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1. 发明授权

US06558804B2 Coating composition and coated article 失效
公开(公告)号：US06558804B2
公开(公告)日：2003-05-06
申请号：US09919936
申请日：2001-08-02
申请人： Kazuharu Sato , Masaaki Yamaya , Mitsuo Asai , Kazuyuki Matsumura
发明人： Kazuharu Sato , Masaaki Yamaya , Mitsuo Asai , Kazuyuki Matsumura
IPC分类号： B32B904
CPC分类号： C09D183/08 , C08G77/24 , Y10T428/31663
摘要： A coating composition comprising a silicone resin having at least two types of fluorinated organic substituent groups and hydroxyl or monovalent hydrolyzable groups forms, through brief curing at low temperature, a uniform transparent coating having a low refractive index (e.g., below 1.42) and a high hardness as well as excellent water repellency, oil repellency, and antifouling property. Stacking the coating on a high refractive index layer results in an antireflection article having an improved reflectance.

2. 发明授权

US07052770B2 Hardcoat compositions and hardcoated articles 有权
标题翻译：硬涂层组合物和硬涂层制品
公开(公告)号：US07052770B2
公开(公告)日：2006-05-30
申请号：US10461463
申请日：2003-06-16
申请人： Masahiro Furuya , Koichi Higuchi , Kazuharu Sato , Kazuyuki Matsumura , Masaaki Yamaya
发明人： Masahiro Furuya , Koichi Higuchi , Kazuharu Sato , Kazuyuki Matsumura , Masaaki Yamaya
IPC分类号： B32B25/20 , C08L83/04
CPC分类号： C09D183/14 , C08K3/22 , C08K5/0091 , C09D183/04 , Y10T428/31663
摘要： A hardcoat composition comprising (A) a hydrolytic condensate of a hydrolyzable silicon compound of formula: R1aSiX(4-a) with at least 1 mole of water per mole of hydrolyzable group X, (B) a metal oxide, (C) a siloxane resin of formula: R2bSi(OR3)c(OH)dO(4-b-c-d)/2 and having a Mw of at least 2,000, which is solid at a temperature of not higher than 40° C., and (D) a curing catalyst forms a hardcoat film having satisfactory hardness, transparency and adhesion as well as improved weather resistance and presenting a surface that is repellent to marker ink.
摘要翻译：一种硬涂层组合物，其包含（A）下式的可水解硅化合物的水解缩合物：R 1，S 1，S 4（4-a）每摩尔可水解基团X至少1摩尔水，（B）金属氧化物，（C）下式的硅氧烷树脂：（2S）（OH）2（4-bcd）/ 2＆gt;并且具有至少2,000的Mw，其在不高于40℃的温度下是固体，（D）固化催化剂形成具有令人满意的硬度，透明度和粘合性以及改进的耐候性的硬涂层，并且具有对标记油墨具有驱避性的表面。

3. 发明授权

US06497964B1 Coating compositions and method for the surface protection of plastic substrate 失效
标题翻译：涂料组合物和塑料基材表面保护方法
公开(公告)号：US06497964B1
公开(公告)日：2002-12-24
申请号：US09621627
申请日：2000-07-21
申请人： Kazuyuki Matsumura , Masaaki Yamaya , Kazuharu Sato , Koichi Higuchi , Muneo Kudo
发明人： Kazuyuki Matsumura , Masaaki Yamaya , Kazuharu Sato , Koichi Higuchi , Muneo Kudo
IPC分类号： B32B904
CPC分类号： C09D183/06 , C09D4/00 , C09D143/04 , Y10T428/31507 , Y10T428/31663 , C08G77/04 , C08L2666/44
摘要： A composition comprising (1) 0.1-50 parts by weight of the reaction product of a hydroxyl group-containing benzophenone compound with a silane and/or a hydrolyzate thereof and (2) 100 parts by weight of a silane compound and/or a hydrolyzate thereof is applied to a polycarbonate sheet to form a protective coating having mar and weather resistance. A composition comprising the reaction product of a hydroxyl group-containing benzophenone compound with a silane and/or a hydrolyzate thereof is useful for undercoating.
摘要翻译：一种组合物，其包含（1）0.1-50重量份的含羟基的二苯甲酮化合物与硅烷和/或其水解产物的反应产物和（2）100重量份的硅烷化合物和/或水解产物将其施加到聚碳酸酯片材上以形成具有耐候性和耐候性的保护涂层。包含含羟基的二苯甲酮化合物与硅烷和/或其水解产物的反应产物的组合物可用于底涂。

