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1. 发明授权

US06787617B1 Process for producing olefin living polymer 失效
标题翻译：生产烯烃活性聚合物的方法
公开(公告)号：US06787617B1
公开(公告)日：2004-09-07
申请号：US10009094
申请日：2001-11-08
申请人： Kazuo Soga , Takeshi Shiono , Michihiko Asai , Yasuzo Suzuki , Akira Miyazawa , Kenji Tsuchihara , Masahide Murata , Hiroyuki Ozaki , Masanao Kawabe , Toshio Kase , Jizhu Jin , Hideaki Hagiwara , Yoshifumi Fukui
发明人： Kazuo Soga , Takeshi Shiono , Michihiko Asai , Yasuzo Suzuki , Akira Miyazawa , Kenji Tsuchihara , Masahide Murata , Hiroyuki Ozaki , Masanao Kawabe , Toshio Kase , Jizhu Jin , Hideaki Hagiwara , Yoshifumi Fukui
IPC分类号： C08F452
CPC分类号： C08F297/08 , C08F4/65904 , C08F4/6592 , C08F4/65922 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , Y10S526/943 , C08F4/65908 , C08F2500/03 , C08F210/14
摘要： A process for preparing olefinic living polymers having a molecular weight distribution (Mw/Mn) of 1 to 1.3, comprising polymerizing an olefinic monomer having 2 to 20 carbon atoms at low temperatures in the presence of a catalyst comprising (A) a hafnium or zirconium-containing compound having one or two cyclopentadienyl backbones, (B) a triphenyl boron compound or a tetraphenyl borate compound and optionally (C) a specific mono-, di- or trialkylaluminum compound. When the catalyst comprising the zirconium-containing compound is prepared by further using a titanium-containing compound (D), the polymerization temperature can be raised.
摘要翻译：一种制备具有1至1.3的分子量分布（Mw / Mn）的烯属活性聚合物的方法，包括在催化剂存在下在低温下聚合具有2至20个碳原子的烯烃单体，所述催化剂包含（A）铪或锆（B）三苯基硼化合物或四苯基硼酸盐化合物和任选的（C）特定的单 - ，二 - 或三烷基铝化合物。当通过进一步使用含钛化合物（D）制备包含含锆化合物的催化剂时，可以提高聚合温度。

2. 发明授权

US06653430B1 Butadiene polymers and process for producing conjugated diene polymers 失效
标题翻译：丁二烯聚合物和共轭二烯聚合物的制备方法
公开(公告)号：US06653430B1
公开(公告)日：2003-11-25
申请号：US09601469
申请日：2001-06-18
申请人： Kazuo Soga , Michihiko Asai , Yasuzo Suzuki , Akira Miyazawa , Kenji Tsuchihara , Masahide Murata , Hiroyuki Ozaki , Masanao Kawabe , Yoshifumi Fukui , Jizhy Jin , Hideaki Hagihara , Toshio Kase
发明人： Kazuo Soga , Michihiko Asai , Yasuzo Suzuki , Akira Miyazawa , Kenji Tsuchihara , Masahide Murata , Hiroyuki Ozaki , Masanao Kawabe , Yoshifumi Fukui , Jizhy Jin , Hideaki Hagihara , Toshio Kase
IPC分类号： C08F3606
CPC分类号： C08C19/44 , C08F36/06 , C08F4/642
摘要： A butadiene polymer (i) having a cis bond unit content of at least 50% based on the total butadiene units, a number average molecular weight (Mn) of 1,000 to 10,000,000, and at least 80%, based on the total molecular chains, of living chains containing a transition metal of group IV of the Periodic table at a terminal thereof; a polymer (ii) obtained by modifying terminals of the polymer (i); and a polymer (iii) obtained by coupling the polymers (i). These polymers (i), (ii) and (iii) are obtained by polymerizing a conjugated diene monomer alone or with a copolymerizable monomer at a specific temperature in the presence of a catalyst comprising a compound (A) of a transition metal of group IV of the periodic table having a cyclopentadienyl structure and a co-catalyst (B) selected from organoaluminum-oxy compound (a) and others and optionally further by contacting the resultant polymer with a terminal modifier or a coupling agent.
摘要翻译：丁二烯聚合物（i）基于总的丁二烯单元具有至少50％的顺式键单元含量，基于总分子链的数均分子量（Mn）为1,000至10,000,000，和至少80％的含有周期表第IV族过渡金属末端的活链; 通过改性聚合物（i）的末端获得的聚合物（ii）; 和通过偶联聚合物（i）获得的聚合物（iii）。这些聚合物（ⅰ），（ⅱ）和（ⅲ）是通过在包含IV族过渡金属的化合物（A）的催化剂存在下，在特定温度下单独或与可共聚单体共聚而获得的具有环戊二烯基结构的周期表和选自有机铝 - 氧化合物（a）等的助催化剂（B），任选地进一步通过使所得聚合物与末端改性剂或偶联剂接触。

