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1. 发明授权

US5387575A Pyrimidine derivatives, process for preparing the same and herbicide using the same 失效
标题翻译：嘧啶衍生物，其制备方法和使用其的除草剂
公开(公告)号：US5387575A
公开(公告)日：1995-02-07
申请号：US894557
申请日：1992-06-05
申请人： Katsumasa Harada , Takaaki Abe , Yuji Akiyoshi , Akio Matsushita , Mikio Kojima , Ikuo Shiraishi , Kaoru Yamamoto , Takashi Hayama , Shohei Fukuda
发明人： Katsumasa Harada , Takaaki Abe , Yuji Akiyoshi , Akio Matsushita , Mikio Kojima , Ikuo Shiraishi , Kaoru Yamamoto , Takashi Hayama , Shohei Fukuda
IPC分类号： A01N43/54 , A01N43/66 , C07D239/60 , C07D251/30 , C07D251/38 , C07D521/00 , C07D239/52 , A01N73/54
CPC分类号： C07D231/12 , A01N43/54 , A01N43/66 , C07D233/56 , C07D239/60 , C07D249/08 , C07D251/30 , C07D251/38
摘要： Disclosed are a pyrimidine or triazine compound represented by the following formula (I): ##STR1## wherein R.sup.1 represents cyano group, a halogen atom, hydroxy group or --O--R.sup.7 where R.sup.7 represents a lower alkyl group, a lower alkenyl group, a lower alkynyl group, a halo-lower alkyl group or a cyano-lower alkyl group; R.sup.2 represents hydrogen atom or a lower alkyl group; R.sup.3 represents hydrogen atom or a lower alkyl group; R.sup.4 represents a 1-imidazolyl group, --NHSO.sub.2 --R.sup.8 where R.sup.8 represents a lower alkyl group or a phenyl group which may have a substituent, hydroxy group, a lower alkoxy group or a benzyloxy group when Z is nitrogen atom; or a 1-imidazolyl group, --NHSO.sub.2 --R.sup.8 where R.sup.8 has the same meaning as defined above, hydroxy group, OK, a lower alkoxy group which may have a substituent, a lower alkenyloxy group, a lower alkynyloxy group, a cycloalkoxy group which may have a substituent, a phenoxy group, a benzyloxy group, a lower alkylthio group, a phenylthio group or an alkylsulfonylamino group when Z is --CH.dbd. group; R.sup.5 represents a lower alkoxy group; R.sup.6 represents a lower alkoxy group or a lower alkyl group; X represents oxygen atom or sulfur atom; and Z represents nitrogen atom or --CH.dbd. group. processes for preparing the same and a herbicide containing the same as an active ingredient(s).
摘要翻译：公开了由下式（I）表示的嘧啶或三嗪化合物：其中R 7表示低级烷基，低级烯基，低级炔基，卤代烷基，低级烷基或氰基 - 低级烷基; R2代表氢原子或低级烷基; R3表示氢原子或低级烷基; R 4表示当Z为氮原子时，可以具有取代基，羟基，低级烷氧基或苄氧基的低级烷基或苯基，-NHSO 2 -R 8，或1-咪唑基，-NHSO 2 -R 8，其中R8具有与上述相同的含义，羟基，OK，可具有取代基的低级烷氧基，低级链烯氧基，低级炔氧基，环烷氧基当Z为-CH =基团时，可具有取代基，苯氧基，苄氧基，低级烷硫基，苯硫基或烷基磺酰基氨基; R5代表低级烷氧基; R6代表低级烷氧基或低级烷基; X表示氧原子或硫原子; Z表示氮原子或-CH =基团。其制备方法和含有其作为活性成分的除草剂。

