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1. 发明授权

US07040747B2 Recording method for printing using two liquids on recording medium 失效
标题翻译：在记录介质上使用两种液体进行打印的记录方法
公开(公告)号：US07040747B2
公开(公告)日：2006-05-09
申请号：US10056231
申请日：2002-01-25
申请人： Kazuhide Kubota , Takashi Oyanagi , Toshiyuki Miyabayashi
发明人： Kazuhide Kubota , Takashi Oyanagi , Toshiyuki Miyabayashi
IPC分类号： B41J2/01
CPC分类号： C09D11/54 , B41J2/2114 , B41J11/002 , B41M5/0017 , B41M5/52 , B41M5/5218 , B41M5/5227 , B41M5/5236 , B41M5/5245 , B41M5/5254 , B41M5/5281 , B41M5/529 , B41M7/00 , C09D11/30 , C09D11/40
摘要： There is provided a recording method that can realize images which possess excellent fixation on recording media, excellent rubbing/scratch resistance and good quality. In the recording method, an ink composition including at least a colorant, resin emulsion particles, a water-soluble organic solvent, and water and a reaction solution containing a reactant capable of forming coagulate upon contact with the ink composition are deposited onto a recording medium to perform printing. This recording method includes the steps of: depositing the reaction solution onto the recording medium; depositing the ink composition onto the recording medium to record an image; and washing the recording medium, on which the reaction solution and the ink composition have been deposited to perform printing, with a polar so olar solvent.
摘要翻译：提供了一种记录方法，可以实现在记录介质上具有优异的固定性，优异的摩擦/耐刮擦性和良好的质量的图像。在记录方法中，至少包括着色剂，树脂乳液颗粒，水溶性有机溶剂和水的油墨组合物和含有能够与油墨组合物接触的凝结物的反应物的反应溶液沉积在记录介质上执行打印。该记录方法包括以下步骤：将反应溶液沉积到记录介质上; 将所述油墨组合物沉积到所述记录介质上以记录图像; 并用极性溶剂洗涤其上沉积有反应溶液和油墨组合物进行印刷的记录介质。

2. 发明授权

US06485138B1 Ink jet recording ink and recording method 有权
标题翻译：喷墨记录油墨和记录方法
公开(公告)号：US06485138B1
公开(公告)日：2002-11-26
申请号：US09281417
申请日：1999-03-30
申请人： Kazuhide Kubota , Kazuaki Watanabe , Kiyohiko Takemoto , Toshiyuki Miyabayashi
发明人： Kazuhide Kubota , Kazuaki Watanabe , Kiyohiko Takemoto , Toshiyuki Miyabayashi
IPC分类号： B41J217
CPC分类号： C09D11/30 , B41J2/2107 , B41M3/00 , B41M3/001 , C09D11/322 , C09D11/54 , Y10T428/24802 , Y10T428/3188 , Y10T428/31895
摘要： An ink jet recording method comprising the step of printing two solutions of a first solution and an ink composition is provided which, even in the case of printing on a recycled paper, can realize a good printed image, especially an image having no significant feathering and free from unevenness of printing and an image free from color bleeding. A first solution containing a polyvalent metal salt and/or a polyallylamine is used in combination with an ink composition containing an inorganic oxide colloid, and optionally an epoxy-containing compound. Specifically, the first solution is deposited onto a recording medium, and the ink composition is then deposited by ink jet printing to perform printing.
摘要翻译：提供一种喷墨记录方法，其包括印刷第一溶液和油墨组合物的两种溶液的步骤，即使在再生纸上进行印刷的情况下，也可以实现良好的印刷图像，特别是不具有显着羽化的图像，没有印刷不均匀和没有颜色渗色的图像。含有多价金属盐和/或聚烯丙胺的第一溶液与含有无机氧化物胶体和任选的含环氧化合物的油墨组合物组合使用。具体地，将第一溶液沉积在记录介质上，然后通过喷墨打印沉积墨水组合物以进行印刷。

