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1. 发明申请

US20050159560A1 PROCESS FOR PREPARING ASPARTATES 有权
标题翻译：制备ASPARTATES的方法
公开(公告)号：US20050159560A1
公开(公告)日：2005-07-21
申请号：US10761643
申请日：2004-01-21
申请人： Karsten Danielmeier , Charles Gambino , Rolf Gertzmann , Richard Roesler , Terrell Wayt , Michele Vargo , Edward Squiller , Karen Henderson
发明人： Karsten Danielmeier , Charles Gambino , Rolf Gertzmann , Richard Roesler , Terrell Wayt , Michele Vargo , Edward Squiller , Karen Henderson
IPC分类号： C07D207/40 , C07D207/416 , C08G18/00 , C08G18/38 , C08G18/79 , C09D175/04 , C08G63/02 , C08G69/26
CPC分类号： C07D207/416 , C08G18/3821 , C08G18/792 , C09D175/04
摘要： The present invention relates to novel aspartates, their method of production and the use of these aspartates as reactive components for polyisocyanates in two-component polyurethane coating compositions and for preparing polyurethane prepolymers. The aspartates are prepared by first reacting a di- or polyamine with an unsaturated ester and then reacting the resultant product with a maleimide.
摘要翻译：本发明涉及新型天冬氨酸盐，其制备方法和这些天冬氨酸盐作为双组分聚氨酯涂料组合物中多异氰酸酯的反应性组分和用于制备聚氨酯预聚物的用途。天冬氨酸酯通过首先使二胺或多胺与不饱和酯反应，然后使所得产物与马来酰亚胺反应来制备。

2. 发明申请

US20060106194A1 Polyaspartimides 有权
标题翻译：聚天冬酰胺
公开(公告)号：US20060106194A1
公开(公告)日：2006-05-18
申请号：US10990082
申请日：2004-11-16
申请人： Karsten Danielmeier , Charles Gambino , Rolf Gertzmann , Richard Roesler , Terrell Wayt , Edward Squiller , Michele Honko , Karen Henderson
发明人： Karsten Danielmeier , Charles Gambino , Rolf Gertzmann , Richard Roesler , Terrell Wayt , Edward Squiller , Michele Honko , Karen Henderson
IPC分类号： C08G69/08
CPC分类号： C08G18/3846 , C07D207/416 , C08G18/792 , C09D175/04
摘要： The present invention relates to novel polyaspartimides, their method of production and the use of these polyaspartimides as reactive components for polyisocyanates in two-component polyurethane coating compositions. The polyaspartimides are prepared by reacting a polyether amine with a maleimide.
摘要翻译：本发明涉及新颖的聚天冬酰亚胺，它们的制备方法和这些聚天冬酰苯胺作为双组分聚氨酯涂料组合物中多异氰酸酯的反应性组分的用途。聚天冬酰胺通过聚醚胺与马来酰亚胺反应制备。

3. 发明申请

US20050075476A1 Process for preparing aspartates 有权
公开(公告)号：US20050075476A1
公开(公告)日：2005-04-07
申请号：US10678491
申请日：2003-10-03
申请人： Richard Roesler , Douglas Wicks , Terrell Wayt , Brian Long , Karsten Danielmeier , Charles Gambino
发明人： Richard Roesler , Douglas Wicks , Terrell Wayt , Brian Long , Karsten Danielmeier , Charles Gambino
IPC分类号： C07C233/00 , C07C235/10 , C07C269/04 , C07C271/00 , C07C271/20 , C07C271/24 , C08G18/38 , C08G18/79 , C08G69/02 , C09D175/02 , C08G18/00 , C08G2/00
CPC分类号： C07C235/10 , C07C271/20 , C07C271/24 , C07C2601/14 , C08G18/3821 , C08G18/792 , C09D175/02
摘要： The present invention relates to novel aspartates, their method of produciotn and the use of these mono and polyaspartates as reactive components for polyisocyanates in two-component polyurethane coating compositions and for preparing polyurethane prepolymers.

