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1. 发明授权

US06841651B2 Polyamide resin 有权
标题翻译：聚酰胺树脂
公开(公告)号：US06841651B2
公开(公告)日：2005-01-11
申请号：US10408566
申请日：2003-04-08
申请人： Kazunobu Maruo , Tomomichi Kanda , Koji Yamamoto
发明人： Kazunobu Maruo , Tomomichi Kanda , Koji Yamamoto
IPC分类号： C08G69/02 , C08G69/04 , C08G69/26 , C08G69/28 , C08K5/51 , C08G69/08 , B32B27/00 , C08L77/00
CPC分类号： C08G69/28 , C08G69/02 , C08G69/04 , C08G69/26 , C08G69/265 , C08K5/51 , C08K2201/014 , Y10T428/13 , Y10T428/139 , Y10T428/31725 , C08L77/00
摘要： The polyamide resin of the present invention is produced by polycondensation of a diamine component comprising 70 mol % or more of m-xylylenediamine and a dicarboxylic acid component comprising 70 mol % or more of a C4-C20 α, ω-straight-chain aliphatic dicarboxylic acid in the presence of at least one phosphorus compound selected from the group consisting of phosphinic acid compounds and phosphonous acid compounds and in the presence of an alkali metal compound of a weak acid. The weak acid has a dissociation constant lower than a first dissociation constant of a dicarboxylic acid mainly constituting the polyamide resin. The polyamide resin satisfies the following requirements (A), (B) and (C): 14000≦a≦40000 (A) b≦1.000 (B) 0.9930≦b−1.1a2×10−11+3.2a×10−7≦0.9980 (C) wherein a and b are as defined in the disclosure.
摘要翻译：本发明的聚酰胺树脂通过由70摩尔％以上的间苯二甲胺和含有70摩尔％以上的C4〜C20α，ω-直链脂肪族二羧酸的二羧酸成分的二胺成分缩聚而制造在至少一种选自次膦酸化合物和膦酸化合物的磷化合物存在下，并在弱酸碱金属化合物存在下进行。弱酸的解离常数低于主要构成聚酰胺树脂的二羧酸的第一解离常数。聚酰胺树脂满足以下要求（A），（B）和（C）：其中a和b如本公开中所定义。

2. 发明申请

US20070049680A1 Resin compositions, intercalates, nanocomposites and laminates prepared with aromatic polyamide and polyphenoxy polymers 失效
标题翻译：用芳族聚酰胺和聚苯氧基聚合物制备的树脂组合物，嵌入剂，纳米复合材料和层压材料
公开(公告)号：US20070049680A1
公开(公告)日：2007-03-01
申请号：US11216692
申请日：2005-08-31
申请人： Kazunobu Maruo , Tomomichi Kanda , Jun Mitadera , Ying Liang , Tie Lan
发明人： Kazunobu Maruo , Tomomichi Kanda , Jun Mitadera , Ying Liang , Tie Lan
IPC分类号： C08K9/04
CPC分类号： C08J5/005 , B32B27/08 , B32B27/16 , B32B27/20 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2270/00 , B32B2307/306 , B32B2307/54 , B32B2307/5825 , B32B2307/702 , B32B2307/7242 , B32B2307/7265 , B32B2439/70 , B82Y30/00 , C08J3/005 , C08J2377/06 , C08K9/04 , C08K2201/011 , C08L71/00 , C08L77/00 , C08L77/06 , C08L2666/14
摘要： A resin composition comprising melt blending a polyamide resin such as nylon MXD6 with a polyphenoxy resin. The polyamide resin and the polyphenoxy resin may be combined prior to or after melting and can be sandwiched between two PET layers in a perform mold to form an article capable of blow molding to form a container with improved delamination resistance. Also, intercalated layered materials are prepared by co-intercalation of an onium ion, an aromatic polyamide oligomer or polymer, e.g., nylon MXD6, and a polyphenoxy oligomer or polymer between the planar layers of a swellable layered material, such as a phyllosilicate, preferably a smectite clay. The co-intercalated layered materials are combined with the aromatic polyamide and polyphenoxy resin to form a nanocomposite composition for sandwiching between PET layers to form containers having improved delamination resistance.
摘要翻译：一种树脂组合物，其包括将聚酰胺树脂如尼龙MXD6与聚苯氧树脂熔融共混。聚酰胺树脂和聚苯氧树脂可以在熔融之前或之后组合，并且可以在执行模具中夹在两个PET层之间以形成能够吹塑以形成具有改善的耐分层性的容器的制品。另外，嵌层的层状材料通过在可溶胀的层状材料如页硅酸盐的平坦层之间共同嵌入鎓离子，芳族聚酰胺低聚物或聚合物，例如尼龙MXD6和聚苯氧基低聚物或聚合物来制备，优选蒙皂石粘土共嵌层层状材料与芳族聚酰胺和聚苯氧树脂结合形成纳米复合组合物，用于夹层在PET层之间以形成具有改善的耐分层性的容器。

