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    • 2. 发明申请
    • POLISHING COMPOUND AND POLISHING METHOD
    • 抛光复合和抛光方法
    • US20090140199A1
    • 2009-06-04
    • US12277468
    • 2008-11-25
    • Hiroyuki KAMIYAKatsuyuki TSUGITA
    • Hiroyuki KAMIYAKatsuyuki TSUGITA
    • C09K13/00
    • C09G1/02C09K3/1409C09K3/1463H01L21/3212H05K3/045H05K3/107H05K2201/0209H05K2203/025H05K2203/0796
    • To provide a polishing compound which can satisfy both high removal rate of an object to be polished and excellent property to eliminate the difference in level, and to provide a polishing method which can polish a wiring metal fast while suppressing increase of a wiring metal resistance and is excellent in the property to eliminate the difference in level.A polishing compound which comprises abrasive particles, an oxidizing agent, ammonium ions, polyvalent carboxylate ions, at least one chelating agent selected from the group consisting of pentaethylenehexamine, triethylenetetramine and tetraethylenepentamine, and an aqueous medium. Further, a polishing method of polishing a wiring metal 3 by using the polishing compound, after providing a wiring trench 2 on a resin substrate 1 and embedding the wiring metal 3 in the wiring trench 2.
    • 为了提供能够满足被研磨对象物的高去除率和优异性能以消除水平差的抛光化合物,并且提供能够在抑制布线金属电阻增加的同时快速抛光布线金属的抛光方法,以及 在物业上是优秀的,以消除差距的水平。 一种抛光剂,其包含磨粒,氧化剂,铵离子,多价羧酸根离子,选自五亚乙基六胺,三亚乙基四胺和四亚乙基五胺中的至少一种螯合剂和水性介质。 另外,在将树脂基板1上配置布线沟槽2并且将布线金属3嵌入布线槽2中之后,通过使用研磨用化合物研磨布线金属3的研磨方法。
    • 3. 发明申请
    • POLISHING COMPOUND AND POLISHING METHOD
    • 抛光复合和抛光方法
    • US20080272088A1
    • 2008-11-06
    • US12025156
    • 2008-02-04
    • Hiroyuki KAMIYAKatsuyuki Tsugita
    • Hiroyuki KAMIYAKatsuyuki Tsugita
    • B44C1/22C09K13/00
    • H05K3/045C09G1/02C09K3/1463H01L21/3212H05K3/107H05K3/26H05K2201/0209H05K2203/025H05K2203/0786
    • To provide a polishing compound that is capable of minimizing formation of scratches on an object to be polished, such as a resin substrate or a metal wiring, and polishing at a high removal rate. To further provide a polishing method that is capable of minimizing formation of scratches on a resin substrate or a metal wiring, and improving the throughput.The polishing compound T comprises an oxidizing agent, an electrolyte and an aqueous medium, wherein ions formed from the electrolyte comprise ammonium ions, at least one type of organic carboxylate ions selected from the group consisting of polycarboxylate ions and hydroxycarboxylate ions, and at least one type of ions selected from the group consisting of carbonate ions, hydrogencarbonate ions, sulfate ions and acetate ions.A wiring trench 2 is formed in a resin substrate 1, then a wiring metal 3 is embedded in the wiring trench 2, and the wiring metal 3 is polished by using the above-mentioned polishing compound, whereby it is possible to minimize formation of scratches on the metal wiring 3 and to improve the throughput.
    • 提供能够最小化待研磨物体(例如树脂基板或金属布线)上的划痕的形成的抛光剂,以高的去除率进行研磨。 为了进一步提供能够最小化在树脂基板或金属布线上形成划痕并且提高生产量的抛光方法。 抛光化合物T包括氧化剂,电解质和水性介质,其中由电解质形成的离子包含铵离子,至少一种选自聚羧酸根离子和羟基羧酸根离子的有机羧酸根离子,以及至少一种 选自碳酸根离子,碳酸氢根离子,硫酸根离子和乙酸根离子的离子类型。 在树脂基板1上形成布线沟槽2,然后将布线金属3埋设在布线沟槽2中,并且通过使用上述抛光剂对布线金属3进行研磨,从而可以最小化划痕的形成 并且提高生产量。
    • 4. 发明申请
    • POLISHING COMPOUND, ITS PRODUCTION PROCESS AND POLISHING METHOD
    • 抛光化合物,其生产工艺和抛光方法
    • US20100009540A1
    • 2010-01-14
    • US12564169
    • 2009-09-22
    • Hiroyuki KAMIYAKatsuyuki Tsugita
    • Hiroyuki KAMIYAKatsuyuki Tsugita
    • H01L21/304
    • C09K3/1463
    • A polishing compound for chemical mechanical polishing of a substrate, which comprises (A) abrasive grains, (B) an aqueous medium, (C) tartaric acid, (D) trishydroxymethylaminomethane and (E) at least one member selected from the group consisting of malonic acid and maleic acid, and more preferably, which further contains a compound having a function to form a protective film on the wiring metal surface to prevent dishing at the wiring metal portion, such as benzotriazole. By use of this polishing compound, the copper wirings on the surface of a semiconductor integrated circuit board can be polished at a high removal rate while suppressing formation of scars as defects in a polishing step. Particularly in a first polishing step of polishing copper wirings having a film made of tantalum or a tantalum compound as a barrier film, excellent selectivity will be obtained, dishing and erosion due to polishing are less likely to occur, and an extremely high precision flat surface of a semiconductor integrated circuit board can be obtained.
    • 一种用于基材的化学机械抛光的抛光剂,其包含(A)磨粒,(B)水性介质,(C)酒石酸,(D)三羟甲基氨基甲烷和(E)至少一种选自 丙二酸和马来酸,更优选还含有具有在布线金属表面上形成保护膜的功能的化合物,以防止布线金属部分如苯并三唑的凹陷。 通过使用该研磨用化合物,半导体集成电路基板的表面的铜布线能够以高的去除率进行抛光,同时抑制疤痕的形成,作为研磨工序的缺陷。 特别是在具有由钽或钽化合物制成的膜作为阻挡膜的铜布线的研磨的第一研磨步骤中,可以获得极好的选择性,因此不太可能发生由于抛光引起的凹陷和侵蚀,并且极高的精密平面 可以获得半导体集成电路板。