2. 发明授权

US5529977A Triazine derivative, process for preparing the same and herbicide using the same 失效
标题翻译：三嗪衍生物，其制备方法和使用其的除草剂
公开(公告)号：US5529977A
公开(公告)日：1996-06-25
申请号：US326830
申请日：1994-10-21
申请人： Katsumasa Harada , Takaaki Abe , Yuji Akiyoshi , Akio Matsushita , Mikio Kojima , Ikuo Shiraishi , Kaoru Yamamoto , Takashi Hayama
发明人： Katsumasa Harada , Takaaki Abe , Yuji Akiyoshi , Akio Matsushita , Mikio Kojima , Ikuo Shiraishi , Kaoru Yamamoto , Takashi Hayama
IPC分类号： A01N43/54 , A01N43/66 , C07D239/60 , C07D251/30 , C07D251/38 , C07D521/00 , C07D251/34 , C07D251/16 , C07D403/12
CPC分类号： C07D231/12 , A01N43/54 , A01N43/66 , C07D233/56 , C07D239/60 , C07D249/08 , C07D251/30 , C07D251/38
摘要： Disclosed are a pyrimidine or triazine compound represented by the following formula (I): ##STR1## wherein R.sup.1 represents cyano group, a halogen atom, hydroxy group or --O--R.sup.7 where R.sup.7 represents a lower alkyl group, a lower alkenyl group, a lower alkynyl group, a halo-lower alkyl group or a cyano-lower alkyl group; R.sup.2 represents hydrogen atom or a lower alkyl group; R.sup.3 represents hydrogen atom or a lower alkyl group; R.sup.4 represents a 1-imidazolyl group, --NHSO.sub.2 --R.sup.8 where R.sup.8 represents a lower alkyl group or a phenyl group which may have a substituent, hydroxy group, a lower alkoxy group or a benzyloxy group when Z is nitrogen atom; or a 1-imidazolyl group, --NHSO.sub.2 --R.sup.8 where R.sup.8 has the same meaning as defined above, hydroxy group, OK, a lower alkoxy group which may have a substituent, a lower alkenyloxy group, a lower alkynyloxy group, a cycloalkoxy group which may have a substituent, a phenoxy group, a benzyloxy group, a lower alkylthio group, a phenylthio group or an alkylsulfonylamino group when Z is --CH.dbd. group; R.sup.5 represents a lower alkoxy group; R.sup.6 represents a lower alkoxy group or a lower alkyl group; X represents oxygen atom or sulfur atom; and Z represents nitrogen atom or --CH.dbd. group.processes for preparing the same and a herbicide containing the same as an active ingredient(s).
摘要翻译：公开了由下式（I）表示的嘧啶或三嗪化合物：其中R 1表示氰基，卤素原子，羟基或-O-R 7，其中R 7表示低级烷基，低级烯基基，低级炔基，卤代低级烷基或氰基 - 低级烷基; R2表示氢原子或低级烷基; R3表示氢原子或低级烷基; R 4表示当Z为氮原子时，可以具有取代基，羟基，低级烷氧基或苄氧基的低级烷基或苯基，-NHSO 2 -R 8，或1-咪唑基，-NHSO 2 -R 8，其中R8具有与上述相同的含义，羟基，OK，可具有取代基的低级烷氧基，低级链烯氧基，低级炔氧基，环烷氧基当Z为-CH =基团时，可具有取代基，苯氧基，苄氧基，低级烷硫基，苯硫基或烷基磺酰基氨基; R5代表低级烷氧基; R6代表低级烷氧基或低级烷基; X表示氧原子或硫原子; Z表示氮原子或-CH =基团。其制备方法和含有其作为活性成分的除草剂。

3. 发明授权

US5994553A Method for preparing 2-mercaptothiazole 失效
标题翻译： 2-巯基噻唑的制备方法
公开(公告)号：US5994553A
公开(公告)日：1999-11-30
申请号：US211446
申请日：1998-12-15
申请人： Katsumasa Harada , Akio Matsushita , Taku Nakamura , Katsuhiko Mizutare , Takafumi Hirakawa , Ken Ikuno , Noriaki Iwase
发明人： Katsumasa Harada , Akio Matsushita , Taku Nakamura , Katsuhiko Mizutare , Takafumi Hirakawa , Ken Ikuno , Noriaki Iwase
IPC分类号： C07D277/20 , C07D277/36
CPC分类号： C07D277/36
摘要： Disclosed is a method for preparing 2-mercaptothiazole, which comprises adding a dithiocarbamate salt represented by the formula (1): ##STR1## wherein M is a cation, to a chloroacetaldehyde solution in the presence of an acid.
摘要翻译：公开了一种2-巯基噻唑的制备方法，该方法包括在酸存在下，向氯乙醛溶液中加入由式（1）表示的二硫代氨基甲酸盐：其中M为阳离子。