3. 发明申请

US20090277858A1 Multilayer Bottle 有权
标题翻译：多层瓶
公开(公告)号：US20090277858A1
公开(公告)日：2009-11-12
申请号：US12158504
申请日：2006-12-21
申请人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
发明人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
IPC分类号： B65D23/00
CPC分类号： B32B27/36 , B32B1/02 , B32B27/28 , B32B27/34 , B65D1/0215 , C08L77/06 , Y10T428/1352 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31725 , Y10T428/31736 , Y10T428/31786 , C08L2666/02
摘要： There is provided a multilayer bottle including an outermost layer and an innermost layer which are each made of a thermoplastic polyester resin, and at least one barrier layer interposed between the outermost layer and the innermost layer. The barrier layer contains at least two components including a polyamide obtained by polycondensing a diamine component containing m-xylylenediamine as a main component with a dicarboxylic acid component containing an α,ω-linear aliphatic dicarboxylic acid as a main component, and a thermoplastic resin having a lower molecular weight than that of the polyamide. The multilayer bottle hardly suffers from delamination upon impact or dropping and, therefore, is not required to have a shape with less irregularities or less bends for preventing the delamination, and further has a large freedom of design choice.
摘要翻译：提供了包括由热塑性聚酯树脂制成的最外层和最内层的多层瓶，以及插入在最外层和最内层之间的至少一个阻挡层。阻挡层含有至少两种成分，包括通过将含有间苯二甲胺作为主要成分的二胺成分与含有α，ω-直链脂族二羧酸为主要成分的二羧酸成分缩聚得到的聚酰胺，以及具有比聚酰胺低的分子量。多层瓶几乎不会在冲击或滴落时发生分层，因此不需要具有较少的不规则形状或较少弯曲的形状以防止分层，并且还具有大的设计选择自由度。

