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    • 3. 发明授权
    • Process for the production of rigid polyurethane foams
    • 生产硬质聚氨酯泡沫的方法
    • US5886062A
    • 1999-03-23
    • US904894
    • 1997-08-01
    • Karl-Werner DietrichTorsten HeinemannManfred Dietrich
    • Karl-Werner DietrichTorsten HeinemannManfred Dietrich
    • C08G18/32C08G18/48C08G18/50C08G18/66C08G101/00
    • C08G18/482C08G18/329C08G18/4891C08G18/5021C08G18/5033C08G18/6696C08G2101/0025
    • This invention provides a process for producing rigid polyurethane foams by reacting A) a polyol component with B) a polyisocyanate component in the presence of C) water, D) at least one catalyst, and, optionally, E) at least one blowing agent. This process specifically requires A) a polyol component which comprises: 1) a polyol containing at least two isocyanate-reactive hydrogen atoms and comprising: a) a mixture of i) an addition product having a OH number of at least 500 of diamines or polyamines containing primary and/or secondary amino groups with alkylene oxides, and ii) castor oil, and/or b) one or more reaction products obtained by reacting i) an addition product having a OH number of at least 500 of diamines or polyamines containing primary and/or secondary amino groups with alkylene oxides, and ii) castor oil; and 2) at least one compound containing at least two isocyanate-reactive hydrogen atoms. Suitable polyisocyanates B) for the present invention are those containing an NCO group content of from 20 to 48% by weight.
    • 本发明提供一种生产刚性聚氨酯泡沫体的方法,该方法通过在C)水,D)至少一种催化剂和任选的E)至少一种发泡剂的存在下,使A)多元醇组分与B)多异氰酸酯组分反应。 该方法特别要求A)多元醇组分,其包括:1)含有至少两个异氰酸酯反应性氢原子的多元醇,其包含:a)i)具有OH数至少为500的二胺或多胺的加成产物 含有伯和/或仲氨基与烯化氧,和ii)蓖麻油和/或b)一种或多种反应产物,其通过使i)具有OH数为至少500个的二胺或含有伯胺的多胺的加成产物 和/或具有环氧烷烃的仲氨基,和ii)蓖麻油; 和2)至少一种含有至少两个异氰酸酯反应性氢原子的化合物。 适用于本发明的多异氰酸酯B)是含有20至48重量%的NCO基团含量的那些。