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1. 发明申请

US20070106055A1 Polyester polymerization catalyst, polyester produced therewith and process for producing the polyester 审中-公开
标题翻译：聚酯聚合催化剂，由其制造的聚酯和聚酯的制造方法
公开(公告)号：US20070106055A1
公开(公告)日：2007-05-10
申请号：US10588652
申请日：2005-02-08
申请人： Katsuhiko Kageyama , Kenichi Funaki , Masaki Fuchikami , Satoru Nakagawa , Kazuo Katayose , Takahiro Nakajima , Naoki Watanabe , Fumikazu Yoshida , Tetsumori Atsuchi , Shoichi Gyobu , Haruo Matsumoto , Ryuichi Murashige , Gaku Maruyama , Yoshiko Akitomo , Hideki Shimizu
发明人： Katsuhiko Kageyama , Kenichi Funaki , Masaki Fuchikami , Satoru Nakagawa , Kazuo Katayose , Takahiro Nakajima , Naoki Watanabe , Fumikazu Yoshida , Tetsumori Atsuchi , Shoichi Gyobu , Haruo Matsumoto , Ryuichi Murashige , Gaku Maruyama , Yoshiko Akitomo , Hideki Shimizu
IPC分类号： C08G63/00
CPC分类号： C08G63/84 , C08G63/87
摘要： The invention provides a polyester produced in the presence of a polycondensation catalyst comprising at least one compound selected from a group consisting of aluminum compounds and at least one compound selected from a group consisting of phosphorus compounds and being excellent in color tone, thermal stability, and transparency and improved in terms of insoluble particles. Particularly, the invention provides a polyester in which the content of an aluminum containing insoluble particles in the polyester is 3500 ppm or lower and a polyester which has a haze value of 2% or lower when being formed into a monoaxially oriented film. The aluminum catalyst for attaining these characteristics and properties may be polyester polymerization catalyst obtained by mixing an aluminum compound and a phosphorus compound in a solvent and has specified spectral characteristics in the side measurement of 31P-NMR spectrum and 27Al-NMR spectrum.
摘要翻译：本发明提供一种在缩聚催化剂存在下制备的聚酯，其包含至少一种选自铝化合物和至少一种选自磷化合物的化合物并且色调优异，热稳定性和透明度和不溶性颗粒方面的改进。特别地，本发明提供一种聚酯，其中在形成单轴取向膜时，聚酯中含有不溶性的铝的含量为3500ppm以下，聚酯的雾度值为2％以下。用于获得这些特性和性质的铝催化剂可以是通过在溶剂中混合铝化合物和磷化合物而获得的聚酯聚合催化剂，并且在侧谱测定中具有特定的光谱特性， Al-NMR光谱。

2. 发明授权

US07868126B2 Process for producing polyester, polyester produced using said process, and polyester molded product 有权
标题翻译：使用该方法制造聚酯，聚酯的方法和聚酯模制品
公开(公告)号：US07868126B2
公开(公告)日：2011-01-11
申请号：US11795556
申请日：2005-06-24
申请人： Katsuhiko Kageyama , Tooru Kitagawa , Kenichi Funaki , Masaki Fuchikami , Kazuo Katayose , Takahiro Nakajima , Toshiyuki Tsuchiya , Satoru Nakagawa , Fumikazu Yoshida , Haruhiko Kohyama , Naoki Watanabe
发明人： Katsuhiko Kageyama , Tooru Kitagawa , Kenichi Funaki , Masaki Fuchikami , Kazuo Katayose , Takahiro Nakajima , Toshiyuki Tsuchiya , Satoru Nakagawa , Fumikazu Yoshida , Haruhiko Kohyama , Naoki Watanabe
IPC分类号： C08G63/00
CPC分类号： C08G63/84 , C08J5/18 , C08J2367/02 , D01F6/62 , Y10T428/13 , Y10T428/1352 , Y10T428/162 , Y10T428/249921
摘要： This invention provides a polyester and a polyester molded product, which, while maintaining color tone, transparency, and thermal stability, can realize a high polycondensation rate, are less likely to cause the production of polycondensation catalyst-derived undesired materials, and can simultaneously meet both quality and cost effectiveness requirements, which can exhibit the characteristic features, for example, in the fields of ultrafine fibers, high transparent films for optical use, or ultrahigh transparent molded products. These advantages can be realized by using, in the production of a polyester in the presence of an aluminum compound-containing polyester polycondensation catalyst, an aluminum compound having an absorbance of not more than 0.0132 as measured in the form of an aqueous aluminum compound solution, prepared by dissolving the aluminum compound in pure water to give a concentration of 2.7 g/liter in terms of the amount of aluminum element, under conditions of cell length 1 cm and wavelength 680 nm.
摘要翻译：本发明提供一种聚酯和聚酯成型体，其在保持色调，透明性和热稳定性的同时，可以实现高缩聚率，不太可能导致产生缩聚催化剂衍生的不需要的材料，并且可以同时满足质量和成本效益要求，其可以表现出特征，例如在超细纤维，用于光学用途的高透明膜或超高透明模制品的领域。这些优点可以通过在含铝化合物的聚酯缩聚催化剂的存在下制造聚酯，通过以铝化合物水溶液的形式测定的吸光度不大于0.0132的铝化合物来实现，通过将铝化合物溶解在纯水中，在细胞长度为1cm和波长680nm的条件下，以铝元素的量计，浓度为2.7g /升。