4. 发明授权

US07786189B2 Oligomer-modified layered inorganic compounds and their use in nanocomposites 有权
标题翻译：低聚物改性层状无机化合物及其在纳米复合材料中的应用
公开(公告)号：US07786189B2
公开(公告)日：2010-08-31
申请号：US10743115
申请日：2003-12-22
申请人： Kazunobu Maruo , Tomomichi Kanda , Scott Omachinski , Ying Liang , Tie Lan
发明人： Kazunobu Maruo , Tomomichi Kanda , Scott Omachinski , Ying Liang , Tie Lan
IPC分类号： C08K9/00 , C08K3/34 , C08L77/00
CPC分类号： C09C1/42 , C01P2002/08 , C01P2002/78 , C08K9/04
摘要： Intercalates, exfoliates thereof, and nanocomposite compositions are formed by intercalating a layered silicate material, e.g., a phyllosilicate, with an oligomer or polymer intercalant that is a reaction product of at least one diamine with at least one dicarboxylic acid, to form a polyamide oligomer containing a xylylenediamine component. The oligomer or polymer may be formed in-situ by contacting the layered phyllosilicate with polymerizable monomer reactants using conditions to cause reaction and polymerization in the intercalating composition and intercalation of the resulting oligomer and/or polymer, between platelet layers of the phyllosilicate. An amine functionality of the oligomer or polymer is protonated for ion-exchange with interlayer cations of the phyllosilicate to bond the intercalant to the phyllosilicate platelet, at the protonated amine, at a negative charge site previously occupied by the interlayer cations.
摘要翻译：通过将层状硅酸盐材料（例如页硅酸盐）与作为至少一种二胺与至少一种二羧酸的反应产物的低聚物或聚合物嵌入剂嵌入以形成聚酰胺低聚物形成插层，去角质和纳米复合组合物含有苯二甲胺成分。低聚物或聚合物可以通过使分层的页硅酸盐与可聚合的单体反应物接触的条件在原位形成，使得在插层组合物中引起反应和聚合并在页硅酸盐的血小板层之间插入所得的低聚物和/或聚合物。低聚物或聚合物的胺官能团被质子化，以与页硅酸盐的层间阳离子进行离子交换，以在层状阳离子预先占据的负电荷位置处将质子化的胺键合至页硅酸盐片晶。

5. 发明申请

US20090120900A1 MULTI-LAYERED BOTTLE 有权
标题翻译：多层瓶
公开(公告)号：US20090120900A1
公开(公告)日：2009-05-14
申请号：US11994660
申请日：2006-07-06
申请人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
发明人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
IPC分类号： B65D90/02
CPC分类号： B65D1/0215 , B32B7/02 , B32B27/36 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383
摘要： There is provided a multilayer bottle comprising a barrel portion including an outermost layer, an innermost layer and at least one barrier layer interposed between the outermost layer and the innermost layer, which satisfies the requirements represented by the following formulae (1) to (3) at the same time: OTR≦0.2 cc·mm/(m2·day·atm) (1) where OTR represents an average oxygen transmission rate of the barrier layer of the barrel portion; 20≦(Average degree of orientation of barrier layer of barrel portion)≦45; and (2) 0≦b/a≦100≦200 (3) where “a” represents an average thickness (μm) of the barrier layer of the barrel portion; and “b” represents an average thickness (μm) of the barrier layer of a bottom portion of the bottle. The multilayer bottle is free from delamination owing to impact upon dropping even when the bottle is formed with irregularities and bends and therefore exhibits a large freedom of design choice.
摘要翻译：提供了一种多层瓶，其包括筒状部分，其包括最外层，最内层和插入在最外层和最内层之间的至少一个阻挡层，其满足由下式（1）至（3）表示的要求，同时：<？in-line-formula description =“In-line Formulas”end =“lead”？> OTR <= 0.2 cc.mm/(m2.day.atm）（1）<？in-line -formulae description =“In-line Formulas”end =“tail”？>其中OTR表示筒部分的阻挡层的平均氧气透过率; <？in-line-formula description =“在线公式”end =“lead”？> 20 <=（筒部阻挡层的平均取向度）<= 45; 和（2）<？in-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description =“In-line Formulas”end =“lead”？> 0 < = b / a <= 100 <= 200（3）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中“a”表示阻挡层的平均厚度（mum）的桶部分; “b”表示瓶的底部的阻挡层的平均厚度（mum）。即使当瓶形成不规则和弯曲时，多层瓶也不会因为落下的冲击而脱层，因此表现出大的设计自由度。