3. 发明授权

US06232370B1 Ink jet recording ink 失效
标题翻译：喷墨记录油墨
公开(公告)号：US06232370B1
公开(公告)日：2001-05-15
申请号：US08816748
申请日：1997-02-21
申请人： Kazuhide Kubota , Kazuaki Watanabe , Kiyohiko Takemoto , Toshiyuki Miyabayashi
发明人： Kazuhide Kubota , Kazuaki Watanabe , Kiyohiko Takemoto , Toshiyuki Miyabayashi
IPC分类号： C09D500
CPC分类号： C09D11/30 , B41J2/2107 , B41M3/00 , B41M3/001 , C09D11/322 , C09D11/54 , Y10T428/24802 , Y10T428/3188 , Y10T428/31895
摘要： A pigment-based ink composition for ink jet recording is provided which can offer prints having excellent scratch resistance and free from uneven printing. Ink jet recording is carried out using an ink composition comprising a pigment and an inorganic oxide colloid in combination. Further, the use of a recording head equipped with a nozzle plate (101), which has been treated to form a fluoropolymer-containing plating layer (104) thereon for rendering the nozzle plate (101) water-repellent, can realize printing free from the ejection of ink droplets with trajectories non-perpendicular to the print head.
摘要翻译：提供了一种用于喷墨记录的颜料基油墨组合物，其可以提供具有优异耐刮擦性和无不均匀印刷的印刷品。使用包含颜料和无机氧化物胶体的油墨组合物进行喷墨记录。此外，使用已经在其上形成含氟聚合物的镀层（104）进行处理以使喷嘴板（101）具有疏水性的喷嘴板（101）的记录头可以实现不需要以不垂直于打印头的轨迹喷射墨滴。

4. 发明授权

US6039796A Ink jet recording ink and method 失效
标题翻译：喷墨记录油墨和方法
公开(公告)号：US6039796A
公开(公告)日：2000-03-21
申请号：US105912
申请日：1998-06-26
申请人： Kazuhide Kubota , Toshiyuki Miyabayashi
发明人： Kazuhide Kubota , Toshiyuki Miyabayashi
IPC分类号： B41M3/00 , C09D11/00
CPC分类号： B41M5/0017 , B41M5/0011 , C09D11/30 , C09D11/322 , C09D11/54
摘要： A good ink composition for ink jet recording, especially an ink composition that can be stably ejected from a recording head and can yield an image possessing excellent rubbing/scratch resistance. An ink jet recording method comprising the step of printing two solutions of a first solution and an ink composition that, even in the case of printing on a recycled paper, can realize a good printed image, especially an image having no significant feathering and free from unevenness of printing and an image free from color bleeding. The ink composition comprises a combination of an inorganic oxide colloid with an alkali metal hydroxide.
摘要翻译：用于喷墨记录的良好的油墨组合物，特别是可以从记录头稳定地喷射的油墨组合物，并且可以产生具有优异的耐擦伤/耐刮擦性的图像。一种喷墨记录方法，包括印刷第一溶液和油墨组合物的两种溶液的步骤，即使在再循环纸上进行印刷的情况下，也可以实现良好的印刷图像，特别是没有显着羽化的图像，并且没有印刷不均匀和无彩色渗色的图像。油墨组合物包含无机氧化物胶体与碱金属氢氧化物的组合。

5. 发明授权

US5948512A Ink jet recording ink and recording method 失效
公开(公告)号：US5948512A
公开(公告)日：1999-09-07
申请号：US803399
申请日：1997-02-20
申请人： Kazuhide Kubota , Kazuaki Watanabe , Kiyohiko Takemoto , Toshiyuki Miyabayashi
发明人： Kazuhide Kubota , Kazuaki Watanabe , Kiyohiko Takemoto , Toshiyuki Miyabayashi
IPC分类号： B41J2/21 , B41M3/00 , C09D11/00 , B32B3/00
CPC分类号： C09D11/30 , B41J2/2107 , B41M3/00 , B41M3/001 , C09D11/322 , C09D11/54 , Y10T428/24802 , Y10T428/3188 , Y10T428/31895
摘要： An ink jet recording method comprising the step of printing two solutions of a first solution and an ink composition is provided which, even in the case of printing on a recycled paper, can realize a good printed image, especially an image having no significant feathering and free from unevenness of printing and an image free from color bleeding. A first solution containing a polyvalent metal salt and/or a polyallylamine is used in combination with an ink composition containing an inorganic oxide colloid, and optionally an epoxy-containing compound. Specifically, the first solution is deposited onto a recording medium, and the ink composition is then deposited by ink jet printing to perform printing.