4. 发明授权

US6093240A Binder composition and aqueous coating composition 失效
标题翻译：粘合剂组合物和水性涂料组合物
公开(公告)号：US6093240A
公开(公告)日：2000-07-25
申请号：US896175
申请日：1997-07-17
申请人： Kazuyuki Matsumura , Masanao Kamei , Mitsuo Asai , Masaaki Yamaya , Fujio Yagihashi
发明人： Kazuyuki Matsumura , Masanao Kamei , Mitsuo Asai , Masaaki Yamaya , Fujio Yagihashi
IPC分类号： C08L83/08 , C08G77/26 , C08G77/28 , C08L83/04 , C09D183/04 , C09D183/08
CPC分类号： C09D183/08 , C08G77/26
摘要： An organic silicon compound is obtained by hydrolyzing (A) a hydrolyzable silane containing an alkoxy or acyloxy group and a nitrogenous organic group: and (B) a hydrolyzable silane containing an alkoxy or acyloxy group. The hydrolyzate or organic licon compound is available as an aqueous solution which is ready for use as a binder composition. An aqueous coating composition comprising the binder composition and optionally, a UV screen compound is also provided. The binder composition and the coating composition are shelf stable and impart water resistance, heat resistance and weatherability.
摘要翻译：通过水解（A）含有烷氧基或酰氧基和含氮有机基团的水解性硅烷得到有机硅化合物：（B）含有烷氧基或酰氧基的可水解硅烷。水解产物或有机icon化合物可作为水溶液使用，其可用作粘合剂组合物。还提供了包含粘合剂组合物和任选的UV屏蔽化合物的水性涂料组合物。粘合剂组合物和涂料组合物是稳定的并具有耐水性，耐热性和耐候性。

5. 发明申请

US20050227092A1 Antifouling coating compositions and coated articles 有权
标题翻译：防污涂料组合物和涂层制品
公开(公告)号：US20050227092A1
公开(公告)日：2005-10-13
申请号：US11098663
申请日：2005-04-05
申请人： Masaaki Yamaya , Kazuharu Sato
发明人： Masaaki Yamaya , Kazuharu Sato
IPC分类号： B32B9/04 , B32B15/08 , B32B17/10 , C08L83/04 , C09D5/16
CPC分类号： C09D183/06 , C09D5/1625 , C09D5/165 , C09D5/1675 , Y10T428/31612 , Y10T428/31663
摘要： An antifouling coating composition is provided comprising an organosilicon compound having a one end-blocked diorganopolysiloxane group and a condensation-curable silyl group in a common molecule, and optionally a heat-curable compound. The composition is applied and cured to a substrate to form a coat which has an improved surface protective function and durable water repellent and antifouling properties.
摘要翻译：提供一种防污涂料组合物，其包含在共同分子中具有一端封闭二有机聚硅氧烷基团和缩合可固化甲硅烷基的有机硅化合物，以及任选的可热固化的化合物。将组合物施加并固化至基底以形成具有改进的表面保护功能和耐久的防水防污性能的涂层。

6. 发明授权

US4981986A Organosilicon compound 失效
标题翻译：有机硅化合物
公开(公告)号：US4981986A
公开(公告)日：1991-01-01
申请号：US178318
申请日：1988-04-06
申请人： Hiroshi Yoshioka , Masaaki Yamaya , Kazuharu Sato , Akinari Itagaki
发明人： Hiroshi Yoshioka , Masaaki Yamaya , Kazuharu Sato , Akinari Itagaki
IPC分类号： C07F7/12 , C07F7/18 , C08G59/68 , C08K5/5419 , C08L83/04 , C09J163/00
CPC分类号： C07F7/12 , C07F7/182 , C07F7/1836
摘要： Disclosed herein is a new organosilicon compound having a .beta.-diketone or .beta.-ketoester structures and a hydrolyzable group. The new organosilicon compound can be effectively used for the production of an immobilized catalyst, an adsorbent for metal recovery, a curing catalyst for organosiloxane and epoxy resins, and an adhesion promoter.

