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1. 发明授权

US06746835B2 Thermally processed image recording material 失效
标题翻译：热处理图像记录材料
公开(公告)号：US06746835B2
公开(公告)日：2004-06-08
申请号：US10080019
申请日：2002-02-22
申请人： Katsuyuki Watanabe , Masaru Takasaki , Toshihide Ezoe , Kohzaburoh Yamada , Yasuhiro Kawanishi , Masahiko Taniguchi
发明人： Katsuyuki Watanabe , Masaru Takasaki , Toshihide Ezoe , Kohzaburoh Yamada , Yasuhiro Kawanishi , Masahiko Taniguchi
IPC分类号： G03C1498
CPC分类号： G03C1/49845
摘要： Disclosed is a thermally processed image recording material containing, on one side of a support having an image-forming layer, a silver salt of an organic acid, a reducing agent and at least one kind of a compound represented by the following formula (1): wherein X and Y represent an electron-withdrawing group and M represents a counter cation, and the conjugate acid of the enolate anion in the formula (1) has a pKa value of 3.0-6.0. This thermally processed image recording material shows low fog, high Dmax, ultrahigh contrast and good storage stability.
摘要翻译：公开了一种热处理图像记录材料，其在具有成像层的载体的一面上包含有机酸的银盐，还原剂和至少一种下式（1）表示的化合物，：其中X和Y表示吸电子基团，M表示抗衡阳离子，式（1）中烯醇化物阴离子的共轭酸的pKa值为3.0-6.0。该热处理图像记录材料具有低雾度，高Dmax，超高对比度和良好的储存稳定性。

2. 发明授权

US06472132B1 Silver halide photographic light-sensitive material and processing method thereof 失效
标题翻译：卤化银照相感光材料及其加工方法
公开(公告)号：US06472132B1
公开(公告)日：2002-10-29
申请号：US09664439
申请日：2000-09-18
申请人： Kohzaburoh Yamada , Hirokazu Kyota , Masahiko Taniguchi , Takashi Hoshimiya , Tetsuo Yamaguchi , Ken-ichi Kuwabara , Toshihide Ezoe
发明人： Kohzaburoh Yamada , Hirokazu Kyota , Masahiko Taniguchi , Takashi Hoshimiya , Tetsuo Yamaguchi , Ken-ichi Kuwabara , Toshihide Ezoe
IPC分类号： G03C106
CPC分类号： G03C7/30511 , G03C1/061
摘要： There is disclosed a silver halide photographic light-sensitive material comprising at least one compound selected from the group consisting of the compounds represented by the following formula (1), (2) or (3): wherein R1 represents a phenyl, aromatic heterocyclic or aliphatic group, having at least one electron-withdrawing group as a substituent, PUG represents a residue of a development inhibitor, Y1 and Z1 respectively represent a substituent which is substitutable on a benzene ring, and n1 and p1 denote integers from 0 to 4, Ar represents an aryl group or an aromatic heterocyclic group, PUG represents a residue of a development inhibitor, TIME represents a timing group and t denotes 0 or 1, A represents a connecting group, m denotes an integer from 2 to 6. According to the silver halide photographic light-sensitive material, an image having excellent photographic properties such as high sensitivity, high contrast (for example, &ggr; is 10 or more) and high Dmax can be formed and it also has good original reproduction in the formation of an image.
摘要翻译：公开了一种卤化银照相感光材料，其包含至少一种选自由下式（1），（2）或（3）表示的化合物的化合物：其中R1表示苯基，芳族杂环或具有至少一个吸电子基团作为取代基的脂族基团，PUG表示显影抑制剂的残基，Y1和Z1分别表示可在苯环上取代的取代基，n1和p1表示0〜4的整数， Ar表示芳基或芳香族杂环基，PUG表示显影抑制剂的残基，TIME表示时基，t表示0或1，A表示连接基，m表示2〜6的整数。根据卤化银照相感光材料，可以形成具有高灵敏度，高对比度（例如，γ为10以上）和高Dmax的优异照相特性的图像，在形成图像时也具有良好的原始再现性。

