具有2至20个碳原子的烯基或具有1至20个碳原子的烷基,亚烯基或烷基中的任何亚甲基(-CH 2 - )可以 被-O - , - S - , - CO - , - CH = CH-或-C = C-取代,但不限于-O-和/或-S-,Ra中的任何氢原子 被卤素原子取代; Rb表示Ra,卤素原子或氰基,Ra和Rb中的至少一个表示具有双键的基团; A1,A2,A3和A4独立地表示反式-1,4-亚环己基,1,4-亚苯基,环上的任何氢原子可以被氟原子或氰基取代,环己烯二基,吡啶-2,5- 二基,嘧啶-2,5-二基或1,3-二恶烷-2,5-二基; 且Z 1,Z 2和Z 3独立地表示具有2至4个碳原子的亚烯基, - (CH 2)2 - , - COO - , - OCO - , - C = C - , - CH 2 O - , - OCH 2 - 键中的任何氢原子可以被卤素原子代替,条件是Z 1,Z 2和Z 3中的至少一个表示具有2至4个碳原子的亚烯基。
    • 5. 发明授权
    • Vinylene compounds and liquid-crystal composition
    • 维尼尼亚化合物和液晶组成
    • US06337034B1
    • 2002-01-08
    • US09125685
    • 1998-08-24
    • Tomoyuki KondoShuichi MatsuiKazutoshi MiyazawaYasuko SekiguchiEtsuo Nakagawa
    • Tomoyuki KondoShuichi MatsuiKazutoshi MiyazawaYasuko SekiguchiEtsuo Nakagawa
    • C09K1930
    • C07D213/79C07C69/75C07C69/753C07C69/76C07D213/80C07D239/28C07D239/34C07D319/06C09K19/04C09K19/3001C09K19/3068
    • Liquid crystalline compounds which have a wide temperature range of liquid crystal phase, low viscosity, and improved threshold voltage; liquid crystal compositions; and liquid crystal display devices comprising the composition can be provided; and the liquid crystalline compounds are expressed by the general formula (1) Ra—A1—Z1—A2—Z2—A3—(Z3—A4)m—Rb  (1) wherein Ra represents an alkyl group having 1 to 20 carbon atoms one or more —CH2— in which alkyl group may be replaced by —O— or the like, and one or more hydrogen atoms in which alkyl group may be replaced by a halogen atom; Rb represents Ra, a halogen atom, or cyano group; A1, A2, A3, and A4 independently represent a divalent ring group; Z1, Z2, and Z3 independently represent an alkenylene group having 2 to 4 carbon atoms, —COO—, a covalent bond, or the like provided that at least one of Z1 to Z3 represents an alkenylene group having 2 to 4 carbon atoms, and at least one of Z1 to Z3 represents —COO— or —OCO—; and m is 0 or 1.
    • 具有液晶相温度范围宽,粘度低,阈值电压提高的液晶化合物; 液晶组合物; 并且可以提供包含该组合物的液晶显示装置; 并且液晶化合物由通式(1)表示,其中R a表示具有1至20个碳原子的烷基,一个或多个-CH 2 - ,其中烷基可以被-O-取代,以及一个或 更多的氢原子,其中烷基可被卤素原子取代; Rb表示Ra,卤素原子或氰基; A1,A2,A3和A4独立地表示二价环基团; Z 1,Z 2和Z 3独立地表示具有2〜4个碳原子的亚烯基,-COO-,共价键等,条件是Z1至Z3中的至少一个表示具有2至4个碳原子的亚烯基, Z1至Z3中的至少一个表示-COO-或-OCO-; m为0或1。