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    • 3. 发明授权
    • Polyamide resin composition
    • 聚酰胺树脂组合物
    • US06451890B1
    • 2002-09-17
    • US09450715
    • 1999-11-30
    • Yasuo ImashiroNaofumi HorieHiroyuki Kayaki
    • Yasuo ImashiroNaofumi HorieHiroyuki Kayaki
    • C08K529
    • C08L77/00C08K3/16C08K5/29C08L77/02C08L77/06C08L79/00C08L2666/20
    • There are provided a polyamide resin composition which alleviates the drawbacks of the prior art and which is improved in resistance to hydrolysis particularly in an acidic medium of high temperatures, oil resistance and metal halide resistance; and a member made from the above polyamide resin composition, which can be applied even to sites where the use of a metallic member has been necessary. The polyamide resin composition of the present invention comprises a polyamide resin and a carbodiimide compound and, owing to the use of the carbodiimide compound, is improved in hydrolysis resistance, oil resistance and metal halide resistance; and the member of the present invention is made from the above polyamide resin composition.
    • 提供一种减轻现有技术缺陷的聚酰胺树脂组合物,特别是在耐高温,耐油和耐金属卤化物的酸性介质中,耐水解性得到改善。 以及由上述聚酰胺树脂组合物制成的构件,其甚至可以应用于需要使用金属构件的位置。 本发明的聚酰胺树脂组合物包含聚酰胺树脂和碳二亚胺化合物,并且由于使用碳二亚胺化合物,耐水解性,耐油性和耐金属卤化物性提高; 并且本发明的构件由上述聚酰胺树脂组合物制成。
    • 4. 发明授权
    • Urea-modified carbodiimide and process for production thereof
    • 脲改性碳化二亚胺及其生产方法
    • US5637769A
    • 1997-06-10
    • US494996
    • 1995-06-27
    • Yasuo ImashiroIkuo TakahashiNaofumi HorieTakeshi Yamane
    • Yasuo ImashiroIkuo TakahashiNaofumi HorieTakeshi Yamane
    • C07C273/18C07C267/00C07C275/14C07C275/18C07C275/26C08G18/02C08G18/28C08G18/78C08L67/02C07C275/06
    • C08G18/2865C07C267/00C07C275/14C07C275/26C08G18/025C08L67/02C07C2101/14
    • The present invention provides: a urea-modified carbodiimide represented by the following general formula ##STR1## (wherein each R is a C.sub.1 -C.sub.12 alkyl group or a C.sub.3 -C.sub.10 cycloalkyl group; each Z is a C.sub.1 -C.sub.12 alkylene group, a C.sub.3 -C.sub.10 cycloalkylene group, a C.sub.4 -C.sub.16 alkylene group having a cyclic or non-cyclic structure, or a C.sub.8 -C.sub.16 alkylene group having an aromatic ring; n is an integer of 1-50; and each m is an integer of 1 or 2), and a process for producing the above urea-modified carbodiimide, which comprises (1) reacting an organic aliphatic diisocyanate represented by the following general formulaO.dbd.C.dbd.N--Z--N.dbd.C.dbd.Owith a primary or secondary organic aliphatic amine to introduce urea bonds into the organic aliphatic diisocyanate and then carbodiimidizing the resulting product in the presence of a carbodiimidization catalyst, or (2) at least partially carbodiimidizing, in the presence of a carbodiimidization catalyst, said organic aliphatic diisocyanate and then reacting the resulting carbodiimide with a primary or secondary organic aliphatic amine to introduce urea bonds into the carbodiimide.The urea-modified carbodiimide of the present invention is free from the problems of the prior art, has good compatibility with polyester resins and other thermoplastic resins, and can improve the heat resistance and hydrolysis resistance of thermoplastic resins.
    • 本发明提供:由以下通式表示的脲改性碳化二亚胺:其中R为C1-C12烷基或C3-C10环烷基;各Z为C1-C12 亚烷基,C 3 -C 10亚环烷基,具有环状或非环状结构的C 4 -C 16亚烷基或具有芳香环的C 8 -C 16亚烷基; n为1-50的整数,m为 1或2的整数),以及上述尿素改性碳二亚胺的制造方法,其包括(1)使由以下通式O = C = NZN = C = O表示的有机脂族二异氰酸酯与伯或仲有机脂族 胺,将脲键引入有机脂族二异氰酸酯中,然后在碳二亚胺化催化剂存在下碳化二亚胺化所得产物,或(2)在碳二亚胺化催化剂存在下至少部分碳二亚胺化所述有机脂族二异氰酸酯,然后使所得产物 g碳二亚胺与一级或二级有机脂族胺,以将脲键引入碳二亚胺。 本发明的尿素改性碳化二亚胺没有现有技术的问题,与聚酯树脂和其它热塑性树脂具有良好的相容性,并且可以提高热塑性树脂的耐热性和耐水解性。
    • 10. 发明授权
    • Polyurethane resins
    • 聚氨酯树脂
    • US6153718A
    • 2000-11-28
    • US338508
    • 1999-06-23
    • Yasuo ImashiroIkuo TakahashiNaofumi HorieTakeshi Yamane
    • Yasuo ImashiroIkuo TakahashiNaofumi HorieTakeshi Yamane
    • C08G18/02C08G18/08C08G18/10C08G18/72C08G18/76C08G18/78C08G18/79C08G18/83
    • C08G18/797C08G18/025C08G18/0895C08G18/10C08G18/725
    • A polyurethane resin obtained from a diol component and a diisocyanate component by an ordinary process, wherein the diisocyanate component comprises:at least one kind of unmodified diisocyanate, andat least one kind of carbodiimide-modified aromatic diisocyanate having, at one or both of the ortho positions of the two isocyanate groups, an aliphatic, alicyclic or aromatic substituent of one or more carbon atoms, or at least one kind of carbodiimide-modified aliphatic diisocyanate wherein at least one of the two carbons each bonded with an isocyanate group is di- or tri-substituted, and the molar ratio of the unmodified diisocyanate and the carbodiimide-modified diisocyanate is 35-0.1:1. The polyurethane resin containing carbodiimide bonds in the molecular chain alleviates the problems of the prior art and exhibits hydrolysis resistance stably over a long period of time without losing the carbodiimide bonds out of the molecule.
    • 通过常规方法由二醇组分和二异氰酸酯组分得到的聚氨酯树脂,其中所述二异氰酸酯组分包括:至少一种未改性的二异氰酸酯和至少一种碳二亚胺改性的芳族二异氰酸酯,所述二异氰酸酯在一个或两个 两个异氰酸酯基的邻位,一个或多个碳原子的脂族,脂环族或芳族取代基,或至少一种碳二亚胺改性的脂族二异氰酸酯,其中每个与异氰酸酯基团键合的两个碳中的至少一个是二 或三取代,未改性二异氰酸酯与碳二亚胺改性二异氰酸酯的摩尔比为35〜0.1:1。 在分子链中含有碳二亚胺键的聚氨酯树脂缓解了现有技术的问题,并且在长时间内稳定地表现出耐水解性,而不会损失分子内的碳二亚胺键。