3. 发明授权

US06521389B2 Silver halide photographic light-sensitive material and processing method thereof 失效
标题翻译：卤化银照相感光材料及其加工方法
公开(公告)号：US06521389B2
公开(公告)日：2003-02-18
申请号：US09925372
申请日：2001-08-10
申请人： Kohzaburoh Yamada , Masahiko Taniguchi , Takashi Hoshimiya , Hirokazu Kyota , Toshihide Ezoe , Shoji Yasuda
发明人： Kohzaburoh Yamada , Masahiko Taniguchi , Takashi Hoshimiya , Hirokazu Kyota , Toshihide Ezoe , Shoji Yasuda
IPC分类号： G03C105
CPC分类号： G03C1/061 , G03C1/035 , G03C5/265 , G03C5/30 , G03C2001/03517 , G03C2001/03541 , G03C2001/108 , G03C2200/44 , G03C2200/52
摘要： A silver halide photographic light-sensitive material, which contains at least one compound of the formula (1): Formula (1) wherein PUG represents a nitrogen-containing heterocyclic group which is bonded to the adjacent carbonyl group through a nitrogen atom, the heterocyclic group directly or indirectly has at least one nitro group as its substituent(s) and can give a pKa value of 9 to 11, ph represents a phenyl group and directly or indirectly has at least one dissociating group as its substituent(s), Z represents a substituent being capable of substitution on the benzene ring, and p is 0 to 4.
摘要翻译：一种卤化银照相感光材料，其含有至少一种式（1）的化合物：式（1）其中PUG表示通过氮原子与相邻羰基键合的含氮杂环基，杂环直接或间接地具有至少一个硝基作为其取代基，并且可以得到pKa值为9至11，ph表示苯基并且直接或间接具有至少一个解离基作为其取代基，Z 表示能够在苯环上取代的取代基，p为0〜4。

4. 发明授权

US06277553B1 Thermographic recording element 失效
标题翻译：热成像记录元件
公开(公告)号：US06277553B1
公开(公告)日：2001-08-21
申请号：US09174105
申请日：1998-10-16
申请人： Masahiko Taniguchi , Kohzaburoh Yamada , Toshihide Ezoe
发明人： Masahiko Taniguchi , Kohzaburoh Yamada , Toshihide Ezoe
IPC分类号： G03C1498
CPC分类号： G03C1/49845 , G03C1/061
摘要： A thermographic recording element having at least one image forming layer contains an organic silver salt, a reducing agent, and a nucleating agent. The element has high Dmax, high sensitivity, satisfactory contrast and minimized black pepper.
摘要翻译：具有至少一个成像层的热成像记录元件含有有机银盐，还原剂和成核剂。该元素具有高Dmax，高灵敏度，令人满意的对比度和最小化的黑胡椒。

5. 发明授权

US06689554B2 Silver handle emulsion and silver halide photographic lightsensitive material 有权
标题翻译：银柄乳液和卤化银照相感光材料
公开(公告)号：US06689554B2
公开(公告)日：2004-02-10
申请号：US10207106
申请日：2002-07-30
申请人： Kohzaburoh Yamada , Masahiko Taniguchi , Naoki Asanuma , Takashi Hoshimiya , Hirokazu Kyota , Masafumi Mizuno
发明人： Kohzaburoh Yamada , Masahiko Taniguchi , Naoki Asanuma , Takashi Hoshimiya , Hirokazu Kyota , Masafumi Mizuno
IPC分类号： G03C112
CPC分类号： G03C1/09 , G03C1/0051 , G03C1/10 , G03C1/12 , G03C2001/0055 , G03C2001/096 , Y10S430/156
摘要： A silver halide emulsion comprises an electron-releasing compound of Types 1 to 4: (Type 1) a compound capable of undergoing a one-electron oxidation (1-EO) to form a one-electron oxidation product (1-EOP), the 1-EOP capable of releasing further two or more electrons accompanying a subsequent bond cleavage reaction, (Type 2) a compound capable of undergoing 1-EO to form 1-EOP, the 1-EOP capable of releasing further one electron accompanying a subsequent bond cleavage reaction, and having, in its molecule, two or more adsorptive groups acting on silver halides, (Type 3) a compound capable of undergoing 1-EO to thereby form 1-EOP, the 1-EOP capable of releasing further one or more electrons after going through a subsequent bond forming process, and (Type 4) a compound capable of undergoing 1-EO to form 1-EOP, the 1-EOP capable of releasing further one or more electrons after going through a subsequent intramolecular ring cleavage reaction.
摘要翻译：卤化银乳剂包含1〜4型的电子发射性化合物：（1型）能够进行单电子氧化（1-EO）的化合物形成单电子氧化产物（1-EOP）的化合物， 1-EOP能够再次释放伴随随后的键断裂反应的两个或更多个电子，（类型2）能够进行1-EO以形成1-EOP的化合物，1-EOP能够进一步释放伴随随后的键的一个电子裂解反应，并且在其分子中具有两个或更多个作用于卤化银的吸附基团（类型3）能够进行1-EO从而形成1-EOP的化合物，所述1-EOP能够进一步释放一个或多个电子经过随后的结合形成过程，和（类型4）能够经历1-EO形成1-EOP的化合物，1-EOP能够在经过随后的分子内环裂解反应后进一步释放一个或多个电子。