6. 发明申请

US20090092778A1 POLYESTER RESIN COMPOSITION, METHOD FOR PRODUCING SAME AND MOLDED BODY 有权
标题翻译：聚酯树脂组合物，其制造方法和成型体
公开(公告)号：US20090092778A1
公开(公告)日：2009-04-09
申请号：US12282372
申请日：2007-03-09
申请人： Katsuya Maruyama , Kazunobu Maruo , Tomomichi Kanda , Tsuneaki Masuda
发明人： Katsuya Maruyama , Kazunobu Maruo , Tomomichi Kanda , Tsuneaki Masuda
IPC分类号： B32B1/08 , C08K5/092
CPC分类号： C08L67/02 , C08K5/092 , C08K2201/008 , C08L77/00 , Y10T428/1352 , Y10T428/139 , C08L2666/20
摘要： Provided are a resin composition which is colored little and has excellent gas barrier properties, transparency and mechanical properties, a method for producing it, and a shaped article. The composition is a polyester resin composition comprising from 2 to 30% by weight of a specific polyamide resin (A), from 69.5 to 97.99% by weight of a specific polyester resin (B) and from 0.01 to 0.5% by weight of a di- and/or tri-polycarboxylic acid compound (c), which satisfies a≦b, 60≦a+b≦150, 1≦c×Cc≦20, 1≦c×Cc/(a×Ca)≦12 (wherein a is a concentration of the terminal amino group of the polyamide resin (A), b is a concentration of the terminal carboxyl group of the polyamide resin (A), c is a concentration of the carboxyl group in the polycarboxylic acid compound (C), Cc is a concentration of the polycarboxylic acid compound (C) in the polyester resin composition, and Ca is a concentration of the polyamide resin (A) in the polyester resin composition (g/g). The method is for producing the resin composition; and the shaped article is obtained by shaping the resin composition.
摘要翻译：提供一种少许着色，具有优异的阻气性，透明性和机械性能的树脂组合物，其制造方法和成型制品。该组合物是一种聚酯树脂组合物，其包含2至30重量％的特定聚酰胺树脂（A），69.5至97.99重量％的特定聚酯树脂（B）和0.01至0.5重量％的二 - 和/或三聚羧酸化合物（c），其满足<= b，60 <= a + b <= 150,1 / = cxCc <= 20,1 <= cxCc /（axCa）其中a是聚酰胺树脂（A）的末端氨基的浓度，b是聚酰胺树脂（A）的末端羧基的浓度，c是多元羧酸化合物（C ），Cc是聚酯树脂组合物中的多元羧酸化合物（C）的浓度，Ca是聚酯树脂组合物中聚酰胺树脂（A）的浓度（g / g），该树脂的制造方法组合物;通过使树脂组合物成形获得成型制品。

7. 发明授权

US08597750B2 Polyester resin composition, method for producing same and molded body 有权
标题翻译：聚酯树脂组合物，其制造方法和成型体
公开(公告)号：US08597750B2
公开(公告)日：2013-12-03
申请号：US12282372
申请日：2007-03-09
申请人： Katsuya Maruyama , Kazunobu Maruo , Tomomichi Kanda , Tsuneaki Masuda
发明人： Katsuya Maruyama , Kazunobu Maruo , Tomomichi Kanda , Tsuneaki Masuda
IPC分类号： C08L67/02 , B01J15/00
CPC分类号： C08L67/02 , C08K5/092 , C08K2201/008 , C08L77/00 , Y10T428/1352 , Y10T428/139 , C08L2666/20
摘要： Provided are a resin composition which is colored little and has excellent gas barrier properties, transparency and mechanical properties, a method for producing it, and a shaped article. The composition is a polyester resin composition comprising from 2 to 30% by weight of a specific polyamide resin (A), from 69.5 to 97.99% by weight of a specific polyester resin (B) and from 0.01 to 0.5% by weight of a di- and/or tri-polycarboxylic acid compound (c), which satisfies a≦b, 60 ≦a+b≦150, 1≦c×Cc≦20, 1≦c×Cc/(a×Ca)≦12 (wherein a is a concentration of the terminal amino group of the polyamide resin (A), b is a concentration of the terminal carboxyl group of the polyamide resin (A), c is a concentration of the carboxyl group in the polycarboxylic acid compound (C), Cc is a concentration of the polycarboxylic acid compound (C) in the polyester resin composition, and Ca is a concentration of the polyamide resin (A) in the polyester resin composition (g/g). The method is for producing the resin composition; and the shaped article is obtained by shaping the resin composition.
摘要翻译：提供一种少许着色，具有优异的阻气性，透明性和机械性能的树脂组合物，其制造方法和成型制品。该组合物是一种聚酯树脂组合物，其包含2至30重量％的特定聚酰胺树脂（A），69.5至97.99重量％的特定聚酯树脂（B）和0.01至0.5重量％的二 - 和/或三聚羧酸化合物（c），其满足@ b，60 @ a + b @ 150,1 / c×Cc @ 20,1 @ c×Cc /（a×Ca）@ 12（其中 a是聚酰胺树脂（A）的末端氨基的浓度，b是聚酰胺树脂（A）的末端羧基的浓度，c是多元羧酸化合物（C）中的羧基浓度， Cc是聚酯树脂组合物中的多元羧酸化合物（C）的浓度，Ca是聚酯树脂组合物中聚酰胺树脂（A）的浓度（g / g），该树脂组合物的制造方法通过使树脂组合物成形而得到成形体。