3. 发明申请

US20080249280A1 Process for Producing Polyester, Polyester Produced Using Said Process, and Polyester Molded Product 有权
标题翻译：使用所述方法生产聚酯，聚酯的方法和聚酯模塑产品的方法
公开(公告)号：US20080249280A1
公开(公告)日：2008-10-09
申请号：US11795556
申请日：2005-06-24
申请人： Katsuhiko Kageyama , Tooru Kitagawa , Kenichi Funaki , Masaki Fuchikami , Kazuo Katayose , Takahiro Nakajima , Toshiyuki Tsuchiya , Satoru Nakagawa , Fumikazu Yoshida , Haruhiko Kohyama , Naoki Watanabe
发明人： Katsuhiko Kageyama , Tooru Kitagawa , Kenichi Funaki , Masaki Fuchikami , Kazuo Katayose , Takahiro Nakajima , Toshiyuki Tsuchiya , Satoru Nakagawa , Fumikazu Yoshida , Haruhiko Kohyama , Naoki Watanabe
IPC分类号： C08G63/00
CPC分类号： C08G63/84 , C08J5/18 , C08J2367/02 , D01F6/62 , Y10T428/13 , Y10T428/1352 , Y10T428/162 , Y10T428/249921
摘要： This invention provides a polyester and a polyester molded product, which, while maintaining color tone, transparency, and thermal stability, can realize a high polycondensation rate, are less likely to cause the production of polycondensation catalyst-derived undesired materials, and can simultaneously meet both quality and cost effectiveness requirements, which can exhibit the characteristic features, for example, in the fields of ultrafine fibers, high transparent films for optical use, or ultrahigh transparent molded products. These advantages can be realized by using, in the production of a polyester in the presence of an aluminum compound-containing polyester polycondensation catalyst, an aluminum compound having an absorbance of not more than 0.0132 as measured in the form of an aqueous aluminum compound solution, prepared by dissolving the aluminum compound in pure water to give a concentration of 2.7 g/liter in terms of the amount of aluminum element, under conditions of cell length 1 cm and wavelength 680 nm.
摘要翻译：本发明提供一种聚酯和聚酯成型体，其在保持色调，透明性和热稳定性的同时，可以实现高缩聚率，不太可能导致产生缩聚催化剂衍生的不需要的材料，并且可以同时满足质量和成本效益要求，其可以表现出特征，例如在超细纤维，用于光学用途的高透明膜或超高透明模制品的领域。这些优点可以通过在含铝化合物的聚酯缩聚催化剂的存在下制造聚酯，通过以铝化合物水溶液的形式测定的吸光度不大于0.0132的铝化合物来实现，通过将铝化合物溶解在纯水中，在细胞长度为1cm和波长680nm的条件下，以铝元素的量计，浓度为2.7g /升。