7. 发明授权

US07842753B2 Composite resin, coating composition containing such resin, and coated article 有权
标题翻译：复合树脂，含有这种树脂的涂料组合物和涂覆制品
公开(公告)号：US07842753B2
公开(公告)日：2010-11-30
申请号：US11783852
申请日：2007-04-12
申请人： Masaaki Yamaya , Kazuharu Sato
发明人： Masaaki Yamaya , Kazuharu Sato
IPC分类号： C08L83/04
CPC分类号： C09D183/14 , C08G77/24 , C08G77/46 , C08G77/50 , C08K7/26 , G02B1/045 , G02B1/113 , G11B7/2545 , Y10T428/31663 , C08L83/08
摘要： A composite resin is produced by hydrolyzing and condensing a silane compound (2) containing a bissilane compound (B) represented by: XnR3-nSi—Y—SiR3-nXn (B) wherein Y is a divalent organic group which is optionally substituted with a fluorine atom or a divalent organic group which optionally contains an aromatic ring, R is a monovalent organic group, X is OH group or a hydrolyzable group, and n is 1, 2, or 3; in the presence of (1) porous and/or hollow inorganic oxide fine particles (A); and which is an integral mixture of component (1) and component (2) which has undergone the hydrolysis and the condensation. The composite resin has voids in the resin since it contains porous and/or hollow inorganic oxide fine particles, and the composite resin can also be formed into a cured article or a cured coating with a reduced refractive index since it contains air which has the lowest refractive index.
摘要翻译：通过水解和缩合含有由下式表示的双硅烷化合物（B）的硅烷化合物（2）制备复合树脂：XnR3-nSi-Y-SiR3-nXn（B）其中Y是二价有机基团，其任选被氟原子或任选含有芳环的二价有机基团，R为一价有机基团，X为OH基或可水解基团，n为1,2或3; 在（1）多孔和/或中空无机氧化物细颗粒（A）的存在下; 并且其是经过水解和缩合的组分（1）和组分（2）的整体混合物。复合树脂由于含有多孔和/或中空的无机氧化物微粒而在树脂中具有空隙，并且复合树脂也可以形成为具有折射率降低的固化物或固化涂层，因为它含有最低的空气折射率。

8. 发明申请

US20060240268A1 Protective coat-forming coating composition, coated article, and multilayer laminate 审中-公开
标题翻译：保护涂层形成涂料组合物，涂覆制品和多层层压材料
公开(公告)号：US20060240268A1
公开(公告)日：2006-10-26
申请号：US11454979
申请日：2006-06-19
申请人： Masaaki Yamaya , Kazuharu Sato , Muneo Kudo
发明人： Masaaki Yamaya , Kazuharu Sato , Muneo Kudo
IPC分类号： B32B17/10 , B32B27/06 , B32B9/04
CPC分类号： C09D183/14 , C09D4/00 , Y10T428/3154 , Y10T428/31612 , Y10T428/31663 , C08G77/24
摘要： A coating composition primarily comprising a disilane compound of the formula (A): XmR13-mSi—Y—SiR13-mXm (A) wherein R1 is a monovalent hydrocarbon group, Y is a divalent fluorinated organo group, X is a hydrolyzable group, and m is 1, 2 or 3, or a (partial) hydrolyzate thereof is applied and cured to form a protective coat having excellent chemical resistance and antireflection.
摘要翻译：主要包含式（A）的乙硅烷化合物的涂料组合物：<？in-line-formula description =“In-line formula”end =“lead”？> X＆lt; （A）3-m Si-Y-SiR 1 - 3-m X（A）其中R 1是一价烃基，Y是二价氟化有机基团，X是可水解的基团，m为1,2或3，或其（部分）水解产物被施加和固化以形成具有优异的耐化学性和抗反射性的保护涂层。