6. 发明申请

US20120225969A1 URETHANE (METH) ACRYLATE AND PRODUCTION METHOD THEREOF, CROSS-LINKED URETHANE (METH) ACRYLATE AND PRODUCTION METHOD THEREOF, AND LIGHT CURABLE AQUEOUS EMULSION 审中-公开
标题翻译：丙烯酸URETHANE（METH）丙烯酸酯及其生产方法，交联的丙烯酸（甲基）丙烯酸酯及其生产方法和光固化水性乳液
公开(公告)号：US20120225969A1
公开(公告)日：2012-09-06
申请号：US13337568
申请日：2011-12-27
申请人： Toshiyuki Miyabayashi , Tomohito Nakano , Hiroki Nakane , Hirotoshi Koyano , Yoshinobu Sato , Hiroshi Sawada , Shinichi Kato
发明人： Toshiyuki Miyabayashi , Tomohito Nakano , Hiroki Nakane , Hirotoshi Koyano , Yoshinobu Sato , Hiroshi Sawada , Shinichi Kato
IPC分类号： C08G18/83
CPC分类号： C09D175/16 , C08F290/067 , C08G18/283 , C08G18/672 , C08G18/673 , C08G18/755 , C08G18/48
摘要： For the purpose of providing a urethane(meth)acrylate excellent in emulsifiability in water and a production method thereof, and a light curable aqueous emulsion using the urethane(meth)acrylate having a low viscosity and excellent in the curability, provided is a urethane(meth)acrylate being represented by the following general formula (1) and having a weight average molecular weight of 1,000 to 10,000: A1-O—(CONH—B1-NHCOO—C1-O)n-CONH—B1-NH—COO-D1 (1) wherein in formula (1), n represents a natural number of 1 to 30, A1 represents a residue of a hydroxyl group-containing (meth)acrylate, B1 represents a residue of diisocyanate, C1 represents a residue of a diol of an acyclic hydrocarbon or a cyclic hydrocarbon, and D1 represents a residue of a polyoxyalkylene glycol monoalkyl ether.
摘要翻译：为了提供在水中的乳化性优异的氨基甲酸酯（甲基）丙烯酸酯及其制造方法，使用粘度低，固化性优异的氨基甲酸酯（甲基）丙烯酸酯的光固化性水性乳液，提供了聚氨酯（（CONH-B1-NHCOO-C1-O）n-CONH-B1-NH-COO-的重均分子量为1,000〜10000的下述通式（1）表示的（甲基） D1（1）其中，在式（1）中，n表示1〜30的自然数，A1表示含羟基的（甲基）丙烯酸酯的残基，B1表示二异氰酸酯的残基，C1表示二醇的残基的非环状烃或环状烃，D1表示聚氧亚烷基二醇单烷基醚的残基。