6. 发明授权

US06458522B1 Silver halide photographic light-sensitive material and processing method thereof 失效
标题翻译：卤化银照相感光材料及其加工方法
公开(公告)号：US06458522B1
公开(公告)日：2002-10-01
申请号：US09663944
申请日：2000-09-18
申请人： Masahiko Taniguchi , Kohzaburoh Yamada , Ken-ichi Kuwabara , Tetsuo Yamaguchi
发明人： Masahiko Taniguchi , Kohzaburoh Yamada , Ken-ichi Kuwabara , Tetsuo Yamaguchi
IPC分类号： G03C106
CPC分类号： G03C1/067 , G03C1/061
摘要： A silver halide photographic light-sensitive material includes a compound selected from: (1) a quaternary nitrogen or phosphorus salt compound, having 20 or more of total recurring units consisting of an ethyleneoxy group and/or a propyleneoxy group; (2) a quaternary salt compound represented by formula (A): wherein Q represents nitrogen or phosphorus, R1, R2 and R3 represent an alkyl, aryl, alkenyl, alkynyl, or heterocyclic group, L1 represents an alkylene group, Y represents —C(═O) or —SO2—, L2 represents a divalent connecting group having at least one hydrophilic group, Xn− represents an n-valent counter anion, n being an integer of 1 to 3; and (3) a quaternary salt compound represented by formula (B): wherein A represents an organic moiety necessary to complete a nitrogen-containing aromatic heterocyclic ring. L2 represents a divalent connecting group having at least one hydrophilic group that divides L2. L1, Y and Xn− have the same meanings as above.
摘要翻译：卤化银摄影感光材料包括选自以下的化合物：（1）具有20个或更多个由乙烯氧基和/或丙烯氧基组成的总重复单元的季氮或磷盐化合物;（2）四由式（A）表示的盐化合物：其中Q表示氮或磷，R 1，R 2和R 3表示烷基，芳基，烯基，炔基或杂环基，L 1表示亚烷基，Y表示-C（= O）或 -SO 2 - ，L 2表示具有至少一个亲水基团的二价连接基团，Xn-表示n价抗衡阴离子，n为1〜3的整数，和（3）由式（B）表示的季盐化合物：其中A表示完成含氮芳族杂环所必需的有机部分。 L2表示具有至少一个分隔L2的亲水基团的二价连接基团。 L1，Y和Xn-具有与上述相同的含义。

7. 发明授权

US06358677B1 Heat-developable recording material 有权
标题翻译：热显影记录材料
公开(公告)号：US06358677B1
公开(公告)日：2002-03-19
申请号：US09528450
申请日：2000-03-17
申请人： Masahiko Taniguchi , Katsuyuki Watanabe , Shigeo Hirano , Minoru Sakai
发明人： Masahiko Taniguchi , Katsuyuki Watanabe , Shigeo Hirano , Minoru Sakai
IPC分类号： G03C1498
CPC分类号： G03C1/49845
摘要： A heat-developable recording material having, at least on one side and the same side of the support, (a) reducible silver salt, (b) a reducing agent other than a compound represented by the general formula (1) below, (c) a binder, and (d) at least one compound represented by the general formula (1) below; content of the compound represented by the general formula (1) being 0.01 to 100 mol % with respect to the reducing agent: [where in the general formula (1), R1, R2, R3, X1 and X2 independently represent a hydrogen atom; halogen atom; or substituent which is bound to the benzene ring via a carbon atom, oxygen atom, nitrogen atom, sulfur atom or phosphorus atom. At least either X1 or X2 represents a group represented as —NR4R5, where R4 and R5 independently represent a group selected from a hydrogen atom, alkyl group and the like.]
摘要翻译：（a）可还原银盐，（b）除了下述通式（1）表示的化合物以外的还原剂，（c）的可热显影记录材料，至少在一个侧面和同一侧上，（c））粘合剂，和（d）至少一种由下述通式（1）表示的化合物; 通式（1）表示的化合物的含量相对于还原剂为0.01〜100摩尔％[其中，在通式（1）中，R 1，R 2，R 3，X 1和X 2独立地表示氢原子; 卤素原子; 或通过碳原子，氧原子，氮原子，硫原子或磷原子与苯环结合的取代基。 X 1或X 2中至少有一个表示为-NR 4 R 5的基团，其中R 4和R 5独立地表示选自氢原子，烷基等的基团。