4. 发明授权

US07132383B2 Polymerization catalyst for polyester, polyester produced with the same, and process for producing polyester 有权
标题翻译：用于聚酯的聚合催化剂，与此相同的聚酯，以及聚酯的制造方法
公开(公告)号：US07132383B2
公开(公告)日：2006-11-07
申请号：US10363648
申请日：2001-09-10
申请人： Takahiro Nakajima , Kenichi Tsukamoto , Shoichi Gyobu , Fumikazu Yoshida , Maki Sato , Naoki Watanabe , Katsuhiko Kageyama , Mitsuyoshi Kuwata , Nobuo Moriyama , Haruo Matsumoto , Yoshitomo Ikehata , Yoshinao Matsui , Masaou Matsuda , Munekazu Okuhara , Hiroki Fukuda
发明人： Takahiro Nakajima , Kenichi Tsukamoto , Shoichi Gyobu , Fumikazu Yoshida , Maki Sato , Naoki Watanabe , Katsuhiko Kageyama , Mitsuyoshi Kuwata , Nobuo Moriyama , Haruo Matsumoto , Yoshitomo Ikehata , Yoshinao Matsui , Masaou Matsuda , Munekazu Okuhara , Hiroki Fukuda
IPC分类号： B01J31/00
CPC分类号： D01F6/62 , C08G63/82 , C08G63/83 , C08G63/84 , C08G63/87
摘要： A polymerization catalyst for polyester production which contains neither a germanium compound nor an antimony compound as a major component. It contains aluminum as the main metallic ingredient, has excellent catalytic activity, and gives a polyester which is effectively inhibited from suffering thermal degradation, during melt molding, without deactivating or removing the catalyst, and is excellent in thermal stability, stability to thermal oxidation, and hydrolytic resistance. The polymerization catalyst contains as a first metallic ingredient at least one member selected among aluminum and compounds thereof and further contains a phosphorus compound represented by a specific chemical formula. The polyester produced with this catalyst is usable as fibers, films, sheets, various moldings including hollow moldings, etc.
摘要翻译：用于聚酯生产的聚合催化剂，既不含锗化合物也不含锑化合物作为主要成分。它含有铝作为主要的金属成分，具有优异的催化活性，并且在熔融成型期间得到有效抑制热降解的聚酯，而不会使催化剂失活或除去，并且热稳定性，热氧化稳定性优异，和耐水解性。聚合催化剂含有选自铝及其化合物中的至少一种元素作为第一金属成分，并且还含有由特定化学式表示的磷化合物。使用该催化剂制造的聚酯可用作纤维，薄膜，片材，各种模制品，包括中空模制品等。

5. 发明申请

US20090297752A1 POLYESTER RESIN, POLYESTER RESIN COMPOSITION THEREFROM AND USE THEREOF 审中-公开
标题翻译：聚酯树脂，聚酯树脂组合物及其用途
公开(公告)号：US20090297752A1
公开(公告)日：2009-12-03
申请号：US12063387
申请日：2005-08-09
申请人： Keiichiro Togawa , Yoshinao Matsui , Kosuke Uotani , Atsushi Hara , Hiroyuki Mitsunaga , Takahiro Nakajima , Naoki Watanabe , Toshio Owari , Yoshitaka Eto
发明人： Keiichiro Togawa , Yoshinao Matsui , Kosuke Uotani , Atsushi Hara , Hiroyuki Mitsunaga , Takahiro Nakajima , Naoki Watanabe , Toshio Owari , Yoshitaka Eto
IPC分类号： B32B1/00 , C08G63/00 , B29C45/00 , B29C43/02 , B29C47/00
CPC分类号： C08G63/6926 , B32B27/08 , B32B27/36 , B32B2255/10 , B32B2272/00 , B32B2307/306 , B32B2307/412 , B32B2307/714 , B32B2307/734 , B32B2439/00 , C08G63/82 , C08K3/32 , C08K5/49 , C08K5/521 , C08L67/02 , C08L2205/02 , C09D167/02 , Y10T428/1397 , C08L2666/18
摘要： A polyester resin that can be beneficially employed as one finding application in deactivation of polycondensation catalysts for polyester production and suppression of forming of acetaldehyde and other aldehydes and cyclic ester oligomers at molding stage. In particular, there is provided a polyester resin composed mainly of an aromatic dicarboxylic acid component and a glycol component wherein a phosphorus compound is incorporated through copolymerization or blending in an amount of 100 to 10,000 ppm in terms of phosphorus element, characterized in that the contents of Zn element, Fe element, Ni element and Cr element are not greater than specified values.
摘要翻译：可以有利地用作聚酯生产缩聚催化剂失活的一个发现应用的聚酯树脂，并且在成型阶段抑制乙醛和其它醛和环状酯低聚物的形成。特别地，提供了一种主要由芳族二羧酸组分和二元醇组分组成的聚酯树脂，其中磷化合物以磷元素计以100至10,000ppm的量通过共聚或共混加入，其特征在于，含量的Zn元素，Fe元素，Ni元素和Cr元素不大于规定值。