3. 发明授权

US06455649B1 Catalyst for producing living olefin polymer and process for producing the polymer 失效
标题翻译：用于生产活性烯烃聚合物的催化剂和用于生产聚合物的方法
公开(公告)号：US06455649B1
公开(公告)日：2002-09-24
申请号：US09486967
申请日：2000-03-03
申请人： Yoshihumi Fukui , Masahide Murata , Kazuo Soga , Michihiko Asai , Yasuzou Suzuki , Akira Miyazawa , Kenji Tsuchihara , Hiroyuki Ozaki , Masanao Kawabe , Naoya Kishi
发明人： Yoshihumi Fukui , Masahide Murata , Kazuo Soga , Michihiko Asai , Yasuzou Suzuki , Akira Miyazawa , Kenji Tsuchihara , Hiroyuki Ozaki , Masanao Kawabe , Naoya Kishi
IPC分类号： C08F468
CPC分类号： C08F10/00 , C08F36/20 , C08F210/06 , C08F4/68 , C08F210/14 , C08F2500/03 , C08F236/20
摘要： A catalyst comprising an organoaluminum compound and a vanadium chelate compound having the lability to cause olefins to undergo living coordination polymerization is contacted with a terminal diolefin to obtain a catalyst for living polymer production. When the above contact is:conducted in the presence of a cycloolefin or an internal olefin, the yield of a living polymer can be improved. By modifying all ends of the living polymer obtained, a telechelic olefin polymer is obtained in which all the polymer chains are modified with functional groups.
摘要翻译：包含有机铝化合物和不溶于烯烃进行活性配位聚合的钒螯合物的催化剂与末端二烯烃接触，得到活性聚合物制造用催化剂。当上述接触是在环烯烃或内烯烃存在下进行时，可提高活性聚合物的收率。通过改变所得活性聚合物的所有端部，获得其中所有聚合物链用官能团改性的遥爪烯烃聚合物。

4. 发明授权

US4639379A Method for the improvement of antistatic performance of synthetic resin shaped articles 失效
标题翻译：提高合成树脂成型制品抗静电性能的方法
公开(公告)号：US4639379A
公开(公告)日：1987-01-27
申请号：US743874
申请日：1985-06-11
申请人： Michihiko Asai , Yukio Shimura , Keishiro Tsuda , Susumu Ueno , Hirokazu Nomura , Kiyoshi Imada
发明人： Michihiko Asai , Yukio Shimura , Keishiro Tsuda , Susumu Ueno , Hirokazu Nomura , Kiyoshi Imada
IPC分类号： C08J7/00 , B05D3/06 , B05D7/26 , B29C71/04 , C08J7/04 , C08J7/12 , C08J7/18 , C08K5/54 , C08L25/04 , C08L77/00
CPC分类号： C08J7/123
摘要： The invention provides a very efficient method for the improvement of the antistatic performance, e.g. decrease in the accumulation of static electricity on the surface and decrease in the surface resistivity, of a synthetic resin shaped article with outstanding durability of the effect. The method comprises two steps in principle, first of which is the formation of a crosslinked layer in the surface portion of the shaped article by a variety of known methods effective for the formation of crosslinks in polymeric materials and the second of which is the exposure of the thus crosslinked surface of the article to low temperature plasma produced in an atmosphere containing a gaseous silicon-containing compound which may be a silane compound or a low-molecular weight vaporizable siloxane compound to form a plasma-polymerized surface film of the silicon compound on the crosslinked layer.
摘要翻译：本发明提供了用于提高抗静电性能的非常有效的方法，例如，具有突出的耐久性的合成树脂成型制品的表面静电积聚减少，表面电阻率降低。该方法原则上包括两个步骤，其中首先是在成型制品的表面部分中通过各种已知的方法形成交联层，所述方法有效地在聚合物材料中形成交联，其中第二步是暴露于将这样交联的制品的表面在含有气态含硅化合物的气氛中产生的低温等离子体，所述气体含硅化合物可以是硅烷化合物或低分子量可汽化硅氧烷化合物，以形成硅化合物的等离子体聚合表面膜交联层。

