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    • 9. 发明申请
    • Use of copolymers containing sulfonic acid groups, as an additive in detergents and cleansers
    • 使用含有磺酸基团的共聚物作为洗涤剂和清洁剂中的添加剂
    • US20050202994A1
    • 2005-09-15
    • US10515638
    • 2003-06-04
    • Pia BaumKathrin MichlFranz WeingartStephan NiedGregor Brodt
    • Pia BaumKathrin MichlFranz WeingartStephan NiedGregor Brodt
    • C08F290/06C11D3/37
    • C11D3/378
    • Use of copolymers containing sulfonic acid groups which comprise (a) 30 to 95 mol % of at least one monoethylenically unsaturated carboxylic acid, one monoethylenically unsaturated carboxylic ester or one water-soluble salt of a monoethylenically unsaturated carboxylic acid, (b) 3 to 35 mol % of at least one monomer containing sulfonic acid groups of the formula I  in which the variables have the following meanings: R is hydrogen or methyl; X is a chemical bond or —COO—R1—; R1 is unbranched or branched C1-C4-alkylene; M is hydrogen, alkali metal or ammonium, and (c) 2 to 35 mol % of at least one nonionic monomer of the formula II  in which the variables have the following meanings: R2 is hydrogen or methyl; R3 is a chemical bond or unbranched or branched C1-C6-alkylene; R4 are identical or different unbranched or branched C2-C4-alkylene radicals; R5 is unbranched or branched C1-C6-alkyl, C5-C8-cycloalkyl or aryl; n is 3 to 50, in random or block copolymerized form, as additive for detergents and cleaners.
    • 使用包含(a)30-95摩尔%至少一种单烯属不饱和羧酸,一种单烯属不饱和羧酸酯或一种单烯属不饱和羧酸的一种水溶性盐的磺酸基团的共聚物,(b)3-35 mol%的至少一种含有式I磺酸基的单体,其中变量具有以下含义:R是氢或甲基; X是化学键或-COO-R 1 - R 1是非支链或支链C 1 -C 4 - 亚烷基; M是氢,碱金属或铵,和(c)2-35mol%的至少一种式II的非离子单体,其中变量具有以下含义:R 2是氢或甲基 ; R 3是化学键或无支链或支链C 1 -C 6 - 亚烷基; R 4是相同或不同的未支链或支链C 2 -C 4 - 亚烷基; R 5是非支链或支链C 1 -C 6 - 烷基,C 5 -C 8 环烷基或芳基; n为3至50,以无规或嵌段共聚形式,作为洗涤剂和清洁剂的添加剂。