6. 发明授权

US09534816B2 Thermo-magnetic cycle apparatus with bypass valve 有权
标题翻译：具有旁通阀的热磁循环装置
公开(公告)号：US09534816B2
公开(公告)日：2017-01-03
申请号：US13467542
申请日：2012-05-09
申请人： Tsuyoshi Morimoto , Naoki Watanabe , Shinichi Yatsuzuka , Kazutoshi Nishizawa , Takuya Fuse
发明人： Tsuyoshi Morimoto , Naoki Watanabe , Shinichi Yatsuzuka , Kazutoshi Nishizawa , Takuya Fuse
IPC分类号： F25B21/00 , F25B41/04
CPC分类号： F25B21/00 , F25B41/04 , F25B2321/0022 , Y02B30/66
摘要： A thermo-magnetic cycle apparatus includes: a magnetic element having a Curie temperature distribution in a distribution direction. A magnetic-field supplier supplies an external magnetic field to the magnetic element. A pump pumps heat transport medium to flow forward and backward in the distribution direction. The heat transport medium transports heat of the magnetic element. A shift device causes a position of a high temperature end and/or a low temperature end of the magnetic element to move.
摘要翻译：一种热磁循环装置，包括：在分配方向上具有居里温度分布的磁性元件。磁场供应商向磁性元件提供外部磁场。泵将热传输介质泵送到分配方向上向前和向后流动。传热介质输送磁性元件的热量。换档装置使得磁性元件的高温端和/或低温端的位置移动。

7. 发明授权

US09079934B2 Antisense nucleic acids 有权
标题翻译：反义核酸
公开(公告)号：US09079934B2
公开(公告)日：2015-07-14
申请号：US13819520
申请日：2011-08-31
申请人： Naoki Watanabe , Youhei Satou , Shin'ichi Takeda , Tetsuya Nagata
发明人： Naoki Watanabe , Youhei Satou , Shin'ichi Takeda , Tetsuya Nagata
IPC分类号： C07H21/02 , C07H21/04 , A61K31/70 , C12N15/11 , C12N15/113 , C07H21/00 , C12Q1/68
CPC分类号： C07H21/04 , C07H21/00 , C12N15/111 , C12N15/113 , C12N2310/11 , C12N2310/3145 , C12N2310/315 , C12N2310/321 , C12N2310/3525 , C12N2320/33
摘要： The present invention provides an oligomer which efficiently enables to cause skipping of the 53rd exon in the human dystrophin gene. Also provided is a pharmaceutical composition which causes skipping of the 53rd exon in the human dystrophin gene with a high efficiency.
摘要翻译：本发明提供了有效地使第53外显子在人肌营养不良蛋白基因中跳过的低聚物。还提供了一种药物组合物，其以高效率使得第53外显子在人肌营养不良蛋白基因中跳过。

8. 发明授权

US09027339B2 Thermo-magnetic engine apparatus and reversible thermo-magnetic cycle apparatus 有权
标题翻译：热磁发动机装置和可逆热循环装置
公开(公告)号：US09027339B2
公开(公告)日：2015-05-12
申请号：US13450649
申请日：2012-04-19
申请人： Tsuyoshi Morimoto , Naoki Watanabe , Shinichi Yatsuzuka , Kazutoshi Nishizawa
发明人： Tsuyoshi Morimoto , Naoki Watanabe , Shinichi Yatsuzuka , Kazutoshi Nishizawa
IPC分类号： F01D1/00 , F03G7/00 , F25B21/00
CPC分类号： F03G7/00 , F25B21/00 , F25B2321/0022 , Y02B30/66
摘要： A thermo-magnetic engine apparatus includes a magnetic element having a high temperature end to which hot energy is supplied and a low temperature end to which cold energy is supplied, a magnetic-field applier device, and a power source device. Curie temperature of the magnetic element is set between a temperature of the high temperature end and a temperature of the low temperature end. The power source device gains a magnetic power generated between the magnetic element and the magnetic-field applier device as kinetic energy.
摘要翻译：热磁引擎装置包括具有供给热能的高温端和供给冷能的低温端的磁性元件，磁场施加装置和电源装置。磁性元件的居里温度设定在高温端的温度与低温端的温度之间。电源装置将磁性元件和磁场施加器装置之间产生的磁力作为动能增益。