7. 发明申请

US20110251298A1 RADIATION-CURABLE INK COMPOSITION, INK JET RECORDING METHOD, AND RECORDED MATTER 有权
标题翻译：辐射固化油墨组合物，喷墨记录方法和记录事项
公开(公告)号：US20110251298A1
公开(公告)日：2011-10-13
申请号：US12979750
申请日：2010-12-28
申请人： Taketoshi Kagose , Toshiyuki Miyabayashi , Satoru Miura , Toru Saito , Hiroki Nakane , Jun Ito , Hiroyuki Kajimoto , Chigusa Sato , Hiroaki Kida
发明人： Taketoshi Kagose , Toshiyuki Miyabayashi , Satoru Miura , Toru Saito , Hiroki Nakane , Jun Ito , Hiroyuki Kajimoto , Chigusa Sato , Hiroaki Kida
IPC分类号： C09D11/10 , B41J2/015
CPC分类号： C09D11/101 , B41J11/002 , B41M7/0072 , C09D11/30
摘要： A radiation-curable ink composition contains (A) aminoacrylate at 1 mass % to 10 mass %, inclusive, (B) phenoxyethyl acrylate at 20 mass % to 50 mass %, inclusive, and (C) tetraethylene glycol diacrylate at 1 mass % to 20 mass %, inclusive, in its reaction component, as well as (E) bis(2,4,6-trimethylbenzoyl)-phenylphosphine oxide at 3 parts by mass to 8 parts by mass, inclusive, (F) 2,4,6-trimethylbenzoyl-diphenyl-phosphine oxide at 3 parts by mass to 5 parts by mass, inclusive, in 100 parts by mass of the reaction component, and (G) diethylthioxanthone at 1 part by mass to 3 parts by mass, inclusive, in 100 parts by mass of the reaction component.
摘要翻译：辐射固化型油墨组合物含有（A）1质量％〜10质量％的氨基丙烯酸酯，（C）20质量％〜50质量％的（B）丙烯酸苯氧基乙酯，（C）1质量％以下的四甘醇二丙烯酸酯，（E）双（2,4,6-三甲基苯甲酰基） - 苯基氧化膦，为3质量份〜8质量份，（F）为2,4质量份，（三甲基苯甲酰基 - 二苯基膦）氧化物，在100质量份的反应组分中含有3质量份〜5质量份，和（G）1质量份〜3质量份的（G）二乙基噻吨酮， 100质量份反应组分。

8. 发明授权

US06972303B1 Ink composition providing image excellent in light stability 失效
标题翻译：油墨组合提供光稳定性优异的图像
公开(公告)号：US06972303B1
公开(公告)日：2005-12-06
申请号：US09486129
申请日：1999-06-24
申请人： Toshiyuki Miyabayashi , Shinichi Kato
发明人： Toshiyuki Miyabayashi , Shinichi Kato
IPC分类号： B41J2/165 , B41J2/17 , B41J2/175 , C09D11/00 , C09D11/023 , C09D11/033 , C09D11/037 , C09D11/10 , C09D11/101 , C09D11/104 , C09D11/106 , C09D11/107 , C09D11/108 , C09D11/322 , C09D11/38 , C08K9/10 , C08L39/00 , C08L45/00
CPC分类号： C09D11/30
摘要： Disclosed are a colorant which can realize an ink compositions possessing excellent lightfastness, waterfastness, color development, and rubbing/scratch resistance, and an ink composition containing the same. The ink composition comprises at least a colorant, a polymer covering the colorant and having, in its molecular chain, sites possessing ultraviolet absorbing activity and/or photostabilizing activity, water, and a water-soluble organic solvent. The ink composition according to the present invention include two preferred embodiments. In the ink composition according to the first preferred embodiment, the polymer functions as a dispersant and covers the colorant. In the ink composition according to the second preferred embodiment, the polymer is in the form of fine particles covering the colorant. Further, the colorant comprises: a dye or a pigment; and a polymer covering the colorant and having, in its molecular chain, sites possessing ultraviolet absorbing activity and/or photostabilizing activity, the dye or the pigment being in the form of fine particles.
摘要翻译：公开了可以实现具有优异的耐光性，耐水性，显色性和耐擦擦性的油墨组合物的着色剂和含有该油墨组合物的油墨组合物。油墨组合物至少包含着色剂，覆盖着色剂的聚合物，并且在其分子链中具有具有紫外线吸收活性和/或光稳定活性的部位，水和水溶性有机溶剂。根据本发明的油墨组合物包括两个优选的实施方案。在根据第一优选实施方案的油墨组合物中，聚合物用作分散剂并覆盖着色剂。在根据第二优选实施方案的油墨组合物中，聚合物是覆盖着色剂的细颗粒的形式。此外，着色剂包括：染料或颜料; 和覆盖着色剂的聚合物，并且在其分子链中具有具有紫外线吸收活性和/或光稳定活性的部位，染料或颜料呈细颗粒形式。