5. 发明授权

US4261806A Method for the treatment of inner surfaces of a tubular body of a plastic with low temperature plasma 失效
标题翻译：用低温等离子体处理塑料管状体的内表面的方法
公开(公告)号：US4261806A
公开(公告)日：1981-04-14
申请号：US112194
申请日：1980-01-15
申请人： Michihiko Asai , Yoshio Suda , Kiyoshi Imada , Susumu Ueno , Hirokazu Nomura
发明人： Michihiko Asai , Yoshio Suda , Kiyoshi Imada , Susumu Ueno , Hirokazu Nomura
IPC分类号： C08J7/00 , A61L33/00 , B05D7/22 , B29C59/14 , B01K1/00 , B05D3/06
CPC分类号： B05D7/22 , A61L33/0094 , B05D1/62 , B05D3/141 , B05D7/222 , B29C59/142 , B05D2201/00 , B29K2023/00 , B29K2027/06 , B29L2023/22
摘要： The invention provides an effective method for subjecting the inner surface of a tubular body made of a plastic resin to a treatment with low temperature plasma according to which the tubular body is dipped in an insulating oil bath while the inside of the tubular body is filled with a plasma gas under a reduced pressure and electric power for the generation of a low temperature plasma is supplied to electrodes surrounding the tubular body in the insulating oil. Several of the problems in the prior art methods can be solved by the present invention such as undesirable thermal degradation of the tube surface by the evolved by the electric discharge, and power loss due to the generation of plasma outside the tubular body. When the method of the invention is applied to the treatment of a continuous length tubular body, the tubular body is continuously moved in the insulating oil through the electrodes surrounding it, with the optional provision of a sleeve made of an insulating material placed between the electrodes and the tubular body, so as that the tubular body is free from adverse effects caused by direct contact with the electrodes.
摘要翻译：本发明提供了一种有效的方法，用于使由塑料树脂制成的管状体的内表面经受低温等离子体处理，根据该等离子体，管状体浸入绝缘油浴中，同时管状体的内部被填充将用于产生低温等离子体的减压下的等离子体气体和电力供给到绝缘油中的管状体周围的电极。通过本发明可以解决现有技术方法中的几个问题，例如通过放电产生的管表面的不期望的热降解，以及由于在管体外部产生等离子体造成的功率损耗。当将本发明的方法应用于连续长度管状体的处理时，管状体通过围绕它的电极在绝缘油中连续移动，可选地提供由置于电极之间的绝缘材料制成的套筒以及管状体，使得管状体没有与电极直接接触引起的不利影响。