4. 发明授权

US06774206B2 Polyaspartate resins with improved flexibility 有权
标题翻译：聚天冬氨酸树脂具有改善的灵活性
公开(公告)号：US06774206B2
公开(公告)日：2004-08-10
申请号：US10255388
申请日：2002-09-26
申请人： Karsten Danielmeier , Catherine M. Britsch , Rolf Gertzmann , Michele E. Vargo , Terrell D. Wayt , Edward P. Squiller
发明人： Karsten Danielmeier , Catherine M. Britsch , Rolf Gertzmann , Michele E. Vargo , Terrell D. Wayt , Edward P. Squiller
IPC分类号： C08G7300
CPC分类号： C07C229/24 , C08G18/3821 , C08G18/792
摘要： The present invention relates to polyaspartates corresponding to the formula wherein X1 represents the residue obtained by removing the amino groups from a polyether polyamine having a functionality of n and a number average molecular weight of less than 600, wherein the amino groups are attached to primary carbon atoms and the ether groups are separated by at least two carbon atoms, R1 and R2 are identical or different and represent organic groups which are inert to isocyanate groups at a temperature of 100° C. or less, R3 and R4 are identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100° C. or less and n is 2 to 4. The present invention also relates to polyureas prepared by reacting the polyaspartates and optionally other isocyanate-reactive compounds with polyisocyanates.
摘要翻译：本发明涉及对应于制备方法的聚天冬氨酸X 1表示通过从官能度为n且数均分子量小于600的聚醚多胺除去氨基而获得的残基，其中氨基与伯碳原子连接，醚基通过至少两个碳原子分开，R 1和R 2相同或不同，表示在100℃或更低的温度下对异氰酸酯基团呈惰性的有机基团，R 3和R 4相同或不同，表示氢或在100℃或更低的温度下对异氰酸酯基团呈惰性的有机基团，并且为2至4.本发明还涉及通过聚天冬氨酸酯和任选的其它异氰酸酯反应性化合物与多异氰酸酯反应制备的聚脲。

5. 发明授权

US06911501B1 Process for preparing aspartates 有权
标题翻译：天冬氨酸的制备方法
公开(公告)号：US06911501B1
公开(公告)日：2005-06-28
申请号：US10761643
申请日：2004-01-21
申请人： Karsten Danielmeier , Charles A. Gambino , Rolf Gertzmann , Richard R. Roesler , Terrell D. Wayt , Michele E. Vargo , Edward P. Squiller , Karen M. Henderson
发明人： Karsten Danielmeier , Charles A. Gambino , Rolf Gertzmann , Richard R. Roesler , Terrell D. Wayt , Michele E. Vargo , Edward P. Squiller , Karen M. Henderson
IPC分类号： C07D207/40 , C07D207/416 , C08G18/00 , C08G18/38 , C08G18/79 , C09D175/04 , C08F283/04 , C08G73/10
CPC分类号： C07D207/416 , C08G18/3821 , C08G18/792 , C09D175/04
摘要： The present invention relates to novel aspartates, their method of production and the use of these aspartates as reactive components for polyisocyanates in two-component polyurethane coating compositions and for preparing polyurethane prepolymers. The aspartates are prepared by first reacting a di- or polyamine with an unsaturated ester and then reacting the resultant product with a maleimide.
摘要翻译：本发明涉及新型天冬氨酸盐，其制备方法和这些天冬氨酸盐作为双组分聚氨酯涂料组合物中多异氰酸酯的反应性组分和用于制备聚氨酯预聚物的用途。天冬氨酸酯通过首先使二胺或多胺与不饱和酯反应，然后使所得产物与马来酰亚胺反应来制备。

6. 发明授权

US07307140B2 Polyaspartimides 有权
标题翻译：聚天冬酰胺
公开(公告)号：US07307140B2
公开(公告)日：2007-12-11
申请号：US10990082
申请日：2004-11-16
申请人： Karsten Danielmeier , Charles A. Gambino , Rolf Gertzmann , Richard R. Roesler , Terrell D. Wayt , Edward P. Squiller , Michele E. Honko , Karen Marie Henderson
发明人： Karsten Danielmeier , Charles A. Gambino , Rolf Gertzmann , Richard R. Roesler , Terrell D. Wayt , Edward P. Squiller , Michele E. Honko , Karen Marie Henderson
IPC分类号： C08F73/10 , C08F283/04
CPC分类号： C08G18/3846 , C07D207/416 , C08G18/792 , C09D175/04
摘要： The present invention relates to novel polyaspartimides, their method of production and the use of these polyaspartimides as reactive components for polyisocyanates in two-component polyurethane coating compositions. The polyaspartimides are prepared by reacting a polyether amine with a maleimide.
摘要翻译：本发明涉及新颖的聚天冬酰亚胺，它们的制备方法和这些聚天冬酰苯胺作为双组分聚氨酯涂料组合物中多异氰酸酯的反应性组分的用途。聚天冬酰胺通过聚醚胺与马来酰亚胺反应制备。