9. 发明申请

US20050176877A1 Microencapsulated pigment, preparation process therefor, aqueous dispersion and ink jet recording ink 有权
标题翻译：微胶囊化颜料，其制备方法，水分散体和喷墨记录油墨
公开(公告)号：US20050176877A1
公开(公告)日：2005-08-11
申请号：US10965000
申请日：2004-10-14
申请人： Toshiyuki Miyabayashi
发明人： Toshiyuki Miyabayashi
IPC分类号： C08L1/00 , C09B67/08 , C09C3/10 , C09D11/00 , C09D17/00
CPC分类号： C09B67/0013 , C01P2004/62 , C01P2004/64 , C09B68/20 , C09B68/24 , C09B68/41 , C09B68/423 , C09B68/441 , C09C3/10 , C09D11/322 , C09D17/001 , Y10T428/2991
摘要： The present invention relates to a microencapsulated pigment in which pigment particles having cationic groups on their surfaces are coated with a polymer having repeating structural units derived from an anionic polymerizable surfactant having at least an anionic group, a hydrophobic group and a polymerizable group, and a microencapsulated pigment in which pigment particles having anionic groups on their surfaces are coated with a polymer having repeating structural units derived from a cationic polymerizable surfactant having a cationic group, a hydrophobic group and a polymerizable group. Further, the invention relates to a process for producing the microencapsulated pigment, an aqueous dispersion containing the microencapsulated pigment, and an ink jet recording ink containing the aqueous dispersion.
摘要翻译：本发明涉及一种微胶囊化颜料，其中表面上具有阳离子基团的颜料颗粒用具有至少具有阴离子基团，疏水基团和可聚合基团的阴离子可聚合表面活性剂的重复结构单元的聚合物涂覆，将其表面具有阴离子性基团的颜料粒子涂布在具有由具有阳离子性基团，疏水性基团和聚合性基团的阳离子性聚合性表面活性剂衍生的重复结构单元的聚合物的微胶囊化颜料中。此外，本发明涉及一种生产微胶囊化颜料的方法，含有微胶囊化颜料的水性分散体和含有该水分散体的喷墨记录油墨。

10. 发明授权

US06864302B2 Ink jet recording method and ink set therefor 失效
标题翻译：喷墨记录方法和墨水设置
公开(公告)号：US06864302B2
公开(公告)日：2005-03-08
申请号：US09952033
申请日：2001-09-12
申请人： Toshiyuki Miyabayashi
发明人： Toshiyuki Miyabayashi
IPC分类号： C09D11/00 , C09D11/10 , B41J2/01 , C08K9/10
CPC分类号： C09D11/40
摘要： An ink jet recording method comprising a step of bringing a first ink composition into contact with a second ink composition on a recording medium to form an aggregate, wherein the first ink composition comprises at least a water-soluble organic solvent, water and a coloring agent comprising a coloring material enclosed with a polymer having an anionic group, and wherein the second ink composition comprising at least a water-soluble organic solvent, water and a coloring agent comprising a coloring material enclosed with a polymer having a cationic group. Also disclosed are ink sets suitable for the ink jet recording method.
摘要翻译：一种喷墨记录方法，包括使第一油墨组合物与记录介质上的第二油墨组合物接触以形成聚集体的步骤，其中所述第一油墨组合物至少包含水溶性有机溶剂，水和着色剂包括用具有阴离子基团的聚合物包封的着色材料，并且其中所述第二油墨组合物至少包含水溶性有机溶剂，水和着色剂，所述着色剂包含用具有阳离子基团的聚合物包封的着色材料。还公开了适用于喷墨记录方法的油墨组。

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