8. 发明授权

US07927678B2 Multilayer bottle 有权
标题翻译：多层瓶
公开(公告)号：US07927678B2
公开(公告)日：2011-04-19
申请号：US12158504
申请日：2006-12-21
申请人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
发明人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
IPC分类号： B32B27/08
CPC分类号： B32B27/36 , B32B1/02 , B32B27/28 , B32B27/34 , B65D1/0215 , C08L77/06 , Y10T428/1352 , Y10T428/1359 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31725 , Y10T428/31736 , Y10T428/31786 , C08L2666/02
摘要： There is provided a multilayer bottle including an outermost layer and an innermost layer which are each made of a thermoplastic polyester resin, and at least one barrier layer interposed between the outermost layer and the innermost layer. The barrier layer contains at least two components including a polyamide obtained by polycondensing a diamine component containing m-xylylenediamine as a main component with a dicarboxylic acid component containing an α,ω-linear aliphatic dicarboxylic acid as a main component, and a thermoplastic resin having a lower molecular weight than that of the polyamide. The multilayer bottle hardly suffers from delamination upon impact or dropping and, therefore, is not required to have a shape with less irregularities or less bends for preventing the delamination, and further has a large freedom of design choice.
摘要翻译：提供了包括由热塑性聚酯树脂制成的最外层和最内层的多层瓶，以及插入在最外层和最内层之间的至少一个阻挡层。阻隔层含有至少两种成分，包括通过使含有间苯二甲胺作为主要成分的二胺组分与含有α，ω-线性脂族二羧酸作为主要成分的二羧酸组分缩聚获得的聚酰胺，以及具有比聚酰胺低的分子量。多层瓶几乎不会在冲击或滴落时发生分层，因此不需要具有较少的不规则形状或较少弯曲的形状以防止分层，并且还具有大的设计选择自由度。