7. 发明授权

US06790925B2 In-situ preparation of polyaspartic ester mixtures 有权
标题翻译：聚天冬氨酸酯混合物的原位制备
公开(公告)号：US06790925B2
公开(公告)日：2004-09-14
申请号：US10310313
申请日：2002-12-05
申请人： Karsten Danielmeier , Catherine M. Britsch , Rolf Gertzmann , Michele E. Vargo , Terrell D. Wayt , Edward P. Squiller , Richard R. Roesler
发明人： Karsten Danielmeier , Catherine M. Britsch , Rolf Gertzmann , Michele E. Vargo , Terrell D. Wayt , Edward P. Squiller , Richard R. Roesler
IPC分类号： C08G1850
CPC分类号： C08G73/1092
摘要： The present invention relates to polyaspartate mixtures containing a) 5 to 50 equiv. %, based on the total equivalents of aspartate groups, of a polyoxypropylene polyaspartate corresponding to the formula wherein X1 represents the residue obtained by removing the amino groups from a polyoxypropylene polyamine having a functionality of n, R1 and R2 are identical or different and represent organic groups which are inert to isocyanate groups at a temperature of 100° C. or less, R3 and R4 are identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100° C. or less and n is 2 to 4, and b) 50 to 95 equiv. %, based on the total equivalents of aspartate groups, of a polyether polyaspartate corresponding to the formula I wherein X1 represents the residue obtained by removing the amino groups from a polyether polyamine having a functionality of n and a number average molecular weight of less than 5000, wherein the amino groups are attached to primary carbon atoms and the ether groups are separated by at least two carbon atoms. The present invention also relates to a process for preparing these polyaspartate mixtures and to the polyureas prepared by reacting the polyaspartate mixtures and optionally other isocyanate-reactive compounds with polyisocyanates.
摘要翻译：本发明涉及含有a）5至50当量的聚天冬氨酸盐混合物基于天冬氨酸酯基团的总当量的％，对应于方解石的聚氧丙烯聚天冬氨酸酯X1代表通过从具有官能度n的聚氧丙烯多胺除去氨基而获得的残基，R 1和R 2相同或不同，并且表示有机基团其在100℃或更低的温度下对异氰酸酯基团是惰性的，R3和R4相同或不同，并且表示在100℃或更低的温度下对异氰酸酯基团呈惰性的氢或有机基团，n为2 至4，和b）50至95当量％，基于天冬氨酸酯基团的总当量，对应于式I的聚醚聚天冬氨酸，其中X1表示通过从官能度为n且数均分子量小于5000的聚醚多胺除去氨基而获得的残基，其中所述氨基连接到伯碳原子上，并且所述醚基团被至少两个碳原子分开。本发明还涉及制备这些聚天冬氨酸酯混合物的方法和通过使聚天冬氨酸盐混合物和任选的其它异氰酸酯反应性化合物与多异氰酸酯反应制备的聚脲。

8. 发明授权

US06774207B2 Polyaspartate resins with good hardness and flexibility 失效
标题翻译：聚天冬氨酸树脂具有良好的硬度和柔韧性
公开(公告)号：US06774207B2
公开(公告)日：2004-08-10
申请号：US10256179
申请日：2002-09-26
申请人： Karsten Danielmeier , Catherine M. Britsch , Rolf Gertzmann , Michele E. Vargo , Terrell Dean Wayt , Edward P. Squiller , Richard R. Roesler
发明人： Karsten Danielmeier , Catherine M. Britsch , Rolf Gertzmann , Michele E. Vargo , Terrell Dean Wayt , Edward P. Squiller , Richard R. Roesler
IPC分类号： C08G7300
CPC分类号： C08G18/792 , C07C229/24 , C08G18/3821 , C09D175/04
摘要： The present invention relates to polyaspartate mixtures containing a) 5 to 70 equiv. %, based on the total equivalents of aspartate groups, of a cyclic polyaspartate corresponding to the formula wherein X1 represents the residue obtained by removing the amino groups from a cyclic polyamine having a functionality of n, R1 and R2 are identical or different and represent organic groups which are inert to isocyanate groups at a temperature of 100° C. or less, R3 and R4 are identical or different and represent hydrogen or organic groups which are inert towards isocyanate groups at a temperature of 100° C. or less and n is 2 to 4, and b) 30 to 95 equiv. %, based on the total equivalents of aspartate groups, of a polyether polyaspartate corresponding to the formula I wherein X1 represents the residue obtained by removing the amino groups from a polyether polyamine having a functionality of n and a number average molecular weight of less than 600, wherein the amino groups are attached to primary carbon atoms and the ether groups are separated by at least two carbon atoms. The present invention also relates to a process for preparing these polyaspartate mixtures and to the polyureas prepared by reacting the polyaspartate mixtures and optionally other isocyanate-reactive compounds with polyisocyanates.
摘要翻译：本发明涉及含有a）5至70当量的聚天冬氨酸盐混合物基于天冬氨酸酯基团的总当量％，对应于方解石的环状聚天冬氨酸X1表示通过从具有官能度n的环状多胺除去氨基而获得的残基，R 1和R 2相同或不同，表示有机基团其在100℃或更低的温度下对异氰酸酯基团是惰性的，R3和R4相同或不同，并且表示在100℃或更低的温度下对异氰酸酯基团呈惰性的氢或有机基团，n为2 至4，和b）30至95当量％，基于天冬氨酸酯基团的总当量，对应于式I的聚醚聚天冬氨酸，其中X1表示通过从官能度为n且数均分子量小于600的聚醚多胺除去氨基而获得的残基其中氨基连接到伯碳原子上，醚基被至少两个碳原子分开。本发明还涉及一种制备这些聚天冬氨酸酯混合物的方法，以及通过使聚天冬氨酸盐混合物和任选的其它物质反应制备的聚脲异氰酸酯反应性化合物与多异氰酸酯。