4. 发明授权

US5677455A Preparation of 3-oxy-5-oxo-6-heptenoic acid derivatives 失效
标题翻译： 3-氧基-5-氧代-6-庚烯酸衍生物的制备
公开(公告)号：US5677455A
公开(公告)日：1997-10-14
申请号：US524045
申请日：1995-09-06
申请人： Katsumasa Harada , Akio Matsushita , Yasuhiro Kawachi , Hiroshi Sasaki
发明人： Katsumasa Harada , Akio Matsushita , Yasuhiro Kawachi , Hiroshi Sasaki
IPC分类号： C07F7/18 , C07F7/02 , C07D213/30
CPC分类号： C07F7/1852 , C07F7/1856 , C07F7/1892
摘要： Methyl (3R,6E)-3-�(tert-butyldimethylsilyl)oxy!-7-�2',6'-diisopropyl-4'-(4"-fluorophenyl)-5'-(methoxymethyl)pyridin-3'-yl!-5-oxy-6-heptenoate or other 3-oxy-5-oxo-6-heptenoic acid derivative is prepared by the reaction of an aromatic aldehyde and an oxyglutaric acid derivative in an aliphatic alcohol containing a small amount of water in the presence of an alkali metal carbonate or hydrogen carbonate.
摘要翻译：将（3R，6E）-3 - [（叔丁基二甲基甲硅烷基）氧基] -7- [2'，6'-二异丙基-4' - （4“ - 氟苯基）-5' - （甲氧基甲基） - 基] -5-氧基-6-庚烯酸乙酯或其它3-氧基-5-氧代-6-庚烯酸衍生物通过芳族醛和羟基戊二酸衍生物在含少量水的脂族醇中的反应来制备在碱金属碳酸盐或碳酸氢盐存在下进行。

5. 发明授权

US5457225A Process for preparation of 5-hydroxy-3-ketoester derivative and optically active substance thereof 失效
标题翻译： 5-羟基-3-酮酯衍生物及其光学活性物质的制备方法
公开(公告)号：US5457225A
公开(公告)日：1995-10-10
申请号：US302342
申请日：1994-09-07
申请人： Nobuki Oguni , Masahiko Hayashi , Katsumasa Harada , Akio Matsushita
发明人： Nobuki Oguni , Masahiko Hayashi , Katsumasa Harada , Akio Matsushita
IPC分类号： C07C67/46 , C07C69/716 , C07C69/76 , C07C69/66
CPC分类号： C07C69/716 , C07C67/46
摘要： Disclosed is a process for the preparation of a 5-hydroxy-3-ketoester derivative of the formula: ##STR1## in which R.sup.1 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group or a heterocyclic group, and R.sup.2 represents an alkyl group or an aryl group, which comprises causing the reaction of an aldehyde compound of the formula R.sup.1 CHO in which R.sup.1 has the meanings as defined above and diketene in the presence of a metal compound selected from a titanium or aluminum compound having at least one group of --OR.sup.3 in which R.sup.3 represents an alkyl group or an aryl group. Further, a process for the preparation of an optically active substance of the 5-hydroxy-3-ketoester derivative causing the reaction of the above compounds in the presence of the metal compound and optically active Schiff base or a complex compound obtained by reacting the metal compound with the optically active Schiff base, also is disclosed.
摘要翻译：公开了制备下式的5-羟基-3-酮酯衍生物的方法：其中R 1表示烷基，烯基，炔基，芳基或杂环基，R 2 表示烷基或芳基，其包括在选自具有至少具有上述含义的钛或铝化合物的金属化合物的存在下使式R 1 CHO的醛化合物与其中R 1具有如上所定义的二烯酮反应一组-OR 3，其中R 3表示烷基或芳基。此外，制备5-羟基-3-酮酯衍生物的光学活性物质的方法，其导致上述化合物在金属化合物和光学活性席夫碱存在下的反应或通过使金属与光学活性席夫碱的化合物也被公开。

6. 发明授权

US5717124A Process for preparation of oxyglutaric acid ester derivatives 失效
标题翻译：氧戊二酸酯衍生物的制备方法
公开(公告)号：US5717124A
公开(公告)日：1998-02-10
申请号：US539173
申请日：1995-10-04
申请人： Katsumasa Harada , Akio Matsushita , Hiroshi Sasaki , Yasuhiro Kawachi
发明人： Katsumasa Harada , Akio Matsushita , Hiroshi Sasaki , Yasuhiro Kawachi
IPC分类号： C07F9/40 , C07F9/53 , C07F7/08
CPC分类号： C07F9/4006 , C07F9/5304 , Y02P20/55
摘要： A process for preparing an oxyglutaric acid ester derivative of the formula: ##STR1## in which each of R.sup.1 and R.sup.2 is C.sub.1-5 alkoxy, C.sub.1-7 aralkyloxy, C.sub.7-9 halogenated aralkyloxy or phenyl, R.sup.4 is a hydroxyl-protecting group, and R.sup.5 is C.sub.1-10 alkyl which may have a substituent, comprises the steps of reacting a methyl phosphonate derivative or methyl phosphine oxide derivative with an oxyglutaric acid mono-ester to give a reaction product which comprises an oxyglutaric acid derivative having a phosphorus-containing group and a pentenedioic acid mono-ester (by-product), removing the pendenedioic acid mono-ester from the reaction product to isolate the oxyglutaric acid derivative, and converting the isolated oxyglutaric acid derivative into the oxyglutaric acid ester derivative. A process for obtaining an optically active oxyglutaric acid ester derivative is also disclosed.
摘要翻译：制备下式的其中R 1和R 2各自为C 1-5烷氧基，C 1-7芳烷氧基，C 7-9卤代芳烷基氧基或苯基的下式的下式的下列通式： R5是可以具有取代基的C1-10烷基，包括使甲基膦酸酯衍生物或甲基氧化膦衍生物与羟基戊二酸单酯反应，得到含有含磷的羟基戊二酸衍生物的反应产物基和戊烯二酸单酯（副产物），从反应产物中除去邻苯二甲酸单酯以分离出氧戊二酸衍生物，并将分离的羟基戊二酸衍生物转化为羟基戊二酸酯衍生物。还公开了获得光学活性的羟基戊二酸酯衍生物的方法。