9. 发明授权

US07619024B2 Resin compositions, intercalates, nanocomposites and laminates prepared with aromatic polyamide and polyphenoxy polymers 失效
标题翻译：用芳族聚酰胺和聚苯氧基聚合物制备的树脂组合物，嵌入剂，纳米复合材料和层压材料
公开(公告)号：US07619024B2
公开(公告)日：2009-11-17
申请号：US11216692
申请日：2005-08-31
申请人： Kazunobu Maruo , Tomomichi Kanda , Jun Mitadera , Ying Liang , Tie Lan
发明人： Kazunobu Maruo , Tomomichi Kanda , Jun Mitadera , Ying Liang , Tie Lan
IPC分类号： C08J5/10 , C08K3/34
CPC分类号： C08J5/005 , B32B27/08 , B32B27/16 , B32B27/20 , B32B27/32 , B32B27/34 , B32B27/36 , B32B2270/00 , B32B2307/306 , B32B2307/54 , B32B2307/5825 , B32B2307/702 , B32B2307/7242 , B32B2307/7265 , B32B2439/70 , B82Y30/00 , C08J3/005 , C08J2377/06 , C08K9/04 , C08K2201/011 , C08L71/00 , C08L77/00 , C08L77/06 , C08L2666/14
摘要： A resin composition comprising melt blending a polyamide resin such as nylon MXD6 with a polyphenoxy resin. The polyamide resin and the polyphenoxy resin may be combined prior to or after melting and can be sandwiched between two PET layers in a perform mold to form an article capable of blow molding to form a container with improved delamination resistance. Also, intercalated layered materials are prepared by co-intercalation of an onium ion, an aromatic polyamide oligomer or polymer, e.g., nylon MXD6, and a polyphenoxy oligomer or polymer between the planar layers of a swellable layered material, such as a phyllosilicate, preferably a smectite clay. The co-intercalated layered materials are combined with the aromatic polyamide and polyphenoxy resin to form a nanocomposite composition for sandwiching between PET layers to form containers having improved delamination resistance.
摘要翻译：一种树脂组合物，其包括将聚酰胺树脂如尼龙MXD6与聚苯氧树脂熔融共混。聚酰胺树脂和聚苯氧树脂可以在熔融之前或之后组合，并且可以在执行模具中夹在两个PET层之间以形成能够吹塑以形成具有改善的耐分层性的容器的制品。另外，嵌层的层状材料通过在可溶胀的层状材料如页硅酸盐的平坦层之间共同嵌入鎓离子，芳族聚酰胺低聚物或聚合物，例如尼龙MXD6和聚苯氧基低聚物或聚合物来制备，优选蒙皂石粘土共嵌层层状材料与芳族聚酰胺和聚苯氧树脂结合形成纳米复合组合物，用于夹层在PET层之间以形成具有改善的耐分层性的容器。

10. 发明授权

US08124204B2 Multi-layered bottle 有权
标题翻译：多层瓶
公开(公告)号：US08124204B2
公开(公告)日：2012-02-28
申请号：US11994660
申请日：2006-07-06
申请人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
发明人： Jun Mitadera , Tomomichi Kanda , Kazunobu Maruo , Masashi Kurokawa
IPC分类号： B32B27/08 , B32B27/34 , B32B27/36
CPC分类号： B65D1/0215 , B32B7/02 , B32B27/36 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383
摘要： There is provided a multilayer bottle comprising a barrel portion including an outermost layer, an innermost layer and at least one barrier layer interposed between the outermost layer and the innermost layer, which satisfies the requirements represented by the following formulae (1) to (3) at the same time: OTR≦0.2 cc·mm/(m2·day·atm) (1) where OTR represents an average oxygen transmission rate of the barrier layer of the barrel portion; 20≦(Average degree of orientation of barrier layer of barrel portion)≦45; and (2) 0≦b/a×100≦200 (3) where “a” represents an average thickness (μm) of the barrier layer of the barrel portion; and “b” represents an average thickness (μm) of the barrier layer of a bottom portion of the bottle. The multilayer bottle is free from delamination owing to impact upon dropping even when the bottle is formed with irregularities and bends and therefore exhibits a large freedom of design choice.
摘要翻译：提供了一种多层瓶，其包括筒状部分，其包括最外层，最内层和插入在最外层和最内层之间的至少一个阻挡层，其满足由下式（1）至（3）表示的要求，同时：OTR＆nlE; 0.2cc·mm /（m2·day·atm）（1）其中OTR表示筒部的阻挡层的平均氧气透过率; 20＆nlE;（桶部分的阻挡层的平均取向度）＆nlE; 45; 和（2）0＆nlE; b / a×100＆nlE; 200（3）其中“a”表示筒部的阻挡层的平均厚度（μm） “b”表示瓶的底部的阻挡层的平均厚度（μm）。即使当瓶形成不规则和弯曲时，多层瓶也不会因为落下的冲击而脱层，因此表现出大的设计自由度。

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