9. 发明申请

US20060011295A1 Aspartic ester functional compounds 审中-公开
标题翻译：天冬氨酸酯官能化合物
公开(公告)号：US20060011295A1
公开(公告)日：2006-01-19
申请号：US10890873
申请日：2004-07-14
申请人： Karsten Danielmeier , Douglas Wicks , Karen Henderson , Evan Minnich , John McLafferty , Stephanie Strazisar , Kurt Frisch
发明人： Karsten Danielmeier , Douglas Wicks , Karen Henderson , Evan Minnich , John McLafferty , Stephanie Strazisar , Kurt Frisch
IPC分类号： C07C229/34
CPC分类号： C08G18/341 , C07C229/24 , C08G18/3821 , C08G18/6651 , C08G18/6685 , C08G18/792 , Y10T428/31547
摘要： A functional aspartate prepared by A) reacting an aziridine with a Michael-acceptor molecule to form an aziridinyl aspartate, and B) reacting the aziridinyl aspartate with an active hydrogen containing compound to form the functional aspartate. The functional aspartate can be used in adhesive, sealant or coating compositions that also include an isocyanate functional material. The composition can be used in a method of bonding a first substrate to a second substrate that includes applying a coating of the above-identified adhesive composition to at least one surface of the first substrate or the second substrate, and contacting a surface of the first substrate with a surface of the second substrate, where at least on of the contacting surfaces has the coating applied thereto. The composition can also be used to coat substrates.
摘要翻译：通过A）将氮丙啶与迈克尔受体分子反应以形成天冬氨酸吖丙酯反应制备的功能性天冬氨酸，和B）将天冬氨酸吖丙酯与含活性氢化合物反应以形成功能性天冬氨酸。功能性天冬氨酸可用于还包括异氰酸酯官能材料的粘合剂，密封剂或涂料组合物。该组合物可用于将第一基底粘合到第二基底上的方法，该方法包括将上述粘合剂组合物的涂层施加到第一基底或第二基底的至少一个表面，并使第一基底衬底，其具有第二衬底的表面，其中至少在接触表面上施加有涂层。该组合物也可用于涂覆底物。

10. 发明申请

US20060173140A1 Moisture-curable, polyether urethanes with reactive silane groups and their use as sealants, adhesives and coatings 有权
标题翻译：具有反应性硅烷基团的水分固化型聚醚聚氨酯及其作为密封剂，粘合剂和涂料的用途
公开(公告)号：US20060173140A1
公开(公告)日：2006-08-03
申请号：US10690751
申请日：2003-10-22
申请人： Richard Roesler , Derek Crawford , Kurt Frisch , Dinesh Pethiyagoda , Karsten Danielmeier
发明人： Richard Roesler , Derek Crawford , Kurt Frisch , Dinesh Pethiyagoda , Karsten Danielmeier
IPC分类号： C08L83/00 , C08G77/04 , C08G77/00 , C08G18/00 , B32B27/40
CPC分类号： C09J175/08 , C08G18/10 , C08G18/283 , C08G18/4866 , C08G2190/00 , C08G18/289
摘要： A moisture-curable, alkoxysilane-functional polyether urethanes containing a) 20 to 90% by weight, of a polyether urethane containing two or more reactive silane groups and one or more polyether segments, where the polyether segments have a number average molecular weight (Mn) of at least 3000 and a degree of unsaturation of less than 0.04 milliequivalents/g, and the sum of Mn of all of the polyether segments per molecule averages 6000 to 20,000, and the reactive silane groups are incorporated by the reaction of an isocyanate group with a compound of formula and b) 10 to 80% by weight, of a polyether urethane containing one reactive silane group and one or more polyether segments having Mn of 1000 to 15,000.
摘要翻译：含有a）20〜90重量％的含有两个以上反应性硅烷基团和一个以上聚醚部分的聚醚型聚氨酯的水分固化性烷氧基硅烷官能团聚氨酯，其中聚醚链段的数均分子量（Mn ）至少为3000，不饱和度小于0.04毫当量/ g，并且每个分子中所有聚醚链段的Mn的总和平均为6000至20,000，并且反应性硅烷基团通过异氰酸酯基团具有式和b）10至80重量％的含有一个反应性硅烷基团的聚醚聚氨酯和一个或多个Mn为1000至15,000的聚醚链段的化合物。

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