6. 发明授权

US4276138A Method for reducing electrostatic charging on shaped articles of polyvinyl chloride resins 失效
标题翻译：降低聚氯乙烯树脂成型制品静电荷的方法
公开(公告)号：US4276138A
公开(公告)日：1981-06-30
申请号：US051148
申请日：1979-06-22
申请人： Michihiko Asai , Yoshio Suda , Kiyoshi Imada , Susumu Ueno , Hirokazu Nomura
发明人： Michihiko Asai , Yoshio Suda , Kiyoshi Imada , Susumu Ueno , Hirokazu Nomura
IPC分类号： C08J3/28 , C08J5/00 , C08J5/18 , C08J7/12 , C08J7/18 , C08K5/04 , C08K5/06 , C08K5/09 , C08K5/17 , C08K5/42 , C08L27/06 , G02B1/10
CPC分类号： C08J7/123 , C08J2327/06 , Y10S260/19 , Y10S260/20
摘要： A method for reducing static electricity on the surface of a shaped article made of polyvinyl chloride resins, which method comprises the steps of (a) blending a surface active agent with the polyvinyl chloride resin prior to fabrication of the resin into a shaped article, (b) fabricating the resin admixed with the surface active agent into a shaped article, and (c) subjecting the shaped article to a treatment with low temperature plasma of a gas.
摘要翻译：一种用于减少由聚氯乙烯树脂制成的成型制品表面的静电的方法，该方法包括以下步骤：（a）在将树脂制成之前将表面活性剂与聚氯乙烯树脂混合成成型制品（ b）将与表面活性剂混合的树脂制成成型制品，和（c）使成形制品用气体的低温等离子体处理。

7. 发明授权

US4272559A Method for surface treatment of shaped articles of polyvinyl chloride resins 失效
标题翻译：聚氯乙烯树脂成型制品的表面处理方法
公开(公告)号：US4272559A
公开(公告)日：1981-06-09
申请号：US955211
申请日：1978-10-27
申请人： Michihiko Asai , Keishiro Tsuda , Akira Okada
发明人： Michihiko Asai , Keishiro Tsuda , Akira Okada
IPC分类号： C08J7/00 , B29C35/08 , B29C59/16 , B05D3/06
CPC分类号： B29C59/16 , B29C2035/0827 , B29K2027/06
摘要： Shaped articles of polyvinyl chloride resins containing low-molecular plasticizers are irradiated with ultraviolet light of a wavelength in the vacuum ultraviolet region to cause the shaped articles to form therein a cross linked layer capable of preventing otherwise possible exudation of plasticizers to their surface.
摘要翻译：用真空紫外线区域的波长的紫外线照射含有低分子增塑剂的聚氯乙烯树脂成型体，使成形制品在其中形成交联层，能够防止另外可能渗出增塑剂的表面。

8. 发明授权

US4336211A Method for the preparation of shaped articles of a vinyl chloride based resin having improved surface properties 失效
标题翻译：用于制备具有改进的表面性能的氯乙烯基树脂成形制品的方法
公开(公告)号：US4336211A
公开(公告)日：1982-06-22
申请号：US206992
申请日：1980-11-14
申请人： Michihiko Asai , Yoshio Suda , Kiyoshi Imada , Susumu Ueno , Hirokazu Nomura
发明人： Michihiko Asai , Yoshio Suda , Kiyoshi Imada , Susumu Ueno , Hirokazu Nomura
IPC分类号： C08J7/00 , B29C35/08 , B29C59/16 , C08F2/48 , C08K5/1515 , C08L27/06 , C08L63/00
CPC分类号： C08K5/1515 , B29C59/16 , C08L27/06 , B29C2035/0827 , B29K2027/06 , C08L63/00
摘要： The invention provides a novel method for obtaining a shaped article of a vinyl chloride-based resin which is markedly insusceptible to the undesirable phenomenon of exudation or bleeding of the plasticizer and other additive ingredients contained therein on to the surface of the article. The method comprises formulating the resin composition for the fabrication of the shaped article with an epoxy compound containing, preferably, at least 2% by weight of the oxirane oxygen in the molecule in an amount of at least 0.05% by weight based on the vinyl chloride-based resin and irradiating the shaped article with ultraviolet light having a substantial energy distribution in the wavelength region of 200 nm or shorter. The shaped article obtained by the inventive method is remarkably insusceptible to the plasticizer bleeding even after prolonged outdoor exposure or irradiation with ultraviolet light having wavelengths longer than 290 nm.
摘要翻译：本发明提供了一种用于获得氯乙烯基树脂的成型制品的新方法，其显着地不能渗透到其中包含的增塑剂和其它添加剂成分的渗出或渗出到制品的表面上。该方法包括用分散体中至少含有2重量％至少2重量％环氧乙烷氧气的环氧化合物配制用于制造成型制品的树脂组合物，其量为至少0.05重量％，基于氯乙烯并且在200nm以下的波长范围内用具有实质的能量分布的紫外线照射成形制品。通过本发明方法获得的成型制品即使在长时间室外暴露或用波长超过290nm的紫外线照射之后也显着地不易受到增塑剂的渗透。