9. 发明授权

US06846568B2 Antireflective, mar-resistant multilayer laminate 失效
标题翻译：抗反射，耐腐蚀的多层叠层
公开(公告)号：US06846568B2
公开(公告)日：2005-01-25
申请号：US10195434
申请日：2002-07-16
申请人： Masaaki Yamaya , Kazuharu Sato
发明人： Masaaki Yamaya , Kazuharu Sato
IPC分类号： B32B27/00 , B32B7/02 , B32B27/30 , C08J7/04 , B32B25/20 , B32B27/08
CPC分类号： C08J7/045 , G02B1/111 , Y10T428/265 , Y10T428/31533 , Y10T428/31612 , Y10T428/31663 , Y10T428/31855 , Y10T428/31935
摘要： A multilayer laminate is composed of a transparent substrate such as glass, ceramic or plastic on which are applied, in order, a protective layer, a high refractive index layer with a refractive index of at least 1.60, and a low refractive index layer with a refractive index of not more than 1.45, each having a specific resin-based composition. The resulting films, when cured, have an excellent adhesion to the substrate and exhibit outstanding mar resistance and antireflective properties.
摘要翻译：多层层叠体由玻璃，陶瓷或塑料等透明基板构成，依次涂敷保护层，折射率至少为1.60的高折射率层和低折射率层，折射率不大于1.45，各自具有特定的树脂基组合物。所得薄膜在固化时具有优异的基材粘附性，并具有出色的耐擦伤性和抗反射性能。

10. 发明授权

US5945172A Coating agent composition and articles treated with said composition 失效
标题翻译：涂料组合物和用所述组合物处理的制品
公开(公告)号：US5945172A
公开(公告)日：1999-08-31
申请号：US891202
申请日：1997-07-10
申请人： Masaaki Yamaya , Kazuharu Sato , Hiroaki Kizaki , Masahiro Furuya
发明人： Masaaki Yamaya , Kazuharu Sato , Hiroaki Kizaki , Masahiro Furuya
IPC分类号： C08F2/48 , C08F283/12 , C08F290/00 , C08F290/06 , C08F299/08 , C08G77/20 , C09D4/00 , C09D4/06 , C09D183/04 , C09D183/06 , C09D183/07 , C09D183/08 , C08J7/04
CPC分类号： C09D4/06 , C08F283/12 , C08F290/068 , C08G77/20 , C09D183/06 , C09D183/08 , Y10T428/31663
摘要： A coating agent composition comprising an organopolysiloxane resin: with the organopolysiloxane resin having a number average molecular weight of at least 500 and acrylic or methacrylic functional group-attached silicon atoms in a proportion of 5 to 100 mole % to the total silicon atoms; and with the resin comprising units represented by formula R.sup.1 LSiX.sub.3 in a proportion of 30 to 100 mole %, wherein R.sup.1 is a hydrogen atom or a substituted or unsubstituted organic group having 1 to 18 carbon atoms and X is a hydroxyl group, a hydrolyzable group or a siloxane residue, provided that at least one X is a siloxane residue; wherein from 30 to 80 mole % of the R.sup.1 SiX.sub.3 units are one silanol group-containing units represented by formula R.sup.1 Si(OH)Y.sub.2 wherein Y is a siloxane residue.
摘要翻译：一种包含有机聚硅氧烷树脂的涂层剂组合物：其数均分子量为至少500的有机聚硅氧烷树脂和与总硅原子相比为5至100摩尔％的丙烯酸或甲基丙烯酸官能团的硅原子; 并且所述树脂包含由式R1LSiX3表示的以30-100摩尔％的比例表示的单元，其中R1是氢原子或具有1至18个碳原子的取代或未取代的有机基团，X是羟基，可水解基团或硅氧烷残基，条件是至少一个X是硅氧烷残基; 其中30〜80摩尔％的R 1 SiX 3单元是由式R 1 Si（OH）Y 2表示的一个含硅烷醇基的单元，其中Y是硅氧烷残基。

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