8. 发明授权

US08703935B2 Method of producing a metal phthalocyanine compound, and method of producing a phthalocyanine compound and an analogue thereof 有权
标题翻译：金属酞菁化合物的制造方法以及酞菁类化合物的制造方法及其类似物
公开(公告)号：US08703935B2
公开(公告)日：2014-04-22
申请号：US13620046
申请日：2012-09-14
申请人： Keiichi Tateishi , Masahiko Taniguchi , Hideo Hanawa , Nobuo Seto , Kazufumi Omura
发明人： Keiichi Tateishi , Masahiko Taniguchi , Hideo Hanawa , Nobuo Seto , Kazufumi Omura
IPC分类号： C07D487/22 , C07B47/00
CPC分类号： C07D487/22 , C09B47/063 , C09B47/0675
摘要： A method of producing a metal phthalocyanine compound, which contains: conducting a reaction between at least two compounds selected from among Compounds A to F of formula (I), and a metal compound, in a buffer solution of an organic base or an inorganic base and an acid, in the presence of a dehydrating agent: wherein R is a hydrogen atom or a substituent; 1 is an integer of 0 to 4; a plurality of Rs may be the same or different from each other when 1 is 2 to 4; and G is a group of atoms necessary for forming at least one of a 5- or 6-membered aromatic ring and a 5- or 6-membered hetero ring.
摘要翻译：一种制备金属酞菁化合物的方法，其包含：在有机碱或无机碱的缓冲溶液中，在选自式（I）的化合物A至F中的至少两种化合物和金属化合物之间进行反应和一种酸，在脱水剂存在下，其中R是氢原子或取代基; 1为0〜4的整数，当1为2〜4时，多个Rs可以相同或不同; 并且G是形成5-或6-元芳环和5-或6-元杂环中的至少一个所必需的一组原子。

9. 发明授权

US08299240B2 Method of producing a metal phthalocyanine compound, and method of producing a phthalocyanine compound and an analogue thereof 有权
标题翻译：金属酞菁化合物的制造方法以及酞菁类化合物的制造方法及其类似物
公开(公告)号：US08299240B2
公开(公告)日：2012-10-30
申请号：US12088412
申请日：2006-05-17
申请人： Keiichi Tateishi , Masahiko Taniguchi , Hideo Hanawa , Nobuo Seto , Kazufumi Omura
发明人： Keiichi Tateishi , Masahiko Taniguchi , Hideo Hanawa , Nobuo Seto , Kazufumi Omura
IPC分类号： C07D487/22 , C07B47/00
CPC分类号： C07D487/22 , C09B47/063 , C09B47/0675
摘要： A method of producing a metal phthalocyanine compound, which contains: conducting a reaction between at least two compounds selected from among Compounds A to F of formula (I), and a metal compound, in a buffer solution of an organic base or an inorganic base and an acid, in the presence of a dehydrating agent: wherein R is a hydrogen atom or a substituent; l is an integer of 0 to 4; a plurality of Rs may be the same or different from each other when l is 2 to 4; and G is a group of atoms necessary for forming at least one of a 5- or 6-membered aromatic ring and a 5- or 6-membered hetero ring.
摘要翻译：一种制备金属酞菁化合物的方法，其包含：在有机碱或无机碱的缓冲溶液中，在选自式（I）的化合物A至F中的至少两种化合物和金属化合物之间进行反应和一种酸，在脱水剂存在下，其中R是氢原子或取代基; l为0〜4的整数; 当l为2〜4时，多个Rs可以相同或不同; 并且G是形成5-或6-元芳环和5-或6-元杂环中的至少一个所必需的一组原子。

10. 发明授权

US08110597B2 Radioactive isotope-labeled dye compound 失效
标题翻译：放射性同位素标记的染料化合物
公开(公告)号：US08110597B2
公开(公告)日：2012-02-07
申请号：US11925228
申请日：2007-10-26
申请人： Masahiko Taniguchi , Junji Nishigaki
发明人： Masahiko Taniguchi , Junji Nishigaki
IPC分类号： A61K31/40 , C07D209/02
CPC分类号： C07D209/14 , C07D209/96 , C07D401/14 , C07D403/14 , C09B23/0008 , C09B23/0016 , C09B23/0025 , C09B23/0033 , C09B23/0041 , C09B23/0066 , C09B23/06 , C09B23/086
摘要： A radioactive isotope-labeled dye compound represented by the following general formula (I): wherein R1 and R2 represent a substituent, R3 to R6 represent a substituted or unsubstituted alkyl group; R7 and R8 represent a substituted or unsubstituted alkyl group; L1 to L3 represent a substituted or unsubstituted methine group; r represents an integer of 0 to 3; P and Q represent 123I, 124I, 125I, 131I or 18F; M represents hydrogen atom, Na, or K; and m and n represent an integer of 0 to 2.
摘要翻译：由以下通式（I）表示的放射性同位素标记的染料化合物：其中R1和R2表示取代基，R3至R6表示取代或未取代的烷基; R7和R8表示取代或未取代的烷基; L1至L3表示取代或未取代的次甲基; r表示0〜3的整数， P和Q表示123I，124I，125I，131I或18F; M表示氢原子，Na或K; m和n表示0〜2的整数。

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