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    • 4. 发明授权
    • Negative type photoresist composition used for light beam with short
wavelength and method of forming pattern using the same
    • 用于短波长光束的负型光致抗蚀剂组合物及其形成方法
    • US6140010A
    • 2000-10-31
    • US140650
    • 1998-08-26
    • Shigeyuki IwasaKatsumi MaedaKaichiro NakanoEtsuo Hasegawa
    • Shigeyuki IwasaKatsumi MaedaKaichiro NakanoEtsuo Hasegawa
    • G03F7/004G03F7/033G03F7/038H01L21/027
    • G03F7/038G03F7/0045
    • A negative type photoresist composition includes a polymer which contains a repetition unit which is expressed by a general chemical formula (1) and has a weight average molecule weight in a range of 1000 to 500000, a crosslinker composed of a compound which contains a functional group which is expressed by a general chemical formula (2), and a photo-acid generator which generates acid in response to a light. The general chemical formula (1) is as follows, ##STR1## where in the general chemical formula (1), R.sup.1 is a hydrogen atom or a methyl group, R.sup.2 is an alkylene group containing carbon atoms in a range of 7 to 18 and having a bridged cyclic hydrocarbon group. Also, the general chemical formula (2) is as follows, ##STR2## In the general chemical formula (2), X is a group expressed by a general chemical formula (3), a hydrogen atom, a hydrocarbon group containing carbon atoms in a range of 1 to 6, an alkoxy group containing carbon atoms in a range of 1 to 3, or a hydroxyl group, a1, a2 and a3 are 1 or 2, respectively, b1, b2 and b3 are 0 or 1, respectively, and a1+b1=2, a2+b2=2, and a3+b3=2, and R.sup.8 is a hydrogen atom, or an alkyl group containing carbon atoms in a range of 1 to 6. ##STR3##
    • 负型光致抗蚀剂组合物包括含有由通式(1)表示的重复单元,重均分子量为1000〜500000的聚合物,由含有官能团的化合物构成的交联剂 其由一般化学式(2)表示,光生酸剂响应于光而产生酸。 一般化学式(1)如下,其中在通式(1)中,R 1为氢原子或甲基,R 2为碳原子数为7〜18的亚烷基,桥连 环状烃基。 另外,通式(2)中,通式(2)中,X为通式(3)表示的基团,氢原子,碳原子数为 1〜6中,碳原子数1〜3的烷氧基或羟基a1,a2,a3分别为1或2,b1,b2和b3分别为0或1,a1 + b1 = 2,a2 + b2 = 2,a3 + b3 = 2,R8为氢原子或碳原子数为1〜6的烷基。