9. 发明授权

US4233419A Method for preventing plasticizer bleeding on polyvinyl chloride shaped articles 失效
标题翻译：防止聚氯乙烯制品上增塑剂渗色的方法
公开(公告)号：US4233419A
公开(公告)日：1980-11-11
申请号：US51150
申请日：1979-06-22
申请人： Michihiko Asai , Yoshio Suda , Kiyoshi Imada , Susumu Ueno , Hirokazu Nomura
发明人： Michihiko Asai , Yoshio Suda , Kiyoshi Imada , Susumu Ueno , Hirokazu Nomura
IPC分类号： C08L27/00 , C08F259/00 , C08F259/04 , C08J7/00 , C08J7/18 , C08K5/54 , C08K5/5425 , C08L1/00 , C08L27/06 , C08L27/22 , C08L33/00 , C08L33/02
CPC分类号： C08J7/123 , C08J2327/06
摘要： A novel method is proposed for preventing bleeding of plasticizers on the surface of shaped articles of plasticized polyvinyl chloride resins. The method comprises blending a limited amount of an organosilane compound represented by the general formulaCH.sub.2 .dbd.CR.sup.1 --CO--O--CH.sub.2).sub.a Si(R.sup.2).sub.b (OR.sup.3).sub.3-bin which R.sup.1 and R.sup.3 are each a hydrogen atom or an alkyl group, R.sup.2 is a monovalent hydrocarbon group, a is an integer from 1 to 6 and b is a number of 0, 1 or 2 with the polyvinyl chloride resin prior to fabrication of the resin into shaped articles, fabricating the resin admixed with the organosilane compound into a desired shaped article, and subjecting the shaped article to a treatment with low temperature plasma of a gas. Carbon monoxide is preferred as the gas for plasma atmosphere.
摘要翻译：提出了一种防止增塑剂在塑化聚氯乙烯树脂成型体表面渗出的新方法。该方法包括将有限量的由通式CH 2 = CR 1 -CO-O-CH 2表示的有机硅烷化合物与Si（R 2）b（OR 3）3-b混合，其中R 1和R 3各自为氢原子或烷基，R2是单价烃基，a是1〜6的整数，b是在将树脂制成成型制品之前用聚氯乙烯树脂的数量为0,1或2，制造与将有机硅烷化合物转化为所需的成型制品，并使成形制品用气体的低温等离子体处理。作为等离子体气体的气体，优选一氧化碳。

10. 发明授权

US5271795A Method of growing crystals 失效
标题翻译：生长晶体的方法
公开(公告)号：US5271795A
公开(公告)日：1993-12-21
申请号：US759379
申请日：1991-09-13
申请人： Mitsuo Ataka , Michihiko Asai , Masaki Kato , Kazuhide Kamimura
发明人： Mitsuo Ataka , Michihiko Asai , Masaki Kato , Kazuhide Kamimura
IPC分类号： B01D9/02 , C30B7/00 , C30B7/08 , C30B29/58 , C30B29/54
CPC分类号： C30B7/00 , C30B29/54
摘要： A method of growing crystals utilizing the temperature dependence of solubility of a crystalline material which is characterized in that crystals are deposited by locally controlling the temperature of a solution containing the crystalline material to take a suitable value. Larger crystals can be formed.
摘要翻译：利用结晶材料的溶解度的温度依赖性生长晶体的方法，其特征在于通过局部控制含有结晶材料的溶液的温度来沉积晶体以获得合适的值。可以形成更大的晶体。

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