7. 发明授权

US5892126A Process for preparing 4-fluoro-3-trifluoromethylphenol 失效
标题翻译：制备4-氟-3-三氟甲基苯酚的方法
公开(公告)号：US5892126A
公开(公告)日：1999-04-06
申请号：US969692
申请日：1997-11-13
申请人： Katsumasa Harada , Akio Matsushita , Yasuhiro Kawachi
发明人： Katsumasa Harada , Akio Matsushita , Yasuhiro Kawachi
IPC分类号： C07C39/26 , C07C39/24
CPC分类号： C07C39/26
摘要： Disclosed is a process for preparing 4-fluoro-3-trifluoromethylphenol from 4-fluoro-3-trifluoromethylaniline, which comprises the steps of (1) using about 1 to 20 parts by weight of water based on 1 part by weight of 4-fluoro-3-trifluoromethylaniline in the presence of sulfuric acid to obtain 4-fluoro-3-trifluoromethylaniline sulfate; (2) subjecting the obtained 4-fluoro-3-trifluoromethylaniline sulfate to a diazotization reaction by using a diazotizing agent to obtain an aqueous solution containing about 8 to 25% by weight of a 4-fluoro-3-trifluoromethylbenzene-diazonium salt where a sulfuric acid concentration after diazotization is about 30 to 70% by weight in terms of the amount of sulfuric acid added, and the amount of water used is about 1 to 20 parts by weight based on 1 part by weight of 4-fluoro-3-trifluoromethylaniline; and (3) hydrolyzing the obtained 4-fluoro-3-trifluoromethylbenzenediazonium salt where a sulfuric acid concentration is about 30 to 70% by weight in terms of the amount of sulfuric acid added in a copper sulfate aqueous solution.
摘要翻译：公开了从4-氟-3-三氟甲基苯胺制备4-氟-3-三氟甲基苯酚的方法，其包括以下步骤：（1）使用约1至20重量份的水，基于1重量份的4-氟 -3-三氟甲基苯胺在硫酸存在下反应，得到4-氟-3-三氟甲基苯胺硫酸盐; （2）通过使用重氮化试剂使得到的4-氟-3-三氟甲基苯胺硫酸盐进行重氮化反应，得到含有约8-25重量％的4-氟-3-三氟甲基苯 - 重氮盐的水溶液，其中重氮化后的硫酸浓度以加入的硫酸的量计为约30〜70重量％，相对于1重量份的4-氟-3-甲基丙烯酸，使用的水的量为约1〜20重量份，三氟甲基苯胺; 和（3）水解所得到的硫酸浓度为硫酸铜水溶液中加入的硫酸的量的约30〜70重量％的4-氟-3-三氟甲基苯二氮鎓盐。