9. 发明授权

US08390157B2 Cooling mechanism for axial gap type rotating machines 有权
标题翻译：轴向间隙式旋转机的冷却机构
公开(公告)号：US08390157B2
公开(公告)日：2013-03-05
申请号：US12775127
申请日：2010-05-06
申请人： Naoki Watanabe , Minori Miyata , Atsushi Miyata
发明人： Naoki Watanabe , Koji Miyata
IPC分类号： H02K5/18 , H02K9/04
CPC分类号： H02K21/24 , H02K3/522 , H02K7/14 , H02K9/04 , H02K9/22
摘要： A stator has a mechanism for effectively dissipating internally generated heat, and is for use in a high power axial gap type rotating machine. The stator comprises a coil holding member and a coil secured to the coil holding member, in which the coil holding member comprises a material having a thermal conductivity of not less than 5 W/mK that is measured compliant with the ASTM E1530 and having an electrical conductivity of not more than 1×105 S/m that is measured compliant with the ASTM E345. This stator preferably comprises a radiation fin, having a thermal conductivity of not less than 150 W/mK, and having a bumpy surface so as to increase the surface area thereof threefold or more, at the circumference of the coil holding member.
摘要翻译：定子具有有效地消散内部产生的热量的机构，并且用于高功率轴向间隙型旋转机械。定子包括线圈保持构件和固定到线圈保持构件的线圈，其中线圈保持构件包括具有不小于5W / mK的热导率的材料，该材料根据ASTM E1530测量并具有电气电导率不超过1×105 S / m，符合ASTM E345标准。该定子优选地包括具有不小于150W / mK的导热率的辐射翅片，并且在线圈保持构件的圆周处具有颠簸的表面以将其表面积增加三倍或更多。

10. 发明授权

US08298717B2 Fuel cell body, fuel cell unit, fuel cell stack, and fuel cell device including each of them 有权
标题翻译：燃料电池体，燃料电池单元，燃料电池堆和包括它们的燃料电池装置
公开(公告)号：US08298717B2
公开(公告)日：2012-10-30
申请号：US13315709
申请日：2011-12-09
申请人： Naoki Watanabe , Akira Kawakami
发明人： Naoki Watanabe , Akira Kawakami
IPC分类号： H01M4/86
CPC分类号： H01M8/12 , H01M8/0252 , H01M8/04201 , H01M8/243 , H01M8/2465 , H01M8/2485
摘要： A fuel cell unit (1) according to the present invention comprises a fuel cell (6) having an inner electrode layer (16), an outer electrode layer (20) and a through passage (15); and inner and outer electrode terminals (24, 26) fixed at the opposite ends (6a, 6b) of the fuel cell (6). The fuel cell (6) has an inner electrode peripheral surface (21) electrically communicating with the inner electrode layer (16) and an outer electrode peripheral surface (22) electrically communicating with the outer electrode layer (20). The inner and outer electrode terminals are respectively disposed so that they cover over the inner and outer electrode peripheral surfaces (21, 22) and they are electrically connected thereto. The inner and outer electrode terminals have respective connecting passages which are communicated with the through passage (15).
摘要翻译：根据本发明的燃料电池单元（1）包括具有内电极层（16），外电极层（20）和穿通通道（15）的燃料电池（6）。以及固定在燃料电池（6）的相对端（6a，6b）的内外电极端子（24,26）。燃料电池（6）具有与内电极层（16）电连通的内电极周面（21）和与外电极层（20）电连通的外电极周面（22）。内电极端子和外电极端子分别设置成使得它们覆盖在内电极周边表面（21）和外电极外表面（22）上，并且它们电连接到其上。内电极端子和外电极端子具有与通路（15）连通的各自的连接通道。

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