8. 发明授权

US5744604A Preparation of 3-oxy-5-oxo-6-heptenoic acid derivatives 失效
标题翻译： 3-氧基-5-氧代-6-庚烯酸衍生物的制备
公开(公告)号：US5744604A
公开(公告)日：1998-04-28
申请号：US858937
申请日：1997-05-20
申请人： Katsumasa Harada , Akio Matsushita , Yasuhiro Kawachi , Hiroshi Sasaki
发明人： Katsumasa Harada , Akio Matsushita , Yasuhiro Kawachi , Hiroshi Sasaki
IPC分类号： C07F7/18 , C07F7/02
CPC分类号： C07F7/1852 , C07F7/1856 , C07F7/1892
摘要： Methyl (3R, 6E)-3-�(tert-butyldimethylsilyl)oxy!-7-�2', 6'-diisopropyl-4'-(4"-fluorophenyl)-5'-(methoxymethyl)pyridin-3'-yl!-5-oxy-6-heptenoate or other 3-oxy-5-oxo-6-heptenoic acid derivative is prepared by the reaction of an aromatic aldehyde and an oxyglutaric acid derivative in an aliphatic alcohol containing a small amount of water in the presence of an alkali metal carbonate or hydrogen carbonate.
摘要翻译：将（3R，6E）-3 - [（叔丁基二甲基甲硅烷基）氧基] -7- [2'，6'-二异丙基-4' - （4“ - 氟苯基）-5' - （甲氧基甲基） - 基] -5-氧基-6-庚烯酸乙酯或其它3-氧基-5-氧代-6-庚烯酸衍生物通过芳族醛和羟基戊二酸衍生物在含少量水的脂族醇中的反应来制备在碱金属碳酸盐或碳酸氢盐存在下进行。

9. 发明申请

US20140154510A1 FILM STRUCTURE AND METHOD FOR PRODUCING SAME 审中-公开
标题翻译：电影结构及其制作方法
公开(公告)号：US20140154510A1
公开(公告)日：2014-06-05
申请号：US14131197
申请日：2012-07-04
申请人： Akihiro Odagawa , Akio Matsushita , Nozomu Matsukawa
发明人： Akihiro Odagawa , Akio Matsushita , Nozomu Matsukawa
IPC分类号： H01L29/16 , C23C14/08 , C23C14/06 , C23C14/35
CPC分类号： H01L29/1606 , B82Y10/00 , B82Y40/00 , C23C14/06 , C23C14/0694 , C23C14/081 , C23C14/3407 , C23C14/352 , H01L21/02175 , H01L21/02266 , H01L43/08 , Y10T428/30
摘要： A film structure (carbon material-insulating film structure) of the present invention includes a carbon material and an insulating film disposed on the carbon material and composed of fluorine-added magnesium oxide. The amount of added fluorine in the magnesium oxide is 0.0049 atomic percent or more and 0.1508 atomic percent or less. This film structure facilitates the realization of an electronic device, such as a spin device, which uses a carbon material such as graphene. This film structure is formed, for example, by sputtering using a target containing magnesium oxide and magnesium fluoride.
摘要翻译：本发明的膜结构（碳材料绝缘膜结构）包括碳材料和设置在碳材料上并由含氟氧化镁构成的绝缘膜。氧化镁中的氟的添加量为0.0049原子％以上且0.1508原子％以下。该薄膜结构有助于实现诸如石墨烯之类的碳材料的诸如旋转装置的电子装置。该膜结构例如通过使用含有氧化镁和氟化镁的靶进行溅射而形成。

10. 发明授权

US07816528B2 Preparation of aminopyrimidine compounds 有权
标题翻译：氨基嘧啶化合物的制备
公开(公告)号：US07816528B2
公开(公告)日：2010-10-19
申请号：US11933626
申请日：2007-11-01
申请人： Akio Matsushita , Mizuho Oda , Yasuhiro Kawachi , Jun-ichi Chika
发明人： Akio Matsushita , Mizuho Oda , Yasuhiro Kawachi , Jun-ichi Chika
IPC分类号： C07D239/34 , C07D239/22 , C07D239/42 , A61K31/505 , A61P3/06
CPC分类号： C07D239/22 , C07D239/30 , C07D239/34 , C07D239/36 , C07D239/42
摘要： A 2-(N-methyl-N-methanesulfonylamino)pyrimidine compound of the formula (3): [R is a hydrocarbyl group], is prepared by the steps of: (I) reacting an isobutyrylacetate ester with 4-fluorobenzaldehyde and urea in the presence of a protonic compound and a metal salt; (II) oxidizing the reaction product of the step (I); (III) reacting the oxidation product of the step (II) with an organic sulfonyl halide or an organic sulfonyl anhydride; and (IV) reacting the reaction product of the step (III) with N-methyl-N-methanesulfonamide.
摘要翻译：通过以下步骤制备式（3）的2-（N-甲基-N-甲磺酰基氨基）嘧啶化合物：[R是烃基]：（I）使异丁酰乙酸酯与4-氟苯甲醛和尿素反应质子化合物和金属盐的存在; （II）氧化步骤（I）的反应产物; （III）使步骤（II）的氧化产物与有机磺酰卤或有机磺酰酐反应; 和（IV）使步骤（III）的反应产物与N-甲基-N-甲磺酰胺反应。

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